Miljković, Miroslav

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  • Miljković, Miroslav (9)
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Author's Bibliography

Synthesis and characterization of biomorphic CeO2 obtained by using egg shell membrane as template

Prekajski, Marija D.; Babić, Biljana M.; Bučevac, Dušan; Pantić, Jelena R.; Gulicovski, Jelena J.; Miljković, Miroslav; Matović, Branko

(2014)

TY  - JOUR
AU  - Prekajski, Marija D.
AU  - Babić, Biljana M.
AU  - Bučevac, Dušan
AU  - Pantić, Jelena R.
AU  - Gulicovski, Jelena J.
AU  - Miljković, Miroslav
AU  - Matović, Branko
PY  - 2014
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/2747
AB  - A new technology based on bio-templating approach was proposed in this paper. Egg-shell membrane (ESM) has been employed as a natural biotemplate. Fibrous oxide ceramics was prepared by wet impregnation of biological template with water solution of cerium nitrate. The template was derived from membranes of fresh chicken eggs. Repeated impregnation, pyrolysis and final calcination in the range of 600 to 1200 degrees C in air resulted in template burnout and consolidation of the oxide layers. At low temperatures, the obtained products had structure which corresponded to the negative replication of biological templates. Unique bio-morphic CeO2 microstructures with interwoven networks were synthesized and characterized by scanning electron microscope (SEM) and X-ray diffraction (XRD), whereas low-temperature nitrogen adsorption (BET) method was used in order to characterize porous properties.
T2  - Processing and Application of Ceramics
T1  - Synthesis and characterization of biomorphic CeO2 obtained by using egg shell membrane as template
VL  - 8
IS  - 2
SP  - 81
EP  - 85
DO  - 10.2298/PAC1402081P
ER  - 
@article{
author = "Prekajski, Marija D. and Babić, Biljana M. and Bučevac, Dušan and Pantić, Jelena R. and Gulicovski, Jelena J. and Miljković, Miroslav and Matović, Branko",
year = "2014",
abstract = "A new technology based on bio-templating approach was proposed in this paper. Egg-shell membrane (ESM) has been employed as a natural biotemplate. Fibrous oxide ceramics was prepared by wet impregnation of biological template with water solution of cerium nitrate. The template was derived from membranes of fresh chicken eggs. Repeated impregnation, pyrolysis and final calcination in the range of 600 to 1200 degrees C in air resulted in template burnout and consolidation of the oxide layers. At low temperatures, the obtained products had structure which corresponded to the negative replication of biological templates. Unique bio-morphic CeO2 microstructures with interwoven networks were synthesized and characterized by scanning electron microscope (SEM) and X-ray diffraction (XRD), whereas low-temperature nitrogen adsorption (BET) method was used in order to characterize porous properties.",
journal = "Processing and Application of Ceramics",
title = "Synthesis and characterization of biomorphic CeO2 obtained by using egg shell membrane as template",
volume = "8",
number = "2",
pages = "81-85",
doi = "10.2298/PAC1402081P"
}
Prekajski, M. D., Babić, B. M., Bučevac, D., Pantić, J. R., Gulicovski, J. J., Miljković, M.,& Matović, B.. (2014). Synthesis and characterization of biomorphic CeO2 obtained by using egg shell membrane as template. in Processing and Application of Ceramics, 8(2), 81-85.
https://doi.org/10.2298/PAC1402081P
Prekajski MD, Babić BM, Bučevac D, Pantić JR, Gulicovski JJ, Miljković M, Matović B. Synthesis and characterization of biomorphic CeO2 obtained by using egg shell membrane as template. in Processing and Application of Ceramics. 2014;8(2):81-85.
doi:10.2298/PAC1402081P .
Prekajski, Marija D., Babić, Biljana M., Bučevac, Dušan, Pantić, Jelena R., Gulicovski, Jelena J., Miljković, Miroslav, Matović, Branko, "Synthesis and characterization of biomorphic CeO2 obtained by using egg shell membrane as template" in Processing and Application of Ceramics, 8, no. 2 (2014):81-85,
https://doi.org/10.2298/PAC1402081P . .
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Synthesis and characterization of hafnium carbide fine powders

Matović, Branko; Babić, Biljana M.; Bučevac, Dušan; Čebela, Maria; Maksimović, Vesna; Pantić, Jelena R.; Miljković, Miroslav

(2013)

TY  - JOUR
AU  - Matović, Branko
AU  - Babić, Biljana M.
AU  - Bučevac, Dušan
AU  - Čebela, Maria
AU  - Maksimović, Vesna
AU  - Pantić, Jelena R.
AU  - Miljković, Miroslav
PY  - 2013
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/5326
AB  - Hafnium carbide powder was synthesized by sol-gel polycondensation of hafnium chloride with citric acid. The starting materials were dissolved in water and mixed homogeneously on a hot plate until precursor gel was formed. Pyrolysis of this gel resulted in monoclinic hafnia which after subsequent heat treatment transformed into hafnium carbide. The obtained materials were analyzed by means of X-ray diffraction and scanning electron microscopy. The results showed that the obtained carbide powders were composed of nearly equiaxed particles with narrow size distribution. Characterization by nitrogen adsorption showed that the obtained powders were micro- and mesoporous materials with high specific surface area. (C) 2012 Elsevier Ltd and Techna Group S.r.l. All rights reserved.
T2  - Ceramics International
T1  - Synthesis and characterization of hafnium carbide fine powders
VL  - 39
IS  - 1
SP  - 719
EP  - 723
DO  - 10.1016/j.ceramint.2012.06.083
ER  - 
@article{
author = "Matović, Branko and Babić, Biljana M. and Bučevac, Dušan and Čebela, Maria and Maksimović, Vesna and Pantić, Jelena R. and Miljković, Miroslav",
year = "2013",
abstract = "Hafnium carbide powder was synthesized by sol-gel polycondensation of hafnium chloride with citric acid. The starting materials were dissolved in water and mixed homogeneously on a hot plate until precursor gel was formed. Pyrolysis of this gel resulted in monoclinic hafnia which after subsequent heat treatment transformed into hafnium carbide. The obtained materials were analyzed by means of X-ray diffraction and scanning electron microscopy. The results showed that the obtained carbide powders were composed of nearly equiaxed particles with narrow size distribution. Characterization by nitrogen adsorption showed that the obtained powders were micro- and mesoporous materials with high specific surface area. (C) 2012 Elsevier Ltd and Techna Group S.r.l. All rights reserved.",
journal = "Ceramics International",
title = "Synthesis and characterization of hafnium carbide fine powders",
volume = "39",
number = "1",
pages = "719-723",
doi = "10.1016/j.ceramint.2012.06.083"
}
Matović, B., Babić, B. M., Bučevac, D., Čebela, M., Maksimović, V., Pantić, J. R.,& Miljković, M.. (2013). Synthesis and characterization of hafnium carbide fine powders. in Ceramics International, 39(1), 719-723.
https://doi.org/10.1016/j.ceramint.2012.06.083
Matović B, Babić BM, Bučevac D, Čebela M, Maksimović V, Pantić JR, Miljković M. Synthesis and characterization of hafnium carbide fine powders. in Ceramics International. 2013;39(1):719-723.
doi:10.1016/j.ceramint.2012.06.083 .
Matović, Branko, Babić, Biljana M., Bučevac, Dušan, Čebela, Maria, Maksimović, Vesna, Pantić, Jelena R., Miljković, Miroslav, "Synthesis and characterization of hafnium carbide fine powders" in Ceramics International, 39, no. 1 (2013):719-723,
https://doi.org/10.1016/j.ceramint.2012.06.083 . .
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New mesoporous carbon materials synthesized by a templating procedure

Babić, Biljana M.; Kokunešoski, Maja; Miljković, Miroslav; Matović, Branko; Gulicovski, Jelena J.; Stojmenović, Marija; Bučevac, Dušan

(2013)

TY  - JOUR
AU  - Babić, Biljana M.
AU  - Kokunešoski, Maja
AU  - Miljković, Miroslav
AU  - Matović, Branko
AU  - Gulicovski, Jelena J.
AU  - Stojmenović, Marija
AU  - Bučevac, Dušan
PY  - 2013
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/5464
AB  - The new porous carbon materials were obtained by templating procedure using mesoporous silica (SBA-15) as template. The ordered mesoporous silica materials were synthesized by using Pluronic P123 (non-ionic triblock copolymer, EO20PO70O20). SBA-15/cryogel carbon composites were obtained by sol gel polycondenzation of resorcinol and formaldehyde in the presence of different amount of SBA-15. The polycondenzation was followed by freeze drying and subsequent pyrolysis. One set of SBA-15/sucrose carbon composites was prepared by using sucrose as carbon source. The silica template was eliminated by dissolving in hydrofluoric acid (HF) to recover the carbon material. The obtained carbon replicas were characterized by nitrogen adsorption-desorption measurements, X-ray diffraction and scanning electron microscopy (SEM). It was revealed that the samples have high specific surface (533-771 m(2) g(-1)), developed meso- and micro-porosity and amorphous structure. Porous structure of carbon replicas was found to be a function of the carbon source, properties of SBA-15 and silica/carbon ratio. Room temperature adsorption of nitrogen and adsorption of phenol from aqueous solutions were investigated. (C) 2012 Elsevier Ltd and Techna Group S.r.l. All rights reserved.
T2  - Ceramics International
T1  - New mesoporous carbon materials synthesized by a templating procedure
VL  - 39
IS  - 4
SP  - 4035
EP  - 4043
DO  - 10.1016/j.ceramint.2012.10.254
ER  - 
@article{
author = "Babić, Biljana M. and Kokunešoski, Maja and Miljković, Miroslav and Matović, Branko and Gulicovski, Jelena J. and Stojmenović, Marija and Bučevac, Dušan",
year = "2013",
abstract = "The new porous carbon materials were obtained by templating procedure using mesoporous silica (SBA-15) as template. The ordered mesoporous silica materials were synthesized by using Pluronic P123 (non-ionic triblock copolymer, EO20PO70O20). SBA-15/cryogel carbon composites were obtained by sol gel polycondenzation of resorcinol and formaldehyde in the presence of different amount of SBA-15. The polycondenzation was followed by freeze drying and subsequent pyrolysis. One set of SBA-15/sucrose carbon composites was prepared by using sucrose as carbon source. The silica template was eliminated by dissolving in hydrofluoric acid (HF) to recover the carbon material. The obtained carbon replicas were characterized by nitrogen adsorption-desorption measurements, X-ray diffraction and scanning electron microscopy (SEM). It was revealed that the samples have high specific surface (533-771 m(2) g(-1)), developed meso- and micro-porosity and amorphous structure. Porous structure of carbon replicas was found to be a function of the carbon source, properties of SBA-15 and silica/carbon ratio. Room temperature adsorption of nitrogen and adsorption of phenol from aqueous solutions were investigated. (C) 2012 Elsevier Ltd and Techna Group S.r.l. All rights reserved.",
journal = "Ceramics International",
title = "New mesoporous carbon materials synthesized by a templating procedure",
volume = "39",
number = "4",
pages = "4035-4043",
doi = "10.1016/j.ceramint.2012.10.254"
}
Babić, B. M., Kokunešoski, M., Miljković, M., Matović, B., Gulicovski, J. J., Stojmenović, M.,& Bučevac, D.. (2013). New mesoporous carbon materials synthesized by a templating procedure. in Ceramics International, 39(4), 4035-4043.
https://doi.org/10.1016/j.ceramint.2012.10.254
Babić BM, Kokunešoski M, Miljković M, Matović B, Gulicovski JJ, Stojmenović M, Bučevac D. New mesoporous carbon materials synthesized by a templating procedure. in Ceramics International. 2013;39(4):4035-4043.
doi:10.1016/j.ceramint.2012.10.254 .
Babić, Biljana M., Kokunešoski, Maja, Miljković, Miroslav, Matović, Branko, Gulicovski, Jelena J., Stojmenović, Marija, Bučevac, Dušan, "New mesoporous carbon materials synthesized by a templating procedure" in Ceramics International, 39, no. 4 (2013):4035-4043,
https://doi.org/10.1016/j.ceramint.2012.10.254 . .
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Effect of preparation route on the microstructure and electrical conductivity of co-doped ceria

Bučevac, Dušan; Radojkovic, Aleksandar; Miljković, Miroslav; Babić, Biljana M.; Matović, Branko

(2013)

TY  - JOUR
AU  - Bučevac, Dušan
AU  - Radojkovic, Aleksandar
AU  - Miljković, Miroslav
AU  - Babić, Biljana M.
AU  - Matović, Branko
PY  - 2013
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/5462
AB  - Dense Ce0.8Sm0.1Gd0.1O2-delta electrolytes were fabricated by sintering of CeO2 solid solutions which were prepared from metal nitrates and NaOH using self propagating room temperature synthesis (SPRT). Three different routes were employed to obtain CeO2 solid solution powders: (I) hand mixing of reactants, (II) ball milling of reactants and (III) ball milling of Ce0.8Sm0.2O2-delta and Ce0.8Gd0.2O2-delta solid solutions previously prepared by ball milling of corresponding nitrates and NaOH. Density measurements showed that ball milling, which is more convenient than hand mixing, is an effective way to obtain almost full dense samples after presureless sintering at 1550 degrees C for 1 h. These samples had larger grain size and consequently higher conductivity than the samples obtained by hand mixing. The highest conductivity of 2.704 x 10(-2) (Omega cm)(-1) was measured at 700 degrees C in a sample prepared by route II. It was found that reduced grain size in samples obtained by hand mixing leads to a decrease in grain boundary conductivity and therefore decrease in the total conductivity. The results showed that mixing of single doped ceria solid solutions improved densification and inhibited grain growth. (C) 2012 Elsevier Ltd and Techna Group S.r.l. All rights reserved.
T2  - Ceramics International
T1  - Effect of preparation route on the microstructure and electrical conductivity of co-doped ceria
VL  - 39
IS  - 4
SP  - 3603
EP  - 3611
DO  - 10.1016/j.ceramint.2012.10.188
ER  - 
@article{
author = "Bučevac, Dušan and Radojkovic, Aleksandar and Miljković, Miroslav and Babić, Biljana M. and Matović, Branko",
year = "2013",
abstract = "Dense Ce0.8Sm0.1Gd0.1O2-delta electrolytes were fabricated by sintering of CeO2 solid solutions which were prepared from metal nitrates and NaOH using self propagating room temperature synthesis (SPRT). Three different routes were employed to obtain CeO2 solid solution powders: (I) hand mixing of reactants, (II) ball milling of reactants and (III) ball milling of Ce0.8Sm0.2O2-delta and Ce0.8Gd0.2O2-delta solid solutions previously prepared by ball milling of corresponding nitrates and NaOH. Density measurements showed that ball milling, which is more convenient than hand mixing, is an effective way to obtain almost full dense samples after presureless sintering at 1550 degrees C for 1 h. These samples had larger grain size and consequently higher conductivity than the samples obtained by hand mixing. The highest conductivity of 2.704 x 10(-2) (Omega cm)(-1) was measured at 700 degrees C in a sample prepared by route II. It was found that reduced grain size in samples obtained by hand mixing leads to a decrease in grain boundary conductivity and therefore decrease in the total conductivity. The results showed that mixing of single doped ceria solid solutions improved densification and inhibited grain growth. (C) 2012 Elsevier Ltd and Techna Group S.r.l. All rights reserved.",
journal = "Ceramics International",
title = "Effect of preparation route on the microstructure and electrical conductivity of co-doped ceria",
volume = "39",
number = "4",
pages = "3603-3611",
doi = "10.1016/j.ceramint.2012.10.188"
}
Bučevac, D., Radojkovic, A., Miljković, M., Babić, B. M.,& Matović, B.. (2013). Effect of preparation route on the microstructure and electrical conductivity of co-doped ceria. in Ceramics International, 39(4), 3603-3611.
https://doi.org/10.1016/j.ceramint.2012.10.188
Bučevac D, Radojkovic A, Miljković M, Babić BM, Matović B. Effect of preparation route on the microstructure and electrical conductivity of co-doped ceria. in Ceramics International. 2013;39(4):3603-3611.
doi:10.1016/j.ceramint.2012.10.188 .
Bučevac, Dušan, Radojkovic, Aleksandar, Miljković, Miroslav, Babić, Biljana M., Matović, Branko, "Effect of preparation route on the microstructure and electrical conductivity of co-doped ceria" in Ceramics International, 39, no. 4 (2013):3603-3611,
https://doi.org/10.1016/j.ceramint.2012.10.188 . .
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Synthesis and Characterization of Biomorphic Ceo2 Obtained By Using Egg Shell Membrane as Template

Babić, Biljana M.; Bučevac, Dušan; Prekajski, Marija D.; Pantić, Jelena R.; Gulicovski, Jelena J.; Miljković, Miroslav; Matović, Branko

(2012)

TY  - CONF
AU  - Babić, Biljana M.
AU  - Bučevac, Dušan
AU  - Prekajski, Marija D.
AU  - Pantić, Jelena R.
AU  - Gulicovski, Jelena J.
AU  - Miljković, Miroslav
AU  - Matović, Branko
PY  - 2012
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/7150
AB  - Porous CeO2 was obtained by bio-inspired route using egg shell membranes (ESM) as a template. ESM extracted from the fresh chicken eggs were washed with distilled water and immersed in solution of Ce(NO3)(3) x 6 H2O for seven days. Samples were subsequently thermally treated at temperature ranging from 600 to 1200 degrees C in argon and air.To study the crystallization process, samples were heated to temperature ranging from 600 to 1200 degrees C, in air, at different temperatures (600, 800, 1000 and 1200 degrees C). Samples were characterized by nitrogen adsorption measurements, X-ray diffraction (XRD) and scanning electron microscopy (SEM). XRD of samples revealed that well crystallized CeO2 is obtained even at temperature as low as 600 degrees C. SEM images confirmed that morphology of obtained CeO2 is a replica of the morphology of the original ESM.
T1  - Synthesis and Characterization of Biomorphic Ceo2 Obtained By Using Egg Shell Membrane as Template
SP  - 45
EP  - 48
UR  - https://hdl.handle.net/21.15107/rcub_vinar_7150
ER  - 
@conference{
author = "Babić, Biljana M. and Bučevac, Dušan and Prekajski, Marija D. and Pantić, Jelena R. and Gulicovski, Jelena J. and Miljković, Miroslav and Matović, Branko",
year = "2012",
abstract = "Porous CeO2 was obtained by bio-inspired route using egg shell membranes (ESM) as a template. ESM extracted from the fresh chicken eggs were washed with distilled water and immersed in solution of Ce(NO3)(3) x 6 H2O for seven days. Samples were subsequently thermally treated at temperature ranging from 600 to 1200 degrees C in argon and air.To study the crystallization process, samples were heated to temperature ranging from 600 to 1200 degrees C, in air, at different temperatures (600, 800, 1000 and 1200 degrees C). Samples were characterized by nitrogen adsorption measurements, X-ray diffraction (XRD) and scanning electron microscopy (SEM). XRD of samples revealed that well crystallized CeO2 is obtained even at temperature as low as 600 degrees C. SEM images confirmed that morphology of obtained CeO2 is a replica of the morphology of the original ESM.",
title = "Synthesis and Characterization of Biomorphic Ceo2 Obtained By Using Egg Shell Membrane as Template",
pages = "45-48",
url = "https://hdl.handle.net/21.15107/rcub_vinar_7150"
}
Babić, B. M., Bučevac, D., Prekajski, M. D., Pantić, J. R., Gulicovski, J. J., Miljković, M.,& Matović, B.. (2012). Synthesis and Characterization of Biomorphic Ceo2 Obtained By Using Egg Shell Membrane as Template. , 45-48.
https://hdl.handle.net/21.15107/rcub_vinar_7150
Babić BM, Bučevac D, Prekajski MD, Pantić JR, Gulicovski JJ, Miljković M, Matović B. Synthesis and Characterization of Biomorphic Ceo2 Obtained By Using Egg Shell Membrane as Template. 2012;:45-48.
https://hdl.handle.net/21.15107/rcub_vinar_7150 .
Babić, Biljana M., Bučevac, Dušan, Prekajski, Marija D., Pantić, Jelena R., Gulicovski, Jelena J., Miljković, Miroslav, Matović, Branko, "Synthesis and Characterization of Biomorphic Ceo2 Obtained By Using Egg Shell Membrane as Template" (2012):45-48,
https://hdl.handle.net/21.15107/rcub_vinar_7150 .

Low-Temperature Synthetic Route for Hafnium Carbide Powder

Matović, Branko; Babić, Biljana M.; Bučevac, Dušan; Čebela, Maria; Maksimović, Vesna; Minović-Arsić, Tamara; Miljković, Miroslav

(2012)

TY  - CONF
AU  - Matović, Branko
AU  - Babić, Biljana M.
AU  - Bučevac, Dušan
AU  - Čebela, Maria
AU  - Maksimović, Vesna
AU  - Minović-Arsić, Tamara
AU  - Miljković, Miroslav
PY  - 2012
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/7012
AB  - Hafnium carbide powder was synthesized by sol-gel polycondensation of hafnium chloride with citric acid. The starting materials were dissolved in water and mixed on a hot plate until a precomposite gel was formed. Pyrolysis of these gels resulted in monoclinic hafnia and cubic hafnium carbide materials, which after subsequent heat treatment completely transformed into hafnium carbide. The obtained materials were analyzed by means of X-ray diffraction and electron microscopy investigations. The results showed that the obtained carbide powder was composed of nearly equiaxed particles of narrow size distribution. Characterization by nitrogen adsorption showed that the precomposite gels and the composite powders were micro and mesoporous materials with high surface areas.
C3  - ModTech International Conference : 16th International Conference on Modern Technologies, Quality and Innovation
T1  - Low-Temperature Synthetic Route for Hafnium Carbide Powder
SP  - 537
EP  - 540
UR  - https://hdl.handle.net/21.15107/rcub_vinar_7012
ER  - 
@conference{
author = "Matović, Branko and Babić, Biljana M. and Bučevac, Dušan and Čebela, Maria and Maksimović, Vesna and Minović-Arsić, Tamara and Miljković, Miroslav",
year = "2012",
abstract = "Hafnium carbide powder was synthesized by sol-gel polycondensation of hafnium chloride with citric acid. The starting materials were dissolved in water and mixed on a hot plate until a precomposite gel was formed. Pyrolysis of these gels resulted in monoclinic hafnia and cubic hafnium carbide materials, which after subsequent heat treatment completely transformed into hafnium carbide. The obtained materials were analyzed by means of X-ray diffraction and electron microscopy investigations. The results showed that the obtained carbide powder was composed of nearly equiaxed particles of narrow size distribution. Characterization by nitrogen adsorption showed that the precomposite gels and the composite powders were micro and mesoporous materials with high surface areas.",
journal = "ModTech International Conference : 16th International Conference on Modern Technologies, Quality and Innovation",
title = "Low-Temperature Synthetic Route for Hafnium Carbide Powder",
pages = "537-540",
url = "https://hdl.handle.net/21.15107/rcub_vinar_7012"
}
Matović, B., Babić, B. M., Bučevac, D., Čebela, M., Maksimović, V., Minović-Arsić, T.,& Miljković, M.. (2012). Low-Temperature Synthetic Route for Hafnium Carbide Powder. in ModTech International Conference : 16th International Conference on Modern Technologies, Quality and Innovation, 537-540.
https://hdl.handle.net/21.15107/rcub_vinar_7012
Matović B, Babić BM, Bučevac D, Čebela M, Maksimović V, Minović-Arsić T, Miljković M. Low-Temperature Synthetic Route for Hafnium Carbide Powder. in ModTech International Conference : 16th International Conference on Modern Technologies, Quality and Innovation. 2012;:537-540.
https://hdl.handle.net/21.15107/rcub_vinar_7012 .
Matović, Branko, Babić, Biljana M., Bučevac, Dušan, Čebela, Maria, Maksimović, Vesna, Minović-Arsić, Tamara, Miljković, Miroslav, "Low-Temperature Synthetic Route for Hafnium Carbide Powder" in ModTech International Conference : 16th International Conference on Modern Technologies, Quality and Innovation (2012):537-540,
https://hdl.handle.net/21.15107/rcub_vinar_7012 .

Synthesis and characterization of the SBA-15/carbon cryogel nanocomposites

Babić, Biljana M.; Kokunešoski, Maja; Miljković, Miroslav; Prekajski, Marija D.; Matović, Branko; Gulicovski, Jelena J.; Bučevac, Dušan

(2012)

TY  - JOUR
AU  - Babić, Biljana M.
AU  - Kokunešoski, Maja
AU  - Miljković, Miroslav
AU  - Prekajski, Marija D.
AU  - Matović, Branko
AU  - Gulicovski, Jelena J.
AU  - Bučevac, Dušan
PY  - 2012
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/4921
AB  - The ordered mesoporous silica SBA-15 materials were synthesized using Pluronic P123 (non-ionic triblock copolymer, EO20PO70O20), under acidic conditions. SBA-15/carbon cryogel composites were obtained by sol gel polycondensation of resorcinol and formaldehyde followed by freeze drying, and subsequent pyrolysis, in the presence of different amounts of SBA-15. For comparison purpose, SBA-15/carbon composite was also prepared using sucrose as carbon source. These materials were characterized by room temperature nitrogen adsorption-desorption measurement, X-ray diffraction, scanning electron microscopy (SEM) and Fourier transform infrared (FT-IR) spectroscopy. It was revealed that the samples have amorphous structure, high specific surface area (350-520 m(2) g(-1)) and developed meso- as well as microporosity. The porosity of structure depends on the carbon source and Si/C ratio which can be easily controlled by varying concentration of starting solution. (C) 2012 Elsevier Ltd and Techna Group S.r.l. All rights reserved.
T2  - Ceramics International
T1  - Synthesis and characterization of the SBA-15/carbon cryogel nanocomposites
VL  - 38
IS  - 6
SP  - 4875
EP  - 4883
DO  - 10.1016/j.ceramint.2012.02.078
ER  - 
@article{
author = "Babić, Biljana M. and Kokunešoski, Maja and Miljković, Miroslav and Prekajski, Marija D. and Matović, Branko and Gulicovski, Jelena J. and Bučevac, Dušan",
year = "2012",
abstract = "The ordered mesoporous silica SBA-15 materials were synthesized using Pluronic P123 (non-ionic triblock copolymer, EO20PO70O20), under acidic conditions. SBA-15/carbon cryogel composites were obtained by sol gel polycondensation of resorcinol and formaldehyde followed by freeze drying, and subsequent pyrolysis, in the presence of different amounts of SBA-15. For comparison purpose, SBA-15/carbon composite was also prepared using sucrose as carbon source. These materials were characterized by room temperature nitrogen adsorption-desorption measurement, X-ray diffraction, scanning electron microscopy (SEM) and Fourier transform infrared (FT-IR) spectroscopy. It was revealed that the samples have amorphous structure, high specific surface area (350-520 m(2) g(-1)) and developed meso- as well as microporosity. The porosity of structure depends on the carbon source and Si/C ratio which can be easily controlled by varying concentration of starting solution. (C) 2012 Elsevier Ltd and Techna Group S.r.l. All rights reserved.",
journal = "Ceramics International",
title = "Synthesis and characterization of the SBA-15/carbon cryogel nanocomposites",
volume = "38",
number = "6",
pages = "4875-4883",
doi = "10.1016/j.ceramint.2012.02.078"
}
Babić, B. M., Kokunešoski, M., Miljković, M., Prekajski, M. D., Matović, B., Gulicovski, J. J.,& Bučevac, D.. (2012). Synthesis and characterization of the SBA-15/carbon cryogel nanocomposites. in Ceramics International, 38(6), 4875-4883.
https://doi.org/10.1016/j.ceramint.2012.02.078
Babić BM, Kokunešoski M, Miljković M, Prekajski MD, Matović B, Gulicovski JJ, Bučevac D. Synthesis and characterization of the SBA-15/carbon cryogel nanocomposites. in Ceramics International. 2012;38(6):4875-4883.
doi:10.1016/j.ceramint.2012.02.078 .
Babić, Biljana M., Kokunešoski, Maja, Miljković, Miroslav, Prekajski, Marija D., Matović, Branko, Gulicovski, Jelena J., Bučevac, Dušan, "Synthesis and characterization of the SBA-15/carbon cryogel nanocomposites" in Ceramics International, 38, no. 6 (2012):4875-4883,
https://doi.org/10.1016/j.ceramint.2012.02.078 . .
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Synthesis of biomorphic SiC and SiO2 ceramics

Egelja, Adela; Gulicovski, Jelena J.; Devečerski, Aleksandar; Babić, Biljana M.; Miljković, Miroslav; Bošković, Snežana B.; Matović, Branko

(2008)

TY  - JOUR
AU  - Egelja, Adela
AU  - Gulicovski, Jelena J.
AU  - Devečerski, Aleksandar
AU  - Babić, Biljana M.
AU  - Miljković, Miroslav
AU  - Bošković, Snežana B.
AU  - Matović, Branko
PY  - 2008
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/3497
AB  - Coniferous wood (fir) was transformed by pyrolysis into carbon preforms, which were subsequently converted into biomorphic ceramics by the pressure infiltration technique with colloidal silica. An in situ reaction between the silica and the carbon template occurred in the cellular wall at a high sintering temperature. Depending on the employed atmosphere, non-oxide (SiC) or oxide (SiO2) ceramics were obtained. The morphology of the resulting porous ceramics and their phase composition were investigated by scanning electron microscopy (SEM/EDX) and X-ray diffraction (XRD). The experimental results showed that the biomorphic cellular morphology of the wood maintained in both the SiC and silica ceramics, which consisted of only the beta-SiC phase and SiO2, respectively.
T2  - Journal of the Serbian Chemical Society
T1  - Synthesis of biomorphic SiC and SiO2 ceramics
VL  - 73
IS  - 7
SP  - 745
EP  - 751
DO  - 10.2298/JSC0807745E
ER  - 
@article{
author = "Egelja, Adela and Gulicovski, Jelena J. and Devečerski, Aleksandar and Babić, Biljana M. and Miljković, Miroslav and Bošković, Snežana B. and Matović, Branko",
year = "2008",
abstract = "Coniferous wood (fir) was transformed by pyrolysis into carbon preforms, which were subsequently converted into biomorphic ceramics by the pressure infiltration technique with colloidal silica. An in situ reaction between the silica and the carbon template occurred in the cellular wall at a high sintering temperature. Depending on the employed atmosphere, non-oxide (SiC) or oxide (SiO2) ceramics were obtained. The morphology of the resulting porous ceramics and their phase composition were investigated by scanning electron microscopy (SEM/EDX) and X-ray diffraction (XRD). The experimental results showed that the biomorphic cellular morphology of the wood maintained in both the SiC and silica ceramics, which consisted of only the beta-SiC phase and SiO2, respectively.",
journal = "Journal of the Serbian Chemical Society",
title = "Synthesis of biomorphic SiC and SiO2 ceramics",
volume = "73",
number = "7",
pages = "745-751",
doi = "10.2298/JSC0807745E"
}
Egelja, A., Gulicovski, J. J., Devečerski, A., Babić, B. M., Miljković, M., Bošković, S. B.,& Matović, B.. (2008). Synthesis of biomorphic SiC and SiO2 ceramics. in Journal of the Serbian Chemical Society, 73(7), 745-751.
https://doi.org/10.2298/JSC0807745E
Egelja A, Gulicovski JJ, Devečerski A, Babić BM, Miljković M, Bošković SB, Matović B. Synthesis of biomorphic SiC and SiO2 ceramics. in Journal of the Serbian Chemical Society. 2008;73(7):745-751.
doi:10.2298/JSC0807745E .
Egelja, Adela, Gulicovski, Jelena J., Devečerski, Aleksandar, Babić, Biljana M., Miljković, Miroslav, Bošković, Snežana B., Matović, Branko, "Synthesis of biomorphic SiC and SiO2 ceramics" in Journal of the Serbian Chemical Society, 73, no. 7 (2008):745-751,
https://doi.org/10.2298/JSC0807745E . .
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Fabrication of SiC by carbothermal-reduction reactions of diatomaceous earth

Matović, Branko; Šaponjić, Aleksandra; Devečerski, Aleksandar; Miljković, Miroslav

(2007)

TY  - JOUR
AU  - Matović, Branko
AU  - Šaponjić, Aleksandra
AU  - Devečerski, Aleksandar
AU  - Miljković, Miroslav
PY  - 2007
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/3211
AB  - In this paper the possibility of using diatomaceous earth as Si precursor for low temperature synthesis of silicon carbide (SiC) by carbothermal-reduction reactions was studied. A diatomaceous earth of Serbian origin and carbon black as reducing agent were used. The green bodies with constant C/SiO2 ratio (C/Si = 4) were heated at temperatures between 1,250 degrees C and 1,550 degrees C with controlled Ar flow atmosphere. Phase evolution was followed as a function of annealing time and sintering temperature. It was found that reaction proceeded via many intermediate phases. The comparatively low reaction temperature is attributed to the nano-porous nature of the raw material. By means of XRD and SEM investigations powders have been characterized. The results show that diatomaceous earth can be very effective source for obtaining of silicon carbide powders.
T2  - Journal of Materials Science
T1  - Fabrication of SiC by carbothermal-reduction reactions of diatomaceous earth
VL  - 42
IS  - 14
SP  - 5448
EP  - 5451
DO  - 10.1007/s10853-006-0780-6
ER  - 
@article{
author = "Matović, Branko and Šaponjić, Aleksandra and Devečerski, Aleksandar and Miljković, Miroslav",
year = "2007",
abstract = "In this paper the possibility of using diatomaceous earth as Si precursor for low temperature synthesis of silicon carbide (SiC) by carbothermal-reduction reactions was studied. A diatomaceous earth of Serbian origin and carbon black as reducing agent were used. The green bodies with constant C/SiO2 ratio (C/Si = 4) were heated at temperatures between 1,250 degrees C and 1,550 degrees C with controlled Ar flow atmosphere. Phase evolution was followed as a function of annealing time and sintering temperature. It was found that reaction proceeded via many intermediate phases. The comparatively low reaction temperature is attributed to the nano-porous nature of the raw material. By means of XRD and SEM investigations powders have been characterized. The results show that diatomaceous earth can be very effective source for obtaining of silicon carbide powders.",
journal = "Journal of Materials Science",
title = "Fabrication of SiC by carbothermal-reduction reactions of diatomaceous earth",
volume = "42",
number = "14",
pages = "5448-5451",
doi = "10.1007/s10853-006-0780-6"
}
Matović, B., Šaponjić, A., Devečerski, A.,& Miljković, M.. (2007). Fabrication of SiC by carbothermal-reduction reactions of diatomaceous earth. in Journal of Materials Science, 42(14), 5448-5451.
https://doi.org/10.1007/s10853-006-0780-6
Matović B, Šaponjić A, Devečerski A, Miljković M. Fabrication of SiC by carbothermal-reduction reactions of diatomaceous earth. in Journal of Materials Science. 2007;42(14):5448-5451.
doi:10.1007/s10853-006-0780-6 .
Matović, Branko, Šaponjić, Aleksandra, Devečerski, Aleksandar, Miljković, Miroslav, "Fabrication of SiC by carbothermal-reduction reactions of diatomaceous earth" in Journal of Materials Science, 42, no. 14 (2007):5448-5451,
https://doi.org/10.1007/s10853-006-0780-6 . .
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