Structural and electrical properties of ferroelectric poly(vinylidene fluoride) and mechanically activated ZnO nanoparticle composite films
Authors
Peleš, AdrianaAleksić, Obrad S.
Pavlović, Vera P.
Đoković, Vladimir
Dojčilović, Radovan
Nikolić, Zoran M.
Marinković, Filip S.
Mitrić, Miodrag
Blagojević, Vladimir D.
Vlahović, Branislav
Pavlović, Vladimir B.
Article (Published version)
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The influence of the mechanical activation of ZnO nanoparticle fillers on the structural and electrical properties of the matrix of poly(vinylidenefluoride)-ZnO (PVDF-ZnO) films was investigated. Transmission electron microscopy and scanning electron microscopy analyses showed that mechanical activation in a high energy planetary ball mill reduces the size of ZnO particles. X-ray diffraction and Raman spectroscopy revealed that PVDF crystallized predominantly as the γ-phase. Non-activated ZnO filler reduces the degree of the crystallinity of the matrix and promotes crystallization of α-phase of PVDF in the film, while the fillers activated for 5 and 10 min induce crystallization of β-phase, indicating that mechanical activation of the filler can be used as a general method for fabrication of PVDF composites with increased content of piezoelectric β-phase crystals. Dielectric spectroscopy measurements show that polymer composite with the high content of β-phase (with ZnO filler activate...d for 5 min) exhibits the highest value of dielectric permittivity in 150-400 K range of temperatures. Kinetic analysis shows combined effects of increased surface area and increased concentration of surface defects on the interactions between polymer chains and activated nanoparticles. © 2018 IOP Publishing Ltd.
Keywords:
polymer composites / mechanical activation / crystallization / dielectric properties / PVDF / ZnOSource:
Physica Scripta, 2018, 93, 10, 105801-Funding / projects:
- Size-, shape- and structure- dependent properties of nanoparticles and nanocomposites (RS-MESTD-Basic Research (BR or ON)-172056)
- Directed synthesis, structure and properties of multifunctional materials (RS-MESTD-Basic Research (BR or ON)-172057)
- Materials of Reduced Dimensions for Efficient Light Harvesting and Energy conversion (RS-MESTD-Integrated and Interdisciplinary Research (IIR or III)-45020)
- NSF CREST (HRD-0833184)
- NASA (NNX09AV07A)
DOI: 10.1088/1402-4896/aad749
ISSN: 0031-8949; 1402-4896
WoS: 000442645300001
Scopus: 2-s2.0-85054040483
URI
http://stacks.iop.org/1402-4896/93/i=10/a=105801?key=crossref.54536d8babe95dbc820e50211f592252https://vinar.vin.bg.ac.rs/handle/123456789/7898
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VinčaTY - JOUR AU - Peleš, Adriana AU - Aleksić, Obrad S. AU - Pavlović, Vera P. AU - Đoković, Vladimir AU - Dojčilović, Radovan AU - Nikolić, Zoran M. AU - Marinković, Filip S. AU - Mitrić, Miodrag AU - Blagojević, Vladimir D. AU - Vlahović, Branislav AU - Pavlović, Vladimir B. PY - 2018 UR - http://stacks.iop.org/1402-4896/93/i=10/a=105801?key=crossref.54536d8babe95dbc820e50211f592252 UR - https://vinar.vin.bg.ac.rs/handle/123456789/7898 AB - The influence of the mechanical activation of ZnO nanoparticle fillers on the structural and electrical properties of the matrix of poly(vinylidenefluoride)-ZnO (PVDF-ZnO) films was investigated. Transmission electron microscopy and scanning electron microscopy analyses showed that mechanical activation in a high energy planetary ball mill reduces the size of ZnO particles. X-ray diffraction and Raman spectroscopy revealed that PVDF crystallized predominantly as the γ-phase. Non-activated ZnO filler reduces the degree of the crystallinity of the matrix and promotes crystallization of α-phase of PVDF in the film, while the fillers activated for 5 and 10 min induce crystallization of β-phase, indicating that mechanical activation of the filler can be used as a general method for fabrication of PVDF composites with increased content of piezoelectric β-phase crystals. Dielectric spectroscopy measurements show that polymer composite with the high content of β-phase (with ZnO filler activated for 5 min) exhibits the highest value of dielectric permittivity in 150-400 K range of temperatures. Kinetic analysis shows combined effects of increased surface area and increased concentration of surface defects on the interactions between polymer chains and activated nanoparticles. © 2018 IOP Publishing Ltd. T2 - Physica Scripta T1 - Structural and electrical properties of ferroelectric poly(vinylidene fluoride) and mechanically activated ZnO nanoparticle composite films VL - 93 IS - 10 SP - 105801 DO - 10.1088/1402-4896/aad749 ER -
@article{ author = "Peleš, Adriana and Aleksić, Obrad S. and Pavlović, Vera P. and Đoković, Vladimir and Dojčilović, Radovan and Nikolić, Zoran M. and Marinković, Filip S. and Mitrić, Miodrag and Blagojević, Vladimir D. and Vlahović, Branislav and Pavlović, Vladimir B.", year = "2018", abstract = "The influence of the mechanical activation of ZnO nanoparticle fillers on the structural and electrical properties of the matrix of poly(vinylidenefluoride)-ZnO (PVDF-ZnO) films was investigated. Transmission electron microscopy and scanning electron microscopy analyses showed that mechanical activation in a high energy planetary ball mill reduces the size of ZnO particles. X-ray diffraction and Raman spectroscopy revealed that PVDF crystallized predominantly as the γ-phase. Non-activated ZnO filler reduces the degree of the crystallinity of the matrix and promotes crystallization of α-phase of PVDF in the film, while the fillers activated for 5 and 10 min induce crystallization of β-phase, indicating that mechanical activation of the filler can be used as a general method for fabrication of PVDF composites with increased content of piezoelectric β-phase crystals. Dielectric spectroscopy measurements show that polymer composite with the high content of β-phase (with ZnO filler activated for 5 min) exhibits the highest value of dielectric permittivity in 150-400 K range of temperatures. Kinetic analysis shows combined effects of increased surface area and increased concentration of surface defects on the interactions between polymer chains and activated nanoparticles. © 2018 IOP Publishing Ltd.", journal = "Physica Scripta", title = "Structural and electrical properties of ferroelectric poly(vinylidene fluoride) and mechanically activated ZnO nanoparticle composite films", volume = "93", number = "10", pages = "105801", doi = "10.1088/1402-4896/aad749" }
Peleš, A., Aleksić, O. S., Pavlović, V. P., Đoković, V., Dojčilović, R., Nikolić, Z. M., Marinković, F. S., Mitrić, M., Blagojević, V. D., Vlahović, B.,& Pavlović, V. B.. (2018). Structural and electrical properties of ferroelectric poly(vinylidene fluoride) and mechanically activated ZnO nanoparticle composite films. in Physica Scripta, 93(10), 105801. https://doi.org/10.1088/1402-4896/aad749
Peleš A, Aleksić OS, Pavlović VP, Đoković V, Dojčilović R, Nikolić ZM, Marinković FS, Mitrić M, Blagojević VD, Vlahović B, Pavlović VB. Structural and electrical properties of ferroelectric poly(vinylidene fluoride) and mechanically activated ZnO nanoparticle composite films. in Physica Scripta. 2018;93(10):105801. doi:10.1088/1402-4896/aad749 .
Peleš, Adriana, Aleksić, Obrad S., Pavlović, Vera P., Đoković, Vladimir, Dojčilović, Radovan, Nikolić, Zoran M., Marinković, Filip S., Mitrić, Miodrag, Blagojević, Vladimir D., Vlahović, Branislav, Pavlović, Vladimir B., "Structural and electrical properties of ferroelectric poly(vinylidene fluoride) and mechanically activated ZnO nanoparticle composite films" in Physica Scripta, 93, no. 10 (2018):105801, https://doi.org/10.1088/1402-4896/aad749 . .