Popovic, N

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  • Popovic, N (15)
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Subsolidus phase equilibria in the CeO2-x-SiO2-ZrO2 system: An experimental study

Zec, Slavica; Bošković, Snežana B.; Popovic, N; Bogdanov, Žarko

(2006)

TY  - JOUR
AU  - Zec, Slavica
AU  - Bošković, Snežana B.
AU  - Popovic, N
AU  - Bogdanov, Žarko
PY  - 2006
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/3035
AB  - The phase equilibria in the CeO2-xSiO2-ZrO2 system were studied in the subsolidus region in argon atmosphere, under isothermal heating and hot pressing, at 1400 degrees C, different ceria, silica, and zirconia mixtures. X-ray diffraction (XRD), scanning electron microscopy (SEM) and electron probe microanalysis (EPMA) were performed to identify phases and to establish phase equilibria. Based on the results of many preliminarily investigated ternary compositions, possible tie lines are predicted. Compositions from the proposed tie lines were successively fired and ground until the changes of the phase compositions were not detected or were low enough to be neglected. Phases identified in these compositions confirmed the existence of five tie lines: Ce2Si2O7-ZrSiO4, Ce2Si2O7-ZrO2, Ce-4.67(SiO4)(3)O-ZrO2, Ce-4.67(SiO4)(3)O-Ce2Zr2O7 and Ce2SiO5-Ce2Zr2O7, which divide the CeO2-x-SiO2ZrO2 composition triangle into six compatibility triangles. The formation of ternary compounds or ternary solid solutions in the CeO2-x-SiO2-ZrO2 system was not observed. The monoclinic high temperature polymorph of Ce2Si2O7 was detected. The cubic pyrochlore phases had different lattice parameters, caused by incomplete reduction of the tetravalent cerium ions also observed in the non-stoichiometric cerium oxide.
T2  - International Journal of Materials Research
T1  - Subsolidus phase equilibria in the CeO2-x-SiO2-ZrO2 system: An experimental study
VL  - 97
IS  - 5
SP  - 579
EP  - 583
DO  - 10.3139/146.101274
ER  - 
@article{
author = "Zec, Slavica and Bošković, Snežana B. and Popovic, N and Bogdanov, Žarko",
year = "2006",
abstract = "The phase equilibria in the CeO2-xSiO2-ZrO2 system were studied in the subsolidus region in argon atmosphere, under isothermal heating and hot pressing, at 1400 degrees C, different ceria, silica, and zirconia mixtures. X-ray diffraction (XRD), scanning electron microscopy (SEM) and electron probe microanalysis (EPMA) were performed to identify phases and to establish phase equilibria. Based on the results of many preliminarily investigated ternary compositions, possible tie lines are predicted. Compositions from the proposed tie lines were successively fired and ground until the changes of the phase compositions were not detected or were low enough to be neglected. Phases identified in these compositions confirmed the existence of five tie lines: Ce2Si2O7-ZrSiO4, Ce2Si2O7-ZrO2, Ce-4.67(SiO4)(3)O-ZrO2, Ce-4.67(SiO4)(3)O-Ce2Zr2O7 and Ce2SiO5-Ce2Zr2O7, which divide the CeO2-x-SiO2ZrO2 composition triangle into six compatibility triangles. The formation of ternary compounds or ternary solid solutions in the CeO2-x-SiO2-ZrO2 system was not observed. The monoclinic high temperature polymorph of Ce2Si2O7 was detected. The cubic pyrochlore phases had different lattice parameters, caused by incomplete reduction of the tetravalent cerium ions also observed in the non-stoichiometric cerium oxide.",
journal = "International Journal of Materials Research",
title = "Subsolidus phase equilibria in the CeO2-x-SiO2-ZrO2 system: An experimental study",
volume = "97",
number = "5",
pages = "579-583",
doi = "10.3139/146.101274"
}
Zec, S., Bošković, S. B., Popovic, N.,& Bogdanov, Ž.. (2006). Subsolidus phase equilibria in the CeO2-x-SiO2-ZrO2 system: An experimental study. in International Journal of Materials Research, 97(5), 579-583.
https://doi.org/10.3139/146.101274
Zec S, Bošković SB, Popovic N, Bogdanov Ž. Subsolidus phase equilibria in the CeO2-x-SiO2-ZrO2 system: An experimental study. in International Journal of Materials Research. 2006;97(5):579-583.
doi:10.3139/146.101274 .
Zec, Slavica, Bošković, Snežana B., Popovic, N, Bogdanov, Žarko, "Subsolidus phase equilibria in the CeO2-x-SiO2-ZrO2 system: An experimental study" in International Journal of Materials Research, 97, no. 5 (2006):579-583,
https://doi.org/10.3139/146.101274 . .
1
1
1

Low temperature Ce2Si2O7 polymorph formed by mechanical activation

Zec, Slavica; Bošković, Snežana B.; Bogdanov, Žarko; Popovic, N

(2006)

TY  - JOUR
AU  - Zec, Slavica
AU  - Bošković, Snežana B.
AU  - Bogdanov, Žarko
AU  - Popovic, N
PY  - 2006
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/2939
AB  - Studying solid state reaction between mechanically activated oxide powders of CeO2 and quartz-SiO2, we obtained directly during heat treatment, the low temperature polymorph of Ce2Si2O7 instead of the high temperature polymorph formed in non-activated oxides mixture. The mixture with composition corresponded to Ce2Si2O7 stoichiometry was mechanically activated by milling in high energetic vibratory mill for 2-120 min. Heating was done in an Astro furnace in a flowing argon atmosphere at 1200-1550 degrees C for 1 h while the specimens were furnace cooled. Crystallite size, lattice distortion and phases identification was performed by X-ray powder diffraction (XRD) analysis. Microstructure characterization of the mixtures was done using scanning electron microscopy (SEM). Low temperature polymorph of Ce2Si2O7 was obtained in activated mixtures at temperatures below 1400 degrees C. (c) 2005 Elsevier B.V All rights reserved.
T2  - Materials Chemistry and Physics
T1  - Low temperature Ce2Si2O7 polymorph formed by mechanical activation
VL  - 95
IS  - 1
SP  - 150
EP  - 153
DO  - 10.1016/j.matchemphys.2005.05.036
ER  - 
@article{
author = "Zec, Slavica and Bošković, Snežana B. and Bogdanov, Žarko and Popovic, N",
year = "2006",
abstract = "Studying solid state reaction between mechanically activated oxide powders of CeO2 and quartz-SiO2, we obtained directly during heat treatment, the low temperature polymorph of Ce2Si2O7 instead of the high temperature polymorph formed in non-activated oxides mixture. The mixture with composition corresponded to Ce2Si2O7 stoichiometry was mechanically activated by milling in high energetic vibratory mill for 2-120 min. Heating was done in an Astro furnace in a flowing argon atmosphere at 1200-1550 degrees C for 1 h while the specimens were furnace cooled. Crystallite size, lattice distortion and phases identification was performed by X-ray powder diffraction (XRD) analysis. Microstructure characterization of the mixtures was done using scanning electron microscopy (SEM). Low temperature polymorph of Ce2Si2O7 was obtained in activated mixtures at temperatures below 1400 degrees C. (c) 2005 Elsevier B.V All rights reserved.",
journal = "Materials Chemistry and Physics",
title = "Low temperature Ce2Si2O7 polymorph formed by mechanical activation",
volume = "95",
number = "1",
pages = "150-153",
doi = "10.1016/j.matchemphys.2005.05.036"
}
Zec, S., Bošković, S. B., Bogdanov, Ž.,& Popovic, N.. (2006). Low temperature Ce2Si2O7 polymorph formed by mechanical activation. in Materials Chemistry and Physics, 95(1), 150-153.
https://doi.org/10.1016/j.matchemphys.2005.05.036
Zec S, Bošković SB, Bogdanov Ž, Popovic N. Low temperature Ce2Si2O7 polymorph formed by mechanical activation. in Materials Chemistry and Physics. 2006;95(1):150-153.
doi:10.1016/j.matchemphys.2005.05.036 .
Zec, Slavica, Bošković, Snežana B., Bogdanov, Žarko, Popovic, N, "Low temperature Ce2Si2O7 polymorph formed by mechanical activation" in Materials Chemistry and Physics, 95, no. 1 (2006):150-153,
https://doi.org/10.1016/j.matchemphys.2005.05.036 . .
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Detection of gastrointestinal and abdominal infections by, Tc-99m-ciprofloxacin

Artiko, V; Davidovic, B; Nikolic, N; Petrović, M; Vlajkovic, M; Pesko, P; Knežević, S.; Dukić, V; Stefanovic, B; Tulic, C; Popovic, N; Milosavljevic, T; Obradović, V

(2005)

TY  - JOUR
AU  - Artiko, V
AU  - Davidovic, B
AU  - Nikolic, N
AU  - Petrović, M
AU  - Vlajkovic, M
AU  - Pesko, P
AU  - Knežević, S.
AU  - Dukić, V
AU  - Stefanovic, B
AU  - Tulic, C
AU  - Popovic, N
AU  - Milosavljevic, T
AU  - Obradović, V
PY  - 2005
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/2874
AB  - Background/Aims: The aim of the study is detection and evaluation of the abdominal and gastrointestinal; infective foci using Tc-99m-ciprofloxacin (Laboratory for radioactive isotopes, Vinca). Methodology: In total 21 patients with clinical suspicion on abdominal or gastrointestinal infection were investigated. In all the patients, planar liver/spleen scintigraphy was performed. Ciprofloxacin chloride (3.5mg) was mixed with 555MBq of Tc-99m in 3mL of physiological solution and incubated for 20 min. After slow i.v. injection in a cubital vein, dynamic acquisition (1 f/min) was performed during the first 60 min in the position of interest, followed by static acquisition (500 000 imp) anterior and posterior view, abdomen and pelvis after 1 h and 4 h in all patients. When necessary, additional scintigrams were acquired after 24h. In all the patients with negative or equivocal findings of planar scintigraphy, emission computerized tomography (SPECT) was performed (60 positions, 6 degrees). Interpretation was made by three independent observers. Additional data were provided using clinical findings, ultrasonography, computed tomography and magnetic resonance imaging, laboratory analyses, and surgical or microbiological confirmation of infection. Results: There were eleven true-positive findings, seven true negative, two were false negative while one was false positive due to intestinal obstruction. Sensitivity was 79%, specificity 91%, positive predictive value 92%, negative predictive value 77% accuracy 84%. Conclusions: According to our results, scintigraphy with radiolabeled ciprofloxacin is a useful method for detection and assessment of exact localization of abdominal and gastrointestinal infections.
T2  - Hepato-gastroenterology
T1  - Detection of gastrointestinal and abdominal infections by, Tc-99m-ciprofloxacin
VL  - 52
IS  - 62
SP  - 491
EP  - 495
UR  - https://hdl.handle.net/21.15107/rcub_vinar_2874
ER  - 
@article{
author = "Artiko, V and Davidovic, B and Nikolic, N and Petrović, M and Vlajkovic, M and Pesko, P and Knežević, S. and Dukić, V and Stefanovic, B and Tulic, C and Popovic, N and Milosavljevic, T and Obradović, V",
year = "2005",
abstract = "Background/Aims: The aim of the study is detection and evaluation of the abdominal and gastrointestinal; infective foci using Tc-99m-ciprofloxacin (Laboratory for radioactive isotopes, Vinca). Methodology: In total 21 patients with clinical suspicion on abdominal or gastrointestinal infection were investigated. In all the patients, planar liver/spleen scintigraphy was performed. Ciprofloxacin chloride (3.5mg) was mixed with 555MBq of Tc-99m in 3mL of physiological solution and incubated for 20 min. After slow i.v. injection in a cubital vein, dynamic acquisition (1 f/min) was performed during the first 60 min in the position of interest, followed by static acquisition (500 000 imp) anterior and posterior view, abdomen and pelvis after 1 h and 4 h in all patients. When necessary, additional scintigrams were acquired after 24h. In all the patients with negative or equivocal findings of planar scintigraphy, emission computerized tomography (SPECT) was performed (60 positions, 6 degrees). Interpretation was made by three independent observers. Additional data were provided using clinical findings, ultrasonography, computed tomography and magnetic resonance imaging, laboratory analyses, and surgical or microbiological confirmation of infection. Results: There were eleven true-positive findings, seven true negative, two were false negative while one was false positive due to intestinal obstruction. Sensitivity was 79%, specificity 91%, positive predictive value 92%, negative predictive value 77% accuracy 84%. Conclusions: According to our results, scintigraphy with radiolabeled ciprofloxacin is a useful method for detection and assessment of exact localization of abdominal and gastrointestinal infections.",
journal = "Hepato-gastroenterology",
title = "Detection of gastrointestinal and abdominal infections by, Tc-99m-ciprofloxacin",
volume = "52",
number = "62",
pages = "491-495",
url = "https://hdl.handle.net/21.15107/rcub_vinar_2874"
}
Artiko, V., Davidovic, B., Nikolic, N., Petrović, M., Vlajkovic, M., Pesko, P., Knežević, S., Dukić, V., Stefanovic, B., Tulic, C., Popovic, N., Milosavljevic, T.,& Obradović, V.. (2005). Detection of gastrointestinal and abdominal infections by, Tc-99m-ciprofloxacin. in Hepato-gastroenterology, 52(62), 491-495.
https://hdl.handle.net/21.15107/rcub_vinar_2874
Artiko V, Davidovic B, Nikolic N, Petrović M, Vlajkovic M, Pesko P, Knežević S, Dukić V, Stefanovic B, Tulic C, Popovic N, Milosavljevic T, Obradović V. Detection of gastrointestinal and abdominal infections by, Tc-99m-ciprofloxacin. in Hepato-gastroenterology. 2005;52(62):491-495.
https://hdl.handle.net/21.15107/rcub_vinar_2874 .
Artiko, V, Davidovic, B, Nikolic, N, Petrović, M, Vlajkovic, M, Pesko, P, Knežević, S., Dukić, V, Stefanovic, B, Tulic, C, Popovic, N, Milosavljevic, T, Obradović, V, "Detection of gastrointestinal and abdominal infections by, Tc-99m-ciprofloxacin" in Hepato-gastroenterology, 52, no. 62 (2005):491-495,
https://hdl.handle.net/21.15107/rcub_vinar_2874 .
10

Growth of non-regular a-CNx : H cluster arrays on pulse plasma nitrided hot work steel samples

Zlatanovic, M; Popovic, N; Zlatanovic, S

(2005)

TY  - JOUR
AU  - Zlatanovic, M
AU  - Popovic, N
AU  - Zlatanovic, S
PY  - 2005
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/6558
AB  - Samples made of hot work steel grade H11 were pulse plasma nitrided in hydrogen nitrogen mixture and post-nitrocarburized in carbon-containing discharge. Microhardness measurements, optical microscopy, SEM, Raman, XRD and infrared spectra analyses revealed the existence of a thin epsilon+ gamma compound zone onto 150 pin thick diffusion layer after plasma nitriding, while a dense 3 gm thick amorphous hydrogenated carbon nitride overcoating was grown during plasma post-processing in carbon-containing atmosphere. On the surface of plasma deposited hydrogenated carbonitride films intended for tribological applications non-regular arrays of different size conductive clusters were found. Similar arrays architecture, when obtained intentionally, could be used for the resonant optical connections in nanooptics and macro optics. Some coupled arrays, like the fiberoptic waveguide in fiber optics interferometers, were also observed. Computer simulation showed that in the case of similar geometry spherical Ag clusters deposited onto dielectric substrate the resonant interaction of light beam with coupled arrays is possible resembling to the light beam coupler on nanoscale. (c) 2005 Elsevier B.V. All rights reserved.
T2  - Surface and Coatings Technology
T1  - Growth of non-regular a-CNx : H cluster arrays on pulse plasma nitrided hot work steel samples
VL  - 200
IS  - 5-6
SP  - 1445
EP  - 1450
DO  - 10.1016/j.surfcoat.2005.08.073
ER  - 
@article{
author = "Zlatanovic, M and Popovic, N and Zlatanovic, S",
year = "2005",
abstract = "Samples made of hot work steel grade H11 were pulse plasma nitrided in hydrogen nitrogen mixture and post-nitrocarburized in carbon-containing discharge. Microhardness measurements, optical microscopy, SEM, Raman, XRD and infrared spectra analyses revealed the existence of a thin epsilon+ gamma compound zone onto 150 pin thick diffusion layer after plasma nitriding, while a dense 3 gm thick amorphous hydrogenated carbon nitride overcoating was grown during plasma post-processing in carbon-containing atmosphere. On the surface of plasma deposited hydrogenated carbonitride films intended for tribological applications non-regular arrays of different size conductive clusters were found. Similar arrays architecture, when obtained intentionally, could be used for the resonant optical connections in nanooptics and macro optics. Some coupled arrays, like the fiberoptic waveguide in fiber optics interferometers, were also observed. Computer simulation showed that in the case of similar geometry spherical Ag clusters deposited onto dielectric substrate the resonant interaction of light beam with coupled arrays is possible resembling to the light beam coupler on nanoscale. (c) 2005 Elsevier B.V. All rights reserved.",
journal = "Surface and Coatings Technology",
title = "Growth of non-regular a-CNx : H cluster arrays on pulse plasma nitrided hot work steel samples",
volume = "200",
number = "5-6",
pages = "1445-1450",
doi = "10.1016/j.surfcoat.2005.08.073"
}
Zlatanovic, M., Popovic, N.,& Zlatanovic, S.. (2005). Growth of non-regular a-CNx : H cluster arrays on pulse plasma nitrided hot work steel samples. in Surface and Coatings Technology, 200(5-6), 1445-1450.
https://doi.org/10.1016/j.surfcoat.2005.08.073
Zlatanovic M, Popovic N, Zlatanovic S. Growth of non-regular a-CNx : H cluster arrays on pulse plasma nitrided hot work steel samples. in Surface and Coatings Technology. 2005;200(5-6):1445-1450.
doi:10.1016/j.surfcoat.2005.08.073 .
Zlatanovic, M, Popovic, N, Zlatanovic, S, "Growth of non-regular a-CNx : H cluster arrays on pulse plasma nitrided hot work steel samples" in Surface and Coatings Technology, 200, no. 5-6 (2005):1445-1450,
https://doi.org/10.1016/j.surfcoat.2005.08.073 . .
3
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TiN thin films deposited by ion beam sputtering: effects of energetic particles bombardment

Popovic, N; Bogdanov, Žarko; Goncić, Bratislav; Zec, Slavica; Rakočević, Zlatko Lj.; Zlatanovic, M; Peruško, Davor

(2004)

TY  - JOUR
AU  - Popovic, N
AU  - Bogdanov, Žarko
AU  - Goncić, Bratislav
AU  - Zec, Slavica
AU  - Rakočević, Zlatko Lj.
AU  - Zlatanovic, M
AU  - Peruško, Davor
PY  - 2004
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/6452
AB  - The low energy broad argon ion beam (1.35-2.0) keV was used for sputtering of a Ti target in an atmosphere of nitrogen gas to form TiN films. During deposition the growing thin film was under argon ion irradiation from the beam periphery. The influence of the ion beam energy (E-b) and average energy delivered by assisting ions to condensing film atoms (E-n) on TiN film properties was investigated. The titanium nitride thin films were deposited at a low working pressure of 1 x 10(-4) mbar and at ambient substrate temperature. XRD analysis revealed the formation of a delta-TiN phase with preferred (220) orientation for the stoichiometric composition of TiN films (RBS). The increase of both the intensity of the (220) peak and TiN film crystallite dimension with increasing the energy of Ti target bombarding Ar+ ions (E-b) was observed. By increasing the average ion energy per deposited metal atom (E-n) the (220) peak intensity and crystallite dimension decrease and a complete loss of (220) orientation at E-n close to 162 eV/at was found. In the range of E-n considered, the TiN films grain size decreases leading to the nanostructured surface as revealed by the STM analysis. The incident angle and energy of the assisted bombarding strongly influence the film-preferred orientation and sub-microstructure. (C) 2003 Elsevier B.V. All rights reserved.
T2  - Thin Solid Films
T1  - TiN thin films deposited by ion beam sputtering: effects of energetic particles bombardment
VL  - 459
IS  - 1-2
SP  - 286
EP  - 291
DO  - 10.1016/j.tsf.2003.12.130
ER  - 
@article{
author = "Popovic, N and Bogdanov, Žarko and Goncić, Bratislav and Zec, Slavica and Rakočević, Zlatko Lj. and Zlatanovic, M and Peruško, Davor",
year = "2004",
abstract = "The low energy broad argon ion beam (1.35-2.0) keV was used for sputtering of a Ti target in an atmosphere of nitrogen gas to form TiN films. During deposition the growing thin film was under argon ion irradiation from the beam periphery. The influence of the ion beam energy (E-b) and average energy delivered by assisting ions to condensing film atoms (E-n) on TiN film properties was investigated. The titanium nitride thin films were deposited at a low working pressure of 1 x 10(-4) mbar and at ambient substrate temperature. XRD analysis revealed the formation of a delta-TiN phase with preferred (220) orientation for the stoichiometric composition of TiN films (RBS). The increase of both the intensity of the (220) peak and TiN film crystallite dimension with increasing the energy of Ti target bombarding Ar+ ions (E-b) was observed. By increasing the average ion energy per deposited metal atom (E-n) the (220) peak intensity and crystallite dimension decrease and a complete loss of (220) orientation at E-n close to 162 eV/at was found. In the range of E-n considered, the TiN films grain size decreases leading to the nanostructured surface as revealed by the STM analysis. The incident angle and energy of the assisted bombarding strongly influence the film-preferred orientation and sub-microstructure. (C) 2003 Elsevier B.V. All rights reserved.",
journal = "Thin Solid Films",
title = "TiN thin films deposited by ion beam sputtering: effects of energetic particles bombardment",
volume = "459",
number = "1-2",
pages = "286-291",
doi = "10.1016/j.tsf.2003.12.130"
}
Popovic, N., Bogdanov, Ž., Goncić, B., Zec, S., Rakočević, Z. Lj., Zlatanovic, M.,& Peruško, D.. (2004). TiN thin films deposited by ion beam sputtering: effects of energetic particles bombardment. in Thin Solid Films, 459(1-2), 286-291.
https://doi.org/10.1016/j.tsf.2003.12.130
Popovic N, Bogdanov Ž, Goncić B, Zec S, Rakočević ZL, Zlatanovic M, Peruško D. TiN thin films deposited by ion beam sputtering: effects of energetic particles bombardment. in Thin Solid Films. 2004;459(1-2):286-291.
doi:10.1016/j.tsf.2003.12.130 .
Popovic, N, Bogdanov, Žarko, Goncić, Bratislav, Zec, Slavica, Rakočević, Zlatko Lj., Zlatanovic, M, Peruško, Davor, "TiN thin films deposited by ion beam sputtering: effects of energetic particles bombardment" in Thin Solid Films, 459, no. 1-2 (2004):286-291,
https://doi.org/10.1016/j.tsf.2003.12.130 . .
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8

Plasma oxidation of salt bath nitrided C 15 steel samples

Zlatanovic, M; Popovic, N; Bogdanov, Žarko; Kunosic, A

(2004)

TY  - JOUR
AU  - Zlatanovic, M
AU  - Popovic, N
AU  - Bogdanov, Žarko
AU  - Kunosic, A
PY  - 2004
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/6419
AB  - Quenched and tempered samples made of plain carbon steel C 15 were salt bath nitrided at 580(0)C for 210 minutes and subsequently water quenched. The nitrided samples were half cut to obtain ail untreated surface that was polished before further processing. Both, salt bath nitrocarburized and untreated surfaces, were subjected to oxygen containing gas mixture glow discharge in the same bath. The plasma pulse power supply generated 16.6 kHz pulses with 0.95% duty cycle at a temperature of 480(0)C and pressure of 400 Pa for 60 minutes. The thickness of compound surface layer was measured by calotest method, while optical microscopy and SEM analyses were used to investigate the modified surface zone structure and morphology. The phase composition of obtained surface structure was analyzed by XRD. It was found that the salt bath treatment may produce the single epsilon phase or the single gamma zone on the plain carbon steel specimens depending on the active species concentration in the salt bath. The oxide layer phase formed depends on the applied surface pretreatment.
T2  - Materials Science Forum
T1  - Plasma oxidation of salt bath nitrided C 15 steel samples
VL  - 453-454
SP  - 61
EP  - 66
DO  - 10.4028/www.scientific.net/MSF.453-454.61
ER  - 
@article{
author = "Zlatanovic, M and Popovic, N and Bogdanov, Žarko and Kunosic, A",
year = "2004",
abstract = "Quenched and tempered samples made of plain carbon steel C 15 were salt bath nitrided at 580(0)C for 210 minutes and subsequently water quenched. The nitrided samples were half cut to obtain ail untreated surface that was polished before further processing. Both, salt bath nitrocarburized and untreated surfaces, were subjected to oxygen containing gas mixture glow discharge in the same bath. The plasma pulse power supply generated 16.6 kHz pulses with 0.95% duty cycle at a temperature of 480(0)C and pressure of 400 Pa for 60 minutes. The thickness of compound surface layer was measured by calotest method, while optical microscopy and SEM analyses were used to investigate the modified surface zone structure and morphology. The phase composition of obtained surface structure was analyzed by XRD. It was found that the salt bath treatment may produce the single epsilon phase or the single gamma zone on the plain carbon steel specimens depending on the active species concentration in the salt bath. The oxide layer phase formed depends on the applied surface pretreatment.",
journal = "Materials Science Forum",
title = "Plasma oxidation of salt bath nitrided C 15 steel samples",
volume = "453-454",
pages = "61-66",
doi = "10.4028/www.scientific.net/MSF.453-454.61"
}
Zlatanovic, M., Popovic, N., Bogdanov, Ž.,& Kunosic, A.. (2004). Plasma oxidation of salt bath nitrided C 15 steel samples. in Materials Science Forum, 453-454, 61-66.
https://doi.org/10.4028/www.scientific.net/MSF.453-454.61
Zlatanovic M, Popovic N, Bogdanov Ž, Kunosic A. Plasma oxidation of salt bath nitrided C 15 steel samples. in Materials Science Forum. 2004;453-454:61-66.
doi:10.4028/www.scientific.net/MSF.453-454.61 .
Zlatanovic, M, Popovic, N, Bogdanov, Žarko, Kunosic, A, "Plasma oxidation of salt bath nitrided C 15 steel samples" in Materials Science Forum, 453-454 (2004):61-66,
https://doi.org/10.4028/www.scientific.net/MSF.453-454.61 . .
1
1
1

Plasma post oxidation of nitrocarburized hot work steel samples

Zlatanovic, M; Popovic, N; Bogdanov, Žarko; Zlatanovic, S

(2004)

TY  - JOUR
AU  - Zlatanovic, M
AU  - Popovic, N
AU  - Bogdanov, Žarko
AU  - Zlatanovic, S
PY  - 2004
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/6403
AB  - Pulse plasma oxidation of untreated, salt bath nitrocarburized and plasma nitrided/nitrocarburized samples made of hot work steel grade H11 was investigated. A continuous multi-step plasma processing was performed consisting of a half an hour plasma nitriding at 520 degreesC followed by 3.5 h nitrocarburizing at the same temperature and by a subsequent post-oxidation in a low current density H2O glow discharge during 45 min at 450 degreesC. The salt bath nitrocarburizing was carried out at a temperature of 580 degreesC for 210 min and was followed by the oil quench. In order to compare the oxide layer growth on the base material and on the epsilon-Fe-2(N,C)(1-x) layer, the salt bath treated sample. was half cut and plasma post-oxidized in a 80% H2O-20% H-2 glow discharge for 45 min at the temperature of 480 degreesC. In plasma processing pulse power supply was used with 57 mus pulse duration and 3 mus pulse pause. The surface structures were analyzed by optical microscopy, SEM and XRD, while Vickers microhardness test was used for measuring the surface microhardness and microhardness distribution over the sample cross sections. On the nitrocarburized surfaces XRD analyses revealed the existence of a superficial magnetite oxide layer and the presence of a e phase and a small amount of gamma phase, while a hematite Fe2O3 layer was formed on untreated sample surface. (C) 2003 Elsevier B.V. All rights reserved.
T2  - Surface and Coatings Technology
T1  - Plasma post oxidation of nitrocarburized hot work steel samples
VL  - 177
SP  - 277
EP  - 283
DO  - 10.1016/j.surfcoat.2003.09.012
ER  - 
@article{
author = "Zlatanovic, M and Popovic, N and Bogdanov, Žarko and Zlatanovic, S",
year = "2004",
abstract = "Pulse plasma oxidation of untreated, salt bath nitrocarburized and plasma nitrided/nitrocarburized samples made of hot work steel grade H11 was investigated. A continuous multi-step plasma processing was performed consisting of a half an hour plasma nitriding at 520 degreesC followed by 3.5 h nitrocarburizing at the same temperature and by a subsequent post-oxidation in a low current density H2O glow discharge during 45 min at 450 degreesC. The salt bath nitrocarburizing was carried out at a temperature of 580 degreesC for 210 min and was followed by the oil quench. In order to compare the oxide layer growth on the base material and on the epsilon-Fe-2(N,C)(1-x) layer, the salt bath treated sample. was half cut and plasma post-oxidized in a 80% H2O-20% H-2 glow discharge for 45 min at the temperature of 480 degreesC. In plasma processing pulse power supply was used with 57 mus pulse duration and 3 mus pulse pause. The surface structures were analyzed by optical microscopy, SEM and XRD, while Vickers microhardness test was used for measuring the surface microhardness and microhardness distribution over the sample cross sections. On the nitrocarburized surfaces XRD analyses revealed the existence of a superficial magnetite oxide layer and the presence of a e phase and a small amount of gamma phase, while a hematite Fe2O3 layer was formed on untreated sample surface. (C) 2003 Elsevier B.V. All rights reserved.",
journal = "Surface and Coatings Technology",
title = "Plasma post oxidation of nitrocarburized hot work steel samples",
volume = "177",
pages = "277-283",
doi = "10.1016/j.surfcoat.2003.09.012"
}
Zlatanovic, M., Popovic, N., Bogdanov, Ž.,& Zlatanovic, S.. (2004). Plasma post oxidation of nitrocarburized hot work steel samples. in Surface and Coatings Technology, 177, 277-283.
https://doi.org/10.1016/j.surfcoat.2003.09.012
Zlatanovic M, Popovic N, Bogdanov Ž, Zlatanovic S. Plasma post oxidation of nitrocarburized hot work steel samples. in Surface and Coatings Technology. 2004;177:277-283.
doi:10.1016/j.surfcoat.2003.09.012 .
Zlatanovic, M, Popovic, N, Bogdanov, Žarko, Zlatanovic, S, "Plasma post oxidation of nitrocarburized hot work steel samples" in Surface and Coatings Technology, 177 (2004):277-283,
https://doi.org/10.1016/j.surfcoat.2003.09.012 . .
24
29
36

Formation of magnetite overlayer on nitrocarburized low-alloy steel by plasma postoxidation

Zlantanovic, M; Popovic, N; Bogdanov, Žarko

(2004)

TY  - JOUR
AU  - Zlantanovic, M
AU  - Popovic, N
AU  - Bogdanov, Žarko
PY  - 2004
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/6483
AB  - Duplex surface treatments of steel products are known to enhance fatigue strength, tribological properties, and corrosion resistance. In combined nitriding/coating deposition or nitriding/oxidation processes, a precise control of all steps of process parameters is necessary to get the required surface architecture. The process parameters are specific for different steel grades, which require detailed investigations and surface treatment of different steel-grade workpieces in separate charges. The samples made of steel grades AISI C 1045, 4140, and H 11 were salt bath and pulse plasma-nitrided, and untreated and surface treated samples were plasma-postoxidized. The Vickerss method was used for surface microhardness and depth profiling measurements, while the microstructure and surface zone morphology were examined by optical microscopy and scanning electron microscopy (SEM). The surface zone phase composition was analyzed by X-ray diffraction (XRD) method using CuKalpha radiation, and ball-grinding technique was used to measure the compound zone thickness. It was demonstrated that a low-friction, chemically stable, single-phase magnetite Fe3O4 superficial layer can be formed by plasma postoxidation of various steel-grade substrates in the same batch. Based on experiments performed on different steel-grade substrates, a source drain model was proposed to predict the phase composition of nitrided and postoxidized selected steel-grade samples. (C) 2004 Elsevier B.V. All rights reserved.
T2  - Surface and Coatings Technology
T1  - Formation of magnetite overlayer on nitrocarburized low-alloy steel by plasma postoxidation
VL  - 188
SP  - 307
EP  - 313
DO  - 10.1016/j.surfcoat.2004.08.049
ER  - 
@article{
author = "Zlantanovic, M and Popovic, N and Bogdanov, Žarko",
year = "2004",
abstract = "Duplex surface treatments of steel products are known to enhance fatigue strength, tribological properties, and corrosion resistance. In combined nitriding/coating deposition or nitriding/oxidation processes, a precise control of all steps of process parameters is necessary to get the required surface architecture. The process parameters are specific for different steel grades, which require detailed investigations and surface treatment of different steel-grade workpieces in separate charges. The samples made of steel grades AISI C 1045, 4140, and H 11 were salt bath and pulse plasma-nitrided, and untreated and surface treated samples were plasma-postoxidized. The Vickerss method was used for surface microhardness and depth profiling measurements, while the microstructure and surface zone morphology were examined by optical microscopy and scanning electron microscopy (SEM). The surface zone phase composition was analyzed by X-ray diffraction (XRD) method using CuKalpha radiation, and ball-grinding technique was used to measure the compound zone thickness. It was demonstrated that a low-friction, chemically stable, single-phase magnetite Fe3O4 superficial layer can be formed by plasma postoxidation of various steel-grade substrates in the same batch. Based on experiments performed on different steel-grade substrates, a source drain model was proposed to predict the phase composition of nitrided and postoxidized selected steel-grade samples. (C) 2004 Elsevier B.V. All rights reserved.",
journal = "Surface and Coatings Technology",
title = "Formation of magnetite overlayer on nitrocarburized low-alloy steel by plasma postoxidation",
volume = "188",
pages = "307-313",
doi = "10.1016/j.surfcoat.2004.08.049"
}
Zlantanovic, M., Popovic, N.,& Bogdanov, Ž.. (2004). Formation of magnetite overlayer on nitrocarburized low-alloy steel by plasma postoxidation. in Surface and Coatings Technology, 188, 307-313.
https://doi.org/10.1016/j.surfcoat.2004.08.049
Zlantanovic M, Popovic N, Bogdanov Ž. Formation of magnetite overlayer on nitrocarburized low-alloy steel by plasma postoxidation. in Surface and Coatings Technology. 2004;188:307-313.
doi:10.1016/j.surfcoat.2004.08.049 .
Zlantanovic, M, Popovic, N, Bogdanov, Žarko, "Formation of magnetite overlayer on nitrocarburized low-alloy steel by plasma postoxidation" in Surface and Coatings Technology, 188 (2004):307-313,
https://doi.org/10.1016/j.surfcoat.2004.08.049 . .
5
8

Low-energy broad-beam sputter deposition of TiNx thin films

Goncić, Bratislav; Popovic, N; Bogdanov, Žarko; Zec, Slavica; Zlatanovic, M

(2003)

TY  - JOUR
AU  - Goncić, Bratislav
AU  - Popovic, N
AU  - Bogdanov, Žarko
AU  - Zec, Slavica
AU  - Zlatanovic, M
PY  - 2003
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/6350
AB  - The method and parameters of TiN film deposition processes are of dominant influence on the film growth microstructure and its physical properties. One of the PVD methods is the low energy ion beam reactive sputter deposition that offers the changes in the film properties by means of changing the beam parameters such as energy, divergence and current density. In this work, a laboratory made, broad beam, argon ion source was used for the reactive sputter deposition of TiN, thin films onto the glass substrates at ambient temperature. At constant argon beam energy (2keV), partial pressure of nitrogen (up to 6.6x10(-6) mbar), the substrate ion current and residual gas pressure were changed. The film deposition rate and thickness were controlled in situ by means of a light sensitive device placed on the rear side of the glass substrate. The physical properties of films: color, electrical resistivity and grain size, were correlated with the deposition parameters. High energy ion bombardment of growing film, relatively small ion to atom flux ratio up to 0.04, and low working pressure of 10(-5) mbar enabled the formation of a strong (220) preferred orientation rarely obtained for TiNx thin films.
T2  - Materials Science Forum
T1  - Low-energy broad-beam sputter deposition of TiNx thin films
VL  - 413
SP  - 159
EP  - 164
UR  - https://hdl.handle.net/21.15107/rcub_vinar_6350
ER  - 
@article{
author = "Goncić, Bratislav and Popovic, N and Bogdanov, Žarko and Zec, Slavica and Zlatanovic, M",
year = "2003",
abstract = "The method and parameters of TiN film deposition processes are of dominant influence on the film growth microstructure and its physical properties. One of the PVD methods is the low energy ion beam reactive sputter deposition that offers the changes in the film properties by means of changing the beam parameters such as energy, divergence and current density. In this work, a laboratory made, broad beam, argon ion source was used for the reactive sputter deposition of TiN, thin films onto the glass substrates at ambient temperature. At constant argon beam energy (2keV), partial pressure of nitrogen (up to 6.6x10(-6) mbar), the substrate ion current and residual gas pressure were changed. The film deposition rate and thickness were controlled in situ by means of a light sensitive device placed on the rear side of the glass substrate. The physical properties of films: color, electrical resistivity and grain size, were correlated with the deposition parameters. High energy ion bombardment of growing film, relatively small ion to atom flux ratio up to 0.04, and low working pressure of 10(-5) mbar enabled the formation of a strong (220) preferred orientation rarely obtained for TiNx thin films.",
journal = "Materials Science Forum",
title = "Low-energy broad-beam sputter deposition of TiNx thin films",
volume = "413",
pages = "159-164",
url = "https://hdl.handle.net/21.15107/rcub_vinar_6350"
}
Goncić, B., Popovic, N., Bogdanov, Ž., Zec, S.,& Zlatanovic, M.. (2003). Low-energy broad-beam sputter deposition of TiNx thin films. in Materials Science Forum, 413, 159-164.
https://hdl.handle.net/21.15107/rcub_vinar_6350
Goncić B, Popovic N, Bogdanov Ž, Zec S, Zlatanovic M. Low-energy broad-beam sputter deposition of TiNx thin films. in Materials Science Forum. 2003;413:159-164.
https://hdl.handle.net/21.15107/rcub_vinar_6350 .
Goncić, Bratislav, Popovic, N, Bogdanov, Žarko, Zec, Slavica, Zlatanovic, M, "Low-energy broad-beam sputter deposition of TiNx thin films" in Materials Science Forum, 413 (2003):159-164,
https://hdl.handle.net/21.15107/rcub_vinar_6350 .
3

Pulsed plasma-oxidation of nitrided steel samples

Zlatanovic, M; Popovic, N; Bogdanov, Žarko; Zlatanovic, S

(2003)

TY  - JOUR
AU  - Zlatanovic, M
AU  - Popovic, N
AU  - Bogdanov, Žarko
AU  - Zlatanovic, S
PY  - 2003
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/6382
AB  - Plasma nitrided/nitrocarburized samples made of steel grade DIN C15 were post oxidized in a mixtures of H-2 and O-2 gases using pulse power supply. Plasma nitrocarburizing post-oxidation were performed at 520 degreesC. The applied process is a combination of plasma nitriding, plasma nitrocarburizing and plasma-oxidation of the compound layer. Pulse plasma was used in all process steps at 5 kHz frequency and pause/pulse ratio 1:19. The XRD examination revealed the existence of the compound zone composed of of the gamma or gamma+ epsilon carbonitride phase with a thin overlayer of magnetite Fe3O4. The architecture of formed surface structure provides the unique mechanical and tribological properties with the diffusion zone responsible for load bearing capacity, wear and fatigue resistance and the double compound layer resistant to wear and corrosion. The results of Vickers microhardness measurements, optical microscopy, XRD and SEM analyses were presented. The obtained surface structures were compared with the samples salt bath nitrided in a conventional industrial unit. (C) 2003 Elsevier Science B.V. All rights reserved.
T2  - Surface and Coatings Technology
T1  - Pulsed plasma-oxidation of nitrided steel samples
VL  - 174
SP  - 1220
EP  - 1224
DO  - 10.1016/S0257-8972(03)00590-5
ER  - 
@article{
author = "Zlatanovic, M and Popovic, N and Bogdanov, Žarko and Zlatanovic, S",
year = "2003",
abstract = "Plasma nitrided/nitrocarburized samples made of steel grade DIN C15 were post oxidized in a mixtures of H-2 and O-2 gases using pulse power supply. Plasma nitrocarburizing post-oxidation were performed at 520 degreesC. The applied process is a combination of plasma nitriding, plasma nitrocarburizing and plasma-oxidation of the compound layer. Pulse plasma was used in all process steps at 5 kHz frequency and pause/pulse ratio 1:19. The XRD examination revealed the existence of the compound zone composed of of the gamma or gamma+ epsilon carbonitride phase with a thin overlayer of magnetite Fe3O4. The architecture of formed surface structure provides the unique mechanical and tribological properties with the diffusion zone responsible for load bearing capacity, wear and fatigue resistance and the double compound layer resistant to wear and corrosion. The results of Vickers microhardness measurements, optical microscopy, XRD and SEM analyses were presented. The obtained surface structures were compared with the samples salt bath nitrided in a conventional industrial unit. (C) 2003 Elsevier Science B.V. All rights reserved.",
journal = "Surface and Coatings Technology",
title = "Pulsed plasma-oxidation of nitrided steel samples",
volume = "174",
pages = "1220-1224",
doi = "10.1016/S0257-8972(03)00590-5"
}
Zlatanovic, M., Popovic, N., Bogdanov, Ž.,& Zlatanovic, S.. (2003). Pulsed plasma-oxidation of nitrided steel samples. in Surface and Coatings Technology, 174, 1220-1224.
https://doi.org/10.1016/S0257-8972(03)00590-5
Zlatanovic M, Popovic N, Bogdanov Ž, Zlatanovic S. Pulsed plasma-oxidation of nitrided steel samples. in Surface and Coatings Technology. 2003;174:1220-1224.
doi:10.1016/S0257-8972(03)00590-5 .
Zlatanovic, M, Popovic, N, Bogdanov, Žarko, Zlatanovic, S, "Pulsed plasma-oxidation of nitrided steel samples" in Surface and Coatings Technology, 174 (2003):1220-1224,
https://doi.org/10.1016/S0257-8972(03)00590-5 . .
16
18
24

The influence of ion bombardment intensity during deposition on nickel films microstructure

Popovic, N; Bogdanov, Žarko; Goncić, Bratislav; Zec, Slavica; Rakočević, Zlatko Lj.

(1999)

TY  - JOUR
AU  - Popovic, N
AU  - Bogdanov, Žarko
AU  - Goncić, Bratislav
AU  - Zec, Slavica
AU  - Rakočević, Zlatko Lj.
PY  - 1999
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/6271
AB  - Nickel films were deposited from a vapour phase (e-gun source) onto amorphous glass substrates at room temperature during a simultaneous bombardment with nitrogen ions at low pressure (4 x 10(-2) Pa). Under a constant partial pressure of nitrogen and negative substrate bias voltages the effect of bombardment intensity on the texture and morphology of Ni films (about 1 mu m) has been investigated by XRD and STM methods. The films under investigation exhibit a Variable degree of (200) preferred orientation by changing the ion to atom flux ratio (IAR) from 0.03 to 0.3. It was found that complete (200) texture was achieved for an IAR of about 0.1 and that further increase of IAR induces the decrease of preferred orientation. X-ray diffraction in combination with profiling by a 1 keV argon ion beam bombardment has been used for in depth texture and grain size analysis. It has been shown that oriented growth, grain size and morphology correlate with changes of bombardment intensity during the deposition as well as with the substrate bias potential. (C) 1999 Elsevier Science S.A. All rights reserved.
T2  - Thin Solid Films
T1  - The influence of ion bombardment intensity during deposition on nickel films microstructure
VL  - 343
SP  - 75
EP  - 80
DO  - 10.1016/S0040-6090(98)01578-8
ER  - 
@article{
author = "Popovic, N and Bogdanov, Žarko and Goncić, Bratislav and Zec, Slavica and Rakočević, Zlatko Lj.",
year = "1999",
abstract = "Nickel films were deposited from a vapour phase (e-gun source) onto amorphous glass substrates at room temperature during a simultaneous bombardment with nitrogen ions at low pressure (4 x 10(-2) Pa). Under a constant partial pressure of nitrogen and negative substrate bias voltages the effect of bombardment intensity on the texture and morphology of Ni films (about 1 mu m) has been investigated by XRD and STM methods. The films under investigation exhibit a Variable degree of (200) preferred orientation by changing the ion to atom flux ratio (IAR) from 0.03 to 0.3. It was found that complete (200) texture was achieved for an IAR of about 0.1 and that further increase of IAR induces the decrease of preferred orientation. X-ray diffraction in combination with profiling by a 1 keV argon ion beam bombardment has been used for in depth texture and grain size analysis. It has been shown that oriented growth, grain size and morphology correlate with changes of bombardment intensity during the deposition as well as with the substrate bias potential. (C) 1999 Elsevier Science S.A. All rights reserved.",
journal = "Thin Solid Films",
title = "The influence of ion bombardment intensity during deposition on nickel films microstructure",
volume = "343",
pages = "75-80",
doi = "10.1016/S0040-6090(98)01578-8"
}
Popovic, N., Bogdanov, Ž., Goncić, B., Zec, S.,& Rakočević, Z. Lj.. (1999). The influence of ion bombardment intensity during deposition on nickel films microstructure. in Thin Solid Films, 343, 75-80.
https://doi.org/10.1016/S0040-6090(98)01578-8
Popovic N, Bogdanov Ž, Goncić B, Zec S, Rakočević ZL. The influence of ion bombardment intensity during deposition on nickel films microstructure. in Thin Solid Films. 1999;343:75-80.
doi:10.1016/S0040-6090(98)01578-8 .
Popovic, N, Bogdanov, Žarko, Goncić, Bratislav, Zec, Slavica, Rakočević, Zlatko Lj., "The influence of ion bombardment intensity during deposition on nickel films microstructure" in Thin Solid Films, 343 (1999):75-80,
https://doi.org/10.1016/S0040-6090(98)01578-8 . .
12
14
14

Investigations of TiN films optical and mechanical characteristics

Zlatanovic, M; Sesum, D; Đukić, D; Popovic, N

(1998)

TY  - JOUR
AU  - Zlatanovic, M
AU  - Sesum, D
AU  - Đukić, D
AU  - Popovic, N
PY  - 1998
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/6245
AB  - The TiN films produced in different magnetron deposition systems (double magnetron and magnetron only) have shown variations in color, reflectivity and some mechanical characteristics as well as some changes induced by aging. STM, SEM, XRD analyses and reflectivity and ellipsometry measurements were performed in order to examine the correlation between the structural and optical coating properties.
T2  - Materials Science Forum
T1  - Investigations of TiN films optical and mechanical characteristics
VL  - 282-2
SP  - 139
EP  - 146
DO  - 10.4028/www.scientific.net/MSF.282-283.139
ER  - 
@article{
author = "Zlatanovic, M and Sesum, D and Đukić, D and Popovic, N",
year = "1998",
abstract = "The TiN films produced in different magnetron deposition systems (double magnetron and magnetron only) have shown variations in color, reflectivity and some mechanical characteristics as well as some changes induced by aging. STM, SEM, XRD analyses and reflectivity and ellipsometry measurements were performed in order to examine the correlation between the structural and optical coating properties.",
journal = "Materials Science Forum",
title = "Investigations of TiN films optical and mechanical characteristics",
volume = "282-2",
pages = "139-146",
doi = "10.4028/www.scientific.net/MSF.282-283.139"
}
Zlatanovic, M., Sesum, D., Đukić, D.,& Popovic, N.. (1998). Investigations of TiN films optical and mechanical characteristics. in Materials Science Forum, 282-2, 139-146.
https://doi.org/10.4028/www.scientific.net/MSF.282-283.139
Zlatanovic M, Sesum D, Đukić D, Popovic N. Investigations of TiN films optical and mechanical characteristics. in Materials Science Forum. 1998;282-2:139-146.
doi:10.4028/www.scientific.net/MSF.282-283.139 .
Zlatanovic, M, Sesum, D, Đukić, D, Popovic, N, "Investigations of TiN films optical and mechanical characteristics" in Materials Science Forum, 282-2 (1998):139-146,
https://doi.org/10.4028/www.scientific.net/MSF.282-283.139 . .
2
3
3

Mechanical and microstructural changes of magnetron sputtered TiN films with various magnetic field configurations

Zlatanovic, M; Belosevac, R; Popovic, N; Kunosic, A

(1998)

TY  - JOUR
AU  - Zlatanovic, M
AU  - Belosevac, R
AU  - Popovic, N
AU  - Kunosic, A
PY  - 1998
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/2193
AB  - TiN coatings were deposited in a single magnetron sputter ion plating system in balanced and unbalanced mode with a closed magnetic field configuration. The film microhardness, thickness, adhesion, microstructure, preferred orientation and topography were analyzed as a function of the substrate position inside the deposition volume. In the static deposition mode and under the limitations of the experimental set-up used, no real homogeneous deposition conditions were achieved, but a significant possibility of controlling the spatial distribution of deposition conditions was demonstrated. The variation of the coating microhardness over the target-to-substrate distance, d(S-T), ranging from about 80 to 210 mm was acceptable for practical applications, while the critical load for adhesive failure was found to decrease significantly with increasing d(S-T) in a balanced magnetron configuration. The variation of magnetic field configuration provided a relatively homogeneous distribution of the bias current density over the deposition volume, but the preferred orientation of the coating was changed from (200) to (111) with increasing d(S-T). The energy delivered per unit volume of growing film, S-E, and bombarding ion to deposited metal atom flux ratio j(i)/j(m) were considered. It was found that j(i)/j(m) can be used to describe qualitatively the change of preferred crystalline orientation of coatings. (C) 1998 Elsevier Science S.A.
T2  - Surface and Coatings Technology
T1  - Mechanical and microstructural changes of magnetron sputtered TiN films with various magnetic field configurations
VL  - 106
IS  - 2-3
SP  - 150
EP  - 155
DO  - 10.1016/S0257-8972(98)00509-X
ER  - 
@article{
author = "Zlatanovic, M and Belosevac, R and Popovic, N and Kunosic, A",
year = "1998",
abstract = "TiN coatings were deposited in a single magnetron sputter ion plating system in balanced and unbalanced mode with a closed magnetic field configuration. The film microhardness, thickness, adhesion, microstructure, preferred orientation and topography were analyzed as a function of the substrate position inside the deposition volume. In the static deposition mode and under the limitations of the experimental set-up used, no real homogeneous deposition conditions were achieved, but a significant possibility of controlling the spatial distribution of deposition conditions was demonstrated. The variation of the coating microhardness over the target-to-substrate distance, d(S-T), ranging from about 80 to 210 mm was acceptable for practical applications, while the critical load for adhesive failure was found to decrease significantly with increasing d(S-T) in a balanced magnetron configuration. The variation of magnetic field configuration provided a relatively homogeneous distribution of the bias current density over the deposition volume, but the preferred orientation of the coating was changed from (200) to (111) with increasing d(S-T). The energy delivered per unit volume of growing film, S-E, and bombarding ion to deposited metal atom flux ratio j(i)/j(m) were considered. It was found that j(i)/j(m) can be used to describe qualitatively the change of preferred crystalline orientation of coatings. (C) 1998 Elsevier Science S.A.",
journal = "Surface and Coatings Technology",
title = "Mechanical and microstructural changes of magnetron sputtered TiN films with various magnetic field configurations",
volume = "106",
number = "2-3",
pages = "150-155",
doi = "10.1016/S0257-8972(98)00509-X"
}
Zlatanovic, M., Belosevac, R., Popovic, N.,& Kunosic, A.. (1998). Mechanical and microstructural changes of magnetron sputtered TiN films with various magnetic field configurations. in Surface and Coatings Technology, 106(2-3), 150-155.
https://doi.org/10.1016/S0257-8972(98)00509-X
Zlatanovic M, Belosevac R, Popovic N, Kunosic A. Mechanical and microstructural changes of magnetron sputtered TiN films with various magnetic field configurations. in Surface and Coatings Technology. 1998;106(2-3):150-155.
doi:10.1016/S0257-8972(98)00509-X .
Zlatanovic, M, Belosevac, R, Popovic, N, Kunosic, A, "Mechanical and microstructural changes of magnetron sputtered TiN films with various magnetic field configurations" in Surface and Coatings Technology, 106, no. 2-3 (1998):150-155,
https://doi.org/10.1016/S0257-8972(98)00509-X . .
7
10
11

Microstructural modification of TiN deposited by magnetron ion plating: Influence of magnetic field configuration

Zlatanovic, M; Popovic, N; Bogdanov, Žarko; Belosevac, R; Kunosic, A; Goncić, Bratislav

(1998)

TY  - JOUR
AU  - Zlatanovic, M
AU  - Popovic, N
AU  - Bogdanov, Žarko
AU  - Belosevac, R
AU  - Kunosic, A
AU  - Goncić, Bratislav
PY  - 1998
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/6235
AB  - Three operating modes of a single magnetron were used during deposition processes: balanced magnetron configuration with no external magnetic field and no bias potential applied (magnetron only), balanced magnetron configuration with permanent magnet cages positioned around the deposition volume to form a closed field configuration (BM mode) and an unbalanced magnetron closed field configuration (UBM mode). The influence of the deposition rate and ion j(i) to deposited metal atom j(m) flux ratio j(i)/j(m) at the substrate surface on the texture evolution was discussed. The deposition rate distribution over the target to substrate distance was found to depend on magnetic field configuration and also to be different in metallic and reactive mode. In UBM mode it was possible to obtain nearly constant bias current density along the deposition volume at the constant bias potential. The preferred crystalline orientation was changed from (200) to (111) by increasing target to substrate distance in both BM and UBM modes, while the film deposited in magnetron-only configuration preserved (111) texture. (C) 1998 Elsevier Science S.A.
T2  - Thin Solid Films
T1  - Microstructural modification of TiN deposited by magnetron ion plating: Influence of magnetic field configuration
VL  - 317
IS  - 1-2
SP  - 463
EP  - 467
DO  - 10.1016/S0040-6090(97)00557-9
ER  - 
@article{
author = "Zlatanovic, M and Popovic, N and Bogdanov, Žarko and Belosevac, R and Kunosic, A and Goncić, Bratislav",
year = "1998",
abstract = "Three operating modes of a single magnetron were used during deposition processes: balanced magnetron configuration with no external magnetic field and no bias potential applied (magnetron only), balanced magnetron configuration with permanent magnet cages positioned around the deposition volume to form a closed field configuration (BM mode) and an unbalanced magnetron closed field configuration (UBM mode). The influence of the deposition rate and ion j(i) to deposited metal atom j(m) flux ratio j(i)/j(m) at the substrate surface on the texture evolution was discussed. The deposition rate distribution over the target to substrate distance was found to depend on magnetic field configuration and also to be different in metallic and reactive mode. In UBM mode it was possible to obtain nearly constant bias current density along the deposition volume at the constant bias potential. The preferred crystalline orientation was changed from (200) to (111) by increasing target to substrate distance in both BM and UBM modes, while the film deposited in magnetron-only configuration preserved (111) texture. (C) 1998 Elsevier Science S.A.",
journal = "Thin Solid Films",
title = "Microstructural modification of TiN deposited by magnetron ion plating: Influence of magnetic field configuration",
volume = "317",
number = "1-2",
pages = "463-467",
doi = "10.1016/S0040-6090(97)00557-9"
}
Zlatanovic, M., Popovic, N., Bogdanov, Ž., Belosevac, R., Kunosic, A.,& Goncić, B.. (1998). Microstructural modification of TiN deposited by magnetron ion plating: Influence of magnetic field configuration. in Thin Solid Films, 317(1-2), 463-467.
https://doi.org/10.1016/S0040-6090(97)00557-9
Zlatanovic M, Popovic N, Bogdanov Ž, Belosevac R, Kunosic A, Goncić B. Microstructural modification of TiN deposited by magnetron ion plating: Influence of magnetic field configuration. in Thin Solid Films. 1998;317(1-2):463-467.
doi:10.1016/S0040-6090(97)00557-9 .
Zlatanovic, M, Popovic, N, Bogdanov, Žarko, Belosevac, R, Kunosic, A, Goncić, Bratislav, "Microstructural modification of TiN deposited by magnetron ion plating: Influence of magnetic field configuration" in Thin Solid Films, 317, no. 1-2 (1998):463-467,
https://doi.org/10.1016/S0040-6090(97)00557-9 . .
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Nickel film orientation change by nitrogen ion bombardment during deposition

Popovic, N; Dimitrijevic, T; Bogdanov, Žarko; Goncić, Bratislav; Štrbac, Svetlana; Rakočević, Zlatko Lj.

(1997)

TY  - JOUR
AU  - Popovic, N
AU  - Dimitrijevic, T
AU  - Bogdanov, Žarko
AU  - Goncić, Bratislav
AU  - Štrbac, Svetlana
AU  - Rakočević, Zlatko Lj.
PY  - 1997
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/6226
AB  - The influence of nitrogen ion bombardment during e-beam triode ion plating of nickel on the microstructure and film orientation has been investigated. The deposition variables explored were the ion current density and deposition rate while the substrate temperature (ambient), partial pressure of nitrogen (3 x 10(-4) Torr) and substrate bias potential (4.5kV) were constant. The orientation and growth morphology change for films about 1 mu m thick were determined by XRD, SEM and STM method. The preferred orientation changes from (111) to nearly complete (200) as a function of ion to atom arrival ratio (IAR), and was independent of the substrate type (amorphous or monocrystalline). The ion beam bombardment of films after deposition enables the in depth determination of the nickel texture change during growth. For the highest IAR value the complete (200) texture was achieved at the beginning of deposition. The surface morphology (STM) and preferred orientation changes were correlated with ion to atom flux ratio and discussed on the basis of lowering the overall energy of the film. (C) 1997 Elsevier Science Ltd.
T2  - Vacuum
T1  - Nickel film orientation change by nitrogen ion bombardment during deposition
VL  - 48
IS  - 7-9
SP  - 705
EP  - 708
DO  - 10.1016/S0042-207X(97)00035-3
ER  - 
@article{
author = "Popovic, N and Dimitrijevic, T and Bogdanov, Žarko and Goncić, Bratislav and Štrbac, Svetlana and Rakočević, Zlatko Lj.",
year = "1997",
abstract = "The influence of nitrogen ion bombardment during e-beam triode ion plating of nickel on the microstructure and film orientation has been investigated. The deposition variables explored were the ion current density and deposition rate while the substrate temperature (ambient), partial pressure of nitrogen (3 x 10(-4) Torr) and substrate bias potential (4.5kV) were constant. The orientation and growth morphology change for films about 1 mu m thick were determined by XRD, SEM and STM method. The preferred orientation changes from (111) to nearly complete (200) as a function of ion to atom arrival ratio (IAR), and was independent of the substrate type (amorphous or monocrystalline). The ion beam bombardment of films after deposition enables the in depth determination of the nickel texture change during growth. For the highest IAR value the complete (200) texture was achieved at the beginning of deposition. The surface morphology (STM) and preferred orientation changes were correlated with ion to atom flux ratio and discussed on the basis of lowering the overall energy of the film. (C) 1997 Elsevier Science Ltd.",
journal = "Vacuum",
title = "Nickel film orientation change by nitrogen ion bombardment during deposition",
volume = "48",
number = "7-9",
pages = "705-708",
doi = "10.1016/S0042-207X(97)00035-3"
}
Popovic, N., Dimitrijevic, T., Bogdanov, Ž., Goncić, B., Štrbac, S.,& Rakočević, Z. Lj.. (1997). Nickel film orientation change by nitrogen ion bombardment during deposition. in Vacuum, 48(7-9), 705-708.
https://doi.org/10.1016/S0042-207X(97)00035-3
Popovic N, Dimitrijevic T, Bogdanov Ž, Goncić B, Štrbac S, Rakočević ZL. Nickel film orientation change by nitrogen ion bombardment during deposition. in Vacuum. 1997;48(7-9):705-708.
doi:10.1016/S0042-207X(97)00035-3 .
Popovic, N, Dimitrijevic, T, Bogdanov, Žarko, Goncić, Bratislav, Štrbac, Svetlana, Rakočević, Zlatko Lj., "Nickel film orientation change by nitrogen ion bombardment during deposition" in Vacuum, 48, no. 7-9 (1997):705-708,
https://doi.org/10.1016/S0042-207X(97)00035-3 . .
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