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Influence of anode/filtration setup on X-ray multimeter energy response in mammography applications

Kojić, Andrea; Kržanović, Nikola; Živanović, Miloš; Toroi, Paula; Bakrač, Luka; Božović, Predrag; Stanković Petrović, Jelena

(2024)

TY  - JOUR
AU  - Kojić, Andrea
AU  - Kržanović, Nikola
AU  - Živanović, Miloš
AU  - Toroi, Paula
AU  - Bakrač, Luka
AU  - Božović, Predrag
AU  - Stanković Petrović, Jelena
PY  - 2024
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/13192
AB  - Quality control and assurance of mammography X-ray generators include usage of solid-state detectors and/or ionization chambers which are calibrated in standard reference radiation fields. IEC 61267:2005 standard defines reference mammography radiation fields for Mo/Mo anode/filtration, while various anode/filtration combinations are encountered in clinical mammography X-ray units. Not all Secondary Standard Dosimetry Laboratories have an X-ray generator with Mo/Mo radiation setup, thus traceability can be established only for the available anode/filter combinations which is commonly limited to W/Al. In this study, W/Al radiation fields were established under laboratory conditions by performing half-value layer measurements, and characterization of four solid-state detectors was performed. X-ray multimeter performance was evaluated in terms of energy response in the W/Al radiation fields. In the laboratory conditions the energy response of the dosimeters had larger deviation from unity for dosimeters without appropriate anode/filter combination selected in the software settings, even though most of the dosimeters had uniform relative response. Discrepancy in the response was further investigated by examining its variation induced by available detector software settings, and it was determined that the dosimeter response can vary up to 20 %. In clinical setup, half-value layer was determined, and detector performance was examined. Dosimeters were tested in clinical fields with Mo/Mo, Mo/Rh, W/Rh, W/Ag anode/filter combinations in the X-ray tube voltage range from 25 kV to 35 kV. For most clinical radiation fields, multi-element detectors had energy response deviation within ±5 %. The single-element detector had one software setting available and has exhibited strong energy dependence. Extensive testing of detector response such as presented in this paper allows for correction factor interpolation based on half-value layer.
T2  - Radiation Measurements
T1  - Influence of anode/filtration setup on X-ray multimeter energy response in mammography applications
IS  - InPress
SP  - 107135
DO  - 10.1016/j.radmeas.2024.107135
ER  - 
@article{
author = "Kojić, Andrea and Kržanović, Nikola and Živanović, Miloš and Toroi, Paula and Bakrač, Luka and Božović, Predrag and Stanković Petrović, Jelena",
year = "2024",
abstract = "Quality control and assurance of mammography X-ray generators include usage of solid-state detectors and/or ionization chambers which are calibrated in standard reference radiation fields. IEC 61267:2005 standard defines reference mammography radiation fields for Mo/Mo anode/filtration, while various anode/filtration combinations are encountered in clinical mammography X-ray units. Not all Secondary Standard Dosimetry Laboratories have an X-ray generator with Mo/Mo radiation setup, thus traceability can be established only for the available anode/filter combinations which is commonly limited to W/Al. In this study, W/Al radiation fields were established under laboratory conditions by performing half-value layer measurements, and characterization of four solid-state detectors was performed. X-ray multimeter performance was evaluated in terms of energy response in the W/Al radiation fields. In the laboratory conditions the energy response of the dosimeters had larger deviation from unity for dosimeters without appropriate anode/filter combination selected in the software settings, even though most of the dosimeters had uniform relative response. Discrepancy in the response was further investigated by examining its variation induced by available detector software settings, and it was determined that the dosimeter response can vary up to 20 %. In clinical setup, half-value layer was determined, and detector performance was examined. Dosimeters were tested in clinical fields with Mo/Mo, Mo/Rh, W/Rh, W/Ag anode/filter combinations in the X-ray tube voltage range from 25 kV to 35 kV. For most clinical radiation fields, multi-element detectors had energy response deviation within ±5 %. The single-element detector had one software setting available and has exhibited strong energy dependence. Extensive testing of detector response such as presented in this paper allows for correction factor interpolation based on half-value layer.",
journal = "Radiation Measurements",
title = "Influence of anode/filtration setup on X-ray multimeter energy response in mammography applications",
number = "InPress",
pages = "107135",
doi = "10.1016/j.radmeas.2024.107135"
}
Kojić, A., Kržanović, N., Živanović, M., Toroi, P., Bakrač, L., Božović, P.,& Stanković Petrović, J.. (2024). Influence of anode/filtration setup on X-ray multimeter energy response in mammography applications. in Radiation Measurements(InPress), 107135.
https://doi.org/10.1016/j.radmeas.2024.107135
Kojić A, Kržanović N, Živanović M, Toroi P, Bakrač L, Božović P, Stanković Petrović J. Influence of anode/filtration setup on X-ray multimeter energy response in mammography applications. in Radiation Measurements. 2024;(InPress):107135.
doi:10.1016/j.radmeas.2024.107135 .
Kojić, Andrea, Kržanović, Nikola, Živanović, Miloš, Toroi, Paula, Bakrač, Luka, Božović, Predrag, Stanković Petrović, Jelena, "Influence of anode/filtration setup on X-ray multimeter energy response in mammography applications" in Radiation Measurements, no. InPress (2024):107135,
https://doi.org/10.1016/j.radmeas.2024.107135 . .

Sustainable recovery of cobalt and lithium from lithium-ion battery cathode material by combining sulfate leachates and aqueous biphasic systems based on tetrabutylphosphonium-ionic liquids

Mušović, Jasmina; Tekić, Danijela; Marić, Slađana; Jocić, Ana; Stanković, Dalibor; Dimitrijević, Aleksandra

(2024)

TY  - JOUR
AU  - Mušović, Jasmina
AU  - Tekić, Danijela
AU  - Marić, Slađana
AU  - Jocić, Ana
AU  - Stanković, Dalibor
AU  - Dimitrijević, Aleksandra
PY  - 2024
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/13218
AB  - The consistent expansion of the lithium-ion battery (LIB) market, coupled with their relatively brief lifespan, necessitates the development of efficient and sustainable LIB recycling strategies. Recycling is crucial not only for the recovery of critical metals like Co(II) and Li(I) from the cathode material as a secondary resource but also from an environmental perspective. This study explores the use of a series of aqueous biphasic systems (ABS) with synthesized tetrabutylphosphonium ionic liquids (ILs) and ammonium sulfate as extraction platforms for metals from LIB cathode. Firstly, liquid–liquid equilibrium phase diagrams for each ABS were established, and partitioning experiments were conducted to assess the Co(II), Ni(II), Mn(II), and Li(I) recovery efficiencies. We observed distinct partitioning behaviors for the metals, with tetrabutylphosphonium diethylenetriaminepentaacetate, [TBP][DTPA], showing recovery efficiencies exceeding 98% for Co(II), Ni(II), and Mn(II). At the same time, Li(I) was predominantly retained in the aqueous salt-rich phase. By fine-tuning ABS operational parameters such as pH, temperature, system composition, and phase ratio, we identified optimal conditions for extracting metals from the cathode material of lithium-cobalt-oxide (LCO) batteries using sulfate lixiviate. Introducing [TBP][DTPA] after the leaching process induced ABS, achieving remarkable recovery efficiency over 95% for Co(II) in the IL-rich phase, with all Li(I) remaining in the lower phase. Cobalt was subsequently extracted using oxalic acid to precipitate as Co-oxalate from concentrate, while Li(I) was isolated from the aqueous phase using ammonium carbonate. After the “cleaning” of the IL-rich phase, the [TBP][DTPA] was recovered and reused in four consecutive cycles, with small detected losses on the recovery efficiency of Co(II) and Li(I). Therefore, our innovative strategy combines sulfate-based lixiviants with IL-ABS technology, thereby enhancing selectivity and sustainability within one of the most efficient lixiviant systems widely employed in the industry. This technological advancement presents a promising pathway for the recycling of spent batteries, offering substantial environmental advantages within the well-established and extensively utilized realm of metal recovery technology in the industry.
T2  - Separation and Purification Technology
T1  - Sustainable recovery of cobalt and lithium from lithium-ion battery cathode material by combining sulfate leachates and aqueous biphasic systems based on tetrabutylphosphonium-ionic liquids
VL  - 348
SP  - 127707
DO  - 10.1016/j.seppur.2024.127707
ER  - 
@article{
author = "Mušović, Jasmina and Tekić, Danijela and Marić, Slađana and Jocić, Ana and Stanković, Dalibor and Dimitrijević, Aleksandra",
year = "2024",
abstract = "The consistent expansion of the lithium-ion battery (LIB) market, coupled with their relatively brief lifespan, necessitates the development of efficient and sustainable LIB recycling strategies. Recycling is crucial not only for the recovery of critical metals like Co(II) and Li(I) from the cathode material as a secondary resource but also from an environmental perspective. This study explores the use of a series of aqueous biphasic systems (ABS) with synthesized tetrabutylphosphonium ionic liquids (ILs) and ammonium sulfate as extraction platforms for metals from LIB cathode. Firstly, liquid–liquid equilibrium phase diagrams for each ABS were established, and partitioning experiments were conducted to assess the Co(II), Ni(II), Mn(II), and Li(I) recovery efficiencies. We observed distinct partitioning behaviors for the metals, with tetrabutylphosphonium diethylenetriaminepentaacetate, [TBP][DTPA], showing recovery efficiencies exceeding 98% for Co(II), Ni(II), and Mn(II). At the same time, Li(I) was predominantly retained in the aqueous salt-rich phase. By fine-tuning ABS operational parameters such as pH, temperature, system composition, and phase ratio, we identified optimal conditions for extracting metals from the cathode material of lithium-cobalt-oxide (LCO) batteries using sulfate lixiviate. Introducing [TBP][DTPA] after the leaching process induced ABS, achieving remarkable recovery efficiency over 95% for Co(II) in the IL-rich phase, with all Li(I) remaining in the lower phase. Cobalt was subsequently extracted using oxalic acid to precipitate as Co-oxalate from concentrate, while Li(I) was isolated from the aqueous phase using ammonium carbonate. After the “cleaning” of the IL-rich phase, the [TBP][DTPA] was recovered and reused in four consecutive cycles, with small detected losses on the recovery efficiency of Co(II) and Li(I). Therefore, our innovative strategy combines sulfate-based lixiviants with IL-ABS technology, thereby enhancing selectivity and sustainability within one of the most efficient lixiviant systems widely employed in the industry. This technological advancement presents a promising pathway for the recycling of spent batteries, offering substantial environmental advantages within the well-established and extensively utilized realm of metal recovery technology in the industry.",
journal = "Separation and Purification Technology",
title = "Sustainable recovery of cobalt and lithium from lithium-ion battery cathode material by combining sulfate leachates and aqueous biphasic systems based on tetrabutylphosphonium-ionic liquids",
volume = "348",
pages = "127707",
doi = "10.1016/j.seppur.2024.127707"
}
Mušović, J., Tekić, D., Marić, S., Jocić, A., Stanković, D.,& Dimitrijević, A.. (2024). Sustainable recovery of cobalt and lithium from lithium-ion battery cathode material by combining sulfate leachates and aqueous biphasic systems based on tetrabutylphosphonium-ionic liquids. in Separation and Purification Technology, 348, 127707.
https://doi.org/10.1016/j.seppur.2024.127707
Mušović J, Tekić D, Marić S, Jocić A, Stanković D, Dimitrijević A. Sustainable recovery of cobalt and lithium from lithium-ion battery cathode material by combining sulfate leachates and aqueous biphasic systems based on tetrabutylphosphonium-ionic liquids. in Separation and Purification Technology. 2024;348:127707.
doi:10.1016/j.seppur.2024.127707 .
Mušović, Jasmina, Tekić, Danijela, Marić, Slađana, Jocić, Ana, Stanković, Dalibor, Dimitrijević, Aleksandra, "Sustainable recovery of cobalt and lithium from lithium-ion battery cathode material by combining sulfate leachates and aqueous biphasic systems based on tetrabutylphosphonium-ionic liquids" in Separation and Purification Technology, 348 (2024):127707,
https://doi.org/10.1016/j.seppur.2024.127707 . .

Customizable cholinium-based aqueous biphasic systems as ecofriendly extraction platform for removal of pesticide from wastewaters

Marić, Slađana; Jocić, Ana; Tekić, Danijela; Mušović, Jasmina; Milićević, Jelena; Dimitrijević, Aleksandra

(2024)

TY  - JOUR
AU  - Marić, Slađana
AU  - Jocić, Ana
AU  - Tekić, Danijela
AU  - Mušović, Jasmina
AU  - Milićević, Jelena
AU  - Dimitrijević, Aleksandra
PY  - 2024
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/12838
AB  - This study explores the use of a series of cholinium ionic liquids (ILs) or salts in combination with polypropylene glycol 400 to form aqueous biphasic systems (ABS) for extracting various polarity pesticides (dicamba, clomazone, pyraclostrobin, and deltamethrin) from water. We assessed five cholinium-based salting-out agents ([Ch][DHP], [Ch]Cl, [Ch][Ac], [Ch][Lac], and [Ch][Nic]), chosen for their structural diversity and unique properties, such as high salting-out potential and different ability to undergo specific interactions. Liquid-liquid equilibrium phase diagrams were established, and partition experiments were conducted to evaluate extraction efficiency. Different partition patterns were obtained for studied pesticides, with [Ch][DHP] demonstrating the highest efficiency exceeding 90 % for each target pesticide due to its strong salting-out ability. On the other hand, more diverse partition trends due to specific interactions were obtained for low-melting cholinium-ILs ABS. The effect of pH and temperature on the partitioning behavior in [Ch][Ac]-based ABS highlighted the cholinium ILs extraction system's customizable nature. Focusing on [Ch]Cl for its eco-friendly aspects, widespread availability and excellent extraction performance, we optimized parameters for the removal of pesticides from real samples, applying the technology to spiked agricultural wastewater with an extraction efficiency of over 99 %. Our findings demonstrate the potential of cholinium-based IL-ABS in reducing environmental pollution through efficient pesticide extraction.
T2  - Separation and Purification Technology
T1  - Customizable cholinium-based aqueous biphasic systems as ecofriendly extraction platform for removal of pesticide from wastewaters
VL  - 340
SP  - 126609
DO  - 10.1016/j.seppur.2024.126609
ER  - 
@article{
author = "Marić, Slađana and Jocić, Ana and Tekić, Danijela and Mušović, Jasmina and Milićević, Jelena and Dimitrijević, Aleksandra",
year = "2024",
abstract = "This study explores the use of a series of cholinium ionic liquids (ILs) or salts in combination with polypropylene glycol 400 to form aqueous biphasic systems (ABS) for extracting various polarity pesticides (dicamba, clomazone, pyraclostrobin, and deltamethrin) from water. We assessed five cholinium-based salting-out agents ([Ch][DHP], [Ch]Cl, [Ch][Ac], [Ch][Lac], and [Ch][Nic]), chosen for their structural diversity and unique properties, such as high salting-out potential and different ability to undergo specific interactions. Liquid-liquid equilibrium phase diagrams were established, and partition experiments were conducted to evaluate extraction efficiency. Different partition patterns were obtained for studied pesticides, with [Ch][DHP] demonstrating the highest efficiency exceeding 90 % for each target pesticide due to its strong salting-out ability. On the other hand, more diverse partition trends due to specific interactions were obtained for low-melting cholinium-ILs ABS. The effect of pH and temperature on the partitioning behavior in [Ch][Ac]-based ABS highlighted the cholinium ILs extraction system's customizable nature. Focusing on [Ch]Cl for its eco-friendly aspects, widespread availability and excellent extraction performance, we optimized parameters for the removal of pesticides from real samples, applying the technology to spiked agricultural wastewater with an extraction efficiency of over 99 %. Our findings demonstrate the potential of cholinium-based IL-ABS in reducing environmental pollution through efficient pesticide extraction.",
journal = "Separation and Purification Technology",
title = "Customizable cholinium-based aqueous biphasic systems as ecofriendly extraction platform for removal of pesticide from wastewaters",
volume = "340",
pages = "126609",
doi = "10.1016/j.seppur.2024.126609"
}
Marić, S., Jocić, A., Tekić, D., Mušović, J., Milićević, J.,& Dimitrijević, A.. (2024). Customizable cholinium-based aqueous biphasic systems as ecofriendly extraction platform for removal of pesticide from wastewaters. in Separation and Purification Technology, 340, 126609.
https://doi.org/10.1016/j.seppur.2024.126609
Marić S, Jocić A, Tekić D, Mušović J, Milićević J, Dimitrijević A. Customizable cholinium-based aqueous biphasic systems as ecofriendly extraction platform for removal of pesticide from wastewaters. in Separation and Purification Technology. 2024;340:126609.
doi:10.1016/j.seppur.2024.126609 .
Marić, Slađana, Jocić, Ana, Tekić, Danijela, Mušović, Jasmina, Milićević, Jelena, Dimitrijević, Aleksandra, "Customizable cholinium-based aqueous biphasic systems as ecofriendly extraction platform for removal of pesticide from wastewaters" in Separation and Purification Technology, 340 (2024):126609,
https://doi.org/10.1016/j.seppur.2024.126609 . .
1
1

Green Extraction Strategy Using Bio-Based Aqueous Biphasic Systems for Polyphenol Valorization from Grape By-Product

Dimitrijević, Aleksandra; Marić, Slađana; Jocić, Ana; Tekić, Danijela; Mušović, Jasmina; Amaral, Joana S.

(2024)

TY  - JOUR
AU  - Dimitrijević, Aleksandra
AU  - Marić, Slađana
AU  - Jocić, Ana
AU  - Tekić, Danijela
AU  - Mušović, Jasmina
AU  - Amaral, Joana S.
PY  - 2024
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/13029
AB  - Polyphenols are natural compounds with enhanced antioxidant properties. They are present in relatively high concentrations in fruit/vegetable by-products. Therefore, there is a need for the development of efficient and cost-effective methods for the separation and purification of these valuable compounds. Traditional extraction with organic solvents needs to be switched to novel methods that are more efficient, with reduced extraction times and low consumption of organic solvents. Aiming at developing sustainable processes for the separation and purification of phenolic compounds, we used three model compounds, namely resveratrol, quercetin, and gallic acid, to investigate ionic liquid-based aqueous biphasic systems (IL-ABSs) formed by choliniumbased IL in combination with polypropylene glycol with a molecular mass of 400 g/mol (PPG400). The ABS composition in the two-phase region was selected according to a previously determined phase diagram. Extraction studies indicated the preferential partition of resveratrol and quercetin toward the hydrophobic PPG-rich phase that is mainly dominated by its hydrophobic nature and the strong salting-out effect of ILs. On the other hand, due to its considerably hydrophilic nature, gallic acid preferentially migrates toward the IL phase. The achieved results from grape stem extract demonstrated high extraction efficiencies of cholinium dihydrogen phosphate (~99% for resveratrol for the PPG phase and 78% for gallic acid for the IL phase), with considerable selectivity, demonstrating promising outcomes for potential applications.
T2  - Foods
T1  - Green Extraction Strategy Using Bio-Based Aqueous Biphasic Systems for Polyphenol Valorization from Grape By-Product
VL  - 13
IS  - 6
SP  - 954
DO  - 10.3390/foods13060954
ER  - 
@article{
author = "Dimitrijević, Aleksandra and Marić, Slađana and Jocić, Ana and Tekić, Danijela and Mušović, Jasmina and Amaral, Joana S.",
year = "2024",
abstract = "Polyphenols are natural compounds with enhanced antioxidant properties. They are present in relatively high concentrations in fruit/vegetable by-products. Therefore, there is a need for the development of efficient and cost-effective methods for the separation and purification of these valuable compounds. Traditional extraction with organic solvents needs to be switched to novel methods that are more efficient, with reduced extraction times and low consumption of organic solvents. Aiming at developing sustainable processes for the separation and purification of phenolic compounds, we used three model compounds, namely resveratrol, quercetin, and gallic acid, to investigate ionic liquid-based aqueous biphasic systems (IL-ABSs) formed by choliniumbased IL in combination with polypropylene glycol with a molecular mass of 400 g/mol (PPG400). The ABS composition in the two-phase region was selected according to a previously determined phase diagram. Extraction studies indicated the preferential partition of resveratrol and quercetin toward the hydrophobic PPG-rich phase that is mainly dominated by its hydrophobic nature and the strong salting-out effect of ILs. On the other hand, due to its considerably hydrophilic nature, gallic acid preferentially migrates toward the IL phase. The achieved results from grape stem extract demonstrated high extraction efficiencies of cholinium dihydrogen phosphate (~99% for resveratrol for the PPG phase and 78% for gallic acid for the IL phase), with considerable selectivity, demonstrating promising outcomes for potential applications.",
journal = "Foods",
title = "Green Extraction Strategy Using Bio-Based Aqueous Biphasic Systems for Polyphenol Valorization from Grape By-Product",
volume = "13",
number = "6",
pages = "954",
doi = "10.3390/foods13060954"
}
Dimitrijević, A., Marić, S., Jocić, A., Tekić, D., Mušović, J.,& Amaral, J. S.. (2024). Green Extraction Strategy Using Bio-Based Aqueous Biphasic Systems for Polyphenol Valorization from Grape By-Product. in Foods, 13(6), 954.
https://doi.org/10.3390/foods13060954
Dimitrijević A, Marić S, Jocić A, Tekić D, Mušović J, Amaral JS. Green Extraction Strategy Using Bio-Based Aqueous Biphasic Systems for Polyphenol Valorization from Grape By-Product. in Foods. 2024;13(6):954.
doi:10.3390/foods13060954 .
Dimitrijević, Aleksandra, Marić, Slađana, Jocić, Ana, Tekić, Danijela, Mušović, Jasmina, Amaral, Joana S., "Green Extraction Strategy Using Bio-Based Aqueous Biphasic Systems for Polyphenol Valorization from Grape By-Product" in Foods, 13, no. 6 (2024):954,
https://doi.org/10.3390/foods13060954 . .

Nano-size cobalt-doped cerium oxide particles embedded into graphitic carbon nitride for enhanced electrochemical sensing of insecticide fenitrothion in environmental samples: An experimental study with the theoretical elucidation of redox events

Đurđić, Slađana; Vlahović, Filip; Ognjanović, Miloš; Gemeiner, Pavol; Sarakhman, Olha; Stanković, Vesna; Mutić, Jelena; Stanković, Dalibor; Švorc, Lubomír

(2024)

TY  - JOUR
AU  - Đurđić, Slađana
AU  - Vlahović, Filip
AU  - Ognjanović, Miloš
AU  - Gemeiner, Pavol
AU  - Sarakhman, Olha
AU  - Stanković, Vesna
AU  - Mutić, Jelena
AU  - Stanković, Dalibor
AU  - Švorc, Lubomír
PY  - 2024
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/12205
AB  - In the present work, a nanocomposite, based on embedding Co-doped CeO2 nanoparticles into graphitic carbon nitride (g-C3N4), was applied to functionalize commercial glassy carbon paste. This is the first application of the electrochemical sensor, developed through the proposed procedure, in electrochemical sensing. The sensor was utilized for the electrochemical determination of organophosphate pesticide fenitrothion (FNT). Cyclic voltammetry identified reversible oxidation of FNT (oxidation at 0.18 V and reduction at 0.13 V) and additional reduction at 0.62 V vs. Ag/AgCl in HCl solution (pH =1). Theoretical calculations were carried out to model and elucidate experimentally observed redox processes. Special attention was devoted to modeling experimental conditions, and based on the obtained results, a detailed redox mechanism of the investigated analyte was proposed. This represents the first complete and unambiguous elucidation of the FNT redox mechanism, supported by joined experimental and theoretical data. Square wave voltammetry (SWV) was utilized for quantification, whereby the FNT oxidation peak was chosen for monitoring the analyte concentration. The developed sensor provided a nanomolar detection limit (3.2 nmol L 1), a wide linear concentration range (from 0.01 to 13.7 μmol L 1), and good precision, repeatability, and selectivity towards FNT. Practical application possibility was explored by testing the sensor performance for examining tap water and apple samples. Recovery tests, conducted during the FNT-spiked sample assays, showed a great application capability of the developed sensor for real-time monitoring of FNT traces in environmental samples.
T2  - Science of The Total Environment
T1  - Nano-size cobalt-doped cerium oxide particles embedded into graphitic carbon nitride for enhanced electrochemical sensing of insecticide fenitrothion in environmental samples: An experimental study with the theoretical elucidation of redox events
VL  - 909
SP  - 168483
DO  - 10.1016/j.scitotenv.2023.168483
ER  - 
@article{
author = "Đurđić, Slađana and Vlahović, Filip and Ognjanović, Miloš and Gemeiner, Pavol and Sarakhman, Olha and Stanković, Vesna and Mutić, Jelena and Stanković, Dalibor and Švorc, Lubomír",
year = "2024",
abstract = "In the present work, a nanocomposite, based on embedding Co-doped CeO2 nanoparticles into graphitic carbon nitride (g-C3N4), was applied to functionalize commercial glassy carbon paste. This is the first application of the electrochemical sensor, developed through the proposed procedure, in electrochemical sensing. The sensor was utilized for the electrochemical determination of organophosphate pesticide fenitrothion (FNT). Cyclic voltammetry identified reversible oxidation of FNT (oxidation at 0.18 V and reduction at 0.13 V) and additional reduction at 0.62 V vs. Ag/AgCl in HCl solution (pH =1). Theoretical calculations were carried out to model and elucidate experimentally observed redox processes. Special attention was devoted to modeling experimental conditions, and based on the obtained results, a detailed redox mechanism of the investigated analyte was proposed. This represents the first complete and unambiguous elucidation of the FNT redox mechanism, supported by joined experimental and theoretical data. Square wave voltammetry (SWV) was utilized for quantification, whereby the FNT oxidation peak was chosen for monitoring the analyte concentration. The developed sensor provided a nanomolar detection limit (3.2 nmol L 1), a wide linear concentration range (from 0.01 to 13.7 μmol L 1), and good precision, repeatability, and selectivity towards FNT. Practical application possibility was explored by testing the sensor performance for examining tap water and apple samples. Recovery tests, conducted during the FNT-spiked sample assays, showed a great application capability of the developed sensor for real-time monitoring of FNT traces in environmental samples.",
journal = "Science of The Total Environment",
title = "Nano-size cobalt-doped cerium oxide particles embedded into graphitic carbon nitride for enhanced electrochemical sensing of insecticide fenitrothion in environmental samples: An experimental study with the theoretical elucidation of redox events",
volume = "909",
pages = "168483",
doi = "10.1016/j.scitotenv.2023.168483"
}
Đurđić, S., Vlahović, F., Ognjanović, M., Gemeiner, P., Sarakhman, O., Stanković, V., Mutić, J., Stanković, D.,& Švorc, L.. (2024). Nano-size cobalt-doped cerium oxide particles embedded into graphitic carbon nitride for enhanced electrochemical sensing of insecticide fenitrothion in environmental samples: An experimental study with the theoretical elucidation of redox events. in Science of The Total Environment, 909, 168483.
https://doi.org/10.1016/j.scitotenv.2023.168483
Đurđić S, Vlahović F, Ognjanović M, Gemeiner P, Sarakhman O, Stanković V, Mutić J, Stanković D, Švorc L. Nano-size cobalt-doped cerium oxide particles embedded into graphitic carbon nitride for enhanced electrochemical sensing of insecticide fenitrothion in environmental samples: An experimental study with the theoretical elucidation of redox events. in Science of The Total Environment. 2024;909:168483.
doi:10.1016/j.scitotenv.2023.168483 .
Đurđić, Slađana, Vlahović, Filip, Ognjanović, Miloš, Gemeiner, Pavol, Sarakhman, Olha, Stanković, Vesna, Mutić, Jelena, Stanković, Dalibor, Švorc, Lubomír, "Nano-size cobalt-doped cerium oxide particles embedded into graphitic carbon nitride for enhanced electrochemical sensing of insecticide fenitrothion in environmental samples: An experimental study with the theoretical elucidation of redox events" in Science of The Total Environment, 909 (2024):168483,
https://doi.org/10.1016/j.scitotenv.2023.168483 . .
5
5

Triangle-Shaped Cerium Tungstate Nanoparticles Used to Modify Carbon Paste Electrode for Sensitive Hydroquinone Detection in Water Samples

Stanković, Vesna; Đurđić, Slađana; Ognjanović, Miloš; Zlatić, Gloria; Stanković, Dalibor

(2024)

TY  - JOUR
AU  - Stanković, Vesna
AU  - Đurđić, Slađana
AU  - Ognjanović, Miloš
AU  - Zlatić, Gloria
AU  - Stanković, Dalibor
PY  - 2024
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/12670
AB  - In this study, we propose an eco-friendly method for synthesizing cerium tungstate nanoparticles using hydrothermal techniques. We used scanning, transmission electron microscopy, and X-ray diffraction to analyze the morphology of the synthesized nanoparticles. The results showed that the synthesized nanoparticles were uniform and highly crystalline, with a particle size of about 50 nm. The electrocatalytic properties of the nanoparticles were then investigated using cyclic voltammetry and electrochemical impedance spectroscopy. We further used the synthesized nanoparticles to develop an electrochemical sensor based on a carbon paste electrode that can detect hydroquinone. By optimizing the differential pulse voltammetric method, a wide linearity range of 0.4 to 45 µM and a low detection limit of 0.06 µM were obtained. The developed sensor also expressed excellent repeatability (RSD up to 3.8%) and reproducibility (RSD below 5%). Interferences had an insignificant impact on the determination of analytes, making it possible to use this method for monitoring hydroquinone concentrations in tap water. This study introduces a new approach to the chemistry of materials and the environment and demonstrates that a careful selection of components can lead to new horizons in analytical chemistry.
T2  - Sensors
T1  - Triangle-Shaped Cerium Tungstate Nanoparticles Used to Modify Carbon Paste Electrode for Sensitive Hydroquinone Detection in Water Samples
VL  - 24
IS  - 2
SP  - 705
DO  - 10.3390/s24020705
ER  - 
@article{
author = "Stanković, Vesna and Đurđić, Slađana and Ognjanović, Miloš and Zlatić, Gloria and Stanković, Dalibor",
year = "2024",
abstract = "In this study, we propose an eco-friendly method for synthesizing cerium tungstate nanoparticles using hydrothermal techniques. We used scanning, transmission electron microscopy, and X-ray diffraction to analyze the morphology of the synthesized nanoparticles. The results showed that the synthesized nanoparticles were uniform and highly crystalline, with a particle size of about 50 nm. The electrocatalytic properties of the nanoparticles were then investigated using cyclic voltammetry and electrochemical impedance spectroscopy. We further used the synthesized nanoparticles to develop an electrochemical sensor based on a carbon paste electrode that can detect hydroquinone. By optimizing the differential pulse voltammetric method, a wide linearity range of 0.4 to 45 µM and a low detection limit of 0.06 µM were obtained. The developed sensor also expressed excellent repeatability (RSD up to 3.8%) and reproducibility (RSD below 5%). Interferences had an insignificant impact on the determination of analytes, making it possible to use this method for monitoring hydroquinone concentrations in tap water. This study introduces a new approach to the chemistry of materials and the environment and demonstrates that a careful selection of components can lead to new horizons in analytical chemistry.",
journal = "Sensors",
title = "Triangle-Shaped Cerium Tungstate Nanoparticles Used to Modify Carbon Paste Electrode for Sensitive Hydroquinone Detection in Water Samples",
volume = "24",
number = "2",
pages = "705",
doi = "10.3390/s24020705"
}
Stanković, V., Đurđić, S., Ognjanović, M., Zlatić, G.,& Stanković, D.. (2024). Triangle-Shaped Cerium Tungstate Nanoparticles Used to Modify Carbon Paste Electrode for Sensitive Hydroquinone Detection in Water Samples. in Sensors, 24(2), 705.
https://doi.org/10.3390/s24020705
Stanković V, Đurđić S, Ognjanović M, Zlatić G, Stanković D. Triangle-Shaped Cerium Tungstate Nanoparticles Used to Modify Carbon Paste Electrode for Sensitive Hydroquinone Detection in Water Samples. in Sensors. 2024;24(2):705.
doi:10.3390/s24020705 .
Stanković, Vesna, Đurđić, Slađana, Ognjanović, Miloš, Zlatić, Gloria, Stanković, Dalibor, "Triangle-Shaped Cerium Tungstate Nanoparticles Used to Modify Carbon Paste Electrode for Sensitive Hydroquinone Detection in Water Samples" in Sensors, 24, no. 2 (2024):705,
https://doi.org/10.3390/s24020705 . .

Enhancing Adrenaline Sensing with Lanthanum Cuprate: A Promising Approach for a Novel Sensor

Korina, Elena; Karaberova, Arina; Bol’shakov, Oleg; Bulatova, Ekaterina; Golovin, Mikhail; Abramyan, Anton; Stanković, Dalibor M.

(2024)

TY  - JOUR
AU  - Korina, Elena
AU  - Karaberova, Arina
AU  - Bol’shakov, Oleg
AU  - Bulatova, Ekaterina
AU  - Golovin, Mikhail
AU  - Abramyan, Anton
AU  - Stanković, Dalibor M.
PY  - 2024
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/12875
AB  - Electrochemical sensing is an excellent analytical means with multiple applications. Most of the electrochemical developments are based on the novel electrochemically active substrates. A lot of them have been adopted from other fields of material science. Every new class of functional materials has impacted on the development of electroanalytical chemistry. In this view, lanthanide cuprates, a well recognized high temperature superconducting materials were considered for adrenaline sensing. Obtained from corresponding oxides, a highly crystalline La2CuO4 found to be a suitable substrate for analytical method development. It inherited sponge-like morphology common for the most of the previously reported lanthanum cuprates with narrow pore size distribution at 400–700 nm. Excellent charge mobility and low resistivity provided a carbon paste electrode with improved linearity range and low limit of detection. Repeatability and stability of the developed sensor were at satisfactory level. Sensor functionality was verified on the real samples with excellent recovery rates. With this work we suggest further development of electroanalytical methods with application of lanthanide cuprates.
T2  - Journal of The Electrochemical Society
T1  - Enhancing Adrenaline Sensing with Lanthanum Cuprate: A Promising Approach for a Novel Sensor
VL  - 171
IS  - 1
SP  - 017513
DO  - 10.1149/1945-7111/ad1ecb
ER  - 
@article{
author = "Korina, Elena and Karaberova, Arina and Bol’shakov, Oleg and Bulatova, Ekaterina and Golovin, Mikhail and Abramyan, Anton and Stanković, Dalibor M.",
year = "2024",
abstract = "Electrochemical sensing is an excellent analytical means with multiple applications. Most of the electrochemical developments are based on the novel electrochemically active substrates. A lot of them have been adopted from other fields of material science. Every new class of functional materials has impacted on the development of electroanalytical chemistry. In this view, lanthanide cuprates, a well recognized high temperature superconducting materials were considered for adrenaline sensing. Obtained from corresponding oxides, a highly crystalline La2CuO4 found to be a suitable substrate for analytical method development. It inherited sponge-like morphology common for the most of the previously reported lanthanum cuprates with narrow pore size distribution at 400–700 nm. Excellent charge mobility and low resistivity provided a carbon paste electrode with improved linearity range and low limit of detection. Repeatability and stability of the developed sensor were at satisfactory level. Sensor functionality was verified on the real samples with excellent recovery rates. With this work we suggest further development of electroanalytical methods with application of lanthanide cuprates.",
journal = "Journal of The Electrochemical Society",
title = "Enhancing Adrenaline Sensing with Lanthanum Cuprate: A Promising Approach for a Novel Sensor",
volume = "171",
number = "1",
pages = "017513",
doi = "10.1149/1945-7111/ad1ecb"
}
Korina, E., Karaberova, A., Bol’shakov, O., Bulatova, E., Golovin, M., Abramyan, A.,& Stanković, D. M.. (2024). Enhancing Adrenaline Sensing with Lanthanum Cuprate: A Promising Approach for a Novel Sensor. in Journal of The Electrochemical Society, 171(1), 017513.
https://doi.org/10.1149/1945-7111/ad1ecb
Korina E, Karaberova A, Bol’shakov O, Bulatova E, Golovin M, Abramyan A, Stanković DM. Enhancing Adrenaline Sensing with Lanthanum Cuprate: A Promising Approach for a Novel Sensor. in Journal of The Electrochemical Society. 2024;171(1):017513.
doi:10.1149/1945-7111/ad1ecb .
Korina, Elena, Karaberova, Arina, Bol’shakov, Oleg, Bulatova, Ekaterina, Golovin, Mikhail, Abramyan, Anton, Stanković, Dalibor M., "Enhancing Adrenaline Sensing with Lanthanum Cuprate: A Promising Approach for a Novel Sensor" in Journal of The Electrochemical Society, 171, no. 1 (2024):017513,
https://doi.org/10.1149/1945-7111/ad1ecb . .

The cathodically pretreated boron-doped diamond electrode as an environmentally friendly electrochemical tool for the detection and monitoring of mesotrione in food samples

Mijajlović, Aleksandar; Stanković, Vesna; Vlahović, Filip; Đurđić, Slađana; Manojlović, Dragan; Stanković, Dalibor

(2024)

TY  - JOUR
AU  - Mijajlović, Aleksandar
AU  - Stanković, Vesna
AU  - Vlahović, Filip
AU  - Đurđić, Slađana
AU  - Manojlović, Dragan
AU  - Stanković, Dalibor
PY  - 2024
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/13021
AB  - Excessive pesticide use can harm human health, making it essential to develop new techniques to monitor hazardous pesticides in food. Our study focuses on detecting mesotrione (MST) using an unmodified boron-doped diamond (BDD) electrode. This was the first application of cathodically pretreated BDD electrode for the detection of MST, based on its oxidation at a high potential value of +1.4 V. We theoretically examined the oxidation mechanism of MST trough the utilization of density functional theory (DFT) methodology. The utilized DPV method achieved a detection limit of 0.45 μM and showed satisfactory selectivity. The practical application of this method was demonstrated by examining corn-based food products. To ensure practical application of the method, MST was deliberately added to the samples to evaluate the accuracy of the proposed method. The effectiveness of the method was confirmed by using HPLC method. This environmentally-friendly approach can establish a solid foundation for future use in food analysis.
T2  - Food Chemistry
T1  - The cathodically pretreated boron-doped diamond electrode as an environmentally friendly electrochemical tool for the detection and monitoring of mesotrione in food samples
VL  - 447
SP  - 138993
DO  - 10.1016/j.foodchem.2024.138993
ER  - 
@article{
author = "Mijajlović, Aleksandar and Stanković, Vesna and Vlahović, Filip and Đurđić, Slađana and Manojlović, Dragan and Stanković, Dalibor",
year = "2024",
abstract = "Excessive pesticide use can harm human health, making it essential to develop new techniques to monitor hazardous pesticides in food. Our study focuses on detecting mesotrione (MST) using an unmodified boron-doped diamond (BDD) electrode. This was the first application of cathodically pretreated BDD electrode for the detection of MST, based on its oxidation at a high potential value of +1.4 V. We theoretically examined the oxidation mechanism of MST trough the utilization of density functional theory (DFT) methodology. The utilized DPV method achieved a detection limit of 0.45 μM and showed satisfactory selectivity. The practical application of this method was demonstrated by examining corn-based food products. To ensure practical application of the method, MST was deliberately added to the samples to evaluate the accuracy of the proposed method. The effectiveness of the method was confirmed by using HPLC method. This environmentally-friendly approach can establish a solid foundation for future use in food analysis.",
journal = "Food Chemistry",
title = "The cathodically pretreated boron-doped diamond electrode as an environmentally friendly electrochemical tool for the detection and monitoring of mesotrione in food samples",
volume = "447",
pages = "138993",
doi = "10.1016/j.foodchem.2024.138993"
}
Mijajlović, A., Stanković, V., Vlahović, F., Đurđić, S., Manojlović, D.,& Stanković, D.. (2024). The cathodically pretreated boron-doped diamond electrode as an environmentally friendly electrochemical tool for the detection and monitoring of mesotrione in food samples. in Food Chemistry, 447, 138993.
https://doi.org/10.1016/j.foodchem.2024.138993
Mijajlović A, Stanković V, Vlahović F, Đurđić S, Manojlović D, Stanković D. The cathodically pretreated boron-doped diamond electrode as an environmentally friendly electrochemical tool for the detection and monitoring of mesotrione in food samples. in Food Chemistry. 2024;447:138993.
doi:10.1016/j.foodchem.2024.138993 .
Mijajlović, Aleksandar, Stanković, Vesna, Vlahović, Filip, Đurđić, Slađana, Manojlović, Dragan, Stanković, Dalibor, "The cathodically pretreated boron-doped diamond electrode as an environmentally friendly electrochemical tool for the detection and monitoring of mesotrione in food samples" in Food Chemistry, 447 (2024):138993,
https://doi.org/10.1016/j.foodchem.2024.138993 . .

Improving gallic acid detection in plant samples: Fabrication and optimization of a sensitive and selective NiO-supported carbon paste electrode

Mutić, Tijana; Ognjanović, Miloš; Ivković, Đurđa; Nikolić, Vladimir; Stanković, Vesna; Ristivojević, Petar; Stanković, Dalibor

(2024)

TY  - JOUR
AU  - Mutić, Tijana
AU  - Ognjanović, Miloš
AU  - Ivković, Đurđa
AU  - Nikolić, Vladimir
AU  - Stanković, Vesna
AU  - Ristivojević, Petar
AU  - Stanković, Dalibor
PY  - 2024
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/13031
AB  - In this study, we successfully prepared a modified nickel oxide (NiO) carbon paste electrode to detect gallic acid (GA). NiO nanoparticles were synthesized by the simple, organic solvent-free chemical coprecipitation method, and the electrochemical properties of the electrode and GA were thoroughly investigated using CV, SWV, and EIS, while morphological properties were examined using ICP-OES, TEM, SEM, and XRD. Excellent catalytic characteristics are displayed by the developed material which facilitates the interaction of the target with the electrode surface. The obtained electrochemical information showed that the incorporation of NiO nanoparticles to the carbon paste electrode effectively facilitates electron transfer processes and enriches the catalytic response of the carbon paste electrode. The fabricated NiO/CPE sensor showed a satisfactory linear relationship between peak current and GA concentration in the broad range of 0.2–100 μM and 100–200 μM with a low detection limit of 0.04 μM and limit of quantification of 0.12 μM at pH 3 of BRBS as supporting electrolyte. The selectivity of the proposed method was satisfactory, with acceptable stability, considerable repeatability, and accurate reproducibility. Moreover, the good practicability performance could be effectuated at the NiO/CPE sensor for the quantitative analysis of GA in bourtree, walnut, primrose, and chamomile tea samples. The results were compared with the standard DPPH test and statistical processing of the results was performed, which confirmed the excellent agreement between the two methods. The developed method can provide a cost-effective, rapid, selective, and sensitive means for GA monitoring. When compared to other works, the developed technique has a wider linear range and lower LOD and LOQ, which makes this work a very important reference for the highly sensitive analysis of GA in the field of food safety.
T2  - Journal of Electroanalytical Chemistry
T1  - Improving gallic acid detection in plant samples: Fabrication and optimization of a sensitive and selective NiO-supported carbon paste electrode
VL  - 960
SP  - 118213
DO  - 10.1016/j.jelechem.2024.118213
ER  - 
@article{
author = "Mutić, Tijana and Ognjanović, Miloš and Ivković, Đurđa and Nikolić, Vladimir and Stanković, Vesna and Ristivojević, Petar and Stanković, Dalibor",
year = "2024",
abstract = "In this study, we successfully prepared a modified nickel oxide (NiO) carbon paste electrode to detect gallic acid (GA). NiO nanoparticles were synthesized by the simple, organic solvent-free chemical coprecipitation method, and the electrochemical properties of the electrode and GA were thoroughly investigated using CV, SWV, and EIS, while morphological properties were examined using ICP-OES, TEM, SEM, and XRD. Excellent catalytic characteristics are displayed by the developed material which facilitates the interaction of the target with the electrode surface. The obtained electrochemical information showed that the incorporation of NiO nanoparticles to the carbon paste electrode effectively facilitates electron transfer processes and enriches the catalytic response of the carbon paste electrode. The fabricated NiO/CPE sensor showed a satisfactory linear relationship between peak current and GA concentration in the broad range of 0.2–100 μM and 100–200 μM with a low detection limit of 0.04 μM and limit of quantification of 0.12 μM at pH 3 of BRBS as supporting electrolyte. The selectivity of the proposed method was satisfactory, with acceptable stability, considerable repeatability, and accurate reproducibility. Moreover, the good practicability performance could be effectuated at the NiO/CPE sensor for the quantitative analysis of GA in bourtree, walnut, primrose, and chamomile tea samples. The results were compared with the standard DPPH test and statistical processing of the results was performed, which confirmed the excellent agreement between the two methods. The developed method can provide a cost-effective, rapid, selective, and sensitive means for GA monitoring. When compared to other works, the developed technique has a wider linear range and lower LOD and LOQ, which makes this work a very important reference for the highly sensitive analysis of GA in the field of food safety.",
journal = "Journal of Electroanalytical Chemistry",
title = "Improving gallic acid detection in plant samples: Fabrication and optimization of a sensitive and selective NiO-supported carbon paste electrode",
volume = "960",
pages = "118213",
doi = "10.1016/j.jelechem.2024.118213"
}
Mutić, T., Ognjanović, M., Ivković, Đ., Nikolić, V., Stanković, V., Ristivojević, P.,& Stanković, D.. (2024). Improving gallic acid detection in plant samples: Fabrication and optimization of a sensitive and selective NiO-supported carbon paste electrode. in Journal of Electroanalytical Chemistry, 960, 118213.
https://doi.org/10.1016/j.jelechem.2024.118213
Mutić T, Ognjanović M, Ivković Đ, Nikolić V, Stanković V, Ristivojević P, Stanković D. Improving gallic acid detection in plant samples: Fabrication and optimization of a sensitive and selective NiO-supported carbon paste electrode. in Journal of Electroanalytical Chemistry. 2024;960:118213.
doi:10.1016/j.jelechem.2024.118213 .
Mutić, Tijana, Ognjanović, Miloš, Ivković, Đurđa, Nikolić, Vladimir, Stanković, Vesna, Ristivojević, Petar, Stanković, Dalibor, "Improving gallic acid detection in plant samples: Fabrication and optimization of a sensitive and selective NiO-supported carbon paste electrode" in Journal of Electroanalytical Chemistry, 960 (2024):118213,
https://doi.org/10.1016/j.jelechem.2024.118213 . .

Micromolar Levofloxacin Sensor by Incorporating Highly Crystalline Co3O4 into a Carbon Paste Electrode Structure

Mutić, Tijana; Stanković, Dalibor M.; Manojlović, Dragan; Petrić, Đorđe; Pastor, Ferenc; Avdin, Vyacheslav V.; Ognjanović, Miloš; Stanković, Vesna

(2024)

TY  - JOUR
AU  - Mutić, Tijana
AU  - Stanković, Dalibor M.
AU  - Manojlović, Dragan
AU  - Petrić, Đorđe
AU  - Pastor, Ferenc
AU  - Avdin, Vyacheslav V.
AU  - Ognjanović, Miloš
AU  - Stanković, Vesna
PY  - 2024
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/13122
AB  - In this work, we successfully prepared a modified cobalt oxide (Co3O4) carbon paste electrode to detect Levofloxacin (LEV). By synthesizing Co3O4 nanoparticles through the chemical coprecipitation method, the electrochemical properties of the electrode and LEV were thoroughly investigated using CV, SWV, and EIS, while material properties were scrutinized using ICP-OES, TEM, SEM, and XRD. The results showed that the prepared electrode displayed a better electrocatalytic response than the bare carbon paste electrode. After optimizing SWV, the electrode exhibited a wide linear working range from 1 to 85 μM at pH 5 of BRBS as the supporting electrolyte. The selectivity of the proposed method was satisfactory, with good repeatability and reproducibility, strongly suggesting a potential application for determining LEV in real samples, particularly in pharmaceutical formulations. The practicality of the approach was demonstrated through good recoveries, and the morphology of the materials was found to be closely related to other parameters, indicating that the developed method can provide a cost-effective, rapid, selective, and sensitive means for LEV monitoring. Overall, this project has made significant progress towards developing a reliable method for detecting LEV and has opened up new opportunities for future research in this field.
T2  - Electrochem
T1  - Micromolar Levofloxacin Sensor by Incorporating Highly Crystalline Co3O4 into a Carbon Paste Electrode Structure
VL  - 5
IS  - 1
SP  - 45
EP  - 56
DO  - 10.3390/electrochem5010003
ER  - 
@article{
author = "Mutić, Tijana and Stanković, Dalibor M. and Manojlović, Dragan and Petrić, Đorđe and Pastor, Ferenc and Avdin, Vyacheslav V. and Ognjanović, Miloš and Stanković, Vesna",
year = "2024",
abstract = "In this work, we successfully prepared a modified cobalt oxide (Co3O4) carbon paste electrode to detect Levofloxacin (LEV). By synthesizing Co3O4 nanoparticles through the chemical coprecipitation method, the electrochemical properties of the electrode and LEV were thoroughly investigated using CV, SWV, and EIS, while material properties were scrutinized using ICP-OES, TEM, SEM, and XRD. The results showed that the prepared electrode displayed a better electrocatalytic response than the bare carbon paste electrode. After optimizing SWV, the electrode exhibited a wide linear working range from 1 to 85 μM at pH 5 of BRBS as the supporting electrolyte. The selectivity of the proposed method was satisfactory, with good repeatability and reproducibility, strongly suggesting a potential application for determining LEV in real samples, particularly in pharmaceutical formulations. The practicality of the approach was demonstrated through good recoveries, and the morphology of the materials was found to be closely related to other parameters, indicating that the developed method can provide a cost-effective, rapid, selective, and sensitive means for LEV monitoring. Overall, this project has made significant progress towards developing a reliable method for detecting LEV and has opened up new opportunities for future research in this field.",
journal = "Electrochem",
title = "Micromolar Levofloxacin Sensor by Incorporating Highly Crystalline Co3O4 into a Carbon Paste Electrode Structure",
volume = "5",
number = "1",
pages = "45-56",
doi = "10.3390/electrochem5010003"
}
Mutić, T., Stanković, D. M., Manojlović, D., Petrić, Đ., Pastor, F., Avdin, V. V., Ognjanović, M.,& Stanković, V.. (2024). Micromolar Levofloxacin Sensor by Incorporating Highly Crystalline Co3O4 into a Carbon Paste Electrode Structure. in Electrochem, 5(1), 45-56.
https://doi.org/10.3390/electrochem5010003
Mutić T, Stanković DM, Manojlović D, Petrić Đ, Pastor F, Avdin VV, Ognjanović M, Stanković V. Micromolar Levofloxacin Sensor by Incorporating Highly Crystalline Co3O4 into a Carbon Paste Electrode Structure. in Electrochem. 2024;5(1):45-56.
doi:10.3390/electrochem5010003 .
Mutić, Tijana, Stanković, Dalibor M., Manojlović, Dragan, Petrić, Đorđe, Pastor, Ferenc, Avdin, Vyacheslav V., Ognjanović, Miloš, Stanković, Vesna, "Micromolar Levofloxacin Sensor by Incorporating Highly Crystalline Co3O4 into a Carbon Paste Electrode Structure" in Electrochem, 5, no. 1 (2024):45-56,
https://doi.org/10.3390/electrochem5010003 . .
1
1

FeM/rGO (M = Ni and Cu) as bifunctional oxygen electrode

Milikić, Jadranka; Nastasić, Ana; Rakočević, Lazar; Radinović, Kristina; Stojadinović, Stevan; Stanković, Dalibor; Šljukić, Biljana

(2024)

TY  - JOUR
AU  - Milikić, Jadranka
AU  - Nastasić, Ana
AU  - Rakočević, Lazar
AU  - Radinović, Kristina
AU  - Stojadinović, Stevan
AU  - Stanković, Dalibor
AU  - Šljukić, Biljana
PY  - 2024
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/13174
AB  - Three different iron-based electrocatalysts deposited on reduced graphene oxide (Fe/rGO, FeNi/rGO, and FeCu/ rGO) were synthesized and examined for oxygen reduction and evolution reactions (ORR and OER, respectively) in alkaline media. X-ray powder diffraction analysis, Fourier transform infrared spectroscopy, scanning electron microscopy with energy-dispersive X-ray spectroscopy, X-ray photoelectron spectroscopy, and transmission electron microscopy were used for a thorough investigation of physico-chemical properties of FeM/rGO electrocatalysts. XPS analysis indicated the presence of transition metals in higher oxidation states. Onset potentials during OER were found to be 1.51, 1.64, and 1.71 V for FeNi/rGO, FeCu/rGO, and Fe/rGO, respectively. Moreover, FeNi/rGO showed the highest OER current density (~40 mA cm benchmark OER electrocatalyst, IrO 2 2 at 2 V), two times higher than the -1 , and the lowest Tafel slope (88 mV dec ), lower than IrO . The somewhat better catalytic activity of Fe/rGO for ORR in alkaline media compared to FeNi/rGO and FeCu/rGO was noticed. Tafel slopes of 105, 112, and 113 mV dec 2-1 during ORR were found for Fe/rGO, FeCu/rGO, and FeNi/rGO, respectively. Almost constant ORR current densities during chronoamperometric measurements were noticed for Fe/rGO and FeCu/rGO indicating stable performance.
T2  - Fuel
T1  - FeM/rGO (M = Ni and Cu) as bifunctional oxygen electrode
VL  - 368
SP  - 131654
DO  - 10.1016/j.fuel.2024.131654
ER  - 
@article{
author = "Milikić, Jadranka and Nastasić, Ana and Rakočević, Lazar and Radinović, Kristina and Stojadinović, Stevan and Stanković, Dalibor and Šljukić, Biljana",
year = "2024",
abstract = "Three different iron-based electrocatalysts deposited on reduced graphene oxide (Fe/rGO, FeNi/rGO, and FeCu/ rGO) were synthesized and examined for oxygen reduction and evolution reactions (ORR and OER, respectively) in alkaline media. X-ray powder diffraction analysis, Fourier transform infrared spectroscopy, scanning electron microscopy with energy-dispersive X-ray spectroscopy, X-ray photoelectron spectroscopy, and transmission electron microscopy were used for a thorough investigation of physico-chemical properties of FeM/rGO electrocatalysts. XPS analysis indicated the presence of transition metals in higher oxidation states. Onset potentials during OER were found to be 1.51, 1.64, and 1.71 V for FeNi/rGO, FeCu/rGO, and Fe/rGO, respectively. Moreover, FeNi/rGO showed the highest OER current density (~40 mA cm benchmark OER electrocatalyst, IrO 2 2 at 2 V), two times higher than the -1 , and the lowest Tafel slope (88 mV dec ), lower than IrO . The somewhat better catalytic activity of Fe/rGO for ORR in alkaline media compared to FeNi/rGO and FeCu/rGO was noticed. Tafel slopes of 105, 112, and 113 mV dec 2-1 during ORR were found for Fe/rGO, FeCu/rGO, and FeNi/rGO, respectively. Almost constant ORR current densities during chronoamperometric measurements were noticed for Fe/rGO and FeCu/rGO indicating stable performance.",
journal = "Fuel",
title = "FeM/rGO (M = Ni and Cu) as bifunctional oxygen electrode",
volume = "368",
pages = "131654",
doi = "10.1016/j.fuel.2024.131654"
}
Milikić, J., Nastasić, A., Rakočević, L., Radinović, K., Stojadinović, S., Stanković, D.,& Šljukić, B.. (2024). FeM/rGO (M = Ni and Cu) as bifunctional oxygen electrode. in Fuel, 368, 131654.
https://doi.org/10.1016/j.fuel.2024.131654
Milikić J, Nastasić A, Rakočević L, Radinović K, Stojadinović S, Stanković D, Šljukić B. FeM/rGO (M = Ni and Cu) as bifunctional oxygen electrode. in Fuel. 2024;368:131654.
doi:10.1016/j.fuel.2024.131654 .
Milikić, Jadranka, Nastasić, Ana, Rakočević, Lazar, Radinović, Kristina, Stojadinović, Stevan, Stanković, Dalibor, Šljukić, Biljana, "FeM/rGO (M = Ni and Cu) as bifunctional oxygen electrode" in Fuel, 368 (2024):131654,
https://doi.org/10.1016/j.fuel.2024.131654 . .

Mechanical activation and silver supplementation as determinants of the antibacterial activity of titanium dioxide nanoparticles

Anđelković, Ljubica; Šuljagić, Marija; Pavlović, Vladimir; Mirković, Miljana; Vrbica, Boško; Novaković, Irena; Stanković, Dalibor; Kremenović, Aleksandar; Uskoković, Vuk

(2024)

TY  - JOUR
AU  - Anđelković, Ljubica
AU  - Šuljagić, Marija
AU  - Pavlović, Vladimir
AU  - Mirković, Miljana
AU  - Vrbica, Boško
AU  - Novaković, Irena
AU  - Stanković, Dalibor
AU  - Kremenović, Aleksandar
AU  - Uskoković, Vuk
PY  - 2024
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/13175
AB  - Metals and metal oxides have subpar antibacterial activities compared to those of small-molecule antibiotics, yet there are hopes that with proper compositional and structural adjustments this gap might be bridged. In this study, titanium dioxide (TiO2) nanoparticles were mechanically activated and combined with particulate silver through simple reduction process elicited by UV irradiation and assisted with the ultrasound. The resulting powders in various combinations (Ag vs. no Ag, activated vs. non-activated) were characterized using a range of experimental techniques and assessed for their antibacterial activities. The preparation procedure presented in this work prevails over the disadvantages of many chemical routes, most critically by avoiding the use of toxic substances. The mechanical activation did not reduce the particle size or crystallinity of TiO2 nor did it consistently alter the bandgap, yet it enabled the doubling of the amount of silver incorporable into the material. Further, while both mechanical activation and the addition of silver in the amount not exceeding 0.5 wt% produced barely detectable structural changes in the material, they both augmented its antibacterial activity. The precursor TiO2 powder produced no inhibition zone against any of the four bacterial species tested, while the mechanical activation of TiO2 led to the formation of distinct inhibition zones against each of the four bacterial species tested. The addition of silver to activated TiO2 further widened the inhibition zones and it also imparted the antibacterial activity to non-activated TiO2. The boost in the antibacterial activity achieved by the short mechanical activation was of a similar magnitude as the boost obtained after the addition of silver. The antibacterial activity was not different for different species when no silver was added to the system. However, with the addition of silver, species selectivity was obtained, as the composites were more effective against the two Gram-negative species (Escherichia coli and Klebsiella pneumoniae) than against the two Gram-positive ones (Staphylococcus aureus and Bacillus subtilis). The antibacterial activity increased with the addition of silver in the broth assay, but it was mediocre compared to that detected in the agar assay, attesting to the poor dispersability of the powders and their best performance when the bacterial cells migrate to the composite surface than vice versa. The findings of this study give hope that with appropriate microstructural or compositional alterations, the antibacterial activity of metal oxide powders and inorganic materials in general can be made comparable to that of small-molecule antibiotics.
T2  - Colloids and Surfaces A: Physicochemical and Engineering Aspects
T1  - Mechanical activation and silver supplementation as determinants of the antibacterial activity of titanium dioxide nanoparticles
VL  - 691
SP  - 133890
DO  - 10.1016/j.colsurfa.2024.133890
ER  - 
@article{
author = "Anđelković, Ljubica and Šuljagić, Marija and Pavlović, Vladimir and Mirković, Miljana and Vrbica, Boško and Novaković, Irena and Stanković, Dalibor and Kremenović, Aleksandar and Uskoković, Vuk",
year = "2024",
abstract = "Metals and metal oxides have subpar antibacterial activities compared to those of small-molecule antibiotics, yet there are hopes that with proper compositional and structural adjustments this gap might be bridged. In this study, titanium dioxide (TiO2) nanoparticles were mechanically activated and combined with particulate silver through simple reduction process elicited by UV irradiation and assisted with the ultrasound. The resulting powders in various combinations (Ag vs. no Ag, activated vs. non-activated) were characterized using a range of experimental techniques and assessed for their antibacterial activities. The preparation procedure presented in this work prevails over the disadvantages of many chemical routes, most critically by avoiding the use of toxic substances. The mechanical activation did not reduce the particle size or crystallinity of TiO2 nor did it consistently alter the bandgap, yet it enabled the doubling of the amount of silver incorporable into the material. Further, while both mechanical activation and the addition of silver in the amount not exceeding 0.5 wt% produced barely detectable structural changes in the material, they both augmented its antibacterial activity. The precursor TiO2 powder produced no inhibition zone against any of the four bacterial species tested, while the mechanical activation of TiO2 led to the formation of distinct inhibition zones against each of the four bacterial species tested. The addition of silver to activated TiO2 further widened the inhibition zones and it also imparted the antibacterial activity to non-activated TiO2. The boost in the antibacterial activity achieved by the short mechanical activation was of a similar magnitude as the boost obtained after the addition of silver. The antibacterial activity was not different for different species when no silver was added to the system. However, with the addition of silver, species selectivity was obtained, as the composites were more effective against the two Gram-negative species (Escherichia coli and Klebsiella pneumoniae) than against the two Gram-positive ones (Staphylococcus aureus and Bacillus subtilis). The antibacterial activity increased with the addition of silver in the broth assay, but it was mediocre compared to that detected in the agar assay, attesting to the poor dispersability of the powders and their best performance when the bacterial cells migrate to the composite surface than vice versa. The findings of this study give hope that with appropriate microstructural or compositional alterations, the antibacterial activity of metal oxide powders and inorganic materials in general can be made comparable to that of small-molecule antibiotics.",
journal = "Colloids and Surfaces A: Physicochemical and Engineering Aspects",
title = "Mechanical activation and silver supplementation as determinants of the antibacterial activity of titanium dioxide nanoparticles",
volume = "691",
pages = "133890",
doi = "10.1016/j.colsurfa.2024.133890"
}
Anđelković, L., Šuljagić, M., Pavlović, V., Mirković, M., Vrbica, B., Novaković, I., Stanković, D., Kremenović, A.,& Uskoković, V.. (2024). Mechanical activation and silver supplementation as determinants of the antibacterial activity of titanium dioxide nanoparticles. in Colloids and Surfaces A: Physicochemical and Engineering Aspects, 691, 133890.
https://doi.org/10.1016/j.colsurfa.2024.133890
Anđelković L, Šuljagić M, Pavlović V, Mirković M, Vrbica B, Novaković I, Stanković D, Kremenović A, Uskoković V. Mechanical activation and silver supplementation as determinants of the antibacterial activity of titanium dioxide nanoparticles. in Colloids and Surfaces A: Physicochemical and Engineering Aspects. 2024;691:133890.
doi:10.1016/j.colsurfa.2024.133890 .
Anđelković, Ljubica, Šuljagić, Marija, Pavlović, Vladimir, Mirković, Miljana, Vrbica, Boško, Novaković, Irena, Stanković, Dalibor, Kremenović, Aleksandar, Uskoković, Vuk, "Mechanical activation and silver supplementation as determinants of the antibacterial activity of titanium dioxide nanoparticles" in Colloids and Surfaces A: Physicochemical and Engineering Aspects, 691 (2024):133890,
https://doi.org/10.1016/j.colsurfa.2024.133890 . .

Influence of Modification on the Textural Properties of the Natural Zeolite and Its Efficiency for the Heavy Metals Ions Removal from Contaminated Aqueous Solution

Kragović, Milan; Gulicovski, Jelena; Milićević, Sonja; Pašalić, Snežana; Dašić, Predrag; Ristović, Ivica; Stojmenović, Marija

(Springer Science and Business Media, 2024)

TY  - CONF
AU  - Kragović, Milan
AU  - Gulicovski, Jelena
AU  - Milićević, Sonja
AU  - Pašalić, Snežana
AU  - Dašić, Predrag
AU  - Ristović, Ivica
AU  - Stojmenović, Marija
PY  - 2024
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/13217
AB  - The influence of modification on the textural properties of the natural zeolite (NZ) and its efficiency for the heavy metals ions removal from contaminated aqueous solution was investigated. The mineralogical composition of the NZ showed that the dominant mineral is clinoptilolite. The surface of the NZ was modified combining the methods for pure goethite and iron-coated zeolite preparations. After modification, the cation exchange capacities and the specific surface area increased from 30.2 to 52.5 m2/g, i.e., from 141 to 165 meq/100g, respectively. Adsorption experiments were done for different heavy metals initial concentrations (copper(II) 0.8 - 12.6 Cu2+mmol/dm3 or lead(II) 1.9 – 29.0 Pb2+mmol/dm3), for 24h, at pH 4.2, in batch conditions. Results showed positive influence of modification on the heavy metals ions removal. The results were fitted with Langmuir and Freundlich adsorption models, and the best fits were obtained with Freundlich model (R2 > 0.92).
PB  - Springer Science and Business Media
C3  - The 17th International Conference Interdisciplinarity in Engineering : Conference Proceedings
T1  - Influence of Modification on the Textural Properties of the Natural Zeolite and Its Efficiency for the Heavy Metals Ions Removal from Contaminated Aqueous Solution
VL  - 926
VL  - 1
SP  - 267
EP  - 276
DO  - 10.1007/978-3-031-54664-8_25
ER  - 
@conference{
author = "Kragović, Milan and Gulicovski, Jelena and Milićević, Sonja and Pašalić, Snežana and Dašić, Predrag and Ristović, Ivica and Stojmenović, Marija",
year = "2024",
abstract = "The influence of modification on the textural properties of the natural zeolite (NZ) and its efficiency for the heavy metals ions removal from contaminated aqueous solution was investigated. The mineralogical composition of the NZ showed that the dominant mineral is clinoptilolite. The surface of the NZ was modified combining the methods for pure goethite and iron-coated zeolite preparations. After modification, the cation exchange capacities and the specific surface area increased from 30.2 to 52.5 m2/g, i.e., from 141 to 165 meq/100g, respectively. Adsorption experiments were done for different heavy metals initial concentrations (copper(II) 0.8 - 12.6 Cu2+mmol/dm3 or lead(II) 1.9 – 29.0 Pb2+mmol/dm3), for 24h, at pH 4.2, in batch conditions. Results showed positive influence of modification on the heavy metals ions removal. The results were fitted with Langmuir and Freundlich adsorption models, and the best fits were obtained with Freundlich model (R2 > 0.92).",
publisher = "Springer Science and Business Media",
journal = "The 17th International Conference Interdisciplinarity in Engineering : Conference Proceedings",
title = "Influence of Modification on the Textural Properties of the Natural Zeolite and Its Efficiency for the Heavy Metals Ions Removal from Contaminated Aqueous Solution",
volume = "926, 1",
pages = "267-276",
doi = "10.1007/978-3-031-54664-8_25"
}
Kragović, M., Gulicovski, J., Milićević, S., Pašalić, S., Dašić, P., Ristović, I.,& Stojmenović, M.. (2024). Influence of Modification on the Textural Properties of the Natural Zeolite and Its Efficiency for the Heavy Metals Ions Removal from Contaminated Aqueous Solution. in The 17th International Conference Interdisciplinarity in Engineering : Conference Proceedings
Springer Science and Business Media., 926, 267-276.
https://doi.org/10.1007/978-3-031-54664-8_25
Kragović M, Gulicovski J, Milićević S, Pašalić S, Dašić P, Ristović I, Stojmenović M. Influence of Modification on the Textural Properties of the Natural Zeolite and Its Efficiency for the Heavy Metals Ions Removal from Contaminated Aqueous Solution. in The 17th International Conference Interdisciplinarity in Engineering : Conference Proceedings. 2024;926:267-276.
doi:10.1007/978-3-031-54664-8_25 .
Kragović, Milan, Gulicovski, Jelena, Milićević, Sonja, Pašalić, Snežana, Dašić, Predrag, Ristović, Ivica, Stojmenović, Marija, "Influence of Modification on the Textural Properties of the Natural Zeolite and Its Efficiency for the Heavy Metals Ions Removal from Contaminated Aqueous Solution" in The 17th International Conference Interdisciplinarity in Engineering : Conference Proceedings, 926 (2024):267-276,
https://doi.org/10.1007/978-3-031-54664-8_25 . .

Sustainable Application of Waste Sludges from the Wastewater Treatment Plant Generated during the Production of Heating Devices in the Construction Industry

Stojmenović, Marija; Gulicovski, Jelena; Nišić, Neda; Ristić, Nenad; Liu, Shanke; Loredo, Jorge; Kragović, Milan

(2024)

TY  - JOUR
AU  - Stojmenović, Marija
AU  - Gulicovski, Jelena
AU  - Nišić, Neda
AU  - Ristić, Nenad
AU  - Liu, Shanke
AU  - Loredo, Jorge
AU  - Kragović, Milan
PY  - 2024
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/12916
AB  - This research presented, for the first time, the results of the successful application of the waste press sludges, WSLP (plant for lacquer and paint) and WSEP (powdery enamel plant), from a wastewater treatment plant generated during heating device production in the construction industry. The results of WSEP characterization and its influence on cement paste, mortar, and concrete properties showed that this material could be used as a cement replacement (with a maximum replacement amount of 20%) in producing mortar and concrete. Although waste WSLP sludge does not possess pozzolanic properties and does not meet the criteria prescribed by the standards for application in mortar and concrete due to its chemical inertness and fineness, as well as its extended setting time, it can be used as a replacement for stone filler or other powdered mineral admixture in the production of self-compacting concrete (SCC) in amounts up to 100%, with a maximum quantity of up to 100 kg/m3. The obtained results indicate that with the appropriate conversion, waste sludges, despite representing hazardous waste, can be used as safe products in the construction industry; i.e., the waste material can become a useful and valuable raw material by applying (respecting) all of the principles of the green economy.
T2  - Materials
T1  - Sustainable Application of Waste Sludges from the Wastewater Treatment Plant Generated during the Production of Heating Devices in the Construction Industry
VL  - 17
IS  - 5
SP  - 1089
DO  - 10.3390/ma17051089
ER  - 
@article{
author = "Stojmenović, Marija and Gulicovski, Jelena and Nišić, Neda and Ristić, Nenad and Liu, Shanke and Loredo, Jorge and Kragović, Milan",
year = "2024",
abstract = "This research presented, for the first time, the results of the successful application of the waste press sludges, WSLP (plant for lacquer and paint) and WSEP (powdery enamel plant), from a wastewater treatment plant generated during heating device production in the construction industry. The results of WSEP characterization and its influence on cement paste, mortar, and concrete properties showed that this material could be used as a cement replacement (with a maximum replacement amount of 20%) in producing mortar and concrete. Although waste WSLP sludge does not possess pozzolanic properties and does not meet the criteria prescribed by the standards for application in mortar and concrete due to its chemical inertness and fineness, as well as its extended setting time, it can be used as a replacement for stone filler or other powdered mineral admixture in the production of self-compacting concrete (SCC) in amounts up to 100%, with a maximum quantity of up to 100 kg/m3. The obtained results indicate that with the appropriate conversion, waste sludges, despite representing hazardous waste, can be used as safe products in the construction industry; i.e., the waste material can become a useful and valuable raw material by applying (respecting) all of the principles of the green economy.",
journal = "Materials",
title = "Sustainable Application of Waste Sludges from the Wastewater Treatment Plant Generated during the Production of Heating Devices in the Construction Industry",
volume = "17",
number = "5",
pages = "1089",
doi = "10.3390/ma17051089"
}
Stojmenović, M., Gulicovski, J., Nišić, N., Ristić, N., Liu, S., Loredo, J.,& Kragović, M.. (2024). Sustainable Application of Waste Sludges from the Wastewater Treatment Plant Generated during the Production of Heating Devices in the Construction Industry. in Materials, 17(5), 1089.
https://doi.org/10.3390/ma17051089
Stojmenović M, Gulicovski J, Nišić N, Ristić N, Liu S, Loredo J, Kragović M. Sustainable Application of Waste Sludges from the Wastewater Treatment Plant Generated during the Production of Heating Devices in the Construction Industry. in Materials. 2024;17(5):1089.
doi:10.3390/ma17051089 .
Stojmenović, Marija, Gulicovski, Jelena, Nišić, Neda, Ristić, Nenad, Liu, Shanke, Loredo, Jorge, Kragović, Milan, "Sustainable Application of Waste Sludges from the Wastewater Treatment Plant Generated during the Production of Heating Devices in the Construction Industry" in Materials, 17, no. 5 (2024):1089,
https://doi.org/10.3390/ma17051089 . .
1

Mineralogical Characterization of the Grot Lead and Zinc Mine Tailings from Aspects of Their Further Use as Raw Material

Gulicovski, Jelena; Stojmenović, Marija; Rosić, Milena; Vasić, Andrijana; Ristović, Ivica; Janković-Častvan, Ivona; Kragović, Milan

(2024)

TY  - JOUR
AU  - Gulicovski, Jelena
AU  - Stojmenović, Marija
AU  - Rosić, Milena
AU  - Vasić, Andrijana
AU  - Ristović, Ivica
AU  - Janković-Častvan, Ivona
AU  - Kragović, Milan
PY  - 2024
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/12917
AB  - The possibility of using waste tailings produced by flotation in the lead and zinc mine of Grot, Serbia as a potential source of secondary mineral raw materials was examined. The aim of the research was primarily to carry out a detailed characterization in order to determine the dominant minerals, and, for the first time, to trace the changes occurring in the unit cells of the minerals present in that deposit. There was also a need to determine the exact proportions of the present mineral phases for their further application and utilization as natural resources in environmental protection. Samples were taken from three different sections of tailings: the crest of dam (JKB), outlet pipe of the flotation facility (JOF) and hydrocyclone overflow (JHC). Granulometric separation was performed to facilitate the extraction of certain minerals from waste. The results showed that all samples mainly contained quartz, clinochlore, calcite, albite, pyrite and biotite, but their ratios in each sample varied significantly. After characterization, samples were separated into different fractions and their mineralogical compositions were determined. Depending on the fraction, the mineralogical compositions also changed. Mineralogy and geochemical analysis indicate that waste tailings can be used as a secondary mineral raw materials source applicable in various industries.
T2  - Applied Sciences
T1  - Mineralogical Characterization of the Grot Lead and Zinc Mine Tailings from Aspects of Their Further Use as Raw Material
VL  - 14
IS  - 3
SP  - 1167
DO  - 10.3390/app14031167
ER  - 
@article{
author = "Gulicovski, Jelena and Stojmenović, Marija and Rosić, Milena and Vasić, Andrijana and Ristović, Ivica and Janković-Častvan, Ivona and Kragović, Milan",
year = "2024",
abstract = "The possibility of using waste tailings produced by flotation in the lead and zinc mine of Grot, Serbia as a potential source of secondary mineral raw materials was examined. The aim of the research was primarily to carry out a detailed characterization in order to determine the dominant minerals, and, for the first time, to trace the changes occurring in the unit cells of the minerals present in that deposit. There was also a need to determine the exact proportions of the present mineral phases for their further application and utilization as natural resources in environmental protection. Samples were taken from three different sections of tailings: the crest of dam (JKB), outlet pipe of the flotation facility (JOF) and hydrocyclone overflow (JHC). Granulometric separation was performed to facilitate the extraction of certain minerals from waste. The results showed that all samples mainly contained quartz, clinochlore, calcite, albite, pyrite and biotite, but their ratios in each sample varied significantly. After characterization, samples were separated into different fractions and their mineralogical compositions were determined. Depending on the fraction, the mineralogical compositions also changed. Mineralogy and geochemical analysis indicate that waste tailings can be used as a secondary mineral raw materials source applicable in various industries.",
journal = "Applied Sciences",
title = "Mineralogical Characterization of the Grot Lead and Zinc Mine Tailings from Aspects of Their Further Use as Raw Material",
volume = "14",
number = "3",
pages = "1167",
doi = "10.3390/app14031167"
}
Gulicovski, J., Stojmenović, M., Rosić, M., Vasić, A., Ristović, I., Janković-Častvan, I.,& Kragović, M.. (2024). Mineralogical Characterization of the Grot Lead and Zinc Mine Tailings from Aspects of Their Further Use as Raw Material. in Applied Sciences, 14(3), 1167.
https://doi.org/10.3390/app14031167
Gulicovski J, Stojmenović M, Rosić M, Vasić A, Ristović I, Janković-Častvan I, Kragović M. Mineralogical Characterization of the Grot Lead and Zinc Mine Tailings from Aspects of Their Further Use as Raw Material. in Applied Sciences. 2024;14(3):1167.
doi:10.3390/app14031167 .
Gulicovski, Jelena, Stojmenović, Marija, Rosić, Milena, Vasić, Andrijana, Ristović, Ivica, Janković-Častvan, Ivona, Kragović, Milan, "Mineralogical Characterization of the Grot Lead and Zinc Mine Tailings from Aspects of Their Further Use as Raw Material" in Applied Sciences, 14, no. 3 (2024):1167,
https://doi.org/10.3390/app14031167 . .

Pokretna instalacija za etaloniranјe pretvarača diferencijalnog pritiska koji rade na visokom statičkom pritisku

Vučićević, Biljana; Turanjanin, Valentina; Marković, Zoran; Mrđa, Dragoslav; Mladenović, Milica

(2024)


                                            

                                            
Vučićević, B., Turanjanin, V., Marković, Z., Mrđa, D.,& Mladenović, M.. (2024). Pokretna instalacija za etaloniranјe pretvarača diferencijalnog pritiska koji rade na visokom statičkom pritisku. in Univerzitet u Beogradu : Institut za nuklearne nauke "Vinča" - Institut od nacionalnog značaja za Republiku Srbiju.
https://hdl.handle.net/21.15107/rcub_vinar_12992
Vučićević B, Turanjanin V, Marković Z, Mrđa D, Mladenović M. Pokretna instalacija za etaloniranјe pretvarača diferencijalnog pritiska koji rade na visokom statičkom pritisku. in Univerzitet u Beogradu : Institut za nuklearne nauke "Vinča" - Institut od nacionalnog značaja za Republiku Srbiju. 2024;.
https://hdl.handle.net/21.15107/rcub_vinar_12992 .
Vučićević, Biljana, Turanjanin, Valentina, Marković, Zoran, Mrđa, Dragoslav, Mladenović, Milica, "Pokretna instalacija za etaloniranјe pretvarača diferencijalnog pritiska koji rade na visokom statičkom pritisku" in Univerzitet u Beogradu : Institut za nuklearne nauke "Vinča" - Institut od nacionalnog značaja za Republiku Srbiju (2024),
https://hdl.handle.net/21.15107/rcub_vinar_12992 .

Impact of lockdown on air quality in Belgrade during COVID-19 pandemic

Vučićević, Biljana; Živković, Marija M.; Turanjanin, Valentina; Bakić, Vukman; Jovanović, Marina

(2024)

TY  - JOUR
AU  - Vučićević, Biljana
AU  - Živković, Marija M.
AU  - Turanjanin, Valentina
AU  - Bakić, Vukman
AU  - Jovanović, Marina
PY  - 2024
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/13216
AB  - The Environmental Protection Agency of the Republic of Serbia continuously monitors and collects air quality parameters at numerous measuring points throughout the country. The results revealed that the levels of air pollution recorded during the lockdown differed from those recorded during the same period the previous years. In this paper, we examined pollutant concentration trends in 2020 and a few previous years to determine the underlying causes of these trends. Pollutants are measured at five stations in Belgrade from the beginning of March to the end of July between 2015 and 2020. Because no hourly data were available, NO2, SO2, and suspended particles PM10 and PM2.5 are average daily values, whereas CO and ozone are daily 8-hour maximums. Concentrations were compared and averaged only when data for the same period over time was available, i.e. when comparing 2020 to previous years. The results were compared to the annual and daily limit values (for ozone and CO 8 hours maximum, respectively), as well as the variations in concentrations over time. The goal of calculating and displaying these values is to specifically identify a change in air pollution during the COVID-19 virus pandemic isolation period. In general, for Belgrade in 2020, NO2 concentrations are lower at four stations, PM2.5 concentrations are lower at two stations, PM10 concentrations are higher at one station and lower at another, and SO2 concentrations are higher than in previous years (2015-2019).
T2  - Thermal Science
T1  - Impact of lockdown on air quality in Belgrade during COVID-19 pandemic
VL  - 28
IS  - 1 Part B
SP  - 557
EP  - 567
DO  - 10.2298/TSCI230706212V
ER  - 
@article{
author = "Vučićević, Biljana and Živković, Marija M. and Turanjanin, Valentina and Bakić, Vukman and Jovanović, Marina",
year = "2024",
abstract = "The Environmental Protection Agency of the Republic of Serbia continuously monitors and collects air quality parameters at numerous measuring points throughout the country. The results revealed that the levels of air pollution recorded during the lockdown differed from those recorded during the same period the previous years. In this paper, we examined pollutant concentration trends in 2020 and a few previous years to determine the underlying causes of these trends. Pollutants are measured at five stations in Belgrade from the beginning of March to the end of July between 2015 and 2020. Because no hourly data were available, NO2, SO2, and suspended particles PM10 and PM2.5 are average daily values, whereas CO and ozone are daily 8-hour maximums. Concentrations were compared and averaged only when data for the same period over time was available, i.e. when comparing 2020 to previous years. The results were compared to the annual and daily limit values (for ozone and CO 8 hours maximum, respectively), as well as the variations in concentrations over time. The goal of calculating and displaying these values is to specifically identify a change in air pollution during the COVID-19 virus pandemic isolation period. In general, for Belgrade in 2020, NO2 concentrations are lower at four stations, PM2.5 concentrations are lower at two stations, PM10 concentrations are higher at one station and lower at another, and SO2 concentrations are higher than in previous years (2015-2019).",
journal = "Thermal Science",
title = "Impact of lockdown on air quality in Belgrade during COVID-19 pandemic",
volume = "28",
number = "1 Part B",
pages = "557-567",
doi = "10.2298/TSCI230706212V"
}
Vučićević, B., Živković, M. M., Turanjanin, V., Bakić, V.,& Jovanović, M.. (2024). Impact of lockdown on air quality in Belgrade during COVID-19 pandemic. in Thermal Science, 28(1 Part B), 557-567.
https://doi.org/10.2298/TSCI230706212V
Vučićević B, Živković MM, Turanjanin V, Bakić V, Jovanović M. Impact of lockdown on air quality in Belgrade during COVID-19 pandemic. in Thermal Science. 2024;28(1 Part B):557-567.
doi:10.2298/TSCI230706212V .
Vučićević, Biljana, Živković, Marija M., Turanjanin, Valentina, Bakić, Vukman, Jovanović, Marina, "Impact of lockdown on air quality in Belgrade during COVID-19 pandemic" in Thermal Science, 28, no. 1 Part B (2024):557-567,
https://doi.org/10.2298/TSCI230706212V . .

Removal of lead and cadmium from aqueous solution using octacalcium phosphate as an adsorbent

Mirković, Miljana; Bracanović, Ivan; Krstić, Aleksandar; Đukić, Dunja; Dodevski, Vladimir; Kalijadis, Ana

(2024)

TY  - JOUR
AU  - Mirković, Miljana
AU  - Bracanović, Ivan
AU  - Krstić, Aleksandar
AU  - Đukić, Dunja
AU  - Dodevski, Vladimir
AU  - Kalijadis, Ana
PY  - 2024
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/12991
AB  - Octacalcium phosphate (OCP) is a material from the calcium phos-phate group with a crystal structure similar to hydroxyapatite. The removal process of lead and cadmium in aqueous solution using octacalcium phosphate material was investigated. OCP material was synthesized by the solution pre-cipitation method. The structural and phase properties of OCP before and after the removal process were determined by the X-ray diffraction (XRD) method. Microstructural and semi-quantitative analysis of the material was investigated by  scanning  electron  microscopy  and  energy  dispersive  X-ray  spectroscopy (SEM-EDS).  Characteristic  bands  and  functional  group  determination  were revealed  using  the  Fourier-transform  infrared  spectroscopy  with  attenuated total  reflection  (FTIR-ATR).  As  target  pollutants,  Cd(II)  and  Pb(II)  were chosen in adsorption experiments. Results show that OCP in the first 10 min has a very fast removal rate for Pb(II); the equilibrium state was reached after 10 min with more than 98 % adsorption efficiency. Results for Cd(II), results showed  the  same  removal  rate  but  somewhat    lower  adsorption  efficiency, amounted to approximately 63 %.
T2  - Journal of the Serbian Chemical Society
T1  - Removal of lead and cadmium from aqueous solution using octacalcium phosphate as an adsorbent
T1  - Uklanjanje olova i kadmijuma iz vodenog rastvora koristeći okrakalcijum-fosfat kao adsorbent
VL  - 89
IS  - 2
SP  - 231
EP  - 244
DO  - 10.2298/JSC230915104M
ER  - 
@article{
author = "Mirković, Miljana and Bracanović, Ivan and Krstić, Aleksandar and Đukić, Dunja and Dodevski, Vladimir and Kalijadis, Ana",
year = "2024",
abstract = "Octacalcium phosphate (OCP) is a material from the calcium phos-phate group with a crystal structure similar to hydroxyapatite. The removal process of lead and cadmium in aqueous solution using octacalcium phosphate material was investigated. OCP material was synthesized by the solution pre-cipitation method. The structural and phase properties of OCP before and after the removal process were determined by the X-ray diffraction (XRD) method. Microstructural and semi-quantitative analysis of the material was investigated by  scanning  electron  microscopy  and  energy  dispersive  X-ray  spectroscopy (SEM-EDS).  Characteristic  bands  and  functional  group  determination  were revealed  using  the  Fourier-transform  infrared  spectroscopy  with  attenuated total  reflection  (FTIR-ATR).  As  target  pollutants,  Cd(II)  and  Pb(II)  were chosen in adsorption experiments. Results show that OCP in the first 10 min has a very fast removal rate for Pb(II); the equilibrium state was reached after 10 min with more than 98 % adsorption efficiency. Results for Cd(II), results showed  the  same  removal  rate  but  somewhat    lower  adsorption  efficiency, amounted to approximately 63 %.",
journal = "Journal of the Serbian Chemical Society",
title = "Removal of lead and cadmium from aqueous solution using octacalcium phosphate as an adsorbent, Uklanjanje olova i kadmijuma iz vodenog rastvora koristeći okrakalcijum-fosfat kao adsorbent",
volume = "89",
number = "2",
pages = "231-244",
doi = "10.2298/JSC230915104M"
}
Mirković, M., Bracanović, I., Krstić, A., Đukić, D., Dodevski, V.,& Kalijadis, A.. (2024). Removal of lead and cadmium from aqueous solution using octacalcium phosphate as an adsorbent. in Journal of the Serbian Chemical Society, 89(2), 231-244.
https://doi.org/10.2298/JSC230915104M
Mirković M, Bracanović I, Krstić A, Đukić D, Dodevski V, Kalijadis A. Removal of lead and cadmium from aqueous solution using octacalcium phosphate as an adsorbent. in Journal of the Serbian Chemical Society. 2024;89(2):231-244.
doi:10.2298/JSC230915104M .
Mirković, Miljana, Bracanović, Ivan, Krstić, Aleksandar, Đukić, Dunja, Dodevski, Vladimir, Kalijadis, Ana, "Removal of lead and cadmium from aqueous solution using octacalcium phosphate as an adsorbent" in Journal of the Serbian Chemical Society, 89, no. 2 (2024):231-244,
https://doi.org/10.2298/JSC230915104M . .

Enhancement of weak ferromagnetism, exotic structure prediction and diverse electronic properties in bismuth ferrite and holmium-substituted multiferroic bismuth ferrite

Čebela, Maria; Turchenko, Vitalii; Rosić, Milena; Jordanov, Dragana; Dodevski, Vladimir; Zagorac, Dejan

(Belgrade : Vinča Institute of Nuclear Sciences - National Institute of thе Republic of Serbia, University of Belgrade, 2024)

TY  - CONF
AU  - Čebela, Maria
AU  - Turchenko, Vitalii
AU  - Rosić, Milena
AU  - Jordanov, Dragana
AU  - Dodevski, Vladimir
AU  - Zagorac, Dejan
PY  - 2024
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/13142
PB  - Belgrade : Vinča Institute of Nuclear Sciences - National Institute of thе Republic of Serbia, University of Belgrade
PB  - Belgrade : Serbian Society for Innovative Materials in Extreme Conditions (SIM-EXTREME)
C3  - IMEC2024 - 2nd International Conference on Innovative Materials in Extreme Conditions : Book of abstracts
T1  - Enhancement of weak ferromagnetism, exotic structure prediction and diverse electronic properties in bismuth ferrite and holmium-substituted multiferroic bismuth ferrite
SP  - 32
EP  - 32
UR  - https://hdl.handle.net/21.15107/rcub_vinar_13142
ER  - 
@conference{
author = "Čebela, Maria and Turchenko, Vitalii and Rosić, Milena and Jordanov, Dragana and Dodevski, Vladimir and Zagorac, Dejan",
year = "2024",
publisher = "Belgrade : Vinča Institute of Nuclear Sciences - National Institute of thе Republic of Serbia, University of Belgrade, Belgrade : Serbian Society for Innovative Materials in Extreme Conditions (SIM-EXTREME)",
journal = "IMEC2024 - 2nd International Conference on Innovative Materials in Extreme Conditions : Book of abstracts",
title = "Enhancement of weak ferromagnetism, exotic structure prediction and diverse electronic properties in bismuth ferrite and holmium-substituted multiferroic bismuth ferrite",
pages = "32-32",
url = "https://hdl.handle.net/21.15107/rcub_vinar_13142"
}
Čebela, M., Turchenko, V., Rosić, M., Jordanov, D., Dodevski, V.,& Zagorac, D.. (2024). Enhancement of weak ferromagnetism, exotic structure prediction and diverse electronic properties in bismuth ferrite and holmium-substituted multiferroic bismuth ferrite. in IMEC2024 - 2nd International Conference on Innovative Materials in Extreme Conditions : Book of abstracts
Belgrade : Vinča Institute of Nuclear Sciences - National Institute of thе Republic of Serbia, University of Belgrade., 32-32.
https://hdl.handle.net/21.15107/rcub_vinar_13142
Čebela M, Turchenko V, Rosić M, Jordanov D, Dodevski V, Zagorac D. Enhancement of weak ferromagnetism, exotic structure prediction and diverse electronic properties in bismuth ferrite and holmium-substituted multiferroic bismuth ferrite. in IMEC2024 - 2nd International Conference on Innovative Materials in Extreme Conditions : Book of abstracts. 2024;:32-32.
https://hdl.handle.net/21.15107/rcub_vinar_13142 .
Čebela, Maria, Turchenko, Vitalii, Rosić, Milena, Jordanov, Dragana, Dodevski, Vladimir, Zagorac, Dejan, "Enhancement of weak ferromagnetism, exotic structure prediction and diverse electronic properties in bismuth ferrite and holmium-substituted multiferroic bismuth ferrite" in IMEC2024 - 2nd International Conference on Innovative Materials in Extreme Conditions : Book of abstracts (2024):32-32,
https://hdl.handle.net/21.15107/rcub_vinar_13142 .

Spectroscopicand Morphological Properties of Co0.9Ho0.1MoO4 nanopowders

Rosić, Milena; Milošević, Maja; Dodevski, Vladimir; Jordanov, Dragana; Lojpur, Vesna; Vlašković, Tijana; Čebela, Maria

(Belgrade : Vinča Institute of Nuclear Sciences - National Institute of thе Republic of Serbia, University of Belgrade, 2024)

TY  - CONF
AU  - Rosić, Milena
AU  - Milošević, Maja
AU  - Dodevski, Vladimir
AU  - Jordanov, Dragana
AU  - Lojpur, Vesna
AU  - Vlašković, Tijana
AU  - Čebela, Maria
PY  - 2024
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/13160
PB  - Belgrade : Vinča Institute of Nuclear Sciences - National Institute of thе Republic of Serbia, University of Belgrade
PB  - Belgrade : Serbian Society for Innovative Materials in Extreme Conditions (SIM-EXTREME)
C3  - IMEC2024 - 2nd International Conference on Innovative Materials in Extreme Conditions : Book of abstracts
T1  - Spectroscopicand Morphological Properties of Co0.9Ho0.1MoO4 nanopowders
SP  - 64
EP  - 64
UR  - https://hdl.handle.net/21.15107/rcub_vinar_13160
ER  - 
@conference{
author = "Rosić, Milena and Milošević, Maja and Dodevski, Vladimir and Jordanov, Dragana and Lojpur, Vesna and Vlašković, Tijana and Čebela, Maria",
year = "2024",
publisher = "Belgrade : Vinča Institute of Nuclear Sciences - National Institute of thе Republic of Serbia, University of Belgrade, Belgrade : Serbian Society for Innovative Materials in Extreme Conditions (SIM-EXTREME)",
journal = "IMEC2024 - 2nd International Conference on Innovative Materials in Extreme Conditions : Book of abstracts",
title = "Spectroscopicand Morphological Properties of Co0.9Ho0.1MoO4 nanopowders",
pages = "64-64",
url = "https://hdl.handle.net/21.15107/rcub_vinar_13160"
}
Rosić, M., Milošević, M., Dodevski, V., Jordanov, D., Lojpur, V., Vlašković, T.,& Čebela, M.. (2024). Spectroscopicand Morphological Properties of Co0.9Ho0.1MoO4 nanopowders. in IMEC2024 - 2nd International Conference on Innovative Materials in Extreme Conditions : Book of abstracts
Belgrade : Vinča Institute of Nuclear Sciences - National Institute of thе Republic of Serbia, University of Belgrade., 64-64.
https://hdl.handle.net/21.15107/rcub_vinar_13160
Rosić M, Milošević M, Dodevski V, Jordanov D, Lojpur V, Vlašković T, Čebela M. Spectroscopicand Morphological Properties of Co0.9Ho0.1MoO4 nanopowders. in IMEC2024 - 2nd International Conference on Innovative Materials in Extreme Conditions : Book of abstracts. 2024;:64-64.
https://hdl.handle.net/21.15107/rcub_vinar_13160 .
Rosić, Milena, Milošević, Maja, Dodevski, Vladimir, Jordanov, Dragana, Lojpur, Vesna, Vlašković, Tijana, Čebela, Maria, "Spectroscopicand Morphological Properties of Co0.9Ho0.1MoO4 nanopowders" in IMEC2024 - 2nd International Conference on Innovative Materials in Extreme Conditions : Book of abstracts (2024):64-64,
https://hdl.handle.net/21.15107/rcub_vinar_13160 .

Preparation of Ca0.9Er0.1MnO3 nanopowders by combustion method

Vlašković, Tijana; Laban, Bojana; Čebela, Maria; Dodevski, Vladimir; Jordanov, Dragana; Rosić, Milena

(Belgrade : Vinča Institute of Nuclear Sciences - National Institute of thе Republic of Serbia, University of Belgrade, 2024)

TY  - CONF
AU  - Vlašković, Tijana
AU  - Laban, Bojana
AU  - Čebela, Maria
AU  - Dodevski, Vladimir
AU  - Jordanov, Dragana
AU  - Rosić, Milena
PY  - 2024
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/13162
PB  - Belgrade : Vinča Institute of Nuclear Sciences - National Institute of thе Republic of Serbia, University of Belgrade
PB  - Belgrade : Serbian Society for Innovative Materials in Extreme Conditions (SIM-EXTREME)
C3  - IMEC2024 - 2nd International Conference on Innovative Materials in Extreme Conditions : Book of abstracts
T1  - Preparation of Ca0.9Er0.1MnO3 nanopowders by combustion method
SP  - 66
EP  - 66
UR  - https://hdl.handle.net/21.15107/rcub_vinar_13162
ER  - 
@conference{
author = "Vlašković, Tijana and Laban, Bojana and Čebela, Maria and Dodevski, Vladimir and Jordanov, Dragana and Rosić, Milena",
year = "2024",
publisher = "Belgrade : Vinča Institute of Nuclear Sciences - National Institute of thе Republic of Serbia, University of Belgrade, Belgrade : Serbian Society for Innovative Materials in Extreme Conditions (SIM-EXTREME)",
journal = "IMEC2024 - 2nd International Conference on Innovative Materials in Extreme Conditions : Book of abstracts",
title = "Preparation of Ca0.9Er0.1MnO3 nanopowders by combustion method",
pages = "66-66",
url = "https://hdl.handle.net/21.15107/rcub_vinar_13162"
}
Vlašković, T., Laban, B., Čebela, M., Dodevski, V., Jordanov, D.,& Rosić, M.. (2024). Preparation of Ca0.9Er0.1MnO3 nanopowders by combustion method. in IMEC2024 - 2nd International Conference on Innovative Materials in Extreme Conditions : Book of abstracts
Belgrade : Vinča Institute of Nuclear Sciences - National Institute of thе Republic of Serbia, University of Belgrade., 66-66.
https://hdl.handle.net/21.15107/rcub_vinar_13162
Vlašković T, Laban B, Čebela M, Dodevski V, Jordanov D, Rosić M. Preparation of Ca0.9Er0.1MnO3 nanopowders by combustion method. in IMEC2024 - 2nd International Conference on Innovative Materials in Extreme Conditions : Book of abstracts. 2024;:66-66.
https://hdl.handle.net/21.15107/rcub_vinar_13162 .
Vlašković, Tijana, Laban, Bojana, Čebela, Maria, Dodevski, Vladimir, Jordanov, Dragana, Rosić, Milena, "Preparation of Ca0.9Er0.1MnO3 nanopowders by combustion method" in IMEC2024 - 2nd International Conference on Innovative Materials in Extreme Conditions : Book of abstracts (2024):66-66,
https://hdl.handle.net/21.15107/rcub_vinar_13162 .

Thermo-chemical conversion of cigarette butt filters waste through pyrolysis process using thermal analysis techniques

Božilović, Bojana; Janković, Bojan; Pijović-Radovanović, Milena; Waisi, Hadi; Marinović-Cincović, Milena; Krstić, Sanja; Dodevski, Vladimir

(2024)

TY  - JOUR
AU  - Božilović, Bojana
AU  - Janković, Bojan
AU  - Pijović-Radovanović, Milena
AU  - Waisi, Hadi
AU  - Marinović-Cincović, Milena
AU  - Krstić, Sanja
AU  - Dodevski, Vladimir
PY  - 2024
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/13215
AB  - Thermo-chemical conversion of cigarette butt filters (CBF) waste was investigated using various thermal analysis techniques (simultaneous TG-DTG-DTA and DSC methods) at different heating rates in an inert atmosphere. Thermo- and thermo-physical properties of waste material were discussed, from the point of view of chemical structure and the influence of experimental parameters on the conversion process. It was established that acetyl groups of plasticizer (triacetin) interact with cellulose acetate through dipolar interactions and hydrogen bonding’s. Influence of these polar interactions can affect the position of glass transition temperature, Tg, of CBF. Based on estimated value of Tg from DSC analysis, it was found that cellulose acetate present in CBF has degree of substitution equals to 2.8, where the presence of cellulose triacetate was confirmed. It was assumed that an increase of degree of substitution leads to decline in the crystallinity. A decline of crystal-linity causes the reduction of hydroxyl groups, leading to less organized chains, and whereby decreasing of inter-molecular interactions through hydrogen bond-ing. Based on the examination of thermophysical characteristics of the tested ma-terial, it was found that both, the heat capacity and the thermal inertia of material linearly increase with temperature, during pyrolysis progression. It was concluded that the type of bio-char produced in this process would have a large capacity to store the heat, which may depend on the formed particles size diameter and poros-ity. Furthermore, it was inferred that magnitude drops of thermal conductivity, κ, after Tg depends on the material fibrillation
T2  - Thermal Science
T1  - Thermo-chemical conversion of cigarette butt filters waste through pyrolysis process using thermal analysis techniques
VL  - 28
IS  - 1 Part B
SP  - 513
EP  - 527
DO  - 10.2298/TSCI230520153B
ER  - 
@article{
author = "Božilović, Bojana and Janković, Bojan and Pijović-Radovanović, Milena and Waisi, Hadi and Marinović-Cincović, Milena and Krstić, Sanja and Dodevski, Vladimir",
year = "2024",
abstract = "Thermo-chemical conversion of cigarette butt filters (CBF) waste was investigated using various thermal analysis techniques (simultaneous TG-DTG-DTA and DSC methods) at different heating rates in an inert atmosphere. Thermo- and thermo-physical properties of waste material were discussed, from the point of view of chemical structure and the influence of experimental parameters on the conversion process. It was established that acetyl groups of plasticizer (triacetin) interact with cellulose acetate through dipolar interactions and hydrogen bonding’s. Influence of these polar interactions can affect the position of glass transition temperature, Tg, of CBF. Based on estimated value of Tg from DSC analysis, it was found that cellulose acetate present in CBF has degree of substitution equals to 2.8, where the presence of cellulose triacetate was confirmed. It was assumed that an increase of degree of substitution leads to decline in the crystallinity. A decline of crystal-linity causes the reduction of hydroxyl groups, leading to less organized chains, and whereby decreasing of inter-molecular interactions through hydrogen bond-ing. Based on the examination of thermophysical characteristics of the tested ma-terial, it was found that both, the heat capacity and the thermal inertia of material linearly increase with temperature, during pyrolysis progression. It was concluded that the type of bio-char produced in this process would have a large capacity to store the heat, which may depend on the formed particles size diameter and poros-ity. Furthermore, it was inferred that magnitude drops of thermal conductivity, κ, after Tg depends on the material fibrillation",
journal = "Thermal Science",
title = "Thermo-chemical conversion of cigarette butt filters waste through pyrolysis process using thermal analysis techniques",
volume = "28",
number = "1 Part B",
pages = "513-527",
doi = "10.2298/TSCI230520153B"
}
Božilović, B., Janković, B., Pijović-Radovanović, M., Waisi, H., Marinović-Cincović, M., Krstić, S.,& Dodevski, V.. (2024). Thermo-chemical conversion of cigarette butt filters waste through pyrolysis process using thermal analysis techniques. in Thermal Science, 28(1 Part B), 513-527.
https://doi.org/10.2298/TSCI230520153B
Božilović B, Janković B, Pijović-Radovanović M, Waisi H, Marinović-Cincović M, Krstić S, Dodevski V. Thermo-chemical conversion of cigarette butt filters waste through pyrolysis process using thermal analysis techniques. in Thermal Science. 2024;28(1 Part B):513-527.
doi:10.2298/TSCI230520153B .
Božilović, Bojana, Janković, Bojan, Pijović-Radovanović, Milena, Waisi, Hadi, Marinović-Cincović, Milena, Krstić, Sanja, Dodevski, Vladimir, "Thermo-chemical conversion of cigarette butt filters waste through pyrolysis process using thermal analysis techniques" in Thermal Science, 28, no. 1 Part B (2024):513-527,
https://doi.org/10.2298/TSCI230520153B . .

Expression of microRNAs following radiation therapy and association with severity of radiotherapy‑induced toxicity among patients with prostate adenocarcinoma: A systematic review and meta‑analysis

Singh, Jagtar; Thachil, Thanuja; Misir, Sema; Altay, Diler; Yaman, Serap; Singh, Gurpreet; Eapen, Mathew; McAlinden, Kielan; Petrović, Nina; Sohal, Sukhwinder

(2024)

TY  - JOUR
AU  - Singh, Jagtar
AU  - Thachil, Thanuja
AU  - Misir, Sema
AU  - Altay, Diler
AU  - Yaman, Serap
AU  - Singh, Gurpreet
AU  - Eapen, Mathew
AU  - McAlinden, Kielan
AU  - Petrović, Nina
AU  - Sohal, Sukhwinder
PY  - 2024
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/13133
AB  - Radiation‑induced normal tissue toxicity is a common acute and chronic outcome of radiotherapy (RT) for prostate cancer (PCa). There are currently no existing pre‑assessments before treatment to predict acute and late RT‑induced toxicity. Novel predictive blood biomarkers in radiation oncology may improve treatment decision‑making and therapeutic monitoring for patients with PCa. A comprehensive systematic search of microRNA (miRNA/miR) profiling studies published in PubMed, Science Direct and Google Scholar was performed. The present systematic review, supported by meta‑analysis, summarises key findings and discusses the results of prospective clinical studies investigating miRNA expression levels and their association with RT‑induced toxicity in PCa. Out of seven clinical studies, six highlighted levels of 10 miRNAs changing in plasma, serum or peripheral blood mononuclear cells during RT. The post‑RT expression levels of miRNA‑132‑5p, miRNA‑1‑3p, miRNA‑410 and miRNA‑221 were increased, and miRNA‑23a‑3p expression was decreased among patients with low‑grade RT‑induced toxicity. Furthermore, in patients with high‑grade RT toxicity, miRNA‑197‑3p, miRNA‑151a‑5p, miRNA‑18b‑5p, miRNA‑99a and miRNA‑21 expression was increased, while miRNA‑132‑5p expression was decreased. The present miRNA meta‑analysis could be the focus of future studies to identify their potential clinical value as PCa biomarkers and therapeutic mediators in RT‑induced toxicity. The variations in miRNA levels post‑RT could be used as predictive biomarkers of RT‑induced toxicity. However, further extensive validation is required to establish the relationship between miRNA expression levels and RT‑induced toxicity in PCa and to confirm their predictive value.
T2  - World Academy of Sciences Journal
T1  - Expression of microRNAs following radiation therapy and association with severity of radiotherapy‑induced toxicity among patients with prostate adenocarcinoma: A systematic review and meta‑analysis
VL  - 6
IS  - 3
DO  - 10.3892/wasj.2024.242
ER  - 
@article{
author = "Singh, Jagtar and Thachil, Thanuja and Misir, Sema and Altay, Diler and Yaman, Serap and Singh, Gurpreet and Eapen, Mathew and McAlinden, Kielan and Petrović, Nina and Sohal, Sukhwinder",
year = "2024",
abstract = "Radiation‑induced normal tissue toxicity is a common acute and chronic outcome of radiotherapy (RT) for prostate cancer (PCa). There are currently no existing pre‑assessments before treatment to predict acute and late RT‑induced toxicity. Novel predictive blood biomarkers in radiation oncology may improve treatment decision‑making and therapeutic monitoring for patients with PCa. A comprehensive systematic search of microRNA (miRNA/miR) profiling studies published in PubMed, Science Direct and Google Scholar was performed. The present systematic review, supported by meta‑analysis, summarises key findings and discusses the results of prospective clinical studies investigating miRNA expression levels and their association with RT‑induced toxicity in PCa. Out of seven clinical studies, six highlighted levels of 10 miRNAs changing in plasma, serum or peripheral blood mononuclear cells during RT. The post‑RT expression levels of miRNA‑132‑5p, miRNA‑1‑3p, miRNA‑410 and miRNA‑221 were increased, and miRNA‑23a‑3p expression was decreased among patients with low‑grade RT‑induced toxicity. Furthermore, in patients with high‑grade RT toxicity, miRNA‑197‑3p, miRNA‑151a‑5p, miRNA‑18b‑5p, miRNA‑99a and miRNA‑21 expression was increased, while miRNA‑132‑5p expression was decreased. The present miRNA meta‑analysis could be the focus of future studies to identify their potential clinical value as PCa biomarkers and therapeutic mediators in RT‑induced toxicity. The variations in miRNA levels post‑RT could be used as predictive biomarkers of RT‑induced toxicity. However, further extensive validation is required to establish the relationship between miRNA expression levels and RT‑induced toxicity in PCa and to confirm their predictive value.",
journal = "World Academy of Sciences Journal",
title = "Expression of microRNAs following radiation therapy and association with severity of radiotherapy‑induced toxicity among patients with prostate adenocarcinoma: A systematic review and meta‑analysis",
volume = "6",
number = "3",
doi = "10.3892/wasj.2024.242"
}
Singh, J., Thachil, T., Misir, S., Altay, D., Yaman, S., Singh, G., Eapen, M., McAlinden, K., Petrović, N.,& Sohal, S.. (2024). Expression of microRNAs following radiation therapy and association with severity of radiotherapy‑induced toxicity among patients with prostate adenocarcinoma: A systematic review and meta‑analysis. in World Academy of Sciences Journal, 6(3).
https://doi.org/10.3892/wasj.2024.242
Singh J, Thachil T, Misir S, Altay D, Yaman S, Singh G, Eapen M, McAlinden K, Petrović N, Sohal S. Expression of microRNAs following radiation therapy and association with severity of radiotherapy‑induced toxicity among patients with prostate adenocarcinoma: A systematic review and meta‑analysis. in World Academy of Sciences Journal. 2024;6(3).
doi:10.3892/wasj.2024.242 .
Singh, Jagtar, Thachil, Thanuja, Misir, Sema, Altay, Diler, Yaman, Serap, Singh, Gurpreet, Eapen, Mathew, McAlinden, Kielan, Petrović, Nina, Sohal, Sukhwinder, "Expression of microRNAs following radiation therapy and association with severity of radiotherapy‑induced toxicity among patients with prostate adenocarcinoma: A systematic review and meta‑analysis" in World Academy of Sciences Journal, 6, no. 3 (2024),
https://doi.org/10.3892/wasj.2024.242 . .

Synchrotron radiation-FTIR biomolecular assessment in PANC-1 and MIA PaCa-2 pancreatic cancer cells after treatment with Gd-TiO2 nanoparticles

Abu el Rub, Anamarija; Nešić, Maja D.; Dučić, Tanja; Radoičić, Marija; Novaković, Mirjana; Žakula, Jelena; Ralić, Vanja; Petković, Marijana; Stepić, Milutin

(2024)

TY  - JOUR
AU  - Abu el Rub, Anamarija
AU  - Nešić, Maja D.
AU  - Dučić, Tanja
AU  - Radoičić, Marija
AU  - Novaković, Mirjana
AU  - Žakula, Jelena
AU  - Ralić, Vanja
AU  - Petković, Marijana
AU  - Stepić, Milutin
PY  - 2024
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/13214
AB  - The increasing incidence rate of pancreatic cancer worldwide, along with high resistance to existing chemotherapies and radiotherapy, demand new approaches for its treatment. Nanoparticle-guided cancer treatment modalities are promising in their anti-cancer efficiency and upgrading potential. We have synthesized and characterized Gd-doped titanium-dioxide nanoparticles (Gd-TiO 2 NPs), which showed good biocompatibility with MIA PaCa-2 and PANC-1 pancreatic cancer cell lines. To assess the effect that these NPs have on tumor cells, we used synchrotron radiation Fourier transform infrared spectroscopy and principal component analysis. We elucidated the biochemical changes in the two cell lines induced after their interaction with these NPs. Results demonstrated changes in nucleic acids and carbohydrate metabolism and alterations in the protein conformation in both cell lines. In addition, considerable changes in lipid area were observed in PANC-1 cell line, suggesting that Gd-TiO 2 NPs have a prospective to be further studied as systems for pancreatic cancer treatment.
T2  - Journal of Molecular Structure
T1  - Synchrotron radiation-FTIR biomolecular assessment in PANC-1 and MIA PaCa-2 pancreatic cancer cells after treatment with Gd-TiO2 nanoparticles
VL  - 1309
SP  - 138167
DO  - 10.1016/j.molstruc.2024.138167
ER  - 
@article{
author = "Abu el Rub, Anamarija and Nešić, Maja D. and Dučić, Tanja and Radoičić, Marija and Novaković, Mirjana and Žakula, Jelena and Ralić, Vanja and Petković, Marijana and Stepić, Milutin",
year = "2024",
abstract = "The increasing incidence rate of pancreatic cancer worldwide, along with high resistance to existing chemotherapies and radiotherapy, demand new approaches for its treatment. Nanoparticle-guided cancer treatment modalities are promising in their anti-cancer efficiency and upgrading potential. We have synthesized and characterized Gd-doped titanium-dioxide nanoparticles (Gd-TiO 2 NPs), which showed good biocompatibility with MIA PaCa-2 and PANC-1 pancreatic cancer cell lines. To assess the effect that these NPs have on tumor cells, we used synchrotron radiation Fourier transform infrared spectroscopy and principal component analysis. We elucidated the biochemical changes in the two cell lines induced after their interaction with these NPs. Results demonstrated changes in nucleic acids and carbohydrate metabolism and alterations in the protein conformation in both cell lines. In addition, considerable changes in lipid area were observed in PANC-1 cell line, suggesting that Gd-TiO 2 NPs have a prospective to be further studied as systems for pancreatic cancer treatment.",
journal = "Journal of Molecular Structure",
title = "Synchrotron radiation-FTIR biomolecular assessment in PANC-1 and MIA PaCa-2 pancreatic cancer cells after treatment with Gd-TiO2 nanoparticles",
volume = "1309",
pages = "138167",
doi = "10.1016/j.molstruc.2024.138167"
}
Abu el Rub, A., Nešić, M. D., Dučić, T., Radoičić, M., Novaković, M., Žakula, J., Ralić, V., Petković, M.,& Stepić, M.. (2024). Synchrotron radiation-FTIR biomolecular assessment in PANC-1 and MIA PaCa-2 pancreatic cancer cells after treatment with Gd-TiO2 nanoparticles. in Journal of Molecular Structure, 1309, 138167.
https://doi.org/10.1016/j.molstruc.2024.138167
Abu el Rub A, Nešić MD, Dučić T, Radoičić M, Novaković M, Žakula J, Ralić V, Petković M, Stepić M. Synchrotron radiation-FTIR biomolecular assessment in PANC-1 and MIA PaCa-2 pancreatic cancer cells after treatment with Gd-TiO2 nanoparticles. in Journal of Molecular Structure. 2024;1309:138167.
doi:10.1016/j.molstruc.2024.138167 .
Abu el Rub, Anamarija, Nešić, Maja D., Dučić, Tanja, Radoičić, Marija, Novaković, Mirjana, Žakula, Jelena, Ralić, Vanja, Petković, Marijana, Stepić, Milutin, "Synchrotron radiation-FTIR biomolecular assessment in PANC-1 and MIA PaCa-2 pancreatic cancer cells after treatment with Gd-TiO2 nanoparticles" in Journal of Molecular Structure, 1309 (2024):138167,
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The MMP-9 promoter genetic variant rs3918242, mRNA and protein expression in advanced carotid plaque tissue

Živković, Maja; Stanković, Aleksandra; Končar, Igor; Kolaković, Ana; Bošković, Maja; Đurić, Tamara

(2024)

TY  - JOUR
AU  - Živković, Maja
AU  - Stanković, Aleksandra
AU  - Končar, Igor
AU  - Kolaković, Ana
AU  - Bošković, Maja
AU  - Đurić, Tamara
PY  - 2024
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/13193
AB  - Background The MMP-9 is a known player in atherosclerosis, yet associations of the MMP-9 -1562 C/T variant (rs3918242) with various atherosclerotic phenotypes and tissue mRNA expression are still contradictory. This study aimed to investigate the MMP-9 -1562 C/T variant, its mRNA and protein expression in carotid plaque (CP) tissue, as a risk factor for CP presence and as a marker of different plaque phenotypes (hyperechoic and hypoechoic) in patients undergoing carotid endarterectomy. The MnSOD as an MMP-9 negative regulator was also studied in relation to CP phenotypes. Methods and results Genotyping of 770 participants (285 controls/485 patients) was done by tetra-primer ARMS PCR. The MMP-9 mRNA expression in 88 human CP tissues was detected by TaqMan® technology. The protein levels of MMP-9 and MnSOD were assessed by Western blot analysis. The MMP-9 -1562 C/T variant was not recognized as a risk factor for plaque presence or in predisposing MMP-9 mRNA and protein levels in plaque tissue. Patients with hypoechoic plaques had significantly lower MMP-9 mRNA and protein levels than those with hyperechoic plaque (p = 0.008, p = 0.003, respectively). MnSOD protein level was significantly higher in hypoechoic plaque compared to hyperechoic (p = 0.039). MMP-9 protein expression in CP tissue was significantly affected by sex and plaque type interaction (p = 0.009). Conclusions Considering the differences of MMP-9 mRNA and protein expression in CP tissue regarding different plaque phenotypes and the observed sex-specific effect, the role of MMP-9 in human atherosclerotic plaques should be further elucidated.
T2  - Molecular Biology Reports
T1  - The MMP-9 promoter genetic variant rs3918242, mRNA and protein expression in advanced carotid plaque tissue
VL  - 51
IS  - 1
DO  - 10.1007/s11033-024-09458-w
ER  - 
@article{
author = "Živković, Maja and Stanković, Aleksandra and Končar, Igor and Kolaković, Ana and Bošković, Maja and Đurić, Tamara",
year = "2024",
abstract = "Background The MMP-9 is a known player in atherosclerosis, yet associations of the MMP-9 -1562 C/T variant (rs3918242) with various atherosclerotic phenotypes and tissue mRNA expression are still contradictory. This study aimed to investigate the MMP-9 -1562 C/T variant, its mRNA and protein expression in carotid plaque (CP) tissue, as a risk factor for CP presence and as a marker of different plaque phenotypes (hyperechoic and hypoechoic) in patients undergoing carotid endarterectomy. The MnSOD as an MMP-9 negative regulator was also studied in relation to CP phenotypes. Methods and results Genotyping of 770 participants (285 controls/485 patients) was done by tetra-primer ARMS PCR. The MMP-9 mRNA expression in 88 human CP tissues was detected by TaqMan® technology. The protein levels of MMP-9 and MnSOD were assessed by Western blot analysis. The MMP-9 -1562 C/T variant was not recognized as a risk factor for plaque presence or in predisposing MMP-9 mRNA and protein levels in plaque tissue. Patients with hypoechoic plaques had significantly lower MMP-9 mRNA and protein levels than those with hyperechoic plaque (p = 0.008, p = 0.003, respectively). MnSOD protein level was significantly higher in hypoechoic plaque compared to hyperechoic (p = 0.039). MMP-9 protein expression in CP tissue was significantly affected by sex and plaque type interaction (p = 0.009). Conclusions Considering the differences of MMP-9 mRNA and protein expression in CP tissue regarding different plaque phenotypes and the observed sex-specific effect, the role of MMP-9 in human atherosclerotic plaques should be further elucidated.",
journal = "Molecular Biology Reports",
title = "The MMP-9 promoter genetic variant rs3918242, mRNA and protein expression in advanced carotid plaque tissue",
volume = "51",
number = "1",
doi = "10.1007/s11033-024-09458-w"
}
Živković, M., Stanković, A., Končar, I., Kolaković, A., Bošković, M.,& Đurić, T.. (2024). The MMP-9 promoter genetic variant rs3918242, mRNA and protein expression in advanced carotid plaque tissue. in Molecular Biology Reports, 51(1).
https://doi.org/10.1007/s11033-024-09458-w
Živković M, Stanković A, Končar I, Kolaković A, Bošković M, Đurić T. The MMP-9 promoter genetic variant rs3918242, mRNA and protein expression in advanced carotid plaque tissue. in Molecular Biology Reports. 2024;51(1).
doi:10.1007/s11033-024-09458-w .
Živković, Maja, Stanković, Aleksandra, Končar, Igor, Kolaković, Ana, Bošković, Maja, Đurić, Tamara, "The MMP-9 promoter genetic variant rs3918242, mRNA and protein expression in advanced carotid plaque tissue" in Molecular Biology Reports, 51, no. 1 (2024),
https://doi.org/10.1007/s11033-024-09458-w . .