Synthesis and structure of aquamethanol-2,2-(2,6-pyridin-diyldiethylidene)-dioxamohydrazidocobalt(II) perchlorate
Abstract
The complex [Co(H(2)L)(H2O) (MeOH)](ClO4)(2)[H(2)L] = 2,2triple prime-(2,6-pyridindiyl-diethylidene) -dioxamohydrazide] has been prepared by direct and template syntheses and characterized by elemental analysis, IR spectroscopy, and magnetic susceptibility measurements. The crystal structure of the complex has also been determined. The cobalt atom is seven coordinated with approximately pentagonal-bipyramidal geometry. The H2O and methanol are axial with the planar pentadentate H(2)L ligand forming the equatorial plane. The possible reaction mechanism has been proposed.
Keywords:
cobalt(II) complex / 2,6-diacetylpyridine derivative / open chain ligand / crystal structure / pentagonal-bipyramidal geometry / IR spectraSource:
Polyhedron, 1996, 15, 24, 4361-4366Funding / projects:
- Ministry for Science and Technology of the Republic of Serbia
DOI: 10.1016/0277-5387(96)00234-3
ISSN: 0277-5387
WoS: A1996VM01700006
Scopus: 2-s2.0-0000316928
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VinčaTY - JOUR AU - Anđelković, Katarina AU - Ivanović, Ivana AU - Prelesnik, Bogdan V. AU - Leovac, Vukadin M. AU - Poleti, Dejan PY - 1996 UR - https://vinar.vin.bg.ac.rs/handle/123456789/2015 AB - The complex [Co(H(2)L)(H2O) (MeOH)](ClO4)(2)[H(2)L] = 2,2triple prime-(2,6-pyridindiyl-diethylidene) -dioxamohydrazide] has been prepared by direct and template syntheses and characterized by elemental analysis, IR spectroscopy, and magnetic susceptibility measurements. The crystal structure of the complex has also been determined. The cobalt atom is seven coordinated with approximately pentagonal-bipyramidal geometry. The H2O and methanol are axial with the planar pentadentate H(2)L ligand forming the equatorial plane. The possible reaction mechanism has been proposed. T2 - Polyhedron T1 - Synthesis and structure of aquamethanol-2,2-(2,6-pyridin-diyldiethylidene)-dioxamohydrazidocobalt(II) perchlorate VL - 15 IS - 24 SP - 4361 EP - 4366 DO - 10.1016/0277-5387(96)00234-3 ER -
@article{ author = "Anđelković, Katarina and Ivanović, Ivana and Prelesnik, Bogdan V. and Leovac, Vukadin M. and Poleti, Dejan", year = "1996", abstract = "The complex [Co(H(2)L)(H2O) (MeOH)](ClO4)(2)[H(2)L] = 2,2triple prime-(2,6-pyridindiyl-diethylidene) -dioxamohydrazide] has been prepared by direct and template syntheses and characterized by elemental analysis, IR spectroscopy, and magnetic susceptibility measurements. The crystal structure of the complex has also been determined. The cobalt atom is seven coordinated with approximately pentagonal-bipyramidal geometry. The H2O and methanol are axial with the planar pentadentate H(2)L ligand forming the equatorial plane. The possible reaction mechanism has been proposed.", journal = "Polyhedron", title = "Synthesis and structure of aquamethanol-2,2-(2,6-pyridin-diyldiethylidene)-dioxamohydrazidocobalt(II) perchlorate", volume = "15", number = "24", pages = "4361-4366", doi = "10.1016/0277-5387(96)00234-3" }
Anđelković, K., Ivanović, I., Prelesnik, B. V., Leovac, V. M.,& Poleti, D.. (1996). Synthesis and structure of aquamethanol-2,2-(2,6-pyridin-diyldiethylidene)-dioxamohydrazidocobalt(II) perchlorate. in Polyhedron, 15(24), 4361-4366. https://doi.org/10.1016/0277-5387(96)00234-3
Anđelković K, Ivanović I, Prelesnik BV, Leovac VM, Poleti D. Synthesis and structure of aquamethanol-2,2-(2,6-pyridin-diyldiethylidene)-dioxamohydrazidocobalt(II) perchlorate. in Polyhedron. 1996;15(24):4361-4366. doi:10.1016/0277-5387(96)00234-3 .
Anđelković, Katarina, Ivanović, Ivana, Prelesnik, Bogdan V., Leovac, Vukadin M., Poleti, Dejan, "Synthesis and structure of aquamethanol-2,2-(2,6-pyridin-diyldiethylidene)-dioxamohydrazidocobalt(II) perchlorate" in Polyhedron, 15, no. 24 (1996):4361-4366, https://doi.org/10.1016/0277-5387(96)00234-3 . .