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Some aspects of electron-phonon interaction in Zn1-xCdxGeAs2

Romčević, M.; Kilanski, L.; Ćurčić, M.; Paunović, N.; Prekajski-Đorđević, Marija D.; Romčević, N.

TY  - JOUR
AU  - Romčević, M.
AU  - Kilanski, L.
AU  - Ćurčić, M.
AU  - Paunović, N.
AU  - Prekajski-Đorđević, Marija D.
AU  - Romčević, N.
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/13441
AB  - The interaction between charge carriers and phonons is the primary mechanism through which charge carriers exchange energy with the crystal lattice. A proper understanding of the electron-phonon interaction is of great importance. We conducted a comprehensive investigation to examine the electron-phonon interaction in semiconductor crystals of Zn1-xCdxGeAs2 (0 ≤ x ≤ 1). For this objective, X-ray diffraction, far-infrared reflection, and Raman scattering studies were employed. In addition to the two primary phases, namely ZnGeAs2 and CdGeAs2, four component phases were also identified: ZnAs2, CdAs2, GeAs, and GeAs2. A spatially inhomogeneous distribution of charge carriers was detected, with the highest concentration in the vicinity of the formed GeAs. Analysis of the Far-infrared reflection spectrum of ZnGeAs2 (x = 0) revealed that plasmon-4 phonon interaction occurs, while in CdGeAs2 (x = 1), there is a plasmon-3 phonon interaction. All other samples have both of these interactions, according to their percentage in the composition. Raman measurements revealed that due to the influence of free charge carriers, there is an increase in the intensity of phonon modes, their displacement, or their splitting into two modes. The intensity and the way the electron-phonon interaction vary depending on the local concentration of free carriers, and it is the strongest in the areas around the formed GeAs.  The obtained results and performed analyses revealed the existence of different phases in the material, inhomogeneous charge distribution, and electron-phonon interaction, which are essential properties of thermoelectric materials.
T2  - Physica B: Condensed Matter
T1  - Some aspects of electron-phonon interaction in Zn1-xCdxGeAs2
VL  - 690
SP  - 416264
DO  - 10.1016/j.physb.2024.416264
ER  - 
@article{
author = "Romčević, M. and Kilanski, L. and Ćurčić, M. and Paunović, N. and Prekajski-Đorđević, Marija D. and Romčević, N.",
abstract = "The interaction between charge carriers and phonons is the primary mechanism through which charge carriers exchange energy with the crystal lattice. A proper understanding of the electron-phonon interaction is of great importance. We conducted a comprehensive investigation to examine the electron-phonon interaction in semiconductor crystals of Zn1-xCdxGeAs2 (0 ≤ x ≤ 1). For this objective, X-ray diffraction, far-infrared reflection, and Raman scattering studies were employed. In addition to the two primary phases, namely ZnGeAs2 and CdGeAs2, four component phases were also identified: ZnAs2, CdAs2, GeAs, and GeAs2. A spatially inhomogeneous distribution of charge carriers was detected, with the highest concentration in the vicinity of the formed GeAs. Analysis of the Far-infrared reflection spectrum of ZnGeAs2 (x = 0) revealed that plasmon-4 phonon interaction occurs, while in CdGeAs2 (x = 1), there is a plasmon-3 phonon interaction. All other samples have both of these interactions, according to their percentage in the composition. Raman measurements revealed that due to the influence of free charge carriers, there is an increase in the intensity of phonon modes, their displacement, or their splitting into two modes. The intensity and the way the electron-phonon interaction vary depending on the local concentration of free carriers, and it is the strongest in the areas around the formed GeAs.  The obtained results and performed analyses revealed the existence of different phases in the material, inhomogeneous charge distribution, and electron-phonon interaction, which are essential properties of thermoelectric materials.",
journal = "Physica B: Condensed Matter",
title = "Some aspects of electron-phonon interaction in Zn1-xCdxGeAs2",
volume = "690",
pages = "416264",
doi = "10.1016/j.physb.2024.416264"
}
Romčević, M., Kilanski, L., Ćurčić, M., Paunović, N., Prekajski-Đorđević, M. D.,& Romčević, N..Some aspects of electron-phonon interaction in Zn1-xCdxGeAs2. in Physica B: Condensed Matter, 690, 416264.
https://doi.org/10.1016/j.physb.2024.416264
Romčević M, Kilanski L, Ćurčić M, Paunović N, Prekajski-Đorđević MD, Romčević N. Some aspects of electron-phonon interaction in Zn1-xCdxGeAs2. in Physica B: Condensed Matter.690:416264.
doi:10.1016/j.physb.2024.416264 .
Romčević, M., Kilanski, L., Ćurčić, M., Paunović, N., Prekajski-Đorđević, Marija D., Romčević, N., "Some aspects of electron-phonon interaction in Zn1-xCdxGeAs2" in Physica B: Condensed Matter, 690:416264,
https://doi.org/10.1016/j.physb.2024.416264 . .

Synthesis, characterization and antioxidative capacity of nickel(II) and zinc(II) complexes with 4-methylpyrazole

Kočović, David; Holló, Berta Barta; Borišev, Ivana; Leovac, Vukadin; Vojinović Ješić, Ljiljana; Giester, Gerald; Shova, Sergiu; Tomić, Zoran D.; Jaćimović, Željko

(2025)

TY  - JOUR
AU  - Kočović, David
AU  - Holló, Berta Barta
AU  - Borišev, Ivana
AU  - Leovac, Vukadin
AU  - Vojinović Ješić, Ljiljana
AU  - Giester, Gerald
AU  - Shova, Sergiu
AU  - Tomić, Zoran D.
AU  - Jaćimović, Željko
PY  - 2025
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/13739
AB  - In this paper, the coordination of 4-methylpyrazole (L) to Ni(II) and Zn(II) ions is studied through the reactions of Ni(OAc)2·4H2O and Zn(OAc)2·2H₂O with 4-methylpyrazole in a 1:2 metal-to-ligand molar ratio in ethanol at room temperature. From the reaction mixtures, new complex compounds of formulae: [Ni(OAc)2L4] and [Zn(OAc)2L2] were crystallized. The crystal and molecular structure of the synthesized complexes were determined by single-crystal X-ray structure analysis. The coordination environment of Ni(II) in its complex is octahedral, while that of Zn(II) is tetrahedral. The compounds are characterized by IR spectra and elemental analysis. Their thermal stability, a crucial property, is analyzed by thermogravimetry. To get a better insight into the decomposition mechanism coupled TG-MS measurements were carried out, too. The tests of the antioxidative activity of the new complexes on DPPH radical showed that the Zn(II) complex is more effective than the Ni(II) complex.
T2  - Inorganica Chimica Acta
T1  - Synthesis, characterization and antioxidative capacity of nickel(II) and zinc(II) complexes with 4-methylpyrazole
VL  - 574
SP  - 122363
DO  - 10.1016/j.ica.2024.122363
ER  - 
@article{
author = "Kočović, David and Holló, Berta Barta and Borišev, Ivana and Leovac, Vukadin and Vojinović Ješić, Ljiljana and Giester, Gerald and Shova, Sergiu and Tomić, Zoran D. and Jaćimović, Željko",
year = "2025",
abstract = "In this paper, the coordination of 4-methylpyrazole (L) to Ni(II) and Zn(II) ions is studied through the reactions of Ni(OAc)2·4H2O and Zn(OAc)2·2H₂O with 4-methylpyrazole in a 1:2 metal-to-ligand molar ratio in ethanol at room temperature. From the reaction mixtures, new complex compounds of formulae: [Ni(OAc)2L4] and [Zn(OAc)2L2] were crystallized. The crystal and molecular structure of the synthesized complexes were determined by single-crystal X-ray structure analysis. The coordination environment of Ni(II) in its complex is octahedral, while that of Zn(II) is tetrahedral. The compounds are characterized by IR spectra and elemental analysis. Their thermal stability, a crucial property, is analyzed by thermogravimetry. To get a better insight into the decomposition mechanism coupled TG-MS measurements were carried out, too. The tests of the antioxidative activity of the new complexes on DPPH radical showed that the Zn(II) complex is more effective than the Ni(II) complex.",
journal = "Inorganica Chimica Acta",
title = "Synthesis, characterization and antioxidative capacity of nickel(II) and zinc(II) complexes with 4-methylpyrazole",
volume = "574",
pages = "122363",
doi = "10.1016/j.ica.2024.122363"
}
Kočović, D., Holló, B. B., Borišev, I., Leovac, V., Vojinović Ješić, L., Giester, G., Shova, S., Tomić, Z. D.,& Jaćimović, Ž.. (2025). Synthesis, characterization and antioxidative capacity of nickel(II) and zinc(II) complexes with 4-methylpyrazole. in Inorganica Chimica Acta, 574, 122363.
https://doi.org/10.1016/j.ica.2024.122363
Kočović D, Holló BB, Borišev I, Leovac V, Vojinović Ješić L, Giester G, Shova S, Tomić ZD, Jaćimović Ž. Synthesis, characterization and antioxidative capacity of nickel(II) and zinc(II) complexes with 4-methylpyrazole. in Inorganica Chimica Acta. 2025;574:122363.
doi:10.1016/j.ica.2024.122363 .
Kočović, David, Holló, Berta Barta, Borišev, Ivana, Leovac, Vukadin, Vojinović Ješić, Ljiljana, Giester, Gerald, Shova, Sergiu, Tomić, Zoran D., Jaćimović, Željko, "Synthesis, characterization and antioxidative capacity of nickel(II) and zinc(II) complexes with 4-methylpyrazole" in Inorganica Chimica Acta, 574 (2025):122363,
https://doi.org/10.1016/j.ica.2024.122363 . .

Synthesis and characterization of Cu(II)‑meso-HMPAO complex as a model for the development of potential 64Cu radiopharmaceutical

Mirković, Marija; Belaj, Ferdinand; Perić, Marko; Stanković, Dalibor; Radović, Magdalena; Milanović, Zorana; Vranješ-Đurić, Sanja; Janković, Drina; Cvijetić, Ilija; Mihajlović-Lalić, Ljiljana E.

(2025)

TY  - JOUR
AU  - Mirković, Marija
AU  - Belaj, Ferdinand
AU  - Perić, Marko
AU  - Stanković, Dalibor
AU  - Radović, Magdalena
AU  - Milanović, Zorana
AU  - Vranješ-Đurić, Sanja
AU  - Janković, Drina
AU  - Cvijetić, Ilija
AU  - Mihajlović-Lalić, Ljiljana E.
PY  - 2025
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/13738
AB  - In this work, Cu(II) complexes with meso‑HMPAO and d,l-HMPAO were synthesized. The structural characterisation of the isolated compounds has been done by single-crystal X-ray diffraction analysis, FTIR, and mass spectroscopy. Redox properties of complexes and binding to deoxyribonucleic acid (DNA) molecule have been analysed in detail by cyclic voltammetry and DFT calculations. The results of cyclic voltammetry fully agree with the data obtained by DFT calculations and indicate that the first electron removal takes place from the metal, while the second electron is removed from the ligand. The formation of the complex leads to the shift in oxidation peaks of the ligand from ‒0.29 V to 0,47 V and from 1.18 V to 1,24 V, indicating that ligand in the complex is much more difficult to oxidize. Electrochemical data confirmed the binding between the complex and DNA molecules through guanine. DFT calculations show that the complex is suitable not only for binding purine and pyrimidine bases through a coordination bond but also for additional hydrogen and CH-π interactions of the bases with the ligand. The fluorescence titration experiments revealed a moderate binding affinity of the [Cu-HMPAO]ClO4 complex to human serum albumin (HSA). Molecular docking revealed that this ligand preferentially binds to drug binding site 3 of HSA. Therefore, the novel compounds could be of great interest for further investigation, considering the potential anticancer activity, and as a model for the development of radiopharmaceutical with 64Cu.
T2  - Journal of Molecular Structure
T1  - Synthesis and characterization of Cu(II)‑meso-HMPAO complex as a model for the development of potential 64Cu radiopharmaceutical
VL  - 1321
SP  - 139791
DO  - 10.1016/j.molstruc.2024.139791
ER  - 
@article{
author = "Mirković, Marija and Belaj, Ferdinand and Perić, Marko and Stanković, Dalibor and Radović, Magdalena and Milanović, Zorana and Vranješ-Đurić, Sanja and Janković, Drina and Cvijetić, Ilija and Mihajlović-Lalić, Ljiljana E.",
year = "2025",
abstract = "In this work, Cu(II) complexes with meso‑HMPAO and d,l-HMPAO were synthesized. The structural characterisation of the isolated compounds has been done by single-crystal X-ray diffraction analysis, FTIR, and mass spectroscopy. Redox properties of complexes and binding to deoxyribonucleic acid (DNA) molecule have been analysed in detail by cyclic voltammetry and DFT calculations. The results of cyclic voltammetry fully agree with the data obtained by DFT calculations and indicate that the first electron removal takes place from the metal, while the second electron is removed from the ligand. The formation of the complex leads to the shift in oxidation peaks of the ligand from ‒0.29 V to 0,47 V and from 1.18 V to 1,24 V, indicating that ligand in the complex is much more difficult to oxidize. Electrochemical data confirmed the binding between the complex and DNA molecules through guanine. DFT calculations show that the complex is suitable not only for binding purine and pyrimidine bases through a coordination bond but also for additional hydrogen and CH-π interactions of the bases with the ligand. The fluorescence titration experiments revealed a moderate binding affinity of the [Cu-HMPAO]ClO4 complex to human serum albumin (HSA). Molecular docking revealed that this ligand preferentially binds to drug binding site 3 of HSA. Therefore, the novel compounds could be of great interest for further investigation, considering the potential anticancer activity, and as a model for the development of radiopharmaceutical with 64Cu.",
journal = "Journal of Molecular Structure",
title = "Synthesis and characterization of Cu(II)‑meso-HMPAO complex as a model for the development of potential 64Cu radiopharmaceutical",
volume = "1321",
pages = "139791",
doi = "10.1016/j.molstruc.2024.139791"
}
Mirković, M., Belaj, F., Perić, M., Stanković, D., Radović, M., Milanović, Z., Vranješ-Đurić, S., Janković, D., Cvijetić, I.,& Mihajlović-Lalić, L. E.. (2025). Synthesis and characterization of Cu(II)‑meso-HMPAO complex as a model for the development of potential 64Cu radiopharmaceutical. in Journal of Molecular Structure, 1321, 139791.
https://doi.org/10.1016/j.molstruc.2024.139791
Mirković M, Belaj F, Perić M, Stanković D, Radović M, Milanović Z, Vranješ-Đurić S, Janković D, Cvijetić I, Mihajlović-Lalić LE. Synthesis and characterization of Cu(II)‑meso-HMPAO complex as a model for the development of potential 64Cu radiopharmaceutical. in Journal of Molecular Structure. 2025;1321:139791.
doi:10.1016/j.molstruc.2024.139791 .
Mirković, Marija, Belaj, Ferdinand, Perić, Marko, Stanković, Dalibor, Radović, Magdalena, Milanović, Zorana, Vranješ-Đurić, Sanja, Janković, Drina, Cvijetić, Ilija, Mihajlović-Lalić, Ljiljana E., "Synthesis and characterization of Cu(II)‑meso-HMPAO complex as a model for the development of potential 64Cu radiopharmaceutical" in Journal of Molecular Structure, 1321 (2025):139791,
https://doi.org/10.1016/j.molstruc.2024.139791 . .

Nuclear Robotics: Proof of Concept for Localization of Contamination and a Protocol for Decontamination Driven by Robot

Krneta Nikolić, Jelena; Đorđević, Tijana; Pantelić, Ana; Rajačić, Milica; Janković, Marija; Sarap, Nataša

(IEEE : Institute of Electrical and Electronics Engineers (IEEE), 2024)

TY  - CONF
AU  - Krneta Nikolić, Jelena
AU  - Đorđević, Tijana
AU  - Pantelić, Ana
AU  - Rajačić, Milica
AU  - Janković, Marija
AU  - Sarap, Nataša
PY  - 2024
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/13750
AB  - Development of nuclear technology for clean energy and scientific research presents increasing challenge for radiation protection. At the same time, development of robotic technology and new materials presents an opportunity to solve many of the problems by using robots in all situations where the risk for the operator, whether it is caused by not knowing the potential level of exposure, or where the exposure would be prohibitively high, can be reduced or completely avoided. In this paper, proof of concept for a robot, constructed for in situ localization of the contamination and consequent decontamination and a protocol for its operation, is presented. A real robot with a localization capability was constructed and its performance tested in a simulated contamination event. The idea for the upgrade of the robot adding a decontamination capability is presented also.
PB  - IEEE : Institute of Electrical and Electronics Engineers (IEEE)
C3  - 11th International Conference on Electrical, Electronic and Computing Engineering (IcETRAN) : Proceedings
T1  - Nuclear Robotics: Proof of Concept for Localization of Contamination and a Protocol for Decontamination Driven by Robot
DO  - 10.1109/IcETRAN62308.2024.10645170
ER  - 
@conference{
author = "Krneta Nikolić, Jelena and Đorđević, Tijana and Pantelić, Ana and Rajačić, Milica and Janković, Marija and Sarap, Nataša",
year = "2024",
abstract = "Development of nuclear technology for clean energy and scientific research presents increasing challenge for radiation protection. At the same time, development of robotic technology and new materials presents an opportunity to solve many of the problems by using robots in all situations where the risk for the operator, whether it is caused by not knowing the potential level of exposure, or where the exposure would be prohibitively high, can be reduced or completely avoided. In this paper, proof of concept for a robot, constructed for in situ localization of the contamination and consequent decontamination and a protocol for its operation, is presented. A real robot with a localization capability was constructed and its performance tested in a simulated contamination event. The idea for the upgrade of the robot adding a decontamination capability is presented also.",
publisher = "IEEE : Institute of Electrical and Electronics Engineers (IEEE)",
journal = "11th International Conference on Electrical, Electronic and Computing Engineering (IcETRAN) : Proceedings",
title = "Nuclear Robotics: Proof of Concept for Localization of Contamination and a Protocol for Decontamination Driven by Robot",
doi = "10.1109/IcETRAN62308.2024.10645170"
}
Krneta Nikolić, J., Đorđević, T., Pantelić, A., Rajačić, M., Janković, M.,& Sarap, N.. (2024). Nuclear Robotics: Proof of Concept for Localization of Contamination and a Protocol for Decontamination Driven by Robot. in 11th International Conference on Electrical, Electronic and Computing Engineering (IcETRAN) : Proceedings
IEEE : Institute of Electrical and Electronics Engineers (IEEE)..
https://doi.org/10.1109/IcETRAN62308.2024.10645170
Krneta Nikolić J, Đorđević T, Pantelić A, Rajačić M, Janković M, Sarap N. Nuclear Robotics: Proof of Concept for Localization of Contamination and a Protocol for Decontamination Driven by Robot. in 11th International Conference on Electrical, Electronic and Computing Engineering (IcETRAN) : Proceedings. 2024;.
doi:10.1109/IcETRAN62308.2024.10645170 .
Krneta Nikolić, Jelena, Đorđević, Tijana, Pantelić, Ana, Rajačić, Milica, Janković, Marija, Sarap, Nataša, "Nuclear Robotics: Proof of Concept for Localization of Contamination and a Protocol for Decontamination Driven by Robot" in 11th International Conference on Electrical, Electronic and Computing Engineering (IcETRAN) : Proceedings (2024),
https://doi.org/10.1109/IcETRAN62308.2024.10645170 . .

Natural or Artificial Tritium in Rivers – The Assessment Using Symmetrical Index

Janković, Marija; Sarap, Nataša; Janković, Bojan; Krneta Nikolić, Jelena; Rajačić, Milica; Vukanac, Ivana; Jelić, Ivana; Šljivić-Ivanović, Marija

(2024)

TY  - JOUR
AU  - Janković, Marija
AU  - Sarap, Nataša
AU  - Janković, Bojan
AU  - Krneta Nikolić, Jelena
AU  - Rajačić, Milica
AU  - Vukanac, Ivana
AU  - Jelić, Ivana
AU  - Šljivić-Ivanović, Marija
PY  - 2024
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/13422
AB  - Tritium, hydrogen isotope, with a half-life of 12.3 years, is produced in two ways: naturally and artificially. Naturally, tritium is generated through the interaction of cosmic radiation protons and neutrons with gases in the upper atmosphere. Artificially, tritium origins from the atmospheric nuclear tests, production from nuclear reactors, future fusion reactors, fuel reprocessing plants, heavy water production facilities and commercial production for medical diagnostics, radiopharmaceuticals, luminous paints. Elevated concentrations of tritium in the environment are of great public concern. Considering the fact that nuclear power plants are located on rivers, knowing the activity concentration of this isotope in rivers is of great importance. This work presents the results for tritium determination in Danube and Sava River in Belgrade, Serbia. The origin of tritium was estimated using a mathematical parameter, symmetrical index.
T2  - Nuclear Engineering and Design
T1  - Natural or Artificial Tritium in Rivers – The Assessment Using Symmetrical Index
VL  - 427
SP  - 113419
DO  - 10.1016/j.nucengdes.2024.113419
ER  - 
@article{
author = "Janković, Marija and Sarap, Nataša and Janković, Bojan and Krneta Nikolić, Jelena and Rajačić, Milica and Vukanac, Ivana and Jelić, Ivana and Šljivić-Ivanović, Marija",
year = "2024",
abstract = "Tritium, hydrogen isotope, with a half-life of 12.3 years, is produced in two ways: naturally and artificially. Naturally, tritium is generated through the interaction of cosmic radiation protons and neutrons with gases in the upper atmosphere. Artificially, tritium origins from the atmospheric nuclear tests, production from nuclear reactors, future fusion reactors, fuel reprocessing plants, heavy water production facilities and commercial production for medical diagnostics, radiopharmaceuticals, luminous paints. Elevated concentrations of tritium in the environment are of great public concern. Considering the fact that nuclear power plants are located on rivers, knowing the activity concentration of this isotope in rivers is of great importance. This work presents the results for tritium determination in Danube and Sava River in Belgrade, Serbia. The origin of tritium was estimated using a mathematical parameter, symmetrical index.",
journal = "Nuclear Engineering and Design",
title = "Natural or Artificial Tritium in Rivers – The Assessment Using Symmetrical Index",
volume = "427",
pages = "113419",
doi = "10.1016/j.nucengdes.2024.113419"
}
Janković, M., Sarap, N., Janković, B., Krneta Nikolić, J., Rajačić, M., Vukanac, I., Jelić, I.,& Šljivić-Ivanović, M.. (2024). Natural or Artificial Tritium in Rivers – The Assessment Using Symmetrical Index. in Nuclear Engineering and Design, 427, 113419.
https://doi.org/10.1016/j.nucengdes.2024.113419
Janković M, Sarap N, Janković B, Krneta Nikolić J, Rajačić M, Vukanac I, Jelić I, Šljivić-Ivanović M. Natural or Artificial Tritium in Rivers – The Assessment Using Symmetrical Index. in Nuclear Engineering and Design. 2024;427:113419.
doi:10.1016/j.nucengdes.2024.113419 .
Janković, Marija, Sarap, Nataša, Janković, Bojan, Krneta Nikolić, Jelena, Rajačić, Milica, Vukanac, Ivana, Jelić, Ivana, Šljivić-Ivanović, Marija, "Natural or Artificial Tritium in Rivers – The Assessment Using Symmetrical Index" in Nuclear Engineering and Design, 427 (2024):113419,
https://doi.org/10.1016/j.nucengdes.2024.113419 . .
1
1

Establishing control points scheme and baseline measurements for environmental radioactivity monitoring: A case study of the nuclear Institute

Sarap, Nataša; Janković, Marija M.; Krneta Nikolić, Jelena; Vukanac, Ivana; Rajačić, Milica

(2024)

TY  - JOUR
AU  - Sarap, Nataša
AU  - Janković, Marija M.
AU  - Krneta Nikolić, Jelena
AU  - Vukanac, Ivana
AU  - Rajačić, Milica
PY  - 2024
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/13516
AB  - This study deals with the design of the checkpoint system for monitoring the environmental radioactivity in the vicinity of the nuclear reactors. As the design site was selected the Vinča Institute of Nuclear Sciences in the capital city of the Republic of Serbia. There are situated two former nuclear research reactors with potential hazardous materials in controlled conditions. Due to the high risk of ecosystem contamination in the vicinity of various nuclear facilities such as reactor, radiological analyses of coastal soils, sediments and stream/river water were performed at the selected checkpoints. The investigation included determination of gross alpha and gross beta activities, gamma spectrometric analysis and analysis of 90Sr content in the collected environmental samples, as well as determination of 3H activity concentration, but only in water samples. Gross alpha activity ranged from 0.013 Bq/L to 0.057 Bq/L for water samples, from 130 Bq/kg to 280 Bq/kg for soil samples, and from 120 Bq/kg to 270 Bq/kg for sediment samples. Gross beta activity ranged from 0.128 Bq/L to 0.332 Bq/L for water samples, from 850 Bq/kg to 1600 Bq/kg for soil samples, and from 660 Bq/kg to 1200 Bq/kg for sediment samples. The main contribution to gamma radiation in water samples was made by 40K and 137Cs. The 226Ra/238U ratio ranged from 0.37 to 1.24 in soil and from 0.51 to 1.16 in sediment. 90Sr and 3H were detected in all studied samples. The presented results and the increased radiation risk in the above mentioned area show that the surrounding of the nuclear reactors and the exposure of the population to ionizing radiation must be constantly monitored.
T2  - Nuclear Engineering and Design
T1  - Establishing control points scheme and baseline measurements for environmental radioactivity monitoring: A case study of the nuclear Institute
VL  - 427
SP  - 113411
DO  - 10.1016/j.nucengdes.2024.113411
ER  - 
@article{
author = "Sarap, Nataša and Janković, Marija M. and Krneta Nikolić, Jelena and Vukanac, Ivana and Rajačić, Milica",
year = "2024",
abstract = "This study deals with the design of the checkpoint system for monitoring the environmental radioactivity in the vicinity of the nuclear reactors. As the design site was selected the Vinča Institute of Nuclear Sciences in the capital city of the Republic of Serbia. There are situated two former nuclear research reactors with potential hazardous materials in controlled conditions. Due to the high risk of ecosystem contamination in the vicinity of various nuclear facilities such as reactor, radiological analyses of coastal soils, sediments and stream/river water were performed at the selected checkpoints. The investigation included determination of gross alpha and gross beta activities, gamma spectrometric analysis and analysis of 90Sr content in the collected environmental samples, as well as determination of 3H activity concentration, but only in water samples. Gross alpha activity ranged from 0.013 Bq/L to 0.057 Bq/L for water samples, from 130 Bq/kg to 280 Bq/kg for soil samples, and from 120 Bq/kg to 270 Bq/kg for sediment samples. Gross beta activity ranged from 0.128 Bq/L to 0.332 Bq/L for water samples, from 850 Bq/kg to 1600 Bq/kg for soil samples, and from 660 Bq/kg to 1200 Bq/kg for sediment samples. The main contribution to gamma radiation in water samples was made by 40K and 137Cs. The 226Ra/238U ratio ranged from 0.37 to 1.24 in soil and from 0.51 to 1.16 in sediment. 90Sr and 3H were detected in all studied samples. The presented results and the increased radiation risk in the above mentioned area show that the surrounding of the nuclear reactors and the exposure of the population to ionizing radiation must be constantly monitored.",
journal = "Nuclear Engineering and Design",
title = "Establishing control points scheme and baseline measurements for environmental radioactivity monitoring: A case study of the nuclear Institute",
volume = "427",
pages = "113411",
doi = "10.1016/j.nucengdes.2024.113411"
}
Sarap, N., Janković, M. M., Krneta Nikolić, J., Vukanac, I.,& Rajačić, M.. (2024). Establishing control points scheme and baseline measurements for environmental radioactivity monitoring: A case study of the nuclear Institute. in Nuclear Engineering and Design, 427, 113411.
https://doi.org/10.1016/j.nucengdes.2024.113411
Sarap N, Janković MM, Krneta Nikolić J, Vukanac I, Rajačić M. Establishing control points scheme and baseline measurements for environmental radioactivity monitoring: A case study of the nuclear Institute. in Nuclear Engineering and Design. 2024;427:113411.
doi:10.1016/j.nucengdes.2024.113411 .
Sarap, Nataša, Janković, Marija M., Krneta Nikolić, Jelena, Vukanac, Ivana, Rajačić, Milica, "Establishing control points scheme and baseline measurements for environmental radioactivity monitoring: A case study of the nuclear Institute" in Nuclear Engineering and Design, 427 (2024):113411,
https://doi.org/10.1016/j.nucengdes.2024.113411 . .
1
1

National Intercomparison of Indoor Radon Measurements by Charcoal Canisters

Forkapić, Sofija; Knežević Radić, Jovana; Velimirović, Danijel; Hansman, Jan; Arsić, Vesna; Rajačić, Milica

(IEEE : Institute of Electrical and Electronics Engineers (IEEE), 2024)

TY  - CONF
AU  - Forkapić, Sofija
AU  - Knežević Radić, Jovana
AU  - Velimirović, Danijel
AU  - Hansman, Jan
AU  - Arsić, Vesna
AU  - Rajačić, Milica
PY  - 2024
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/13749
AB  - The results and conclusions of the national comparison of indoor radon measurements in 2023 in Serbia are presented in this paper. The participants were three accredited laboratories that use the same method for indoor radon measurement, based on adsorption to activated charcoal, according to international standard protocol. The results of intercomparison were evaluated using the z-score performance criteria. Also, the limitations and advantages of several different methods for indoor radon testing, as well as the possible use for radiological risk assessment are discussed.
PB  - IEEE : Institute of Electrical and Electronics Engineers (IEEE)
C3  - 11th International Conference on Electrical, Electronic and Computing Engineering (IcETRAN) : Proceedings
T1  - National Intercomparison of Indoor Radon Measurements by Charcoal Canisters
SP  - 1
EP  - 4
DO  - 10.1109/IcETRAN62308.2024.10645172
ER  - 
@conference{
author = "Forkapić, Sofija and Knežević Radić, Jovana and Velimirović, Danijel and Hansman, Jan and Arsić, Vesna and Rajačić, Milica",
year = "2024",
abstract = "The results and conclusions of the national comparison of indoor radon measurements in 2023 in Serbia are presented in this paper. The participants were three accredited laboratories that use the same method for indoor radon measurement, based on adsorption to activated charcoal, according to international standard protocol. The results of intercomparison were evaluated using the z-score performance criteria. Also, the limitations and advantages of several different methods for indoor radon testing, as well as the possible use for radiological risk assessment are discussed.",
publisher = "IEEE : Institute of Electrical and Electronics Engineers (IEEE)",
journal = "11th International Conference on Electrical, Electronic and Computing Engineering (IcETRAN) : Proceedings",
title = "National Intercomparison of Indoor Radon Measurements by Charcoal Canisters",
pages = "1-4",
doi = "10.1109/IcETRAN62308.2024.10645172"
}
Forkapić, S., Knežević Radić, J., Velimirović, D., Hansman, J., Arsić, V.,& Rajačić, M.. (2024). National Intercomparison of Indoor Radon Measurements by Charcoal Canisters. in 11th International Conference on Electrical, Electronic and Computing Engineering (IcETRAN) : Proceedings
IEEE : Institute of Electrical and Electronics Engineers (IEEE)., 1-4.
https://doi.org/10.1109/IcETRAN62308.2024.10645172
Forkapić S, Knežević Radić J, Velimirović D, Hansman J, Arsić V, Rajačić M. National Intercomparison of Indoor Radon Measurements by Charcoal Canisters. in 11th International Conference on Electrical, Electronic and Computing Engineering (IcETRAN) : Proceedings. 2024;:1-4.
doi:10.1109/IcETRAN62308.2024.10645172 .
Forkapić, Sofija, Knežević Radić, Jovana, Velimirović, Danijel, Hansman, Jan, Arsić, Vesna, Rajačić, Milica, "National Intercomparison of Indoor Radon Measurements by Charcoal Canisters" in 11th International Conference on Electrical, Electronic and Computing Engineering (IcETRAN) : Proceedings (2024):1-4,
https://doi.org/10.1109/IcETRAN62308.2024.10645172 . .

Novel insights into the problem of enthalpy and entropy convergence in thermal decomposition of coal slag using the data from non-isothermal kinetic measurements

Janković, Bojan; Janković, Marija; Smičiklas, Ivana; Jović, Mihajlo; Vukanac, Ivana; Mraković, Ana; Manić, Nebojša

(2024)

TY  - JOUR
AU  - Janković, Bojan
AU  - Janković, Marija
AU  - Smičiklas, Ivana
AU  - Jović, Mihajlo
AU  - Vukanac, Ivana
AU  - Mraković, Ana
AU  - Manić, Nebojša
PY  - 2024
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/13237
AB  - This study provides insight into benefits of thermo-chemical conversion of coal slag as recovery process into value-added products. This research involves kinetic analysis of process conducted through non-isothermal thermal analysis measurements, with additional raw material characterization. Kinetic results showed that decomposition proceeds through two consecutive reactions steps (first one, including anorthite P1‾ → I1‾ phase transition, and then production of incongruent melting product (ternary system: CaO⋅Al2O3⋅2SiO2 (CAS2), where viscosity of slag changes), and second one including dehydration and formation of meta-muscovite, and subsequently, thermal disruption of muscovite de-hydroxylated phase, which proceeds with breaking of octahedral Al–O bonds), and one single-step reaction (attributed to CO-reduction of hematite to magnetite). Thermodynamic results showed an existence of physically meaningful isokinetic temperature (Tiso), which corresponds to active vibrational frequency of surroundings of SiO2 reaction site, manifested through Si‒O bond weakening by catalytic reaction of freed hydroxide ion (OH􀀀 ). It was concluded that at temperature T = Tiso, the course of process loses its dependence on temperature and pressure, regulating changes between thermodynamic parameters, through enthalpy-entropy compensation (EEC) effect.
T2  - Thermochimica Acta
T1  - Novel insights into the problem of enthalpy and entropy convergence in thermal decomposition of coal slag using the data from non-isothermal kinetic measurements
VL  - 736
SP  - 179763
DO  - 10.1016/j.tca.2024.179763
ER  - 
@article{
author = "Janković, Bojan and Janković, Marija and Smičiklas, Ivana and Jović, Mihajlo and Vukanac, Ivana and Mraković, Ana and Manić, Nebojša",
year = "2024",
abstract = "This study provides insight into benefits of thermo-chemical conversion of coal slag as recovery process into value-added products. This research involves kinetic analysis of process conducted through non-isothermal thermal analysis measurements, with additional raw material characterization. Kinetic results showed that decomposition proceeds through two consecutive reactions steps (first one, including anorthite P1‾ → I1‾ phase transition, and then production of incongruent melting product (ternary system: CaO⋅Al2O3⋅2SiO2 (CAS2), where viscosity of slag changes), and second one including dehydration and formation of meta-muscovite, and subsequently, thermal disruption of muscovite de-hydroxylated phase, which proceeds with breaking of octahedral Al–O bonds), and one single-step reaction (attributed to CO-reduction of hematite to magnetite). Thermodynamic results showed an existence of physically meaningful isokinetic temperature (Tiso), which corresponds to active vibrational frequency of surroundings of SiO2 reaction site, manifested through Si‒O bond weakening by catalytic reaction of freed hydroxide ion (OH􀀀 ). It was concluded that at temperature T = Tiso, the course of process loses its dependence on temperature and pressure, regulating changes between thermodynamic parameters, through enthalpy-entropy compensation (EEC) effect.",
journal = "Thermochimica Acta",
title = "Novel insights into the problem of enthalpy and entropy convergence in thermal decomposition of coal slag using the data from non-isothermal kinetic measurements",
volume = "736",
pages = "179763",
doi = "10.1016/j.tca.2024.179763"
}
Janković, B., Janković, M., Smičiklas, I., Jović, M., Vukanac, I., Mraković, A.,& Manić, N.. (2024). Novel insights into the problem of enthalpy and entropy convergence in thermal decomposition of coal slag using the data from non-isothermal kinetic measurements. in Thermochimica Acta, 736, 179763.
https://doi.org/10.1016/j.tca.2024.179763
Janković B, Janković M, Smičiklas I, Jović M, Vukanac I, Mraković A, Manić N. Novel insights into the problem of enthalpy and entropy convergence in thermal decomposition of coal slag using the data from non-isothermal kinetic measurements. in Thermochimica Acta. 2024;736:179763.
doi:10.1016/j.tca.2024.179763 .
Janković, Bojan, Janković, Marija, Smičiklas, Ivana, Jović, Mihajlo, Vukanac, Ivana, Mraković, Ana, Manić, Nebojša, "Novel insights into the problem of enthalpy and entropy convergence in thermal decomposition of coal slag using the data from non-isothermal kinetic measurements" in Thermochimica Acta, 736 (2024):179763,
https://doi.org/10.1016/j.tca.2024.179763 . .

Comparison of some of the analytical techniques and their applications to environmental radiostrontium determination

Sarap, Nataša; Nodilo, Marijana; Štrok, Marko; Grahek, Željko; Janković, Marija

(2024)

TY  - JOUR
AU  - Sarap, Nataša
AU  - Nodilo, Marijana
AU  - Štrok, Marko
AU  - Grahek, Željko
AU  - Janković, Marija
PY  - 2024
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/13241
AB  - he knowledge about behavior of 90Sr in environment is of importance to prevent and control contamination. A large number of analytical methods have been developed for the determination of 90Sr in environmental samples. The conducted study was focused on interpretation and evaluation of the results obtained using three radiochemical procedures for the separation of 90Sr and/or 90Y including the classical procedures based on a series of semi-selective precipitations, the ion-exchange procedure and the use of fuming nitric acid. The acquired results showed a good agreement between the compared methods within the terms of accuracy and precision.
T2  - Journal of Radioanalytical and Nuclear Chemistry
T1  - Comparison of some of the analytical techniques and their applications to environmental radiostrontium determination
DO  - 10.1007/s10967-024-09499-2
ER  - 
@article{
author = "Sarap, Nataša and Nodilo, Marijana and Štrok, Marko and Grahek, Željko and Janković, Marija",
year = "2024",
abstract = "he knowledge about behavior of 90Sr in environment is of importance to prevent and control contamination. A large number of analytical methods have been developed for the determination of 90Sr in environmental samples. The conducted study was focused on interpretation and evaluation of the results obtained using three radiochemical procedures for the separation of 90Sr and/or 90Y including the classical procedures based on a series of semi-selective precipitations, the ion-exchange procedure and the use of fuming nitric acid. The acquired results showed a good agreement between the compared methods within the terms of accuracy and precision.",
journal = "Journal of Radioanalytical and Nuclear Chemistry",
title = "Comparison of some of the analytical techniques and their applications to environmental radiostrontium determination",
doi = "10.1007/s10967-024-09499-2"
}
Sarap, N., Nodilo, M., Štrok, M., Grahek, Ž.,& Janković, M.. (2024). Comparison of some of the analytical techniques and their applications to environmental radiostrontium determination. in Journal of Radioanalytical and Nuclear Chemistry.
https://doi.org/10.1007/s10967-024-09499-2
Sarap N, Nodilo M, Štrok M, Grahek Ž, Janković M. Comparison of some of the analytical techniques and their applications to environmental radiostrontium determination. in Journal of Radioanalytical and Nuclear Chemistry. 2024;.
doi:10.1007/s10967-024-09499-2 .
Sarap, Nataša, Nodilo, Marijana, Štrok, Marko, Grahek, Željko, Janković, Marija, "Comparison of some of the analytical techniques and their applications to environmental radiostrontium determination" in Journal of Radioanalytical and Nuclear Chemistry (2024),
https://doi.org/10.1007/s10967-024-09499-2 . .
2
2

Application of Model-Free and Model-Based Kinetic Methods in Evaluation of Reactions Complexity during Thermo-Oxidative Degradation Process: Case Study of [4-(Hydroxymethyl)phenoxymethyl] Polystyrene Resin

Janković, Bojan Ž.; Dodevski, Vladimir; Veljković, Filip M.; Janković, Marija M.; Manić, Nebojša

(2024)

TY  - JOUR
AU  - Janković, Bojan Ž.
AU  - Dodevski, Vladimir
AU  - Veljković, Filip M.
AU  - Janković, Marija M.
AU  - Manić, Nebojša
PY  - 2024
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/13254
AB  - This work examined the possibilities and limitations of model-free and model-based methods related to decrypting the kinetic complexity of multi-step thermo-oxidative degradation processes (as a testing system, a [4-(hydroxymethyl)phenoxymethyl] polystyrene resin was used), monitored by thermal analysis (TGA-DTG-DTA) techniques. It was found that isoconversional methods could successfully determine the correct number of process stages and presence of multiple reactions based on derived Ea(α) profiles and identify the negative dependence of the rate constant on the temperature. These methods could not overcome the problem that arose due to mass transfer limitations. The model-based method overcame more successfully the problem associated with mass transfer because its calculation machinery had capabilities for the correct solution of the total mass balance equation. However, a perfect fit with the experimental data was not achieved due to the dependence on the thermal history of the contribution (ctb.) of a given reaction step inside a fitting procedure cycle. On the other hand, through this approach, it was possible to estimate the rate-controlling steps of the process regarding the influence of the heating rate. It was found that for consecutive reaction mechanisms, the production of benzaldehyde and gases in high yields was controlled by the heating rate, where low heating rates were strongly recommended (≤10 K/min). Also, it was shown that the transport phenomenon may be also the rate-determining step (within the set of “intrinsic” kinetic parameters). It was also established that external heat transfer controls the overall rate, where the “pure” kinetic control regime had not been reached but was approached when lowering the temperature and size of the resin particles.
T2  - Fire
T1  - Application of Model-Free and Model-Based Kinetic Methods in Evaluation of Reactions Complexity during Thermo-Oxidative Degradation Process: Case Study of [4-(Hydroxymethyl)phenoxymethyl] Polystyrene Resin
VL  - 7
IS  - 5
SP  - 165
DO  - 10.3390/fire7050165
ER  - 
@article{
author = "Janković, Bojan Ž. and Dodevski, Vladimir and Veljković, Filip M. and Janković, Marija M. and Manić, Nebojša",
year = "2024",
abstract = "This work examined the possibilities and limitations of model-free and model-based methods related to decrypting the kinetic complexity of multi-step thermo-oxidative degradation processes (as a testing system, a [4-(hydroxymethyl)phenoxymethyl] polystyrene resin was used), monitored by thermal analysis (TGA-DTG-DTA) techniques. It was found that isoconversional methods could successfully determine the correct number of process stages and presence of multiple reactions based on derived Ea(α) profiles and identify the negative dependence of the rate constant on the temperature. These methods could not overcome the problem that arose due to mass transfer limitations. The model-based method overcame more successfully the problem associated with mass transfer because its calculation machinery had capabilities for the correct solution of the total mass balance equation. However, a perfect fit with the experimental data was not achieved due to the dependence on the thermal history of the contribution (ctb.) of a given reaction step inside a fitting procedure cycle. On the other hand, through this approach, it was possible to estimate the rate-controlling steps of the process regarding the influence of the heating rate. It was found that for consecutive reaction mechanisms, the production of benzaldehyde and gases in high yields was controlled by the heating rate, where low heating rates were strongly recommended (≤10 K/min). Also, it was shown that the transport phenomenon may be also the rate-determining step (within the set of “intrinsic” kinetic parameters). It was also established that external heat transfer controls the overall rate, where the “pure” kinetic control regime had not been reached but was approached when lowering the temperature and size of the resin particles.",
journal = "Fire",
title = "Application of Model-Free and Model-Based Kinetic Methods in Evaluation of Reactions Complexity during Thermo-Oxidative Degradation Process: Case Study of [4-(Hydroxymethyl)phenoxymethyl] Polystyrene Resin",
volume = "7",
number = "5",
pages = "165",
doi = "10.3390/fire7050165"
}
Janković, B. Ž., Dodevski, V., Veljković, F. M., Janković, M. M.,& Manić, N.. (2024). Application of Model-Free and Model-Based Kinetic Methods in Evaluation of Reactions Complexity during Thermo-Oxidative Degradation Process: Case Study of [4-(Hydroxymethyl)phenoxymethyl] Polystyrene Resin. in Fire, 7(5), 165.
https://doi.org/10.3390/fire7050165
Janković BŽ, Dodevski V, Veljković FM, Janković MM, Manić N. Application of Model-Free and Model-Based Kinetic Methods in Evaluation of Reactions Complexity during Thermo-Oxidative Degradation Process: Case Study of [4-(Hydroxymethyl)phenoxymethyl] Polystyrene Resin. in Fire. 2024;7(5):165.
doi:10.3390/fire7050165 .
Janković, Bojan Ž., Dodevski, Vladimir, Veljković, Filip M., Janković, Marija M., Manić, Nebojša, "Application of Model-Free and Model-Based Kinetic Methods in Evaluation of Reactions Complexity during Thermo-Oxidative Degradation Process: Case Study of [4-(Hydroxymethyl)phenoxymethyl] Polystyrene Resin" in Fire, 7, no. 5 (2024):165,
https://doi.org/10.3390/fire7050165 . .

Enthalpy–entropy compensation and isoequilibrium relationship in thermo-chemical conversion of cigarette butt filters (CBFs) based on cellulose acetate (CA): causes and effects

Janković, Bojan; Marinović-Cincović, Milena; Manić, Nebojša; Janković, Marija; Waisi, Hadi; Dodevski, Vladimir

(2024)

TY  - JOUR
AU  - Janković, Bojan
AU  - Marinović-Cincović, Milena
AU  - Manić, Nebojša
AU  - Janković, Marija
AU  - Waisi, Hadi
AU  - Dodevski, Vladimir
PY  - 2024
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/13370
AB  - The aim of this study is to explain the consequences of the occurrence of enthalpy–entropy compensation (EEC) and isoequilibrium relationship during slow pyrolysis of cigarette butt filters (CBFs), consisting cellulose acetate (AC) as the main component. By using model-free and model-based kinetic methods and thermodynamic calculations, the complete reaction mechanism and extrathermodynamic issues about investigated process are completely resolved. It was established that compensation phenomenon where isoequilibrium temperature occurs is a consequence of formation of low-entropy molecular structure (cellulose II) and breaking of hydrogen bonds. Consequently, it was concluded that mechanisms which include a formation of low-entropy molecular structure and H-bonds breakage enter the changes in both enthalpy and entropy, which compensate each other. For the cellulose II generation, it was necessary to invest energy which represents use up energy. This “wasted” energy turns into work for creation of cellulose II molecular structures, whereby additional energy was provided from “local” decomposition reactions (which were identified in the established process mechanism) that arise from pyrolysis of starting material. Therefore, it was concluded that for “local reactions”, a negative ΔS° value was identified, but for the global process, the entropy change retained a positive value. Considering thermodynamic effects manifested through compensation temperature found below glass transition temperature (Tg) in the undercooling conditions, it was concluded that small amounts of plasticizers affect reduction of free volume in the glassy state. Obtained results indicated a decrease in β-relaxation mode of cellulose acetate by an abatement of the polymer free volume.
T2  - Polymer Bulletin
T1  - Enthalpy–entropy compensation and isoequilibrium relationship in thermo-chemical conversion of cigarette butt filters (CBFs) based on cellulose acetate (CA): causes and effects
DO  - 10.1007/s00289-024-05343-5
ER  - 
@article{
author = "Janković, Bojan and Marinović-Cincović, Milena and Manić, Nebojša and Janković, Marija and Waisi, Hadi and Dodevski, Vladimir",
year = "2024",
abstract = "The aim of this study is to explain the consequences of the occurrence of enthalpy–entropy compensation (EEC) and isoequilibrium relationship during slow pyrolysis of cigarette butt filters (CBFs), consisting cellulose acetate (AC) as the main component. By using model-free and model-based kinetic methods and thermodynamic calculations, the complete reaction mechanism and extrathermodynamic issues about investigated process are completely resolved. It was established that compensation phenomenon where isoequilibrium temperature occurs is a consequence of formation of low-entropy molecular structure (cellulose II) and breaking of hydrogen bonds. Consequently, it was concluded that mechanisms which include a formation of low-entropy molecular structure and H-bonds breakage enter the changes in both enthalpy and entropy, which compensate each other. For the cellulose II generation, it was necessary to invest energy which represents use up energy. This “wasted” energy turns into work for creation of cellulose II molecular structures, whereby additional energy was provided from “local” decomposition reactions (which were identified in the established process mechanism) that arise from pyrolysis of starting material. Therefore, it was concluded that for “local reactions”, a negative ΔS° value was identified, but for the global process, the entropy change retained a positive value. Considering thermodynamic effects manifested through compensation temperature found below glass transition temperature (Tg) in the undercooling conditions, it was concluded that small amounts of plasticizers affect reduction of free volume in the glassy state. Obtained results indicated a decrease in β-relaxation mode of cellulose acetate by an abatement of the polymer free volume.",
journal = "Polymer Bulletin",
title = "Enthalpy–entropy compensation and isoequilibrium relationship in thermo-chemical conversion of cigarette butt filters (CBFs) based on cellulose acetate (CA): causes and effects",
doi = "10.1007/s00289-024-05343-5"
}
Janković, B., Marinović-Cincović, M., Manić, N., Janković, M., Waisi, H.,& Dodevski, V.. (2024). Enthalpy–entropy compensation and isoequilibrium relationship in thermo-chemical conversion of cigarette butt filters (CBFs) based on cellulose acetate (CA): causes and effects. in Polymer Bulletin.
https://doi.org/10.1007/s00289-024-05343-5
Janković B, Marinović-Cincović M, Manić N, Janković M, Waisi H, Dodevski V. Enthalpy–entropy compensation and isoequilibrium relationship in thermo-chemical conversion of cigarette butt filters (CBFs) based on cellulose acetate (CA): causes and effects. in Polymer Bulletin. 2024;.
doi:10.1007/s00289-024-05343-5 .
Janković, Bojan, Marinović-Cincović, Milena, Manić, Nebojša, Janković, Marija, Waisi, Hadi, Dodevski, Vladimir, "Enthalpy–entropy compensation and isoequilibrium relationship in thermo-chemical conversion of cigarette butt filters (CBFs) based on cellulose acetate (CA): causes and effects" in Polymer Bulletin (2024),
https://doi.org/10.1007/s00289-024-05343-5 . .

Application and Experimental Substantiation of the Radioecological Model for Prediction in Behavior 90Sr in Cultivated Soil-Crop System: A Case Study of Two Experimental Agricultural Fields

Sarap, Nataša; Daković, Marko Ž.; Đalović, Ivica; Dolijanović, Željko; Prasad, P.V. Vara; Janković, Marija M.

(2024)

TY  - JOUR
AU  - Sarap, Nataša
AU  - Daković, Marko Ž.
AU  - Đalović, Ivica
AU  - Dolijanović, Željko
AU  - Prasad, P.V. Vara
AU  - Janković, Marija M.
PY  - 2024
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/13467
AB  - The radioactive fission product 90Sr has a sufficient half-life (28.8 years) to be detected long after its appearance in the environment. After its uptake into the soil-edible plant system, it enters the food chain and represents a potential source of contamination that threatens human health. Due to these facts, tracking the distribution of the artificial radionuclide 90Sr in the soil–edible plant system is a subject of intense research. The tracking of the 90Sr radionuclide distribution in the soil profile, as well as in the crops on the long-term experimental fields was carried out using beta radiation spectrometry. The radiochemical analytical method was used to analyze the 90Sr content in cultivated soil and crops. The conducted study focused on the experimental substantiation of the developed model for predicting the behavior of 90Sr in the cultivated soil–crop system. The results of using the applied radioecological model for the transfer of 90Sr from the soil to the above-ground part of crops showed a relatively good agreement with the experimentally determined values of the soil–crop transfer factor, which indicates that the used model can be successfully applied for the prediction of the behavior of 90Sr in the soil–soil solution–crop system.
T2  - Plants
T1  - Application and Experimental Substantiation of the Radioecological Model for Prediction in Behavior 90Sr in Cultivated Soil-Crop System: A Case Study of Two Experimental Agricultural Fields
VL  - 13
IS  - 13
SP  - 1798
DO  - 10.3390/plants13131798
ER  - 
@article{
author = "Sarap, Nataša and Daković, Marko Ž. and Đalović, Ivica and Dolijanović, Željko and Prasad, P.V. Vara and Janković, Marija M.",
year = "2024",
abstract = "The radioactive fission product 90Sr has a sufficient half-life (28.8 years) to be detected long after its appearance in the environment. After its uptake into the soil-edible plant system, it enters the food chain and represents a potential source of contamination that threatens human health. Due to these facts, tracking the distribution of the artificial radionuclide 90Sr in the soil–edible plant system is a subject of intense research. The tracking of the 90Sr radionuclide distribution in the soil profile, as well as in the crops on the long-term experimental fields was carried out using beta radiation spectrometry. The radiochemical analytical method was used to analyze the 90Sr content in cultivated soil and crops. The conducted study focused on the experimental substantiation of the developed model for predicting the behavior of 90Sr in the cultivated soil–crop system. The results of using the applied radioecological model for the transfer of 90Sr from the soil to the above-ground part of crops showed a relatively good agreement with the experimentally determined values of the soil–crop transfer factor, which indicates that the used model can be successfully applied for the prediction of the behavior of 90Sr in the soil–soil solution–crop system.",
journal = "Plants",
title = "Application and Experimental Substantiation of the Radioecological Model for Prediction in Behavior 90Sr in Cultivated Soil-Crop System: A Case Study of Two Experimental Agricultural Fields",
volume = "13",
number = "13",
pages = "1798",
doi = "10.3390/plants13131798"
}
Sarap, N., Daković, M. Ž., Đalović, I., Dolijanović, Ž., Prasad, P.V. V.,& Janković, M. M.. (2024). Application and Experimental Substantiation of the Radioecological Model for Prediction in Behavior 90Sr in Cultivated Soil-Crop System: A Case Study of Two Experimental Agricultural Fields. in Plants, 13(13), 1798.
https://doi.org/10.3390/plants13131798
Sarap N, Daković MŽ, Đalović I, Dolijanović Ž, Prasad PV, Janković MM. Application and Experimental Substantiation of the Radioecological Model for Prediction in Behavior 90Sr in Cultivated Soil-Crop System: A Case Study of Two Experimental Agricultural Fields. in Plants. 2024;13(13):1798.
doi:10.3390/plants13131798 .
Sarap, Nataša, Daković, Marko Ž., Đalović, Ivica, Dolijanović, Željko, Prasad, P.V. Vara, Janković, Marija M., "Application and Experimental Substantiation of the Radioecological Model for Prediction in Behavior 90Sr in Cultivated Soil-Crop System: A Case Study of Two Experimental Agricultural Fields" in Plants, 13, no. 13 (2024):1798,
https://doi.org/10.3390/plants13131798 . .

Trendovi korišćenja crvenog mulja kao adsorbenta za uklanjanje različitih polutanata iz industrijskih otpadnih voda

Rajković, Maja; Jelić, Ivana; Janković, Marija; Antonijević, Dragi; Šljivić-Ivanović, Marija

(Beograd : Savez mašinskih i elektrotehničkih inženjera i tehničara Srbije (SMEITS), 2024)

TY  - CONF
AU  - Rajković, Maja
AU  - Jelić, Ivana
AU  - Janković, Marija
AU  - Antonijević, Dragi
AU  - Šljivić-Ivanović, Marija
PY  - 2024
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/13473
AB  - Poslednjih nekoliko decenija sve se već i značaj pridaje iskorišć avanju otpadnih materijala koji se uz adekvatnu modifikaciju koriste u cilju izdvajanja različitih polutanata iz industrijskih otpadnih voda. Korišćenje otpadnog materijala iz jedne industrije za rešavanje problema zagađenja u drugoj industriji ultimativno vodi ka održivim i cirkularnim pristupima u inženjerstvu životne sredine. Na ovaj način, u jednom koraku mogu se rešiti dva goruć a problema, upravljanje otpadom i tretman otpadnih voda. Trend prenamene industrijskog otpada kao prekursora za formiranje sorbenata koji bi imali širok spektar primene je evidentan. Crveni mulj često se naziva nusproizvodom koji nastaje tokom proizvodnje aluminijuma. Ovaj boksitni ostatak se sve više posmatra kao resurs sa potencijalom za korisnu ponovnu upotrebu, umesto da se strogo označava kao otpad. Najčešći vid odlaganja ove visoko alkalne suspenzije jeste deponovanje na posebnim lokacijama čime se zauzimaju velike površine tla, a moguća je i migracija razli čitih potencijalno toksičnih materija u medijume voda-vazduh-zemljište. Zbog visoke alkalnosti i moguć eg ispiranja teških metala, njegovo odlaganje može biti opasno po životnu sredinu. Jedna od potencijalnih upotreba crvenog mulja, s obzirom na njegov specifičan hemijsko-mineraloški sastav, je u tretmanu industrijskih otpadnih voda u cilju uklanjanja polutanata. Na osnovu pregleda literature, ova studija sumira potencijalnu upotrebu crvenog mulja kao adsorbenta za prečišć avanje industrijskih otpadnih voda, naglašavajuć i tehno-ekonomsku analizu i efikasnost otklanjanja zagađenja. Pregled postojećih istraživanja obuhvata kritičku evaluaciju performansi adsorpcije, faktore koji utiču na efikasnost umesto na efektivnost, i potencijal za uklanjanje specifičnih polutanata poput teških metala i radionuklida iz vodenih rastvora. Ovaj pregled pruža nov pristup implementaciji cirkularne ekonomije u prečišćavanju otpadnih voda, istovremeno usmeravajući buduća istraživanja ka održivim i ekonomski isplativim rešenjima.
AB  - In the last few decades, increasing importance has been placed on waste materials utilization with the necessary modification in order to extract various pollutants from industrial wastewater. Using the waste material from one industry to solve the pollution problem in another industry ultimately leads toward sustainable and circular approaches in environmental engineering. In this way, two pressing problems, waste management and wastewater treatment, can be solved in one step. The trend of repurposing industrial waste as a precursor for the formation of sorbents that would have a wide range of applications is evident. Red mud is often referred to as a byproduct generated during the production of alumina. This bauxite residue is increasingly being viewed as a material with the potential for beneficial reuse rather than being labeled strictly as waste. The most common type of this highly alkaline suspension disposal is deposition at special sites, which occupies large areas, and the migration of various potentially toxic substances in the water-air-soil medium is possible. Due to its high alkalinity and possible leaching of heavy metals, its disposal can be hazardous to the environment. One of the potential uses of red mud, given its specific chemical-mineralogical composition, is in the treatment of industrial wastewater in order to remove pollutants. Based on the literature review, this study summarizes the red mud’s potential usage as an adsorbent for industrial wastewater treatment, emphasizing techno-economic analysis and pollution removal efficiency. An overview of existing research includes a critical evaluation of the adsorption performance, factors influencing efficiency rather than efficacy, and the potential for specific pollutant removal such as heavy metals and radionuclides from aqueous solutions. This review provides a new approach to a circular economy implementation in wastewater treatment while guiding future research directions for sustainable and cost-effective solutions.
PB  - Beograd : Savez mašinskih i elektrotehničkih inženjera i tehničara Srbije (SMEITS)
PB  - Beograd : Društvo za procesnu tehniku
C3  - Procesing '24 : zbornik radova pisanih za 37. Međunarodni kongres o procesnoj industriji
T1  - Trendovi korišćenja crvenog mulja kao adsorbenta za uklanjanje različitih polutanata iz industrijskih otpadnih voda
T1  - Trends in Red Mud Utilization as an Adsorbent for the Removal of Different Pollutants From Industrial Wastewater
SP  - 97
EP  - 98
UR  - https://hdl.handle.net/21.15107/rcub_vinar_13473
ER  - 
@conference{
author = "Rajković, Maja and Jelić, Ivana and Janković, Marija and Antonijević, Dragi and Šljivić-Ivanović, Marija",
year = "2024",
abstract = "Poslednjih nekoliko decenija sve se već i značaj pridaje iskorišć avanju otpadnih materijala koji se uz adekvatnu modifikaciju koriste u cilju izdvajanja različitih polutanata iz industrijskih otpadnih voda. Korišćenje otpadnog materijala iz jedne industrije za rešavanje problema zagađenja u drugoj industriji ultimativno vodi ka održivim i cirkularnim pristupima u inženjerstvu životne sredine. Na ovaj način, u jednom koraku mogu se rešiti dva goruć a problema, upravljanje otpadom i tretman otpadnih voda. Trend prenamene industrijskog otpada kao prekursora za formiranje sorbenata koji bi imali širok spektar primene je evidentan. Crveni mulj često se naziva nusproizvodom koji nastaje tokom proizvodnje aluminijuma. Ovaj boksitni ostatak se sve više posmatra kao resurs sa potencijalom za korisnu ponovnu upotrebu, umesto da se strogo označava kao otpad. Najčešći vid odlaganja ove visoko alkalne suspenzije jeste deponovanje na posebnim lokacijama čime se zauzimaju velike površine tla, a moguća je i migracija razli čitih potencijalno toksičnih materija u medijume voda-vazduh-zemljište. Zbog visoke alkalnosti i moguć eg ispiranja teških metala, njegovo odlaganje može biti opasno po životnu sredinu. Jedna od potencijalnih upotreba crvenog mulja, s obzirom na njegov specifičan hemijsko-mineraloški sastav, je u tretmanu industrijskih otpadnih voda u cilju uklanjanja polutanata. Na osnovu pregleda literature, ova studija sumira potencijalnu upotrebu crvenog mulja kao adsorbenta za prečišć avanje industrijskih otpadnih voda, naglašavajuć i tehno-ekonomsku analizu i efikasnost otklanjanja zagađenja. Pregled postojećih istraživanja obuhvata kritičku evaluaciju performansi adsorpcije, faktore koji utiču na efikasnost umesto na efektivnost, i potencijal za uklanjanje specifičnih polutanata poput teških metala i radionuklida iz vodenih rastvora. Ovaj pregled pruža nov pristup implementaciji cirkularne ekonomije u prečišćavanju otpadnih voda, istovremeno usmeravajući buduća istraživanja ka održivim i ekonomski isplativim rešenjima., In the last few decades, increasing importance has been placed on waste materials utilization with the necessary modification in order to extract various pollutants from industrial wastewater. Using the waste material from one industry to solve the pollution problem in another industry ultimately leads toward sustainable and circular approaches in environmental engineering. In this way, two pressing problems, waste management and wastewater treatment, can be solved in one step. The trend of repurposing industrial waste as a precursor for the formation of sorbents that would have a wide range of applications is evident. Red mud is often referred to as a byproduct generated during the production of alumina. This bauxite residue is increasingly being viewed as a material with the potential for beneficial reuse rather than being labeled strictly as waste. The most common type of this highly alkaline suspension disposal is deposition at special sites, which occupies large areas, and the migration of various potentially toxic substances in the water-air-soil medium is possible. Due to its high alkalinity and possible leaching of heavy metals, its disposal can be hazardous to the environment. One of the potential uses of red mud, given its specific chemical-mineralogical composition, is in the treatment of industrial wastewater in order to remove pollutants. Based on the literature review, this study summarizes the red mud’s potential usage as an adsorbent for industrial wastewater treatment, emphasizing techno-economic analysis and pollution removal efficiency. An overview of existing research includes a critical evaluation of the adsorption performance, factors influencing efficiency rather than efficacy, and the potential for specific pollutant removal such as heavy metals and radionuclides from aqueous solutions. This review provides a new approach to a circular economy implementation in wastewater treatment while guiding future research directions for sustainable and cost-effective solutions.",
publisher = "Beograd : Savez mašinskih i elektrotehničkih inženjera i tehničara Srbije (SMEITS), Beograd : Društvo za procesnu tehniku",
journal = "Procesing '24 : zbornik radova pisanih za 37. Međunarodni kongres o procesnoj industriji",
title = "Trendovi korišćenja crvenog mulja kao adsorbenta za uklanjanje različitih polutanata iz industrijskih otpadnih voda, Trends in Red Mud Utilization as an Adsorbent for the Removal of Different Pollutants From Industrial Wastewater",
pages = "97-98",
url = "https://hdl.handle.net/21.15107/rcub_vinar_13473"
}
Rajković, M., Jelić, I., Janković, M., Antonijević, D.,& Šljivić-Ivanović, M.. (2024). Trendovi korišćenja crvenog mulja kao adsorbenta za uklanjanje različitih polutanata iz industrijskih otpadnih voda. in Procesing '24 : zbornik radova pisanih za 37. Međunarodni kongres o procesnoj industriji
Beograd : Savez mašinskih i elektrotehničkih inženjera i tehničara Srbije (SMEITS)., 97-98.
https://hdl.handle.net/21.15107/rcub_vinar_13473
Rajković M, Jelić I, Janković M, Antonijević D, Šljivić-Ivanović M. Trendovi korišćenja crvenog mulja kao adsorbenta za uklanjanje različitih polutanata iz industrijskih otpadnih voda. in Procesing '24 : zbornik radova pisanih za 37. Međunarodni kongres o procesnoj industriji. 2024;:97-98.
https://hdl.handle.net/21.15107/rcub_vinar_13473 .
Rajković, Maja, Jelić, Ivana, Janković, Marija, Antonijević, Dragi, Šljivić-Ivanović, Marija, "Trendovi korišćenja crvenog mulja kao adsorbenta za uklanjanje različitih polutanata iz industrijskih otpadnih voda" in Procesing '24 : zbornik radova pisanih za 37. Međunarodni kongres o procesnoj industriji (2024):97-98,
https://hdl.handle.net/21.15107/rcub_vinar_13473 .

The impacts of waste materials utilization in liquid radioactive waste solidification by mortar matrix

Jelić, Ivana; Savić, Aleksandar; Miljojčić, Tatjana; Rajković, Maja; Janković, Marija; Sarap, Nataša; Dimović, Slavko; Ćurčić, Milica; Stanić, Vojislav; Antonijević, Dragi; Šljivić-Ivanović, Marija

(University of Belgrade : Technical Faculty in Bor, 2024)

TY  - CONF
AU  - Jelić, Ivana
AU  - Savić, Aleksandar
AU  - Miljojčić, Tatjana
AU  - Rajković, Maja
AU  - Janković, Marija
AU  - Sarap, Nataša
AU  - Dimović, Slavko
AU  - Ćurčić, Milica
AU  - Stanić, Vojislav
AU  - Antonijević, Dragi
AU  - Šljivić-Ivanović, Marija
PY  - 2024
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/13531
AB  - The nuclear industry generates significant radioactive waste (RW) amounts, with its safe disposal being a primary safety and environmental issue. RW management involves solidification and disposal, often in deep underground facilities. Cement mortar is commonly used for liquid RW solidification due to its cost-effectiveness and simplicity. However, Portland cement concrete production raises environmental concerns, such as CO2 emissions and natural resource depletion. Additionally, RW storage and disposal costs drive research into low-cost matrices, especially those made from final waste products. The main requirements for matrix materials for liquid RW immobilization, which accept the role of primary barrier, are compatibility with RW material, good mechanical properties, and resistance to chemical and biological agents. However, partially substituting cement with waste materials can reduce strength and durability, increase susceptibility to cracking, porosity, and corrosion, further leading to harmful substance release. The matrix material must demonstrate longterm stability under various environmental conditions, including changes in temperature, humidity, and exposure to radiation ensuring that RW remains stable and safe within the matrix for decades or centuries. In addition, factors such as groundwater infiltration and seismic activity should also be considered when evaluating the long-term effectiveness of a protective structure. To manage these hazards, the selection, treatment, and preparation of recycled waste are crucial, alongside with proper design and utilization of such concrete. Monitoring concrete performance over time and implementing maintenance measures are necessary to ensure the long-term durability and reliability of structures. This work aims to assess the overall impact of recycled materials utilized in liquid RW solidification matrix.
PB  - University of Belgrade : Technical Faculty in Bor
C3  - EcoTER’24 : 31st International Conference Ecological Truth and Environmental Research : Proceedings
T1  - The impacts of waste materials utilization in liquid radioactive waste solidification by mortar matrix
SP  - 200
EP  - 205
UR  - https://hdl.handle.net/21.15107/rcub_vinar_13531
ER  - 
@conference{
author = "Jelić, Ivana and Savić, Aleksandar and Miljojčić, Tatjana and Rajković, Maja and Janković, Marija and Sarap, Nataša and Dimović, Slavko and Ćurčić, Milica and Stanić, Vojislav and Antonijević, Dragi and Šljivić-Ivanović, Marija",
year = "2024",
abstract = "The nuclear industry generates significant radioactive waste (RW) amounts, with its safe disposal being a primary safety and environmental issue. RW management involves solidification and disposal, often in deep underground facilities. Cement mortar is commonly used for liquid RW solidification due to its cost-effectiveness and simplicity. However, Portland cement concrete production raises environmental concerns, such as CO2 emissions and natural resource depletion. Additionally, RW storage and disposal costs drive research into low-cost matrices, especially those made from final waste products. The main requirements for matrix materials for liquid RW immobilization, which accept the role of primary barrier, are compatibility with RW material, good mechanical properties, and resistance to chemical and biological agents. However, partially substituting cement with waste materials can reduce strength and durability, increase susceptibility to cracking, porosity, and corrosion, further leading to harmful substance release. The matrix material must demonstrate longterm stability under various environmental conditions, including changes in temperature, humidity, and exposure to radiation ensuring that RW remains stable and safe within the matrix for decades or centuries. In addition, factors such as groundwater infiltration and seismic activity should also be considered when evaluating the long-term effectiveness of a protective structure. To manage these hazards, the selection, treatment, and preparation of recycled waste are crucial, alongside with proper design and utilization of such concrete. Monitoring concrete performance over time and implementing maintenance measures are necessary to ensure the long-term durability and reliability of structures. This work aims to assess the overall impact of recycled materials utilized in liquid RW solidification matrix.",
publisher = "University of Belgrade : Technical Faculty in Bor",
journal = "EcoTER’24 : 31st International Conference Ecological Truth and Environmental Research : Proceedings",
title = "The impacts of waste materials utilization in liquid radioactive waste solidification by mortar matrix",
pages = "200-205",
url = "https://hdl.handle.net/21.15107/rcub_vinar_13531"
}
Jelić, I., Savić, A., Miljojčić, T., Rajković, M., Janković, M., Sarap, N., Dimović, S., Ćurčić, M., Stanić, V., Antonijević, D.,& Šljivić-Ivanović, M.. (2024). The impacts of waste materials utilization in liquid radioactive waste solidification by mortar matrix. in EcoTER’24 : 31st International Conference Ecological Truth and Environmental Research : Proceedings
University of Belgrade : Technical Faculty in Bor., 200-205.
https://hdl.handle.net/21.15107/rcub_vinar_13531
Jelić I, Savić A, Miljojčić T, Rajković M, Janković M, Sarap N, Dimović S, Ćurčić M, Stanić V, Antonijević D, Šljivić-Ivanović M. The impacts of waste materials utilization in liquid radioactive waste solidification by mortar matrix. in EcoTER’24 : 31st International Conference Ecological Truth and Environmental Research : Proceedings. 2024;:200-205.
https://hdl.handle.net/21.15107/rcub_vinar_13531 .
Jelić, Ivana, Savić, Aleksandar, Miljojčić, Tatjana, Rajković, Maja, Janković, Marija, Sarap, Nataša, Dimović, Slavko, Ćurčić, Milica, Stanić, Vojislav, Antonijević, Dragi, Šljivić-Ivanović, Marija, "The impacts of waste materials utilization in liquid radioactive waste solidification by mortar matrix" in EcoTER’24 : 31st International Conference Ecological Truth and Environmental Research : Proceedings (2024):200-205,
https://hdl.handle.net/21.15107/rcub_vinar_13531 .

Energetska tranzicija: Prednosti nuklearne energije u kontekstu životne sredine

Rajković, Maja; Jelić, Ivana; Dimović, Slavko; Janković, Marija; Ćurčić, Milica; Šljivić-Ivanović, Marija

(Beograd : Društvo za ETRAN, 2024)

TY  - CONF
AU  - Rajković, Maja
AU  - Jelić, Ivana
AU  - Dimović, Slavko
AU  - Janković, Marija
AU  - Ćurčić, Milica
AU  - Šljivić-Ivanović, Marija
PY  - 2024
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/13737
AB  - Preovlađujući diskurs o energetici u savremenoj eri naglašava klimatske promene i energetsku bezbednost kao najvažnije zabrinutosti. Dok su obnovljivi izvori energije (OIE) zavisni od geografskih i klimatskih uslova, postavljajući izazove kao što su diskontinuirana dostupnost i zahtevi za okupiranjem velikih površina zemljišta, nuklearna energija predstavlja obećavajuću alternativa. Međutim, putanja ka nuklearnoj energiji kao vidu čiste energije je zamagljena strahovima javnosti i državnim propisima i politikama, iako sa sve većim prepoznavanjem njenog potencijala kao pouzdanog i niskougljeničnog izvora energije. Optimalan put ka niskougljeničnom razvoju energetike, pored upotrebe OIE, podrazumeva i korišćenje nuklearne energije. Napredna nulearna tenologijaobezbeđuje poboljšane mere bezbednosti, minimiziranje proizvodnje otpada i dobru alternativu za tranziciju postojećeg energetskog sistema baziranog na konvencionalnim izvorima energije.
AB  - The prevailing discourse on energy in the contemporary era emphasizes climate change and energy security as primary concerns. While renewable energy sources (RES) depend on geographic and climatic conditions, posing challenges such as intermittent availability and the requirement for large land areas, nuclear energy presents a promising alternative. However, the path towards nuclear energy as a form of clean energy is obscured by public fears and governmental regulations and policies, despite increasing recognition of its potential as a reliable and low-carbon energy source. The optimal path to low-carbon energy development, in addition to the use of RES, also implies the utilization of nuclear energy. Advanced nuclear technology provides improved safety measures, minimizes waste production, and offers a viable alternative for transitioning from the existing energy system based on conventional energy sources.
PB  - Beograd : Društvo za ETRAN
PB  - Beograd : Akademska misao
C3  - ETRAN : 68th Conference ETRAN and 11th International Conference IcETRAN 2024 : Program and Book of Abstracts
T1  - Energetska tranzicija: Prednosti nuklearne energije u kontekstu životne sredine
T1  - Energy transition: Advantages of nuclear energy in an environmental context
SP  - 243
EP  - 248
DO  - 10.69994/68E24043
ER  - 
@conference{
author = "Rajković, Maja and Jelić, Ivana and Dimović, Slavko and Janković, Marija and Ćurčić, Milica and Šljivić-Ivanović, Marija",
year = "2024",
abstract = "Preovlađujući diskurs o energetici u savremenoj eri naglašava klimatske promene i energetsku bezbednost kao najvažnije zabrinutosti. Dok su obnovljivi izvori energije (OIE) zavisni od geografskih i klimatskih uslova, postavljajući izazove kao što su diskontinuirana dostupnost i zahtevi za okupiranjem velikih površina zemljišta, nuklearna energija predstavlja obećavajuću alternativa. Međutim, putanja ka nuklearnoj energiji kao vidu čiste energije je zamagljena strahovima javnosti i državnim propisima i politikama, iako sa sve većim prepoznavanjem njenog potencijala kao pouzdanog i niskougljeničnog izvora energije. Optimalan put ka niskougljeničnom razvoju energetike, pored upotrebe OIE, podrazumeva i korišćenje nuklearne energije. Napredna nulearna tenologijaobezbeđuje poboljšane mere bezbednosti, minimiziranje proizvodnje otpada i dobru alternativu za tranziciju postojećeg energetskog sistema baziranog na konvencionalnim izvorima energije., The prevailing discourse on energy in the contemporary era emphasizes climate change and energy security as primary concerns. While renewable energy sources (RES) depend on geographic and climatic conditions, posing challenges such as intermittent availability and the requirement for large land areas, nuclear energy presents a promising alternative. However, the path towards nuclear energy as a form of clean energy is obscured by public fears and governmental regulations and policies, despite increasing recognition of its potential as a reliable and low-carbon energy source. The optimal path to low-carbon energy development, in addition to the use of RES, also implies the utilization of nuclear energy. Advanced nuclear technology provides improved safety measures, minimizes waste production, and offers a viable alternative for transitioning from the existing energy system based on conventional energy sources.",
publisher = "Beograd : Društvo za ETRAN, Beograd : Akademska misao",
journal = "ETRAN : 68th Conference ETRAN and 11th International Conference IcETRAN 2024 : Program and Book of Abstracts",
title = "Energetska tranzicija: Prednosti nuklearne energije u kontekstu životne sredine, Energy transition: Advantages of nuclear energy in an environmental context",
pages = "243-248",
doi = "10.69994/68E24043"
}
Rajković, M., Jelić, I., Dimović, S., Janković, M., Ćurčić, M.,& Šljivić-Ivanović, M.. (2024). Energetska tranzicija: Prednosti nuklearne energije u kontekstu životne sredine. in ETRAN : 68th Conference ETRAN and 11th International Conference IcETRAN 2024 : Program and Book of Abstracts
Beograd : Društvo za ETRAN., 243-248.
https://doi.org/10.69994/68E24043
Rajković M, Jelić I, Dimović S, Janković M, Ćurčić M, Šljivić-Ivanović M. Energetska tranzicija: Prednosti nuklearne energije u kontekstu životne sredine. in ETRAN : 68th Conference ETRAN and 11th International Conference IcETRAN 2024 : Program and Book of Abstracts. 2024;:243-248.
doi:10.69994/68E24043 .
Rajković, Maja, Jelić, Ivana, Dimović, Slavko, Janković, Marija, Ćurčić, Milica, Šljivić-Ivanović, Marija, "Energetska tranzicija: Prednosti nuklearne energije u kontekstu životne sredine" in ETRAN : 68th Conference ETRAN and 11th International Conference IcETRAN 2024 : Program and Book of Abstracts (2024):243-248,
https://doi.org/10.69994/68E24043 . .

Radioprotective effects of linden honey in rat peripheral blood

Stojiljković, Vesna; Gavrilović, Ljubica; Stanić, Vojislav; Stanković, Srboljub; Nikolić, Dragan; Pejić, Snežana; Pajović, Snežana

(2024)

TY  - JOUR
AU  - Stojiljković, Vesna
AU  - Gavrilović, Ljubica
AU  - Stanić, Vojislav
AU  - Stanković, Srboljub
AU  - Nikolić, Dragan
AU  - Pejić, Snežana
AU  - Pajović, Snežana
PY  - 2024
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/13748
AB  - Radiotherapy affects not only malignant, but also a healthy tissue adjacent to tumor by increasing reactive oxygen species generation, with consequent damage to biomolecules, such as the oxidation of membrane lipids, known as lipid peroxidation. The end product of lipid peroxidation is malondialdehyde. Radioprotectors are compounds that could significantly protect normal cells from radiation, without changing the tumor cell radiosensitivity. Synthetic radioprotectors usually have side effects and are toxic. Natural radioprotectors exert protection without adverse effects. In this study, we examined the radioprotective ability of linden honey in rat blood, by detecting alterations in the activities of antioxidant enzymes catalase and glutathione peroxidase and malondialdehyde concentration after the exposure to a therapeutic dose of gamma rays. Sixteen rats were randomly divided into Control and Honey groups. Honey group received honey (1.5 mL(kgd-1)) orally for four weeks, while at the same time Control group were given distilled water. After four weeks, blood was sampled from all animals. Samples were halved, and one series of samples were gamma irradiated (2 Gy). Radiation induced decreased glutathione peroxidase activity and increased malondialdehyde level, while honey treatment attenuated those alterations, keeping glutathione peroxidase and malondialdehyde at physiological levels. These findings confirm radioprotective properties of linden honey.
T2  - Nuclear Technology and Radiation Protection
T1  - Radioprotective effects of linden honey in rat peripheral blood
T1  - Radioprotektivno dejstvo lipovog meda u perifernoj krvi pacova
VL  - 39
IS  - 1
SP  - 81
EP  - 87
DO  - 10.2298/NTRP2401081S
ER  - 
@article{
author = "Stojiljković, Vesna and Gavrilović, Ljubica and Stanić, Vojislav and Stanković, Srboljub and Nikolić, Dragan and Pejić, Snežana and Pajović, Snežana",
year = "2024",
abstract = "Radiotherapy affects not only malignant, but also a healthy tissue adjacent to tumor by increasing reactive oxygen species generation, with consequent damage to biomolecules, such as the oxidation of membrane lipids, known as lipid peroxidation. The end product of lipid peroxidation is malondialdehyde. Radioprotectors are compounds that could significantly protect normal cells from radiation, without changing the tumor cell radiosensitivity. Synthetic radioprotectors usually have side effects and are toxic. Natural radioprotectors exert protection without adverse effects. In this study, we examined the radioprotective ability of linden honey in rat blood, by detecting alterations in the activities of antioxidant enzymes catalase and glutathione peroxidase and malondialdehyde concentration after the exposure to a therapeutic dose of gamma rays. Sixteen rats were randomly divided into Control and Honey groups. Honey group received honey (1.5 mL(kgd-1)) orally for four weeks, while at the same time Control group were given distilled water. After four weeks, blood was sampled from all animals. Samples were halved, and one series of samples were gamma irradiated (2 Gy). Radiation induced decreased glutathione peroxidase activity and increased malondialdehyde level, while honey treatment attenuated those alterations, keeping glutathione peroxidase and malondialdehyde at physiological levels. These findings confirm radioprotective properties of linden honey.",
journal = "Nuclear Technology and Radiation Protection",
title = "Radioprotective effects of linden honey in rat peripheral blood, Radioprotektivno dejstvo lipovog meda u perifernoj krvi pacova",
volume = "39",
number = "1",
pages = "81-87",
doi = "10.2298/NTRP2401081S"
}
Stojiljković, V., Gavrilović, L., Stanić, V., Stanković, S., Nikolić, D., Pejić, S.,& Pajović, S.. (2024). Radioprotective effects of linden honey in rat peripheral blood. in Nuclear Technology and Radiation Protection, 39(1), 81-87.
https://doi.org/10.2298/NTRP2401081S
Stojiljković V, Gavrilović L, Stanić V, Stanković S, Nikolić D, Pejić S, Pajović S. Radioprotective effects of linden honey in rat peripheral blood. in Nuclear Technology and Radiation Protection. 2024;39(1):81-87.
doi:10.2298/NTRP2401081S .
Stojiljković, Vesna, Gavrilović, Ljubica, Stanić, Vojislav, Stanković, Srboljub, Nikolić, Dragan, Pejić, Snežana, Pajović, Snežana, "Radioprotective effects of linden honey in rat peripheral blood" in Nuclear Technology and Radiation Protection, 39, no. 1 (2024):81-87,
https://doi.org/10.2298/NTRP2401081S . .

Comparable Toxicity of Surface-Modified TiO2 Nanoparticles: An In Vivo Experimental Study on Reproductive Toxicity in Rats

Todorović, Ana; Bobić, Katarina; Veljković, Filip; Pejić, Snežana; Glumac, Sofija; Stanković, Sanja; Milovanović, Tijana; Vukoje, Ivana; Nedeljković, Jovan; Radojević Škodrić, Sanja; Pajović, Snežana B.; Drakulić, Dunja

(2024)

TY  - JOUR
AU  - Todorović, Ana
AU  - Bobić, Katarina
AU  - Veljković, Filip
AU  - Pejić, Snežana
AU  - Glumac, Sofija
AU  - Stanković, Sanja
AU  - Milovanović, Tijana
AU  - Vukoje, Ivana
AU  - Nedeljković, Jovan
AU  - Radojević Škodrić, Sanja
AU  - Pajović, Snežana B.
AU  - Drakulić, Dunja
PY  - 2024
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/13090
AB  - Nanoparticles (NPs), a distinct class of particles ranging in size from 1 to 100 nm, are one of the most promising technologies of the 21st century, and titanium dioxide NPs (TiO2 NPs) are among the most widely produced and used NPs globally. The increased application of TiO2 NPs raises concerns regarding their global safety and risks of exposure. Many animal studies have reported the accumulation of TiO2 NPs in female reproductive organs; however, evidence of the resultant toxicity remains ambiguous. Since the surface area and chemical modifications of NPs can significantly change their cytotoxicity, we aimed to compare the toxic effects of pristine TiO2 powder with surface-modified TiO2 powders with salicylic acid (TiO2/SA) and 5-aminosalicylic acid (TiO2/5-ASA) on the ovaries, oviducts, and uterus on the 14th day following acute oral treatment. The results, based on alterations in food and water intake, body mass, organ-to-body mass ratio, hormonal status, histological features of tissues of interest, and antioxidant parameters, suggest that the modification with 5-ASA can mitigate some of the observed toxic effects of TiO2 powder and encourage future investigations to create NPs that can potentially reduce the harmful effects of TiO2 NPs while preserving their positive impacts.
T2  - Antioxidants
T1  - Comparable Toxicity of Surface-Modified TiO2 Nanoparticles: An In Vivo Experimental Study on Reproductive Toxicity in Rats
VL  - 13
IS  - 2
SP  - 231
DO  - 10.3390/antiox13020231
ER  - 
@article{
author = "Todorović, Ana and Bobić, Katarina and Veljković, Filip and Pejić, Snežana and Glumac, Sofija and Stanković, Sanja and Milovanović, Tijana and Vukoje, Ivana and Nedeljković, Jovan and Radojević Škodrić, Sanja and Pajović, Snežana B. and Drakulić, Dunja",
year = "2024",
abstract = "Nanoparticles (NPs), a distinct class of particles ranging in size from 1 to 100 nm, are one of the most promising technologies of the 21st century, and titanium dioxide NPs (TiO2 NPs) are among the most widely produced and used NPs globally. The increased application of TiO2 NPs raises concerns regarding their global safety and risks of exposure. Many animal studies have reported the accumulation of TiO2 NPs in female reproductive organs; however, evidence of the resultant toxicity remains ambiguous. Since the surface area and chemical modifications of NPs can significantly change their cytotoxicity, we aimed to compare the toxic effects of pristine TiO2 powder with surface-modified TiO2 powders with salicylic acid (TiO2/SA) and 5-aminosalicylic acid (TiO2/5-ASA) on the ovaries, oviducts, and uterus on the 14th day following acute oral treatment. The results, based on alterations in food and water intake, body mass, organ-to-body mass ratio, hormonal status, histological features of tissues of interest, and antioxidant parameters, suggest that the modification with 5-ASA can mitigate some of the observed toxic effects of TiO2 powder and encourage future investigations to create NPs that can potentially reduce the harmful effects of TiO2 NPs while preserving their positive impacts.",
journal = "Antioxidants",
title = "Comparable Toxicity of Surface-Modified TiO2 Nanoparticles: An In Vivo Experimental Study on Reproductive Toxicity in Rats",
volume = "13",
number = "2",
pages = "231",
doi = "10.3390/antiox13020231"
}
Todorović, A., Bobić, K., Veljković, F., Pejić, S., Glumac, S., Stanković, S., Milovanović, T., Vukoje, I., Nedeljković, J., Radojević Škodrić, S., Pajović, S. B.,& Drakulić, D.. (2024). Comparable Toxicity of Surface-Modified TiO2 Nanoparticles: An In Vivo Experimental Study on Reproductive Toxicity in Rats. in Antioxidants, 13(2), 231.
https://doi.org/10.3390/antiox13020231
Todorović A, Bobić K, Veljković F, Pejić S, Glumac S, Stanković S, Milovanović T, Vukoje I, Nedeljković J, Radojević Škodrić S, Pajović SB, Drakulić D. Comparable Toxicity of Surface-Modified TiO2 Nanoparticles: An In Vivo Experimental Study on Reproductive Toxicity in Rats. in Antioxidants. 2024;13(2):231.
doi:10.3390/antiox13020231 .
Todorović, Ana, Bobić, Katarina, Veljković, Filip, Pejić, Snežana, Glumac, Sofija, Stanković, Sanja, Milovanović, Tijana, Vukoje, Ivana, Nedeljković, Jovan, Radojević Škodrić, Sanja, Pajović, Snežana B., Drakulić, Dunja, "Comparable Toxicity of Surface-Modified TiO2 Nanoparticles: An In Vivo Experimental Study on Reproductive Toxicity in Rats" in Antioxidants, 13, no. 2 (2024):231,
https://doi.org/10.3390/antiox13020231 . .
2
2

Titanium(IV) oxide nanoparticles surface-modified with salicylic and 5-aminosalicylic acid affect lipid and protein oxidation in the brain of Wistar rats

Bobić, Katarina; Drakulić, Dunja; Pejić, Snežana; Milovanović, Tijana; Miletić Vukajlović, Jadranka; Pajović, Snežana B.; Todorović, Ana

(Warsaw : Nencki Institute of Experimental Biology of the Polish Academy of Sciences, 2024)

TY  - CONF
AU  - Bobić, Katarina
AU  - Drakulić, Dunja
AU  - Pejić, Snežana
AU  - Milovanović, Tijana
AU  - Miletić Vukajlović, Jadranka
AU  - Pajović, Snežana B.
AU  - Todorović, Ana
PY  - 2024
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/13425
PB  - Warsaw : Nencki Institute of Experimental Biology of the Polish Academy of Sciences
C3  - Acta Neurobiologiae Experimentalis
T1  - Titanium(IV) oxide nanoparticles surface-modified with salicylic and 5-aminosalicylic acid affect lipid and protein oxidation in the brain of Wistar rats
VL  - 84
IS  - Supplement
SP  - 126
EP  - 126
UR  - https://hdl.handle.net/21.15107/rcub_vinar_13425
ER  - 
@conference{
author = "Bobić, Katarina and Drakulić, Dunja and Pejić, Snežana and Milovanović, Tijana and Miletić Vukajlović, Jadranka and Pajović, Snežana B. and Todorović, Ana",
year = "2024",
publisher = "Warsaw : Nencki Institute of Experimental Biology of the Polish Academy of Sciences",
journal = "Acta Neurobiologiae Experimentalis",
title = "Titanium(IV) oxide nanoparticles surface-modified with salicylic and 5-aminosalicylic acid affect lipid and protein oxidation in the brain of Wistar rats",
volume = "84",
number = "Supplement",
pages = "126-126",
url = "https://hdl.handle.net/21.15107/rcub_vinar_13425"
}
Bobić, K., Drakulić, D., Pejić, S., Milovanović, T., Miletić Vukajlović, J., Pajović, S. B.,& Todorović, A.. (2024). Titanium(IV) oxide nanoparticles surface-modified with salicylic and 5-aminosalicylic acid affect lipid and protein oxidation in the brain of Wistar rats. in Acta Neurobiologiae Experimentalis
Warsaw : Nencki Institute of Experimental Biology of the Polish Academy of Sciences., 84(Supplement), 126-126.
https://hdl.handle.net/21.15107/rcub_vinar_13425
Bobić K, Drakulić D, Pejić S, Milovanović T, Miletić Vukajlović J, Pajović SB, Todorović A. Titanium(IV) oxide nanoparticles surface-modified with salicylic and 5-aminosalicylic acid affect lipid and protein oxidation in the brain of Wistar rats. in Acta Neurobiologiae Experimentalis. 2024;84(Supplement):126-126.
https://hdl.handle.net/21.15107/rcub_vinar_13425 .
Bobić, Katarina, Drakulić, Dunja, Pejić, Snežana, Milovanović, Tijana, Miletić Vukajlović, Jadranka, Pajović, Snežana B., Todorović, Ana, "Titanium(IV) oxide nanoparticles surface-modified with salicylic and 5-aminosalicylic acid affect lipid and protein oxidation in the brain of Wistar rats" in Acta Neurobiologiae Experimentalis, 84, no. Supplement (2024):126-126,
https://hdl.handle.net/21.15107/rcub_vinar_13425 .

Nanocarriers in topical photodynamic therapy

Dragićević, Nina; Predić-Atkinson, Jelena; Nikolić, Bojan; Pajović, Snežana B.; Ivković, Sanja; Adžić, Miroslav

(2024)

TY  - JOUR
AU  - Dragićević, Nina
AU  - Predić-Atkinson, Jelena
AU  - Nikolić, Bojan
AU  - Pajović, Snežana B.
AU  - Ivković, Sanja
AU  - Adžić, Miroslav
PY  - 2024
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/12828
AB  - Introduction  Photodynamic therapy (PDT) has gained significant attention due to its superiority over conventional treatments. In the context of skin cancers and nonmalignant skin diseases, topical application of photosensitizer formulations onto affected skin, followed by illumination, offers distinct advantages. Topical PDT simplifies therapy by providing easy access to the skin, increasing drug concentration within the target area, and confining residual photosensitivity to the treated skin. However, the effectiveness of topical PDT is often hindered by challenges such as limited skin penetration or photosensitizer instability. Additionally, the hypoxic tumor environment poses further limitations. Nanocarriers present a promising solution to address these challenges. Areas covered  The objective of this review is to comprehensively explore and highlight the role of various nanocarriers in advancing topical PDT for the treatment of skin diseases. The primary focus is to address the challenges associated with conventional topical PDT approaches and demonstrate how nanotechnology-based strategies can overcome these challenges, thereby improving the overall efficiency and efficacy of PDT. Expert opinion  Nanotechnology has revolutionized the field of PDT, offering innovative tools to combat the unfavorable features of photosensitizers and hurdles in PDT. Nanocarriers enhance skin penetration and stability of photosensitizers, provide controlled drug release, reduce needed dose, increase production of reactive oxygen species, while reducing side effects, thereby improving PDT effectiveness.
T2  - Expert Opinion on Drug Delivery
T1  - Nanocarriers in topical photodynamic therapy
VL  - 21
IS  - 2
DO  - 10.1080/17425247.2024.2318460
ER  - 
@article{
author = "Dragićević, Nina and Predić-Atkinson, Jelena and Nikolić, Bojan and Pajović, Snežana B. and Ivković, Sanja and Adžić, Miroslav",
year = "2024",
abstract = "Introduction  Photodynamic therapy (PDT) has gained significant attention due to its superiority over conventional treatments. In the context of skin cancers and nonmalignant skin diseases, topical application of photosensitizer formulations onto affected skin, followed by illumination, offers distinct advantages. Topical PDT simplifies therapy by providing easy access to the skin, increasing drug concentration within the target area, and confining residual photosensitivity to the treated skin. However, the effectiveness of topical PDT is often hindered by challenges such as limited skin penetration or photosensitizer instability. Additionally, the hypoxic tumor environment poses further limitations. Nanocarriers present a promising solution to address these challenges. Areas covered  The objective of this review is to comprehensively explore and highlight the role of various nanocarriers in advancing topical PDT for the treatment of skin diseases. The primary focus is to address the challenges associated with conventional topical PDT approaches and demonstrate how nanotechnology-based strategies can overcome these challenges, thereby improving the overall efficiency and efficacy of PDT. Expert opinion  Nanotechnology has revolutionized the field of PDT, offering innovative tools to combat the unfavorable features of photosensitizers and hurdles in PDT. Nanocarriers enhance skin penetration and stability of photosensitizers, provide controlled drug release, reduce needed dose, increase production of reactive oxygen species, while reducing side effects, thereby improving PDT effectiveness.",
journal = "Expert Opinion on Drug Delivery",
title = "Nanocarriers in topical photodynamic therapy",
volume = "21",
number = "2",
doi = "10.1080/17425247.2024.2318460"
}
Dragićević, N., Predić-Atkinson, J., Nikolić, B., Pajović, S. B., Ivković, S.,& Adžić, M.. (2024). Nanocarriers in topical photodynamic therapy. in Expert Opinion on Drug Delivery, 21(2).
https://doi.org/10.1080/17425247.2024.2318460
Dragićević N, Predić-Atkinson J, Nikolić B, Pajović SB, Ivković S, Adžić M. Nanocarriers in topical photodynamic therapy. in Expert Opinion on Drug Delivery. 2024;21(2).
doi:10.1080/17425247.2024.2318460 .
Dragićević, Nina, Predić-Atkinson, Jelena, Nikolić, Bojan, Pajović, Snežana B., Ivković, Sanja, Adžić, Miroslav, "Nanocarriers in topical photodynamic therapy" in Expert Opinion on Drug Delivery, 21, no. 2 (2024),
https://doi.org/10.1080/17425247.2024.2318460 . .
3
2

Gamma irradiation induced degradation of organic pollutants: Recent advances and future perspective

Egerić, Marija; Matović, Ljiljana; Savić, Marjetka; Stanković, Srboljub; Wu, Yi-nan; Li, Fengting; Vujasin, Radojka

(2024)

TY  - JOUR
AU  - Egerić, Marija
AU  - Matović, Ljiljana
AU  - Savić, Marjetka
AU  - Stanković, Srboljub
AU  - Wu, Yi-nan
AU  - Li, Fengting
AU  - Vujasin, Radojka
PY  - 2024
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/13025
AB  - Different organic compounds in aquatic bodies have been recognized as an emerging issue in Environmental Chemistry. The gamma irradiation technique, as one of the advanced oxidation techniques, has been widely investigated in past decades as a technique for the degradation of organic molecules, such as dyes, pesticides, and pharmaceuticals, which show high persistence to degradation. This review gives an overview of what has been achieved so far using gamma irradiation for different organic compound degradations giving an explanation of the mechanisms of degradations as well as the corresponding limitations and drawbacks, and the answer to why this technique has not yet widely come to life. Also, a new approach, recently presented in the literature, regards coupling gamma irradiation with other techniques and materials, as the latest trend. A critical evaluation of the most recent advances achieved by coupling gamma irradiation with other methods and/or materials, as well as describing the reaction mechanisms of coupling, that is, additional destabilization of molecules achieved by coupling, emphasizing the advantages of the newly proposed approach. Finally, it was concluded what are the perspectives and future directions towards its commercialization since this technique can contribute to waste minimization i.e. not waste transfer to other media. Summarizing and generalization the model of radiolytic degradation with and without coupling with other techniques can further guide designing a new modular, mobile method that will satisfy all the needs for its wide commercial application.
T2  - Chemosphere
T1  - Gamma irradiation induced degradation of organic pollutants: Recent advances and future perspective
VL  - 352
SP  - 141437
DO  - 10.1016/j.chemosphere.2024.141437
ER  - 
@article{
author = "Egerić, Marija and Matović, Ljiljana and Savić, Marjetka and Stanković, Srboljub and Wu, Yi-nan and Li, Fengting and Vujasin, Radojka",
year = "2024",
abstract = "Different organic compounds in aquatic bodies have been recognized as an emerging issue in Environmental Chemistry. The gamma irradiation technique, as one of the advanced oxidation techniques, has been widely investigated in past decades as a technique for the degradation of organic molecules, such as dyes, pesticides, and pharmaceuticals, which show high persistence to degradation. This review gives an overview of what has been achieved so far using gamma irradiation for different organic compound degradations giving an explanation of the mechanisms of degradations as well as the corresponding limitations and drawbacks, and the answer to why this technique has not yet widely come to life. Also, a new approach, recently presented in the literature, regards coupling gamma irradiation with other techniques and materials, as the latest trend. A critical evaluation of the most recent advances achieved by coupling gamma irradiation with other methods and/or materials, as well as describing the reaction mechanisms of coupling, that is, additional destabilization of molecules achieved by coupling, emphasizing the advantages of the newly proposed approach. Finally, it was concluded what are the perspectives and future directions towards its commercialization since this technique can contribute to waste minimization i.e. not waste transfer to other media. Summarizing and generalization the model of radiolytic degradation with and without coupling with other techniques can further guide designing a new modular, mobile method that will satisfy all the needs for its wide commercial application.",
journal = "Chemosphere",
title = "Gamma irradiation induced degradation of organic pollutants: Recent advances and future perspective",
volume = "352",
pages = "141437",
doi = "10.1016/j.chemosphere.2024.141437"
}
Egerić, M., Matović, L., Savić, M., Stanković, S., Wu, Y., Li, F.,& Vujasin, R.. (2024). Gamma irradiation induced degradation of organic pollutants: Recent advances and future perspective. in Chemosphere, 352, 141437.
https://doi.org/10.1016/j.chemosphere.2024.141437
Egerić M, Matović L, Savić M, Stanković S, Wu Y, Li F, Vujasin R. Gamma irradiation induced degradation of organic pollutants: Recent advances and future perspective. in Chemosphere. 2024;352:141437.
doi:10.1016/j.chemosphere.2024.141437 .
Egerić, Marija, Matović, Ljiljana, Savić, Marjetka, Stanković, Srboljub, Wu, Yi-nan, Li, Fengting, Vujasin, Radojka, "Gamma irradiation induced degradation of organic pollutants: Recent advances and future perspective" in Chemosphere, 352 (2024):141437,
https://doi.org/10.1016/j.chemosphere.2024.141437 . .

Gamma Irradiation Induced Dyes Degradation: Recent Progress and Future Perspective for Wastewater Treatment

Egerić, Marija; Petrović, Dimitrije; Savić, Marjetka; Devečerski, Aleksandar; Stanković, Srboljub; Vujasin, Radojka; Matović, Ljiljana

(Belgrade : Vinča Institute of Nuclear Sciences - National Institute of thе Republic of Serbia, University of Belgrade, 2024)

TY  - CONF
AU  - Egerić, Marija
AU  - Petrović, Dimitrije
AU  - Savić, Marjetka
AU  - Devečerski, Aleksandar
AU  - Stanković, Srboljub
AU  - Vujasin, Radojka
AU  - Matović, Ljiljana
PY  - 2024
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/13157
PB  - Belgrade : Vinča Institute of Nuclear Sciences - National Institute of thе Republic of Serbia, University of Belgrade
PB  - Belgrade : Serbian Society for Innovative Materials in Extreme Conditions (SIM-EXTREME)
C3  - IMEC2024 - 2nd International Conference on Innovative Materials in Extreme Conditions : Book of abstracts
T1  - Gamma Irradiation Induced Dyes Degradation: Recent Progress and Future Perspective for Wastewater Treatment
SP  - 61
EP  - 61
UR  - https://hdl.handle.net/21.15107/rcub_vinar_13157
ER  - 
@conference{
author = "Egerić, Marija and Petrović, Dimitrije and Savić, Marjetka and Devečerski, Aleksandar and Stanković, Srboljub and Vujasin, Radojka and Matović, Ljiljana",
year = "2024",
publisher = "Belgrade : Vinča Institute of Nuclear Sciences - National Institute of thе Republic of Serbia, University of Belgrade, Belgrade : Serbian Society for Innovative Materials in Extreme Conditions (SIM-EXTREME)",
journal = "IMEC2024 - 2nd International Conference on Innovative Materials in Extreme Conditions : Book of abstracts",
title = "Gamma Irradiation Induced Dyes Degradation: Recent Progress and Future Perspective for Wastewater Treatment",
pages = "61-61",
url = "https://hdl.handle.net/21.15107/rcub_vinar_13157"
}
Egerić, M., Petrović, D., Savić, M., Devečerski, A., Stanković, S., Vujasin, R.,& Matović, L.. (2024). Gamma Irradiation Induced Dyes Degradation: Recent Progress and Future Perspective for Wastewater Treatment. in IMEC2024 - 2nd International Conference on Innovative Materials in Extreme Conditions : Book of abstracts
Belgrade : Vinča Institute of Nuclear Sciences - National Institute of thе Republic of Serbia, University of Belgrade., 61-61.
https://hdl.handle.net/21.15107/rcub_vinar_13157
Egerić M, Petrović D, Savić M, Devečerski A, Stanković S, Vujasin R, Matović L. Gamma Irradiation Induced Dyes Degradation: Recent Progress and Future Perspective for Wastewater Treatment. in IMEC2024 - 2nd International Conference on Innovative Materials in Extreme Conditions : Book of abstracts. 2024;:61-61.
https://hdl.handle.net/21.15107/rcub_vinar_13157 .
Egerić, Marija, Petrović, Dimitrije, Savić, Marjetka, Devečerski, Aleksandar, Stanković, Srboljub, Vujasin, Radojka, Matović, Ljiljana, "Gamma Irradiation Induced Dyes Degradation: Recent Progress and Future Perspective for Wastewater Treatment" in IMEC2024 - 2nd International Conference on Innovative Materials in Extreme Conditions : Book of abstracts (2024):61-61,
https://hdl.handle.net/21.15107/rcub_vinar_13157 .

Laser processing effects on Ti−45Nb alloy surface, corrosive and biocompatible properties

Cvijović-Alagić, Ivana; Laketić, Slađana; Momčilović, Miloš; Ciganović, Jovan; Veljović, Đorđe; Bajat, Jelena; Kojić, Vesna; Rakin, Marko

(2024)

TY  - JOUR
AU  - Cvijović-Alagić, Ivana
AU  - Laketić, Slađana
AU  - Momčilović, Miloš
AU  - Ciganović, Jovan
AU  - Veljović, Đorđe
AU  - Bajat, Jelena
AU  - Kojić, Vesna
AU  - Rakin, Marko
PY  - 2024
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/13747
AB  - The Ti−45Nb (wt.%) alloy properties were investigated in relation to its potential biomedical use. Laser surface modification was utilized to improve its performance in biological systems. As a result of the laser treatment, (Ti,Nb)O scale was formed and various morphological features appeared on the alloy surface. The electrochemical behavior of Ti−45Nb alloy in simulated body conditions was evaluated and showed that the alloy was highly resistant to corrosion deterioration regardless of additional laser surface modification treatment. Nevertheless, the improved corrosion resistance after laser treatment was evident (the corrosion current density of the alloy before laser irradiation was 2.84×10−8 A/cm2, while that after laser treatment with 5 mJ was 0.65×10−8 A/cm2) and ascribed to the rapid formation of a complex and passivating bi-modal surface oxide layer. Alloy cytotoxicity and effects of the Ti−45Nb alloy laser surface modification on the MRC-5 cell viability, morphology, and proliferation were also investigated. The Ti−45Nb alloy showed no cytotoxic effect. Moreover, cells showed improved viability and adherence to the alloy surface after the laser irradiation treatment. The highest average cell viability of 115.37% was attained for the alloy laser-irradiated with 15 mJ. Results showed that the laser surface modification can be successfully utilized to significantly improve alloy performance in a biological environment.
T2  - Transactions of Nonferrous Metals Society of China
T1  - Laser processing effects on Ti−45Nb alloy surface, corrosive and biocompatible properties
VL  - 34
IS  - 8
SP  - 2533
EP  - 2551
DO  - 10.1016/S1003-6326(24)66558-1
ER  - 
@article{
author = "Cvijović-Alagić, Ivana and Laketić, Slađana and Momčilović, Miloš and Ciganović, Jovan and Veljović, Đorđe and Bajat, Jelena and Kojić, Vesna and Rakin, Marko",
year = "2024",
abstract = "The Ti−45Nb (wt.%) alloy properties were investigated in relation to its potential biomedical use. Laser surface modification was utilized to improve its performance in biological systems. As a result of the laser treatment, (Ti,Nb)O scale was formed and various morphological features appeared on the alloy surface. The electrochemical behavior of Ti−45Nb alloy in simulated body conditions was evaluated and showed that the alloy was highly resistant to corrosion deterioration regardless of additional laser surface modification treatment. Nevertheless, the improved corrosion resistance after laser treatment was evident (the corrosion current density of the alloy before laser irradiation was 2.84×10−8 A/cm2, while that after laser treatment with 5 mJ was 0.65×10−8 A/cm2) and ascribed to the rapid formation of a complex and passivating bi-modal surface oxide layer. Alloy cytotoxicity and effects of the Ti−45Nb alloy laser surface modification on the MRC-5 cell viability, morphology, and proliferation were also investigated. The Ti−45Nb alloy showed no cytotoxic effect. Moreover, cells showed improved viability and adherence to the alloy surface after the laser irradiation treatment. The highest average cell viability of 115.37% was attained for the alloy laser-irradiated with 15 mJ. Results showed that the laser surface modification can be successfully utilized to significantly improve alloy performance in a biological environment.",
journal = "Transactions of Nonferrous Metals Society of China",
title = "Laser processing effects on Ti−45Nb alloy surface, corrosive and biocompatible properties",
volume = "34",
number = "8",
pages = "2533-2551",
doi = "10.1016/S1003-6326(24)66558-1"
}
Cvijović-Alagić, I., Laketić, S., Momčilović, M., Ciganović, J., Veljović, Đ., Bajat, J., Kojić, V.,& Rakin, M.. (2024). Laser processing effects on Ti−45Nb alloy surface, corrosive and biocompatible properties. in Transactions of Nonferrous Metals Society of China, 34(8), 2533-2551.
https://doi.org/10.1016/S1003-6326(24)66558-1
Cvijović-Alagić I, Laketić S, Momčilović M, Ciganović J, Veljović Đ, Bajat J, Kojić V, Rakin M. Laser processing effects on Ti−45Nb alloy surface, corrosive and biocompatible properties. in Transactions of Nonferrous Metals Society of China. 2024;34(8):2533-2551.
doi:10.1016/S1003-6326(24)66558-1 .
Cvijović-Alagić, Ivana, Laketić, Slađana, Momčilović, Miloš, Ciganović, Jovan, Veljović, Đorđe, Bajat, Jelena, Kojić, Vesna, Rakin, Marko, "Laser processing effects on Ti−45Nb alloy surface, corrosive and biocompatible properties" in Transactions of Nonferrous Metals Society of China, 34, no. 8 (2024):2533-2551,
https://doi.org/10.1016/S1003-6326(24)66558-1 . .

Microstructure Formations Resulting from Nanosecond and Picosecond Laser Irradiation of a Ti-Based Alloy under Controlled Atmospheric Conditions and Optimization of the Irradiation Process

Milovanović, Dubravka; Rajčić, Boris; Ranković, Dragan; Stankov, Biljana; Čekada, Miha; Ciganović, Jovan; Đurđević-Milošević, Dragica; Stević, Zoran; Kuzmanović, Miroslav; Šibalija, Tatjana; Petronić, Sanja

(2024)

TY  - JOUR
AU  - Milovanović, Dubravka
AU  - Rajčić, Boris
AU  - Ranković, Dragan
AU  - Stankov, Biljana
AU  - Čekada, Miha
AU  - Ciganović, Jovan
AU  - Đurđević-Milošević, Dragica
AU  - Stević, Zoran
AU  - Kuzmanović, Miroslav
AU  - Šibalija, Tatjana
AU  - Petronić, Sanja
PY  - 2024
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/12723
AB  - This paper presents a study and comparison of surface effects induced by picosecond and nanosecond laser modification of a Ti6Al4V alloy surface under different ambient conditions: air and argon- and nitrogen-rich atmospheres. Detailed surface characterization was performed for all experimental conditions. Damage threshold fluences for picosecond and nanosecond laser irradiation in all three ambient conditions were determined. The observed surface features were a resolidified pool of molten material, craters, hydrodynamic effects and parallel periodic surface structures. Laser-induced periodic surface structures are formed by multi-mode-beam nanosecond laser action and picosecond laser action. Crown-like structures at crater rims are specific features for picosecond Nd:YAG laser action in argon-rich ambient conditions. Elemental analysis of the surfaces indicated nitride compound formation only in the nitrogen-rich ambient conditions. The constituents of the formed plasma were also investigated. Exploring the impact of process control parameters on output responses has been undertaken within the context of laser modification under different environmental conditions. Parametric optimization of the nanosecond laser modification was carried out by implementing an advanced method based on Taguchi’s parametric design and multivariate statistical techniques, and optimal settings are proposed for each atmosphere.
T2  - Micromachines
T1  - Microstructure Formations Resulting from Nanosecond and Picosecond Laser Irradiation of a Ti-Based Alloy under Controlled Atmospheric Conditions and Optimization of the Irradiation Process
VL  - 15
IS  - 1
SP  - 5
DO  - 10.3390/mi15010005
ER  - 
@article{
author = "Milovanović, Dubravka and Rajčić, Boris and Ranković, Dragan and Stankov, Biljana and Čekada, Miha and Ciganović, Jovan and Đurđević-Milošević, Dragica and Stević, Zoran and Kuzmanović, Miroslav and Šibalija, Tatjana and Petronić, Sanja",
year = "2024",
abstract = "This paper presents a study and comparison of surface effects induced by picosecond and nanosecond laser modification of a Ti6Al4V alloy surface under different ambient conditions: air and argon- and nitrogen-rich atmospheres. Detailed surface characterization was performed for all experimental conditions. Damage threshold fluences for picosecond and nanosecond laser irradiation in all three ambient conditions were determined. The observed surface features were a resolidified pool of molten material, craters, hydrodynamic effects and parallel periodic surface structures. Laser-induced periodic surface structures are formed by multi-mode-beam nanosecond laser action and picosecond laser action. Crown-like structures at crater rims are specific features for picosecond Nd:YAG laser action in argon-rich ambient conditions. Elemental analysis of the surfaces indicated nitride compound formation only in the nitrogen-rich ambient conditions. The constituents of the formed plasma were also investigated. Exploring the impact of process control parameters on output responses has been undertaken within the context of laser modification under different environmental conditions. Parametric optimization of the nanosecond laser modification was carried out by implementing an advanced method based on Taguchi’s parametric design and multivariate statistical techniques, and optimal settings are proposed for each atmosphere.",
journal = "Micromachines",
title = "Microstructure Formations Resulting from Nanosecond and Picosecond Laser Irradiation of a Ti-Based Alloy under Controlled Atmospheric Conditions and Optimization of the Irradiation Process",
volume = "15",
number = "1",
pages = "5",
doi = "10.3390/mi15010005"
}
Milovanović, D., Rajčić, B., Ranković, D., Stankov, B., Čekada, M., Ciganović, J., Đurđević-Milošević, D., Stević, Z., Kuzmanović, M., Šibalija, T.,& Petronić, S.. (2024). Microstructure Formations Resulting from Nanosecond and Picosecond Laser Irradiation of a Ti-Based Alloy under Controlled Atmospheric Conditions and Optimization of the Irradiation Process. in Micromachines, 15(1), 5.
https://doi.org/10.3390/mi15010005
Milovanović D, Rajčić B, Ranković D, Stankov B, Čekada M, Ciganović J, Đurđević-Milošević D, Stević Z, Kuzmanović M, Šibalija T, Petronić S. Microstructure Formations Resulting from Nanosecond and Picosecond Laser Irradiation of a Ti-Based Alloy under Controlled Atmospheric Conditions and Optimization of the Irradiation Process. in Micromachines. 2024;15(1):5.
doi:10.3390/mi15010005 .
Milovanović, Dubravka, Rajčić, Boris, Ranković, Dragan, Stankov, Biljana, Čekada, Miha, Ciganović, Jovan, Đurđević-Milošević, Dragica, Stević, Zoran, Kuzmanović, Miroslav, Šibalija, Tatjana, Petronić, Sanja, "Microstructure Formations Resulting from Nanosecond and Picosecond Laser Irradiation of a Ti-Based Alloy under Controlled Atmospheric Conditions and Optimization of the Irradiation Process" in Micromachines, 15, no. 1 (2024):5,
https://doi.org/10.3390/mi15010005 . .

Impact of Microstructural and Surface Modifications on the Ti-45Nb Alloy’s Response to Bio-Environment

Cvijović-Alagić, Ivana; Laketić, Slađana; Momčilović, Miloš; Ciganović, Jovan; Bajat, Jelena; Kojić, Vesna

(2024)

TY  - JOUR
AU  - Cvijović-Alagić, Ivana
AU  - Laketić, Slađana
AU  - Momčilović, Miloš
AU  - Ciganović, Jovan
AU  - Bajat, Jelena
AU  - Kojić, Vesna
PY  - 2024
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/13227
AB  - The Ti-45Nb (mass%) alloy’s corrosive and biocompatible response in simulated physiological conditions was investigated before and after its additional high-pressure torsion (HPT) and laser irradiation processing. The grain size reduction from 2.76 μm to ~ 200 nm and the appearance of laser-induced morphologically altered and highly oxidized surface led to the significant improvement of alloy corrosion resistance and cell–implant interaction. Moreover, an additional increase of the laser pulse energy from 5 to 15 mJ during the alloy irradiation in the air led to an increase in the surface oxygen content from 13.64 to 23.89% accompanied by an increase of excellent cell viability from 127.18 to 134.42%. As a result of the controlled alloy microstructural and surface modifications, the formation of protective bi-modal mixed Ti- and Nb-oxide external scale was enabled. The presence of this surface oxide scale enhanced the alloy’s resistance to corrosion deterioration and simultaneously boosted cell viability and proliferation.
T2  - Acta Metallurgica Sinica (English Letters)
T1  - Impact of Microstructural and Surface Modifications on the Ti-45Nb Alloy’s Response to Bio-Environment
DO  - 10.1007/s40195-024-01705-0
ER  - 
@article{
author = "Cvijović-Alagić, Ivana and Laketić, Slađana and Momčilović, Miloš and Ciganović, Jovan and Bajat, Jelena and Kojić, Vesna",
year = "2024",
abstract = "The Ti-45Nb (mass%) alloy’s corrosive and biocompatible response in simulated physiological conditions was investigated before and after its additional high-pressure torsion (HPT) and laser irradiation processing. The grain size reduction from 2.76 μm to ~ 200 nm and the appearance of laser-induced morphologically altered and highly oxidized surface led to the significant improvement of alloy corrosion resistance and cell–implant interaction. Moreover, an additional increase of the laser pulse energy from 5 to 15 mJ during the alloy irradiation in the air led to an increase in the surface oxygen content from 13.64 to 23.89% accompanied by an increase of excellent cell viability from 127.18 to 134.42%. As a result of the controlled alloy microstructural and surface modifications, the formation of protective bi-modal mixed Ti- and Nb-oxide external scale was enabled. The presence of this surface oxide scale enhanced the alloy’s resistance to corrosion deterioration and simultaneously boosted cell viability and proliferation.",
journal = "Acta Metallurgica Sinica (English Letters)",
title = "Impact of Microstructural and Surface Modifications on the Ti-45Nb Alloy’s Response to Bio-Environment",
doi = "10.1007/s40195-024-01705-0"
}
Cvijović-Alagić, I., Laketić, S., Momčilović, M., Ciganović, J., Bajat, J.,& Kojić, V.. (2024). Impact of Microstructural and Surface Modifications on the Ti-45Nb Alloy’s Response to Bio-Environment. in Acta Metallurgica Sinica (English Letters).
https://doi.org/10.1007/s40195-024-01705-0
Cvijović-Alagić I, Laketić S, Momčilović M, Ciganović J, Bajat J, Kojić V. Impact of Microstructural and Surface Modifications on the Ti-45Nb Alloy’s Response to Bio-Environment. in Acta Metallurgica Sinica (English Letters). 2024;.
doi:10.1007/s40195-024-01705-0 .
Cvijović-Alagić, Ivana, Laketić, Slađana, Momčilović, Miloš, Ciganović, Jovan, Bajat, Jelena, Kojić, Vesna, "Impact of Microstructural and Surface Modifications on the Ti-45Nb Alloy’s Response to Bio-Environment" in Acta Metallurgica Sinica (English Letters) (2024),
https://doi.org/10.1007/s40195-024-01705-0 . .

Mechanical properties and behavior of the Ti–45Nb alloy subjected to extreme conditions

Zagorac, Dejan; Prasad, Dasari; Škundrić, Tamara; Yadav, Kedar; Singh, Surender; Laketić, Slađana; Zagorac, Jelena; Momčilović, Miloš; Cvijović-Alagić, Ivana

(2024)

TY  - JOUR
AU  - Zagorac, Dejan
AU  - Prasad, Dasari
AU  - Škundrić, Tamara
AU  - Yadav, Kedar
AU  - Singh, Surender
AU  - Laketić, Slađana
AU  - Zagorac, Jelena
AU  - Momčilović, Miloš
AU  - Cvijović-Alagić, Ivana
PY  - 2024
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/13300
AB  - Mechanical properties and structure-property relationship of the Ti-45Nb (mass%) alloy with potential applications in biomedicine were investigated using a multidisciplinary approach. Because the biomechanical compatibility of metallic implant materials can be significantly improved by microstructural refinement and laser surface modification (LSM), the present study concentrates on the investigation of the mechanical properties of the Ti-45Nb alloy subjected to extreme processing conditions to evaluate their impact on the alloy improved applicability in the bio-environment. The alloy was therefore subjected to high-pressure torsion (HPT) and LSM processing to obtain favorable alloy characteristics. Crystal structure prediction was conducted using data mining (DM) and evolutionary algorithms (EA). All the obtained potential structure candidates were submitted to the local optimizations at the level of density functional theory (DFT); subsequently, the phonon lattice dynamics and mechanical properties were systematically investigated. The alloy structure progression and mechanical characteristics were examined under the influence of extremely high temperatures induced during the LSM processing and the extreme pressure achieved during the HPT treatment. XRD characterization was performed using experimental and theoretical methods showing the presence of bcc β-Ti and orthorhombic Cmcm Ti4Nb phase. Mechanical properties such as Young's modulus, Vicker's hardness, and plasticity of the most relevant Ti4Nb modifications predicted after DM-EA-DFT were found to corroborate well with the experimental results of nanoindentation measurements. The present study reveals that the additional processing of the Ti-45Nb alloy under extreme conditions leads to significant improvement in the alloy's bio-mechanical compatibility.
T2  - CrystEngComm
T1  - Mechanical properties and behavior of the Ti–45Nb alloy subjected to extreme conditions
VL  - 26
IS  - 22
SP  - 2989
EP  - 3004
DO  - 10.1039/D4CE00076E
ER  - 
@article{
author = "Zagorac, Dejan and Prasad, Dasari and Škundrić, Tamara and Yadav, Kedar and Singh, Surender and Laketić, Slađana and Zagorac, Jelena and Momčilović, Miloš and Cvijović-Alagić, Ivana",
year = "2024",
abstract = "Mechanical properties and structure-property relationship of the Ti-45Nb (mass%) alloy with potential applications in biomedicine were investigated using a multidisciplinary approach. Because the biomechanical compatibility of metallic implant materials can be significantly improved by microstructural refinement and laser surface modification (LSM), the present study concentrates on the investigation of the mechanical properties of the Ti-45Nb alloy subjected to extreme processing conditions to evaluate their impact on the alloy improved applicability in the bio-environment. The alloy was therefore subjected to high-pressure torsion (HPT) and LSM processing to obtain favorable alloy characteristics. Crystal structure prediction was conducted using data mining (DM) and evolutionary algorithms (EA). All the obtained potential structure candidates were submitted to the local optimizations at the level of density functional theory (DFT); subsequently, the phonon lattice dynamics and mechanical properties were systematically investigated. The alloy structure progression and mechanical characteristics were examined under the influence of extremely high temperatures induced during the LSM processing and the extreme pressure achieved during the HPT treatment. XRD characterization was performed using experimental and theoretical methods showing the presence of bcc β-Ti and orthorhombic Cmcm Ti4Nb phase. Mechanical properties such as Young's modulus, Vicker's hardness, and plasticity of the most relevant Ti4Nb modifications predicted after DM-EA-DFT were found to corroborate well with the experimental results of nanoindentation measurements. The present study reveals that the additional processing of the Ti-45Nb alloy under extreme conditions leads to significant improvement in the alloy's bio-mechanical compatibility.",
journal = "CrystEngComm",
title = "Mechanical properties and behavior of the Ti–45Nb alloy subjected to extreme conditions",
volume = "26",
number = "22",
pages = "2989-3004",
doi = "10.1039/D4CE00076E"
}
Zagorac, D., Prasad, D., Škundrić, T., Yadav, K., Singh, S., Laketić, S., Zagorac, J., Momčilović, M.,& Cvijović-Alagić, I.. (2024). Mechanical properties and behavior of the Ti–45Nb alloy subjected to extreme conditions. in CrystEngComm, 26(22), 2989-3004.
https://doi.org/10.1039/D4CE00076E
Zagorac D, Prasad D, Škundrić T, Yadav K, Singh S, Laketić S, Zagorac J, Momčilović M, Cvijović-Alagić I. Mechanical properties and behavior of the Ti–45Nb alloy subjected to extreme conditions. in CrystEngComm. 2024;26(22):2989-3004.
doi:10.1039/D4CE00076E .
Zagorac, Dejan, Prasad, Dasari, Škundrić, Tamara, Yadav, Kedar, Singh, Surender, Laketić, Slađana, Zagorac, Jelena, Momčilović, Miloš, Cvijović-Alagić, Ivana, "Mechanical properties and behavior of the Ti–45Nb alloy subjected to extreme conditions" in CrystEngComm, 26, no. 22 (2024):2989-3004,
https://doi.org/10.1039/D4CE00076E . .
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