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Photoinduced reactive species in interfacial charge transfer complex between TiO2 and taxifolin: DFT and EPR study

Nikšić, Valentina; Malček Šimunková, Miriama; Dyrčíková, Zuzana; Dvoranová, Dana; Brezová, Vlasta; Sredojević, Dušan; Nedeljković, Jovan; Lazić, Vesna

(2024)

TY  - JOUR
AU  - Nikšić, Valentina
AU  - Malček Šimunková, Miriama
AU  - Dyrčíková, Zuzana
AU  - Dvoranová, Dana
AU  - Brezová, Vlasta
AU  - Sredojević, Dušan
AU  - Nedeljković, Jovan
AU  - Lazić, Vesna
PY  - 2024
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/13228
AB  - The TiO2-based interfacial charge transfer (ICT) complex with taxifolin (dihydroquercetin), a polyphenol with pronounced antioxidant ability, displays light absorption in the visible spectral range. The extent of the red absorption shift, obtained using the density functional theory (DFT) calculations on a cluster model that mimics the ICT complex, is in excellent agreement with spectroscopic measurements. The reactive paramagnetic species generated in the dispersed pristine and surface-modified TiO2 powders with taxifolin upon excitation with ultraviolet and visible light were identified by indirect electron paramagnetic resonance (EPR) spectroscopy techniques. The spin trapping and spin scavenging revealed the differences between the behavior of the pristine and surface-modified TiO2 powders with taxifolin before and upon excitation. On one side, the TiO2-based ICT complex with taxifolin efficiently scavenges reactive oxygen species by the taxifolin’s hydroxyl groups and, on the other side, the promotion of electrons from the ground state of taxifolin to the conduction band of TiO2 takes place under visible light excitation.
T2  - Optical Materials
T1  - Photoinduced reactive species in interfacial charge transfer complex between TiO2 and taxifolin: DFT and EPR study
VL  - 152
SP  - 115454
DO  - 10.1016/j.optmat.2024.115454
ER  - 
@article{
author = "Nikšić, Valentina and Malček Šimunková, Miriama and Dyrčíková, Zuzana and Dvoranová, Dana and Brezová, Vlasta and Sredojević, Dušan and Nedeljković, Jovan and Lazić, Vesna",
year = "2024",
abstract = "The TiO2-based interfacial charge transfer (ICT) complex with taxifolin (dihydroquercetin), a polyphenol with pronounced antioxidant ability, displays light absorption in the visible spectral range. The extent of the red absorption shift, obtained using the density functional theory (DFT) calculations on a cluster model that mimics the ICT complex, is in excellent agreement with spectroscopic measurements. The reactive paramagnetic species generated in the dispersed pristine and surface-modified TiO2 powders with taxifolin upon excitation with ultraviolet and visible light were identified by indirect electron paramagnetic resonance (EPR) spectroscopy techniques. The spin trapping and spin scavenging revealed the differences between the behavior of the pristine and surface-modified TiO2 powders with taxifolin before and upon excitation. On one side, the TiO2-based ICT complex with taxifolin efficiently scavenges reactive oxygen species by the taxifolin’s hydroxyl groups and, on the other side, the promotion of electrons from the ground state of taxifolin to the conduction band of TiO2 takes place under visible light excitation.",
journal = "Optical Materials",
title = "Photoinduced reactive species in interfacial charge transfer complex between TiO2 and taxifolin: DFT and EPR study",
volume = "152",
pages = "115454",
doi = "10.1016/j.optmat.2024.115454"
}
Nikšić, V., Malček Šimunková, M., Dyrčíková, Z., Dvoranová, D., Brezová, V., Sredojević, D., Nedeljković, J.,& Lazić, V.. (2024). Photoinduced reactive species in interfacial charge transfer complex between TiO2 and taxifolin: DFT and EPR study. in Optical Materials, 152, 115454.
https://doi.org/10.1016/j.optmat.2024.115454
Nikšić V, Malček Šimunková M, Dyrčíková Z, Dvoranová D, Brezová V, Sredojević D, Nedeljković J, Lazić V. Photoinduced reactive species in interfacial charge transfer complex between TiO2 and taxifolin: DFT and EPR study. in Optical Materials. 2024;152:115454.
doi:10.1016/j.optmat.2024.115454 .
Nikšić, Valentina, Malček Šimunková, Miriama, Dyrčíková, Zuzana, Dvoranová, Dana, Brezová, Vlasta, Sredojević, Dušan, Nedeljković, Jovan, Lazić, Vesna, "Photoinduced reactive species in interfacial charge transfer complex between TiO2 and taxifolin: DFT and EPR study" in Optical Materials, 152 (2024):115454,
https://doi.org/10.1016/j.optmat.2024.115454 . .

Comparable Toxicity of Surface-Modified TiO2 Nanoparticles: An In Vivo Experimental Study on Reproductive Toxicity in Rats

Todorović, Ana; Bobić, Katarina; Veljković, Filip; Pejić, Snežana; Glumac, Sofija; Stanković, Sanja; Milovanović, Tijana; Vukoje, Ivana; Nedeljković, Jovan; Radojević Škodrić, Sanja; Pajović, Snežana B.; Drakulić, Dunja

(2024)

TY  - JOUR
AU  - Todorović, Ana
AU  - Bobić, Katarina
AU  - Veljković, Filip
AU  - Pejić, Snežana
AU  - Glumac, Sofija
AU  - Stanković, Sanja
AU  - Milovanović, Tijana
AU  - Vukoje, Ivana
AU  - Nedeljković, Jovan
AU  - Radojević Škodrić, Sanja
AU  - Pajović, Snežana B.
AU  - Drakulić, Dunja
PY  - 2024
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/13090
AB  - Nanoparticles (NPs), a distinct class of particles ranging in size from 1 to 100 nm, are one of the most promising technologies of the 21st century, and titanium dioxide NPs (TiO2 NPs) are among the most widely produced and used NPs globally. The increased application of TiO2 NPs raises concerns regarding their global safety and risks of exposure. Many animal studies have reported the accumulation of TiO2 NPs in female reproductive organs; however, evidence of the resultant toxicity remains ambiguous. Since the surface area and chemical modifications of NPs can significantly change their cytotoxicity, we aimed to compare the toxic effects of pristine TiO2 powder with surface-modified TiO2 powders with salicylic acid (TiO2/SA) and 5-aminosalicylic acid (TiO2/5-ASA) on the ovaries, oviducts, and uterus on the 14th day following acute oral treatment. The results, based on alterations in food and water intake, body mass, organ-to-body mass ratio, hormonal status, histological features of tissues of interest, and antioxidant parameters, suggest that the modification with 5-ASA can mitigate some of the observed toxic effects of TiO2 powder and encourage future investigations to create NPs that can potentially reduce the harmful effects of TiO2 NPs while preserving their positive impacts.
T2  - Antioxidants
T1  - Comparable Toxicity of Surface-Modified TiO2 Nanoparticles: An In Vivo Experimental Study on Reproductive Toxicity in Rats
VL  - 13
IS  - 2
SP  - 231
DO  - 10.3390/antiox13020231
ER  - 
@article{
author = "Todorović, Ana and Bobić, Katarina and Veljković, Filip and Pejić, Snežana and Glumac, Sofija and Stanković, Sanja and Milovanović, Tijana and Vukoje, Ivana and Nedeljković, Jovan and Radojević Škodrić, Sanja and Pajović, Snežana B. and Drakulić, Dunja",
year = "2024",
abstract = "Nanoparticles (NPs), a distinct class of particles ranging in size from 1 to 100 nm, are one of the most promising technologies of the 21st century, and titanium dioxide NPs (TiO2 NPs) are among the most widely produced and used NPs globally. The increased application of TiO2 NPs raises concerns regarding their global safety and risks of exposure. Many animal studies have reported the accumulation of TiO2 NPs in female reproductive organs; however, evidence of the resultant toxicity remains ambiguous. Since the surface area and chemical modifications of NPs can significantly change their cytotoxicity, we aimed to compare the toxic effects of pristine TiO2 powder with surface-modified TiO2 powders with salicylic acid (TiO2/SA) and 5-aminosalicylic acid (TiO2/5-ASA) on the ovaries, oviducts, and uterus on the 14th day following acute oral treatment. The results, based on alterations in food and water intake, body mass, organ-to-body mass ratio, hormonal status, histological features of tissues of interest, and antioxidant parameters, suggest that the modification with 5-ASA can mitigate some of the observed toxic effects of TiO2 powder and encourage future investigations to create NPs that can potentially reduce the harmful effects of TiO2 NPs while preserving their positive impacts.",
journal = "Antioxidants",
title = "Comparable Toxicity of Surface-Modified TiO2 Nanoparticles: An In Vivo Experimental Study on Reproductive Toxicity in Rats",
volume = "13",
number = "2",
pages = "231",
doi = "10.3390/antiox13020231"
}
Todorović, A., Bobić, K., Veljković, F., Pejić, S., Glumac, S., Stanković, S., Milovanović, T., Vukoje, I., Nedeljković, J., Radojević Škodrić, S., Pajović, S. B.,& Drakulić, D.. (2024). Comparable Toxicity of Surface-Modified TiO2 Nanoparticles: An In Vivo Experimental Study on Reproductive Toxicity in Rats. in Antioxidants, 13(2), 231.
https://doi.org/10.3390/antiox13020231
Todorović A, Bobić K, Veljković F, Pejić S, Glumac S, Stanković S, Milovanović T, Vukoje I, Nedeljković J, Radojević Škodrić S, Pajović SB, Drakulić D. Comparable Toxicity of Surface-Modified TiO2 Nanoparticles: An In Vivo Experimental Study on Reproductive Toxicity in Rats. in Antioxidants. 2024;13(2):231.
doi:10.3390/antiox13020231 .
Todorović, Ana, Bobić, Katarina, Veljković, Filip, Pejić, Snežana, Glumac, Sofija, Stanković, Sanja, Milovanović, Tijana, Vukoje, Ivana, Nedeljković, Jovan, Radojević Škodrić, Sanja, Pajović, Snežana B., Drakulić, Dunja, "Comparable Toxicity of Surface-Modified TiO2 Nanoparticles: An In Vivo Experimental Study on Reproductive Toxicity in Rats" in Antioxidants, 13, no. 2 (2024):231,
https://doi.org/10.3390/antiox13020231 . .
1

Mechanical alloying as a crucial step in the fabrication process of Cu alloys

Simić, Marko; Ružić, Jovana; Božić, Dušan; Radovanović, Željko; Stašić, Jelena

(Belgrade : Vinča Institute of Nuclear Sciences - National Institute of thе Republic of Serbia, University of Belgrade, 2024)

TY  - CONF
AU  - Simić, Marko
AU  - Ružić, Jovana
AU  - Božić, Dušan
AU  - Radovanović, Željko
AU  - Stašić, Jelena
PY  - 2024
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/13161
PB  - Belgrade : Vinča Institute of Nuclear Sciences - National Institute of thе Republic of Serbia, University of Belgrade
PB  - Belgrade : Serbian Society for Innovative Materials in Extreme Conditions (SIM-EXTREME)
C3  - IMEC2024 - 2nd International Conference on Innovative Materials in Extreme Conditions : Book of abstracts
T1  - Mechanical alloying as a crucial step in the fabrication process of Cu alloys
SP  - 65
EP  - 65
UR  - https://hdl.handle.net/21.15107/rcub_vinar_13161
ER  - 
@conference{
author = "Simić, Marko and Ružić, Jovana and Božić, Dušan and Radovanović, Željko and Stašić, Jelena",
year = "2024",
publisher = "Belgrade : Vinča Institute of Nuclear Sciences - National Institute of thе Republic of Serbia, University of Belgrade, Belgrade : Serbian Society for Innovative Materials in Extreme Conditions (SIM-EXTREME)",
journal = "IMEC2024 - 2nd International Conference on Innovative Materials in Extreme Conditions : Book of abstracts",
title = "Mechanical alloying as a crucial step in the fabrication process of Cu alloys",
pages = "65-65",
url = "https://hdl.handle.net/21.15107/rcub_vinar_13161"
}
Simić, M., Ružić, J., Božić, D., Radovanović, Ž.,& Stašić, J.. (2024). Mechanical alloying as a crucial step in the fabrication process of Cu alloys. in IMEC2024 - 2nd International Conference on Innovative Materials in Extreme Conditions : Book of abstracts
Belgrade : Vinča Institute of Nuclear Sciences - National Institute of thе Republic of Serbia, University of Belgrade., 65-65.
https://hdl.handle.net/21.15107/rcub_vinar_13161
Simić M, Ružić J, Božić D, Radovanović Ž, Stašić J. Mechanical alloying as a crucial step in the fabrication process of Cu alloys. in IMEC2024 - 2nd International Conference on Innovative Materials in Extreme Conditions : Book of abstracts. 2024;:65-65.
https://hdl.handle.net/21.15107/rcub_vinar_13161 .
Simić, Marko, Ružić, Jovana, Božić, Dušan, Radovanović, Željko, Stašić, Jelena, "Mechanical alloying as a crucial step in the fabrication process of Cu alloys" in IMEC2024 - 2nd International Conference on Innovative Materials in Extreme Conditions : Book of abstracts (2024):65-65,
https://hdl.handle.net/21.15107/rcub_vinar_13161 .

On the driving forces behind the change of reduction potentials and the prediction of redox properties through analysis of EPR hyperfine couplings in VO(acac)2pyr and VO(acac)2 imidazole complexes. A DFT study

Vranješ-Đurić, Sanja; Milanović, Zorana; Mirković, M.; Radović, M.; Perić, M.

(2024)

TY  - JOUR
AU  - Vranješ-Đurić, Sanja
AU  - Milanović, Zorana
AU  - Mirković, M.
AU  - Radović, M.
AU  - Perić, M.
PY  - 2024
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/13264
AB  - The use of vanadium complexes for potential applications in medicine largely depends on the structural properties of the complex itself, as well as on the electronic configuration of the metal and its oxidation state. When the vanadium complex binds to biomolecules or by binding solvent molecules to the complex, there is a change in the structure but also a change in the redox properties of the complex. Using theoretical methods, especially Density Functional theory (DFT), it is possible to determine which factors influence changes in the redox properties of the complex. Furthermore, by calculating the Electron Paramagnetic Resonance (EPR) constants of hyperfine coupling, it is possible to obtain not only data on the electronic configuration, but also to predict changes in redox properties upon changes in the structure of the complex. DFT results show that the binding of pyridine or imidazole to the VO(acac)2 complex leads to a lowering of the redox potential. The largest changes in the redox potential were observed in the case when the incoming ligand binds in a cis position relative to the V==O bond.
T2  - Polyhedron
T1  - On the driving forces behind the change of reduction potentials and the prediction of redox properties through analysis of EPR hyperfine couplings in VO(acac)2pyr and VO(acac)2 imidazole complexes. A DFT study
IS  - InPress
SP  - 117049
DO  - 10.1016/j.poly.2024.117049
ER  - 
@article{
author = "Vranješ-Đurić, Sanja and Milanović, Zorana and Mirković, M. and Radović, M. and Perić, M.",
year = "2024",
abstract = "The use of vanadium complexes for potential applications in medicine largely depends on the structural properties of the complex itself, as well as on the electronic configuration of the metal and its oxidation state. When the vanadium complex binds to biomolecules or by binding solvent molecules to the complex, there is a change in the structure but also a change in the redox properties of the complex. Using theoretical methods, especially Density Functional theory (DFT), it is possible to determine which factors influence changes in the redox properties of the complex. Furthermore, by calculating the Electron Paramagnetic Resonance (EPR) constants of hyperfine coupling, it is possible to obtain not only data on the electronic configuration, but also to predict changes in redox properties upon changes in the structure of the complex. DFT results show that the binding of pyridine or imidazole to the VO(acac)2 complex leads to a lowering of the redox potential. The largest changes in the redox potential were observed in the case when the incoming ligand binds in a cis position relative to the V==O bond.",
journal = "Polyhedron",
title = "On the driving forces behind the change of reduction potentials and the prediction of redox properties through analysis of EPR hyperfine couplings in VO(acac)2pyr and VO(acac)2 imidazole complexes. A DFT study",
number = "InPress",
pages = "117049",
doi = "10.1016/j.poly.2024.117049"
}
Vranješ-Đurić, S., Milanović, Z., Mirković, M., Radović, M.,& Perić, M.. (2024). On the driving forces behind the change of reduction potentials and the prediction of redox properties through analysis of EPR hyperfine couplings in VO(acac)2pyr and VO(acac)2 imidazole complexes. A DFT study. in Polyhedron(InPress), 117049.
https://doi.org/10.1016/j.poly.2024.117049
Vranješ-Đurić S, Milanović Z, Mirković M, Radović M, Perić M. On the driving forces behind the change of reduction potentials and the prediction of redox properties through analysis of EPR hyperfine couplings in VO(acac)2pyr and VO(acac)2 imidazole complexes. A DFT study. in Polyhedron. 2024;(InPress):117049.
doi:10.1016/j.poly.2024.117049 .
Vranješ-Đurić, Sanja, Milanović, Zorana, Mirković, M., Radović, M., Perić, M., "On the driving forces behind the change of reduction potentials and the prediction of redox properties through analysis of EPR hyperfine couplings in VO(acac)2pyr and VO(acac)2 imidazole complexes. A DFT study" in Polyhedron, no. InPress (2024):117049,
https://doi.org/10.1016/j.poly.2024.117049 . .

Melatonin and its physiological and therapeutic effects: A review

Stefanović, Bojana; Spasojević, Nataša; Ferizović, Harisa; Janković, Milica; Virijević, Kristina; Dronjak, Slađana

(2024)

TY  - JOUR
AU  - Stefanović, Bojana
AU  - Spasojević, Nataša
AU  - Ferizović, Harisa
AU  - Janković, Milica
AU  - Virijević, Kristina
AU  - Dronjak, Slađana
PY  - 2024
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/13263
AB  - Melatonin, an evolutionarily old molecule, is found in many living organisms. This neurohormone is known to control many physiological processes, including circadian rhythm, mood, and behavior. Melatonin was discovered to be a direct free radical scavenger. By activating its receptors, it stimulates a wide range of signaling pathways. It has been proven that melatonin exerts neuroprotective and antidepressant-like effects. Also, many researchers have found that melatonin plays an important role in various cardiovascular diseases. In the near future, melatonin will be a promising agent to control the fate of mesenchymal stem cells by regulating the generation of reactive oxygen species and the release of immune factors in regenerative medicine. Collectively, the studies link melatonin to a variety of outcomes and have a strong regulatory impact on numerous physiological processes in the body.
T2  - Kragujevac Journal of Science
T1  - Melatonin and its physiological and therapeutic effects: A review
IS  - InPress
DO  - 10.5937/KgJSci2400004S
ER  - 
@article{
author = "Stefanović, Bojana and Spasojević, Nataša and Ferizović, Harisa and Janković, Milica and Virijević, Kristina and Dronjak, Slađana",
year = "2024",
abstract = "Melatonin, an evolutionarily old molecule, is found in many living organisms. This neurohormone is known to control many physiological processes, including circadian rhythm, mood, and behavior. Melatonin was discovered to be a direct free radical scavenger. By activating its receptors, it stimulates a wide range of signaling pathways. It has been proven that melatonin exerts neuroprotective and antidepressant-like effects. Also, many researchers have found that melatonin plays an important role in various cardiovascular diseases. In the near future, melatonin will be a promising agent to control the fate of mesenchymal stem cells by regulating the generation of reactive oxygen species and the release of immune factors in regenerative medicine. Collectively, the studies link melatonin to a variety of outcomes and have a strong regulatory impact on numerous physiological processes in the body.",
journal = "Kragujevac Journal of Science",
title = "Melatonin and its physiological and therapeutic effects: A review",
number = "InPress",
doi = "10.5937/KgJSci2400004S"
}
Stefanović, B., Spasojević, N., Ferizović, H., Janković, M., Virijević, K.,& Dronjak, S.. (2024). Melatonin and its physiological and therapeutic effects: A review. in Kragujevac Journal of Science(InPress).
https://doi.org/10.5937/KgJSci2400004S
Stefanović B, Spasojević N, Ferizović H, Janković M, Virijević K, Dronjak S. Melatonin and its physiological and therapeutic effects: A review. in Kragujevac Journal of Science. 2024;(InPress).
doi:10.5937/KgJSci2400004S .
Stefanović, Bojana, Spasojević, Nataša, Ferizović, Harisa, Janković, Milica, Virijević, Kristina, Dronjak, Slađana, "Melatonin and its physiological and therapeutic effects: A review" in Kragujevac Journal of Science, no. InPress (2024),
https://doi.org/10.5937/KgJSci2400004S . .

Synthesis, characterization, and antimicrobial activity of novel ferrocene-containing 1-(thio)acetyl pyrazolines

Todosijević, Anka; Bugarinović, Jovana; Pešić, Marko; Stevanović, Dragana; Damljanović, Ivan; Mihailović, Vladimir; Srećković, Nikola; Novaković, Slađana B.; Bogdanović, Goran A.

(2024)

TY  - JOUR
AU  - Todosijević, Anka
AU  - Bugarinović, Jovana
AU  - Pešić, Marko
AU  - Stevanović, Dragana
AU  - Damljanović, Ivan
AU  - Mihailović, Vladimir
AU  - Srećković, Nikola
AU  - Novaković, Slađana B.
AU  - Bogdanović, Goran A.
PY  - 2024
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/13262
AB  - The pyrazoline pharmacophore is the source of numerous biological activities. The synthesis and biological evaluation of new pyrazoline heterocycles is the first step in the development of new potential drugs. Therefore, ferrocene-containing 1-(thio)acetyl pyrazolines were synthesized to test their in vitro antimicrobial activity. All new heterocycles were characterized by standard spectroscopy methods due to confirmation of the structures. In addition, single-crystal X-ray analyses were performed for three representative pyrazole derivatives. Their electrochemical properties were investigated by cyclic voltammetry indicating a reversible one-electron redox couple originating from the ferrocene/ferrocenium pair. All obtained products were evaluated for their antibacterial and antifungal activity. It has been shown that pyrazolines have slightly better antifungal activity compared with their antibacterial activity.
T2  - Polyhedron
T1  - Synthesis, characterization, and antimicrobial activity of novel ferrocene-containing 1-(thio)acetyl pyrazolines
VL  - 258
SP  - 117028
DO  - 10.1016/j.poly.2024.117028
ER  - 
@article{
author = "Todosijević, Anka and Bugarinović, Jovana and Pešić, Marko and Stevanović, Dragana and Damljanović, Ivan and Mihailović, Vladimir and Srećković, Nikola and Novaković, Slađana B. and Bogdanović, Goran A.",
year = "2024",
abstract = "The pyrazoline pharmacophore is the source of numerous biological activities. The synthesis and biological evaluation of new pyrazoline heterocycles is the first step in the development of new potential drugs. Therefore, ferrocene-containing 1-(thio)acetyl pyrazolines were synthesized to test their in vitro antimicrobial activity. All new heterocycles were characterized by standard spectroscopy methods due to confirmation of the structures. In addition, single-crystal X-ray analyses were performed for three representative pyrazole derivatives. Their electrochemical properties were investigated by cyclic voltammetry indicating a reversible one-electron redox couple originating from the ferrocene/ferrocenium pair. All obtained products were evaluated for their antibacterial and antifungal activity. It has been shown that pyrazolines have slightly better antifungal activity compared with their antibacterial activity.",
journal = "Polyhedron",
title = "Synthesis, characterization, and antimicrobial activity of novel ferrocene-containing 1-(thio)acetyl pyrazolines",
volume = "258",
pages = "117028",
doi = "10.1016/j.poly.2024.117028"
}
Todosijević, A., Bugarinović, J., Pešić, M., Stevanović, D., Damljanović, I., Mihailović, V., Srećković, N., Novaković, S. B.,& Bogdanović, G. A.. (2024). Synthesis, characterization, and antimicrobial activity of novel ferrocene-containing 1-(thio)acetyl pyrazolines. in Polyhedron, 258, 117028.
https://doi.org/10.1016/j.poly.2024.117028
Todosijević A, Bugarinović J, Pešić M, Stevanović D, Damljanović I, Mihailović V, Srećković N, Novaković SB, Bogdanović GA. Synthesis, characterization, and antimicrobial activity of novel ferrocene-containing 1-(thio)acetyl pyrazolines. in Polyhedron. 2024;258:117028.
doi:10.1016/j.poly.2024.117028 .
Todosijević, Anka, Bugarinović, Jovana, Pešić, Marko, Stevanović, Dragana, Damljanović, Ivan, Mihailović, Vladimir, Srećković, Nikola, Novaković, Slađana B., Bogdanović, Goran A., "Synthesis, characterization, and antimicrobial activity of novel ferrocene-containing 1-(thio)acetyl pyrazolines" in Polyhedron, 258 (2024):117028,
https://doi.org/10.1016/j.poly.2024.117028 . .

Ketamine’s Amelioration of Fear Extinction in Adolescent Male Mice Is Associated with the Activation of the Hippocampal Akt-mTOR-GluA1 Pathway

Glavonić, Emilija; Dragić, Milorad; Mitić, Miloš; Aleksić, Minja; Lukić, Iva; Ivković, Sanja; Adžić, Miroslav

(2024)

TY  - JOUR
AU  - Glavonić, Emilija
AU  - Dragić, Milorad
AU  - Mitić, Miloš
AU  - Aleksić, Minja
AU  - Lukić, Iva
AU  - Ivković, Sanja
AU  - Adžić, Miroslav
PY  - 2024
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/13259
AB  - Fear-related disorders, including post-traumatic stress disorder (PTSD), and anxiety disorders are pervasive psychiatric conditions marked by persistent fear, stemming from its dysregulated acquisition and extinction. The primary treatment for these disorders, exposure therapy (ET), relies heavily on fear extinction (FE) principles. Adolescence, a vulnerable period for developing psychiatric disorders, is characterized by neurobiological changes in the fear circuitry, leading to impaired FE and increased susceptibility to relapse following ET. Ketamine, known for relieving anxiety and reducing PTSD symptoms, influences fear-related learning processes and synaptic plasticity across the fear circuitry. Our study aimed to investigate the effects of ketamine (10 mg/kg) on FE in adolescent male C57 BL/6 mice at the behavioral and molecular levels. We analyzed the protein and gene expression of synaptic plasticity markers in the hippocampus (HPC) and prefrontal cortex (PFC) and sought to identify neural correlates associated with ketamine’s effects on adolescent extinction learning. Ketamine ameliorated FE in the adolescent males, likely affecting the consolidation and/or recall of extinction memory. Ketamine also increased the Akt and mTOR activity and the GluA1 and GluN2A levels in the HPC and upregulated BDNF exon IV mRNA expression in the HPC and PFC of the fear-extinguished mice. Furthermore, ketamine increased the c-Fos expression in specific brain regions, including the ventral HPC (vHPC) and the left infralimbic ventromedial PFC (IL vmPFC). Providing a comprehensive exploration of ketamine’s mechanisms in adolescent FE, our study suggests that ketamine’s effects on FE in adolescent males are associated with the activation of hippocampal Akt-mTOR-GluA1 signaling, with the vHPC and the left IL vmPFC as the proposed neural correlates.
T2  - Pharmaceuticals
T1  - Ketamine’s Amelioration of Fear Extinction in Adolescent Male Mice Is Associated with the Activation of the Hippocampal Akt-mTOR-GluA1 Pathway
VL  - 17
IS  - 6
SP  - 669
DO  - 10.3390/ph17060669
ER  - 
@article{
author = "Glavonić, Emilija and Dragić, Milorad and Mitić, Miloš and Aleksić, Minja and Lukić, Iva and Ivković, Sanja and Adžić, Miroslav",
year = "2024",
abstract = "Fear-related disorders, including post-traumatic stress disorder (PTSD), and anxiety disorders are pervasive psychiatric conditions marked by persistent fear, stemming from its dysregulated acquisition and extinction. The primary treatment for these disorders, exposure therapy (ET), relies heavily on fear extinction (FE) principles. Adolescence, a vulnerable period for developing psychiatric disorders, is characterized by neurobiological changes in the fear circuitry, leading to impaired FE and increased susceptibility to relapse following ET. Ketamine, known for relieving anxiety and reducing PTSD symptoms, influences fear-related learning processes and synaptic plasticity across the fear circuitry. Our study aimed to investigate the effects of ketamine (10 mg/kg) on FE in adolescent male C57 BL/6 mice at the behavioral and molecular levels. We analyzed the protein and gene expression of synaptic plasticity markers in the hippocampus (HPC) and prefrontal cortex (PFC) and sought to identify neural correlates associated with ketamine’s effects on adolescent extinction learning. Ketamine ameliorated FE in the adolescent males, likely affecting the consolidation and/or recall of extinction memory. Ketamine also increased the Akt and mTOR activity and the GluA1 and GluN2A levels in the HPC and upregulated BDNF exon IV mRNA expression in the HPC and PFC of the fear-extinguished mice. Furthermore, ketamine increased the c-Fos expression in specific brain regions, including the ventral HPC (vHPC) and the left infralimbic ventromedial PFC (IL vmPFC). Providing a comprehensive exploration of ketamine’s mechanisms in adolescent FE, our study suggests that ketamine’s effects on FE in adolescent males are associated with the activation of hippocampal Akt-mTOR-GluA1 signaling, with the vHPC and the left IL vmPFC as the proposed neural correlates.",
journal = "Pharmaceuticals",
title = "Ketamine’s Amelioration of Fear Extinction in Adolescent Male Mice Is Associated with the Activation of the Hippocampal Akt-mTOR-GluA1 Pathway",
volume = "17",
number = "6",
pages = "669",
doi = "10.3390/ph17060669"
}
Glavonić, E., Dragić, M., Mitić, M., Aleksić, M., Lukić, I., Ivković, S.,& Adžić, M.. (2024). Ketamine’s Amelioration of Fear Extinction in Adolescent Male Mice Is Associated with the Activation of the Hippocampal Akt-mTOR-GluA1 Pathway. in Pharmaceuticals, 17(6), 669.
https://doi.org/10.3390/ph17060669
Glavonić E, Dragić M, Mitić M, Aleksić M, Lukić I, Ivković S, Adžić M. Ketamine’s Amelioration of Fear Extinction in Adolescent Male Mice Is Associated with the Activation of the Hippocampal Akt-mTOR-GluA1 Pathway. in Pharmaceuticals. 2024;17(6):669.
doi:10.3390/ph17060669 .
Glavonić, Emilija, Dragić, Milorad, Mitić, Miloš, Aleksić, Minja, Lukić, Iva, Ivković, Sanja, Adžić, Miroslav, "Ketamine’s Amelioration of Fear Extinction in Adolescent Male Mice Is Associated with the Activation of the Hippocampal Akt-mTOR-GluA1 Pathway" in Pharmaceuticals, 17, no. 6 (2024):669,
https://doi.org/10.3390/ph17060669 . .

Remote optical thermometry by two-dimensional LiAl5O8:Cr3+ luminescence sensor probe

Ćirić, Aleksandar; Maričić, Milica; Ristić, Zoran; Gavrilović, Tamara; Medić, Mina; Dramićanin, Miroslav

(2024)

TY  - JOUR
AU  - Ćirić, Aleksandar
AU  - Maričić, Milica
AU  - Ristić, Zoran
AU  - Gavrilović, Tamara
AU  - Medić, Mina
AU  - Dramićanin, Miroslav
PY  - 2024
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/13260
AB  - Pure-phase LiAl5O8:Cr3+ leaf-like particles were synthesized by combustion synthetic route at various concentrations. Both sharp peaks and broad emission photoluminescence are apparent even at room temperature. The most optimum doping concentration of 0.75 % based on lifetime and emission intensity was chosen. Peaks of different configurations were separated by deconvolution from 120 K to 680 K, where 4T2 peak increases in temperature to the expense of the sharp 2E emissions, giving luminescence intensity ratio (LIR) relative sensitivity of 2.8 % K−1 at room temperature. Large separation between Cr3+ R lines marks their LIR as perspective at low temperatures. At high temperatures luminescence lifetime provided for 0.8 % K−1 sensitivity, while line-shift and bandwidth methods are not sensitive enough for thermometric applications. Deconvolution of peaks enabled for 10 % more precise estimation of Debye temperature (679 K).
T2  - Current Applied Physics
T1  - Remote optical thermometry by two-dimensional LiAl5O8:Cr3+ luminescence sensor probe
VL  - 64
SP  - 48
EP  - 56
DO  - 10.1016/j.cap.2024.05.013
ER  - 
@article{
author = "Ćirić, Aleksandar and Maričić, Milica and Ristić, Zoran and Gavrilović, Tamara and Medić, Mina and Dramićanin, Miroslav",
year = "2024",
abstract = "Pure-phase LiAl5O8:Cr3+ leaf-like particles were synthesized by combustion synthetic route at various concentrations. Both sharp peaks and broad emission photoluminescence are apparent even at room temperature. The most optimum doping concentration of 0.75 % based on lifetime and emission intensity was chosen. Peaks of different configurations were separated by deconvolution from 120 K to 680 K, where 4T2 peak increases in temperature to the expense of the sharp 2E emissions, giving luminescence intensity ratio (LIR) relative sensitivity of 2.8 % K−1 at room temperature. Large separation between Cr3+ R lines marks their LIR as perspective at low temperatures. At high temperatures luminescence lifetime provided for 0.8 % K−1 sensitivity, while line-shift and bandwidth methods are not sensitive enough for thermometric applications. Deconvolution of peaks enabled for 10 % more precise estimation of Debye temperature (679 K).",
journal = "Current Applied Physics",
title = "Remote optical thermometry by two-dimensional LiAl5O8:Cr3+ luminescence sensor probe",
volume = "64",
pages = "48-56",
doi = "10.1016/j.cap.2024.05.013"
}
Ćirić, A., Maričić, M., Ristić, Z., Gavrilović, T., Medić, M.,& Dramićanin, M.. (2024). Remote optical thermometry by two-dimensional LiAl5O8:Cr3+ luminescence sensor probe. in Current Applied Physics, 64, 48-56.
https://doi.org/10.1016/j.cap.2024.05.013
Ćirić A, Maričić M, Ristić Z, Gavrilović T, Medić M, Dramićanin M. Remote optical thermometry by two-dimensional LiAl5O8:Cr3+ luminescence sensor probe. in Current Applied Physics. 2024;64:48-56.
doi:10.1016/j.cap.2024.05.013 .
Ćirić, Aleksandar, Maričić, Milica, Ristić, Zoran, Gavrilović, Tamara, Medić, Mina, Dramićanin, Miroslav, "Remote optical thermometry by two-dimensional LiAl5O8:Cr3+ luminescence sensor probe" in Current Applied Physics, 64 (2024):48-56,
https://doi.org/10.1016/j.cap.2024.05.013 . .

Spent coffee grounds-derived carbon material as an effective adsorbent for removing multiple contaminants from wastewater: A comprehensive kinetic, isotherm, and thermodynamic study

Milanković, Vedran; Tasić, Tamara; Brković, Snežana M.; Potkonjak, Nebojša I.; Unterweger, C.; Bajuk-Bogdanović, Danica V.; Pašti, Igor A.; Lazarević-Pašti, Tamara

(2024)

TY  - JOUR
AU  - Milanković, Vedran
AU  - Tasić, Tamara
AU  - Brković, Snežana M.
AU  - Potkonjak, Nebojša I.
AU  - Unterweger, C.
AU  - Bajuk-Bogdanović, Danica V.
AU  - Pašti, Igor A.
AU  - Lazarević-Pašti, Tamara
PY  - 2024
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/13261
AB  - Environmental contamination from various industrial sources poses a significant global concern, demanding effective remediation strategies. This study investigates the efficacy of spent coffee grounds-derived carbon material in removing various contaminants, including organophosphate pesticides, pharmaceutical residues, and cationic dyes from aqueous solutions. Adsorption experiments were conducted at different temperatures (25 °C, 30 °C, and 35 °C), and the adsorption behavior was analyzed using various kinetic (pseudo-first-order, pseudo-second-order, Elovich, intraparticle diffusion) and isotherm models (Freundlich, Langmuir, Temkin, Dubinin-Radushkevich). Our findings reveal a complex adsorption process involving both monolayer and multilayer adsorption on the heterogeneous surface of the material. Temperature significantly influenced adsorption behavior, affecting maximum capacities and interactions. Using a material concentration of 0.5 mg mL−1 increases adsorption capacities for both pesticides, reaching 92.0 mg g−1 for malathion and 259 mg g−1 for chlorpyrifos adsorption. At a material concentration of 0.1 mg mL−1, the carbon material exhibited high adsorption capacities for methylene blue, rhodamine B, amoxicillin, and ceftriaxone, reaching values of 2085 mg g−1, 8250 mg g−1, 82 mg g−1, and 181 mg g−1, respectively. The adsorbent was successfully regenerated using 25 % ethanol solution and reused for at least 10 cycles without significantly impacting the adsorption capacity. These results underscore the potential of spent coffee grounds-derived carbon material as an efficient adsorbent for diverse contaminants, highlighting its promising role in environmental remediation efforts.
T2  - Journal of Water Process Engineering
T1  - Spent coffee grounds-derived carbon material as an effective adsorbent for removing multiple contaminants from wastewater: A comprehensive kinetic, isotherm, and thermodynamic study
VL  - 63
SP  - 105507
DO  - 10.1016/j.jwpe.2024.105507
ER  - 
@article{
author = "Milanković, Vedran and Tasić, Tamara and Brković, Snežana M. and Potkonjak, Nebojša I. and Unterweger, C. and Bajuk-Bogdanović, Danica V. and Pašti, Igor A. and Lazarević-Pašti, Tamara",
year = "2024",
abstract = "Environmental contamination from various industrial sources poses a significant global concern, demanding effective remediation strategies. This study investigates the efficacy of spent coffee grounds-derived carbon material in removing various contaminants, including organophosphate pesticides, pharmaceutical residues, and cationic dyes from aqueous solutions. Adsorption experiments were conducted at different temperatures (25 °C, 30 °C, and 35 °C), and the adsorption behavior was analyzed using various kinetic (pseudo-first-order, pseudo-second-order, Elovich, intraparticle diffusion) and isotherm models (Freundlich, Langmuir, Temkin, Dubinin-Radushkevich). Our findings reveal a complex adsorption process involving both monolayer and multilayer adsorption on the heterogeneous surface of the material. Temperature significantly influenced adsorption behavior, affecting maximum capacities and interactions. Using a material concentration of 0.5 mg mL−1 increases adsorption capacities for both pesticides, reaching 92.0 mg g−1 for malathion and 259 mg g−1 for chlorpyrifos adsorption. At a material concentration of 0.1 mg mL−1, the carbon material exhibited high adsorption capacities for methylene blue, rhodamine B, amoxicillin, and ceftriaxone, reaching values of 2085 mg g−1, 8250 mg g−1, 82 mg g−1, and 181 mg g−1, respectively. The adsorbent was successfully regenerated using 25 % ethanol solution and reused for at least 10 cycles without significantly impacting the adsorption capacity. These results underscore the potential of spent coffee grounds-derived carbon material as an efficient adsorbent for diverse contaminants, highlighting its promising role in environmental remediation efforts.",
journal = "Journal of Water Process Engineering",
title = "Spent coffee grounds-derived carbon material as an effective adsorbent for removing multiple contaminants from wastewater: A comprehensive kinetic, isotherm, and thermodynamic study",
volume = "63",
pages = "105507",
doi = "10.1016/j.jwpe.2024.105507"
}
Milanković, V., Tasić, T., Brković, S. M., Potkonjak, N. I., Unterweger, C., Bajuk-Bogdanović, D. V., Pašti, I. A.,& Lazarević-Pašti, T.. (2024). Spent coffee grounds-derived carbon material as an effective adsorbent for removing multiple contaminants from wastewater: A comprehensive kinetic, isotherm, and thermodynamic study. in Journal of Water Process Engineering, 63, 105507.
https://doi.org/10.1016/j.jwpe.2024.105507
Milanković V, Tasić T, Brković SM, Potkonjak NI, Unterweger C, Bajuk-Bogdanović DV, Pašti IA, Lazarević-Pašti T. Spent coffee grounds-derived carbon material as an effective adsorbent for removing multiple contaminants from wastewater: A comprehensive kinetic, isotherm, and thermodynamic study. in Journal of Water Process Engineering. 2024;63:105507.
doi:10.1016/j.jwpe.2024.105507 .
Milanković, Vedran, Tasić, Tamara, Brković, Snežana M., Potkonjak, Nebojša I., Unterweger, C., Bajuk-Bogdanović, Danica V., Pašti, Igor A., Lazarević-Pašti, Tamara, "Spent coffee grounds-derived carbon material as an effective adsorbent for removing multiple contaminants from wastewater: A comprehensive kinetic, isotherm, and thermodynamic study" in Journal of Water Process Engineering, 63 (2024):105507,
https://doi.org/10.1016/j.jwpe.2024.105507 . .

Time-resolved photoacoustic response of thin solids measured using minimal volume cell

Galović, Slobodanka; Stanimirović, Zdravko; Stanimirović, Ivanka; Đorđević, Katarina Lj.; Miličević, Dejan; Suljovrujić, Edin H.

(2024)

TY  - JOUR
AU  - Galović, Slobodanka
AU  - Stanimirović, Zdravko
AU  - Stanimirović, Ivanka
AU  - Đorđević, Katarina Lj.
AU  - Miličević, Dejan
AU  - Suljovrujić, Edin H.
PY  - 2024
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/13250
AB  - The photoacoustic effect was explained more than half a century ago and has since been used to develop non-destructive and non-contact techniques for testing materials. Most existing experimental setups are time-consuming. In this paper, we deal with the development of time-resolved photoacoustics to use all the advantages of photoacoustic techniques in the development of real-time characterization of various samples. We propose a model for a time-resolved photoacoustic signal of thin samples measured in a gas-microphone setup with a minimal volume cell, assuming that the gas column in the cell can be shorter than the thermal diffusion length in air. The derived model additionally includes the influence of thermal relaxations and detector transfer function. We also suggest a methodology for inverse problem solving, i.e., to determine the sample properties from measured signals using the presented model. The model has been validated by comparing the model predictions with an experimentally measured signal for a thin metallic sample excited by an optical pulse train of a repetition rate of 12 Hz. The results obtained by the suggested inverse-problem solving methodology are in accordance with the literature, thus confirming the validity of the proposed methodology. We have shown that the proposed model and the methodology of inverse time-resolved photoacoustic problems give the same results as the widespread time-consuming frequency photoacoustic measurements. This means that the presented model and methodology enable the employment of low-frequency time-resolved gas-microphone photoacoustics in the real-time characterization of thin solids.
T2  - International Communications in Heat and Mass Transfer
T1  - Time-resolved photoacoustic response of thin solids measured using minimal volume cell
VL  - 155
SP  - 107574
DO  - 10.1016/j.icheatmasstransfer.2024.107574
ER  - 
@article{
author = "Galović, Slobodanka and Stanimirović, Zdravko and Stanimirović, Ivanka and Đorđević, Katarina Lj. and Miličević, Dejan and Suljovrujić, Edin H.",
year = "2024",
abstract = "The photoacoustic effect was explained more than half a century ago and has since been used to develop non-destructive and non-contact techniques for testing materials. Most existing experimental setups are time-consuming. In this paper, we deal with the development of time-resolved photoacoustics to use all the advantages of photoacoustic techniques in the development of real-time characterization of various samples. We propose a model for a time-resolved photoacoustic signal of thin samples measured in a gas-microphone setup with a minimal volume cell, assuming that the gas column in the cell can be shorter than the thermal diffusion length in air. The derived model additionally includes the influence of thermal relaxations and detector transfer function. We also suggest a methodology for inverse problem solving, i.e., to determine the sample properties from measured signals using the presented model. The model has been validated by comparing the model predictions with an experimentally measured signal for a thin metallic sample excited by an optical pulse train of a repetition rate of 12 Hz. The results obtained by the suggested inverse-problem solving methodology are in accordance with the literature, thus confirming the validity of the proposed methodology. We have shown that the proposed model and the methodology of inverse time-resolved photoacoustic problems give the same results as the widespread time-consuming frequency photoacoustic measurements. This means that the presented model and methodology enable the employment of low-frequency time-resolved gas-microphone photoacoustics in the real-time characterization of thin solids.",
journal = "International Communications in Heat and Mass Transfer",
title = "Time-resolved photoacoustic response of thin solids measured using minimal volume cell",
volume = "155",
pages = "107574",
doi = "10.1016/j.icheatmasstransfer.2024.107574"
}
Galović, S., Stanimirović, Z., Stanimirović, I., Đorđević, K. Lj., Miličević, D.,& Suljovrujić, E. H.. (2024). Time-resolved photoacoustic response of thin solids measured using minimal volume cell. in International Communications in Heat and Mass Transfer, 155, 107574.
https://doi.org/10.1016/j.icheatmasstransfer.2024.107574
Galović S, Stanimirović Z, Stanimirović I, Đorđević KL, Miličević D, Suljovrujić EH. Time-resolved photoacoustic response of thin solids measured using minimal volume cell. in International Communications in Heat and Mass Transfer. 2024;155:107574.
doi:10.1016/j.icheatmasstransfer.2024.107574 .
Galović, Slobodanka, Stanimirović, Zdravko, Stanimirović, Ivanka, Đorđević, Katarina Lj., Miličević, Dejan, Suljovrujić, Edin H., "Time-resolved photoacoustic response of thin solids measured using minimal volume cell" in International Communications in Heat and Mass Transfer, 155 (2024):107574,
https://doi.org/10.1016/j.icheatmasstransfer.2024.107574 . .

Cellulose-Based Waste in a Close Loop as an Adsorbent for Removing Dyes from Textile Industry Wastewater

Vukčević, Marija; Maletić, Marina; Pejić, Biljana; Kalijadis, Ana; Kostić, Mirjana; Trivunac, Katarina; Perić Grujić, Aleksandra

(2024)

TY  - JOUR
AU  - Vukčević, Marija
AU  - Maletić, Marina
AU  - Pejić, Biljana
AU  - Kalijadis, Ana
AU  - Kostić, Mirjana
AU  - Trivunac, Katarina
AU  - Perić Grujić, Aleksandra
PY  - 2024
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/13251
AB  - In an attempt to reuse fibrous textile waste and, at the same time, to address dye pollution in textile wastewater, waste cotton-based yarn was utilized as a cheap and sustainable adsorbent, as well as a row material for carbon adsorbent production. Unmodified yarn and cotton-based carbon adsorbents were used as adsorbents for dye removal from water. Cotton and cotton/polyester yarn samples underwent thermal modification through carbonization followed by chemical activation with KOH. Various techniques, including scanning electron microscopy, Fourier transform infrared spectroscopy, nitrogen adsorption–desorption isotherms, and surface charge determination, were employed to analyze the morphological and surface characteristics of the cotton-based adsorbents. Adsorption properties were evaluated by testing the removal of selected cationic and anionic dyes from water. The impact of temperature, initial pH and concentration of the dye solution, and contact time on adsorption were investigated, and experimentally obtained data were analyzed using theoretical models. While carbonization alone did not significantly enhance adsorption properties, activated samples exhibited high efficacy in removing both cationic and anionic dyes from water. Despite the negative influence of the polyester component in the carbon precursor on the efficiency of activated samples in removing methyl orange, the results indicated that activated cotton and cotton/polyester yarn could be used to prepare highly efficient adsorbents for the rapid removal of methylene blue from real wastewater samples.
T2  - Sustainability
T1  - Cellulose-Based Waste in a Close Loop as an Adsorbent for Removing Dyes from Textile Industry Wastewater
VL  - 16
IS  - 9
SP  - 3660
DO  - 10.3390/su16093660
ER  - 
@article{
author = "Vukčević, Marija and Maletić, Marina and Pejić, Biljana and Kalijadis, Ana and Kostić, Mirjana and Trivunac, Katarina and Perić Grujić, Aleksandra",
year = "2024",
abstract = "In an attempt to reuse fibrous textile waste and, at the same time, to address dye pollution in textile wastewater, waste cotton-based yarn was utilized as a cheap and sustainable adsorbent, as well as a row material for carbon adsorbent production. Unmodified yarn and cotton-based carbon adsorbents were used as adsorbents for dye removal from water. Cotton and cotton/polyester yarn samples underwent thermal modification through carbonization followed by chemical activation with KOH. Various techniques, including scanning electron microscopy, Fourier transform infrared spectroscopy, nitrogen adsorption–desorption isotherms, and surface charge determination, were employed to analyze the morphological and surface characteristics of the cotton-based adsorbents. Adsorption properties were evaluated by testing the removal of selected cationic and anionic dyes from water. The impact of temperature, initial pH and concentration of the dye solution, and contact time on adsorption were investigated, and experimentally obtained data were analyzed using theoretical models. While carbonization alone did not significantly enhance adsorption properties, activated samples exhibited high efficacy in removing both cationic and anionic dyes from water. Despite the negative influence of the polyester component in the carbon precursor on the efficiency of activated samples in removing methyl orange, the results indicated that activated cotton and cotton/polyester yarn could be used to prepare highly efficient adsorbents for the rapid removal of methylene blue from real wastewater samples.",
journal = "Sustainability",
title = "Cellulose-Based Waste in a Close Loop as an Adsorbent for Removing Dyes from Textile Industry Wastewater",
volume = "16",
number = "9",
pages = "3660",
doi = "10.3390/su16093660"
}
Vukčević, M., Maletić, M., Pejić, B., Kalijadis, A., Kostić, M., Trivunac, K.,& Perić Grujić, A.. (2024). Cellulose-Based Waste in a Close Loop as an Adsorbent for Removing Dyes from Textile Industry Wastewater. in Sustainability, 16(9), 3660.
https://doi.org/10.3390/su16093660
Vukčević M, Maletić M, Pejić B, Kalijadis A, Kostić M, Trivunac K, Perić Grujić A. Cellulose-Based Waste in a Close Loop as an Adsorbent for Removing Dyes from Textile Industry Wastewater. in Sustainability. 2024;16(9):3660.
doi:10.3390/su16093660 .
Vukčević, Marija, Maletić, Marina, Pejić, Biljana, Kalijadis, Ana, Kostić, Mirjana, Trivunac, Katarina, Perić Grujić, Aleksandra, "Cellulose-Based Waste in a Close Loop as an Adsorbent for Removing Dyes from Textile Industry Wastewater" in Sustainability, 16, no. 9 (2024):3660,
https://doi.org/10.3390/su16093660 . .

Jedinjenja vanadijuma - novi mogući lekovi u terapiji šećerne bolesti

Dinčić, Marko; Todorović, Jasna; Čolović, Mirjana

(2024)

TY  - JOUR
AU  - Dinčić, Marko
AU  - Todorović, Jasna
AU  - Čolović, Mirjana
PY  - 2024
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/13252
AB  - Glavni ciljevi u lečenju osoba sa dijabetesom su ostvarenje individualnih glikemijskih ciljeva i prevencija komplikacija. Današnja savremena terapija dijabetesa, uz izuzetne uspehe, ima i određena ograničenja kao što su: paranteralni put primene leka, smanjenje efikasnosti leka nakon početnog poboljšanja glikemije, nedostupnost novijih lekova u nerazvijenim zemljama ili nepristupačnost leka zbog visoke cene. Zbog toga postoji stalna potreba za razvojem antihipeglikemijskih lekova jeftinijih i lakših za primenu, sa većom efikasnošću i manje toksičnim. U tom cilju, znatan broj studija ispitivao je uticaj neorganskih i organskih jedinjenja vanadijuma u snižavanju vrednosti hiperglikemije. Pokazano je da neorganska jedinjenja vanadijuma nakon peroralne primene imaju jako nizak stepen apsorpcije, tako da su visoke doze u snižavanju hiperglikemije izazivale ozbiljne neželjene efekte kod ispitanika. S druge strane, organsko jedinjenje vanadijuma bis(etilmaltolat)oksovanadijum(IV) došlo je do faze 2 kliničke studije ispitivanja antidijabetičke efikasnosti i bezbednosti, ali je studija prekinuta zbog nefrotoksičnog neželjenog efekta. Poslednjih nekoliko godina velika pažnja je posvećena istraživanju antidijabetičke aktivnosti polioksovanadata, ali su podaci o toksičnom potencijalu ovih jedinjenja još uvek nedovoljni. Iako je antidijabetička aktivnost odavno dokazana, tačni mehanizmi dejstva jedinjenja vanadijuma još uvek nisu u potpunosti razjašnjeni. U literaturi se navodi da jedinjenja vanadijuma mogu delovati na: sekreciju insulina, osetljivost ciljnih tkiva na insulin, stvaranje glukoze u jetri ili obim apsorpcije glukoze u digestivnom traktu. U zaključku, uprkos obećavajućim rezultatima dobijenim u istraživanjima na životinjama i ljudima, za sada još uvek nije otkriveno jedinjenje vanadijuma delotvorno u snižavanju hiperglikemije, uz istovremeno prihvatljivu bezbednost i sigurnost. Zbog toga je u budućnosti potrebno ulagati u pronalaženje novih jedinjenja vanadijuma, čije koristi će biti veće u odnosu na rizike.
AB  - The general goals of diabetes treatment are to maintain optimal individualized glycemic targets and to prevent complications. Today, there are significant barriers to successful diabetes therapy, such as parenteral drug administration, decreased therapeutic efficacy after an initial improvement in glycemia, inaccessibility of new medicines in lower-income countries, and high drug prices. Accordingly, significant research attention has been devoted to the development of a cheap and comfortable antidiabetic agent, which demonstrates success in lowering blood glucose levels as well as fewer toxicity properties. In recent years, the effects of inorganic and organic vanadium compounds have been investigated in diabetes treatment. These studies have found the low bioavailability of orally administered inorganic vanadium salts; thus, effective doses to reduce blood glucose levels to normal may cause serious adverse events. In addition, the only study with an organo-vanadium compound (bis(maltolato)oxovanadium(IV)), which has reached Phase IIa clinical trial, was terminated after three months due to renal complications. Moreover, despite a growing interest in polyoxovanadates for treating diabetes in the last few years, the toxic potentials of these compounds are still unknown. However, the precise mechanism of their antidiabetic actions remains unclear. A broad spectrum of possible mechanisms and hypotheses, such as enhancement of insulin secretion and enhanced sensitivity to insulin, as well as suppression of hepatic glucose production and decrease of intestinal glucose absorption, have been presented. In conclusion, besides the promising results obtained in animal and human studies, no vanadium compound has successfully reduced blood glucose with acceptable safety and tolerability. More studies of vanadium benefit-risk could lead to a new era in vanadium biomedicine.
T2  - Medicinski podmladak
T1  - Jedinjenja vanadijuma - novi mogući lekovi u terapiji šećerne bolesti
T1  - Vanadium compounds: New potential antidiabetic drugs
VL  - 75
IS  - 1
SP  - 13
EP  - 18
DO  - 10.5937/mp75-43694
ER  - 
@article{
author = "Dinčić, Marko and Todorović, Jasna and Čolović, Mirjana",
year = "2024",
abstract = "Glavni ciljevi u lečenju osoba sa dijabetesom su ostvarenje individualnih glikemijskih ciljeva i prevencija komplikacija. Današnja savremena terapija dijabetesa, uz izuzetne uspehe, ima i određena ograničenja kao što su: paranteralni put primene leka, smanjenje efikasnosti leka nakon početnog poboljšanja glikemije, nedostupnost novijih lekova u nerazvijenim zemljama ili nepristupačnost leka zbog visoke cene. Zbog toga postoji stalna potreba za razvojem antihipeglikemijskih lekova jeftinijih i lakših za primenu, sa većom efikasnošću i manje toksičnim. U tom cilju, znatan broj studija ispitivao je uticaj neorganskih i organskih jedinjenja vanadijuma u snižavanju vrednosti hiperglikemije. Pokazano je da neorganska jedinjenja vanadijuma nakon peroralne primene imaju jako nizak stepen apsorpcije, tako da su visoke doze u snižavanju hiperglikemije izazivale ozbiljne neželjene efekte kod ispitanika. S druge strane, organsko jedinjenje vanadijuma bis(etilmaltolat)oksovanadijum(IV) došlo je do faze 2 kliničke studije ispitivanja antidijabetičke efikasnosti i bezbednosti, ali je studija prekinuta zbog nefrotoksičnog neželjenog efekta. Poslednjih nekoliko godina velika pažnja je posvećena istraživanju antidijabetičke aktivnosti polioksovanadata, ali su podaci o toksičnom potencijalu ovih jedinjenja još uvek nedovoljni. Iako je antidijabetička aktivnost odavno dokazana, tačni mehanizmi dejstva jedinjenja vanadijuma još uvek nisu u potpunosti razjašnjeni. U literaturi se navodi da jedinjenja vanadijuma mogu delovati na: sekreciju insulina, osetljivost ciljnih tkiva na insulin, stvaranje glukoze u jetri ili obim apsorpcije glukoze u digestivnom traktu. U zaključku, uprkos obećavajućim rezultatima dobijenim u istraživanjima na životinjama i ljudima, za sada još uvek nije otkriveno jedinjenje vanadijuma delotvorno u snižavanju hiperglikemije, uz istovremeno prihvatljivu bezbednost i sigurnost. Zbog toga je u budućnosti potrebno ulagati u pronalaženje novih jedinjenja vanadijuma, čije koristi će biti veće u odnosu na rizike., The general goals of diabetes treatment are to maintain optimal individualized glycemic targets and to prevent complications. Today, there are significant barriers to successful diabetes therapy, such as parenteral drug administration, decreased therapeutic efficacy after an initial improvement in glycemia, inaccessibility of new medicines in lower-income countries, and high drug prices. Accordingly, significant research attention has been devoted to the development of a cheap and comfortable antidiabetic agent, which demonstrates success in lowering blood glucose levels as well as fewer toxicity properties. In recent years, the effects of inorganic and organic vanadium compounds have been investigated in diabetes treatment. These studies have found the low bioavailability of orally administered inorganic vanadium salts; thus, effective doses to reduce blood glucose levels to normal may cause serious adverse events. In addition, the only study with an organo-vanadium compound (bis(maltolato)oxovanadium(IV)), which has reached Phase IIa clinical trial, was terminated after three months due to renal complications. Moreover, despite a growing interest in polyoxovanadates for treating diabetes in the last few years, the toxic potentials of these compounds are still unknown. However, the precise mechanism of their antidiabetic actions remains unclear. A broad spectrum of possible mechanisms and hypotheses, such as enhancement of insulin secretion and enhanced sensitivity to insulin, as well as suppression of hepatic glucose production and decrease of intestinal glucose absorption, have been presented. In conclusion, besides the promising results obtained in animal and human studies, no vanadium compound has successfully reduced blood glucose with acceptable safety and tolerability. More studies of vanadium benefit-risk could lead to a new era in vanadium biomedicine.",
journal = "Medicinski podmladak",
title = "Jedinjenja vanadijuma - novi mogući lekovi u terapiji šećerne bolesti, Vanadium compounds: New potential antidiabetic drugs",
volume = "75",
number = "1",
pages = "13-18",
doi = "10.5937/mp75-43694"
}
Dinčić, M., Todorović, J.,& Čolović, M.. (2024). Jedinjenja vanadijuma - novi mogući lekovi u terapiji šećerne bolesti. in Medicinski podmladak, 75(1), 13-18.
https://doi.org/10.5937/mp75-43694
Dinčić M, Todorović J, Čolović M. Jedinjenja vanadijuma - novi mogući lekovi u terapiji šećerne bolesti. in Medicinski podmladak. 2024;75(1):13-18.
doi:10.5937/mp75-43694 .
Dinčić, Marko, Todorović, Jasna, Čolović, Mirjana, "Jedinjenja vanadijuma - novi mogući lekovi u terapiji šećerne bolesti" in Medicinski podmladak, 75, no. 1 (2024):13-18,
https://doi.org/10.5937/mp75-43694 . .

Atenolol uptake from pharmaceutical sources onto carbon aerogel prepared by supercritical CO2 drying

Momčilović, Milan Z.; Nešić, Aleksandra; Gurikov, Pavel; Schroeter, Baldur; Dodevski, Vladimir; Bojić, Aleksandar Lj.

(2024)

TY  - JOUR
AU  - Momčilović, Milan Z.
AU  - Nešić, Aleksandra
AU  - Gurikov, Pavel
AU  - Schroeter, Baldur
AU  - Dodevski, Vladimir
AU  - Bojić, Aleksandar Lj.
PY  - 2024
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/13253
AB  - Atenolol (ATL) is a popular medication which is widely used to treat hypertension and angina. It is often found in aqueous environments, posing potential risk to human health and ecological well-being. In this study, carbon aerogel was prepared by supercritical CO2 drying of resorcinol–formaldehyde resin subsequently carbonized at 600 °C in an inert atmosphere. This porous material was characterized by SEM, BET, FTIR, and XRD and used for the first time for the removal of ATL from aqueous solutions under varying experimental conditions. Carbon aerogel in the form of microbeads exhibited a relatively high specific surface area of 376.02 m2/g and median pore radius of 9.83 nm. The isotherm models of Langmuir, Freundlich, Temkin, Redlich-Peterson and Brouers-Sotolongo were used to interpret the equilibrium data. Although most of the applied models fitted the data well, the calculated values for maximum sorption capacity (qmax) showed a huge deviation when compared to experimental value of 76.66 mg/g. The pseudo-first and pseudo-second-order kinetic models, Chrastil’s model, and the intraparticle diffusion model were employed for fitting the kinetic data. The rate of the process was rapid with most of the uptake attained in the first 20 min of the contacting. The sorption optimum was achieved at pH pH 9.0 and for sorbent’s dosage of 750 mg/L. Reusability study of the spent aerogel conducted in seven cycles evidenced slight decrease of approximately 1 % in removal efficiency across the cycles indicating that the sorbent maintained its high effectiveness and stability throughout its usage.
T2  - Separation and Purification Technology
T1  - Atenolol uptake from pharmaceutical sources onto carbon aerogel prepared by supercritical CO2 drying
VL  - 350
SP  - 127792
DO  - 10.1016/j.seppur.2024.127792
ER  - 
@article{
author = "Momčilović, Milan Z. and Nešić, Aleksandra and Gurikov, Pavel and Schroeter, Baldur and Dodevski, Vladimir and Bojić, Aleksandar Lj.",
year = "2024",
abstract = "Atenolol (ATL) is a popular medication which is widely used to treat hypertension and angina. It is often found in aqueous environments, posing potential risk to human health and ecological well-being. In this study, carbon aerogel was prepared by supercritical CO2 drying of resorcinol–formaldehyde resin subsequently carbonized at 600 °C in an inert atmosphere. This porous material was characterized by SEM, BET, FTIR, and XRD and used for the first time for the removal of ATL from aqueous solutions under varying experimental conditions. Carbon aerogel in the form of microbeads exhibited a relatively high specific surface area of 376.02 m2/g and median pore radius of 9.83 nm. The isotherm models of Langmuir, Freundlich, Temkin, Redlich-Peterson and Brouers-Sotolongo were used to interpret the equilibrium data. Although most of the applied models fitted the data well, the calculated values for maximum sorption capacity (qmax) showed a huge deviation when compared to experimental value of 76.66 mg/g. The pseudo-first and pseudo-second-order kinetic models, Chrastil’s model, and the intraparticle diffusion model were employed for fitting the kinetic data. The rate of the process was rapid with most of the uptake attained in the first 20 min of the contacting. The sorption optimum was achieved at pH pH 9.0 and for sorbent’s dosage of 750 mg/L. Reusability study of the spent aerogel conducted in seven cycles evidenced slight decrease of approximately 1 % in removal efficiency across the cycles indicating that the sorbent maintained its high effectiveness and stability throughout its usage.",
journal = "Separation and Purification Technology",
title = "Atenolol uptake from pharmaceutical sources onto carbon aerogel prepared by supercritical CO2 drying",
volume = "350",
pages = "127792",
doi = "10.1016/j.seppur.2024.127792"
}
Momčilović, M. Z., Nešić, A., Gurikov, P., Schroeter, B., Dodevski, V.,& Bojić, A. Lj.. (2024). Atenolol uptake from pharmaceutical sources onto carbon aerogel prepared by supercritical CO2 drying. in Separation and Purification Technology, 350, 127792.
https://doi.org/10.1016/j.seppur.2024.127792
Momčilović MZ, Nešić A, Gurikov P, Schroeter B, Dodevski V, Bojić AL. Atenolol uptake from pharmaceutical sources onto carbon aerogel prepared by supercritical CO2 drying. in Separation and Purification Technology. 2024;350:127792.
doi:10.1016/j.seppur.2024.127792 .
Momčilović, Milan Z., Nešić, Aleksandra, Gurikov, Pavel, Schroeter, Baldur, Dodevski, Vladimir, Bojić, Aleksandar Lj., "Atenolol uptake from pharmaceutical sources onto carbon aerogel prepared by supercritical CO2 drying" in Separation and Purification Technology, 350 (2024):127792,
https://doi.org/10.1016/j.seppur.2024.127792 . .

Application of Model-Free and Model-Based Kinetic Methods in Evaluation of Reactions Complexity during Thermo-Oxidative Degradation Process: Case Study of [4-(Hydroxymethyl)phenoxymethyl] Polystyrene Resin

Janković, Bojan Ž.; Dodevski, Vladimir; Veljković, Filip M.; Janković, Marija M.; Manić, Nebojša

(2024)

TY  - JOUR
AU  - Janković, Bojan Ž.
AU  - Dodevski, Vladimir
AU  - Veljković, Filip M.
AU  - Janković, Marija M.
AU  - Manić, Nebojša
PY  - 2024
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/13254
AB  - This work examined the possibilities and limitations of model-free and model-based methods related to decrypting the kinetic complexity of multi-step thermo-oxidative degradation processes (as a testing system, a [4-(hydroxymethyl)phenoxymethyl] polystyrene resin was used), monitored by thermal analysis (TGA-DTG-DTA) techniques. It was found that isoconversional methods could successfully determine the correct number of process stages and presence of multiple reactions based on derived Ea(α) profiles and identify the negative dependence of the rate constant on the temperature. These methods could not overcome the problem that arose due to mass transfer limitations. The model-based method overcame more successfully the problem associated with mass transfer because its calculation machinery had capabilities for the correct solution of the total mass balance equation. However, a perfect fit with the experimental data was not achieved due to the dependence on the thermal history of the contribution (ctb.) of a given reaction step inside a fitting procedure cycle. On the other hand, through this approach, it was possible to estimate the rate-controlling steps of the process regarding the influence of the heating rate. It was found that for consecutive reaction mechanisms, the production of benzaldehyde and gases in high yields was controlled by the heating rate, where low heating rates were strongly recommended (≤10 K/min). Also, it was shown that the transport phenomenon may be also the rate-determining step (within the set of “intrinsic” kinetic parameters). It was also established that external heat transfer controls the overall rate, where the “pure” kinetic control regime had not been reached but was approached when lowering the temperature and size of the resin particles.
T2  - Fire
T1  - Application of Model-Free and Model-Based Kinetic Methods in Evaluation of Reactions Complexity during Thermo-Oxidative Degradation Process: Case Study of [4-(Hydroxymethyl)phenoxymethyl] Polystyrene Resin
VL  - 7
IS  - 5
SP  - 165
DO  - 10.3390/fire7050165
ER  - 
@article{
author = "Janković, Bojan Ž. and Dodevski, Vladimir and Veljković, Filip M. and Janković, Marija M. and Manić, Nebojša",
year = "2024",
abstract = "This work examined the possibilities and limitations of model-free and model-based methods related to decrypting the kinetic complexity of multi-step thermo-oxidative degradation processes (as a testing system, a [4-(hydroxymethyl)phenoxymethyl] polystyrene resin was used), monitored by thermal analysis (TGA-DTG-DTA) techniques. It was found that isoconversional methods could successfully determine the correct number of process stages and presence of multiple reactions based on derived Ea(α) profiles and identify the negative dependence of the rate constant on the temperature. These methods could not overcome the problem that arose due to mass transfer limitations. The model-based method overcame more successfully the problem associated with mass transfer because its calculation machinery had capabilities for the correct solution of the total mass balance equation. However, a perfect fit with the experimental data was not achieved due to the dependence on the thermal history of the contribution (ctb.) of a given reaction step inside a fitting procedure cycle. On the other hand, through this approach, it was possible to estimate the rate-controlling steps of the process regarding the influence of the heating rate. It was found that for consecutive reaction mechanisms, the production of benzaldehyde and gases in high yields was controlled by the heating rate, where low heating rates were strongly recommended (≤10 K/min). Also, it was shown that the transport phenomenon may be also the rate-determining step (within the set of “intrinsic” kinetic parameters). It was also established that external heat transfer controls the overall rate, where the “pure” kinetic control regime had not been reached but was approached when lowering the temperature and size of the resin particles.",
journal = "Fire",
title = "Application of Model-Free and Model-Based Kinetic Methods in Evaluation of Reactions Complexity during Thermo-Oxidative Degradation Process: Case Study of [4-(Hydroxymethyl)phenoxymethyl] Polystyrene Resin",
volume = "7",
number = "5",
pages = "165",
doi = "10.3390/fire7050165"
}
Janković, B. Ž., Dodevski, V., Veljković, F. M., Janković, M. M.,& Manić, N.. (2024). Application of Model-Free and Model-Based Kinetic Methods in Evaluation of Reactions Complexity during Thermo-Oxidative Degradation Process: Case Study of [4-(Hydroxymethyl)phenoxymethyl] Polystyrene Resin. in Fire, 7(5), 165.
https://doi.org/10.3390/fire7050165
Janković BŽ, Dodevski V, Veljković FM, Janković MM, Manić N. Application of Model-Free and Model-Based Kinetic Methods in Evaluation of Reactions Complexity during Thermo-Oxidative Degradation Process: Case Study of [4-(Hydroxymethyl)phenoxymethyl] Polystyrene Resin. in Fire. 2024;7(5):165.
doi:10.3390/fire7050165 .
Janković, Bojan Ž., Dodevski, Vladimir, Veljković, Filip M., Janković, Marija M., Manić, Nebojša, "Application of Model-Free and Model-Based Kinetic Methods in Evaluation of Reactions Complexity during Thermo-Oxidative Degradation Process: Case Study of [4-(Hydroxymethyl)phenoxymethyl] Polystyrene Resin" in Fire, 7, no. 5 (2024):165,
https://doi.org/10.3390/fire7050165 . .

Sustainable and fast synthesis of zinc-phthalocyanine for gamma radiation dosimeter application

Vasiljević, Bojana; Odobaša, Daliborka; Vujičić, Ivica; Budimir Filimonović, Milica; Smits, Krisjanis; Mijin, Dušan; Marinković, Dragana

(2024)

TY  - JOUR
AU  - Vasiljević, Bojana
AU  - Odobaša, Daliborka
AU  - Vujičić, Ivica
AU  - Budimir Filimonović, Milica
AU  - Smits, Krisjanis
AU  - Mijin, Dušan
AU  - Marinković, Dragana
PY  - 2024
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/13249
AB  - In the present research, the two different systems of dye based on zinc phthalocyanine were prepared by microwave-induced synthesis and conventional methods. They were evaluated as new effective chemical-based dosimeters for gamma irradiation. The sensitivity of the prepared dosimeters was examined by studying the comparative results between them through the changes in structural and optical properties upon exposure to different gamma irradiation doses. The color bleaching of the solutions was followed spectrophotometrically. Gradual changes from blue to light yellow color of zinc phthalocyanine solution, with the increase of the gamma radiation dose, were observed due to the decomposition of the dyes based on the zinc phthalocyanine. The synthesized zinc phthalocyanine chemical-based dosimeters for measurement of gamma irradiation up to 25kGy showed excellent stability after irradiation in terms of morphology and structure, which makes them a suitable novel material as composite-based dosimeters of gamma irradiation.
T2  - Radiation Physics and Chemistry
T1  - Sustainable and fast synthesis of zinc-phthalocyanine for gamma radiation dosimeter application
VL  - 222
SP  - 111816
DO  - 10.1016/j.radphyschem.2024.111816
ER  - 
@article{
author = "Vasiljević, Bojana and Odobaša, Daliborka and Vujičić, Ivica and Budimir Filimonović, Milica and Smits, Krisjanis and Mijin, Dušan and Marinković, Dragana",
year = "2024",
abstract = "In the present research, the two different systems of dye based on zinc phthalocyanine were prepared by microwave-induced synthesis and conventional methods. They were evaluated as new effective chemical-based dosimeters for gamma irradiation. The sensitivity of the prepared dosimeters was examined by studying the comparative results between them through the changes in structural and optical properties upon exposure to different gamma irradiation doses. The color bleaching of the solutions was followed spectrophotometrically. Gradual changes from blue to light yellow color of zinc phthalocyanine solution, with the increase of the gamma radiation dose, were observed due to the decomposition of the dyes based on the zinc phthalocyanine. The synthesized zinc phthalocyanine chemical-based dosimeters for measurement of gamma irradiation up to 25kGy showed excellent stability after irradiation in terms of morphology and structure, which makes them a suitable novel material as composite-based dosimeters of gamma irradiation.",
journal = "Radiation Physics and Chemistry",
title = "Sustainable and fast synthesis of zinc-phthalocyanine for gamma radiation dosimeter application",
volume = "222",
pages = "111816",
doi = "10.1016/j.radphyschem.2024.111816"
}
Vasiljević, B., Odobaša, D., Vujičić, I., Budimir Filimonović, M., Smits, K., Mijin, D.,& Marinković, D.. (2024). Sustainable and fast synthesis of zinc-phthalocyanine for gamma radiation dosimeter application. in Radiation Physics and Chemistry, 222, 111816.
https://doi.org/10.1016/j.radphyschem.2024.111816
Vasiljević B, Odobaša D, Vujičić I, Budimir Filimonović M, Smits K, Mijin D, Marinković D. Sustainable and fast synthesis of zinc-phthalocyanine for gamma radiation dosimeter application. in Radiation Physics and Chemistry. 2024;222:111816.
doi:10.1016/j.radphyschem.2024.111816 .
Vasiljević, Bojana, Odobaša, Daliborka, Vujičić, Ivica, Budimir Filimonović, Milica, Smits, Krisjanis, Mijin, Dušan, Marinković, Dragana, "Sustainable and fast synthesis of zinc-phthalocyanine for gamma radiation dosimeter application" in Radiation Physics and Chemistry, 222 (2024):111816,
https://doi.org/10.1016/j.radphyschem.2024.111816 . .

Twinning for graphene-based composites in EMI shielding

Jovanović, Svetlana; Kepić, Dejan; Huskić, Miroslav; Yasir, Muhammad; Haddadi, Kamel

(Belgrade : Association of Chemical Engineers of Serbia, 2024)

TY  - CONF
AU  - Jovanović, Svetlana
AU  - Kepić, Dejan
AU  - Huskić, Miroslav
AU  - Yasir, Muhammad
AU  - Haddadi, Kamel
PY  - 2024
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/13188
AB  - In the era of intensive development of microelectronics, energy, and car industries along with Radio-Frequency (RF) telecommunications, the pollution caused by Electromagnetic Waves (EWs) is ever-present. EW interferences (Electromagnetic Interference-EMI) exhibit perturbation and negative impact on devices and systems including those used in everyday life as well as on the specialized, sensitive, and sophisticated instruments used in research laboratories. EMI could cause untrusted signals and RF noise. To prevent these issues, materials able to block or absorb the radiated EWs are urgently required. The GrInShield project is focused on developing new graphene-based shielding nano-materials and increasing researchers' expertise in EMI shielding measuring, protective materials, and possibilities to bring these new products to the market. INTRODUCTION: The GrInShield project uses graphene oxide (GO) obtained by Hummers' reaction and electrochemical exfoliation of graphite [1,2]. We have analysed the factors that affect the shielding efficiency of materials [3] and studied the reaction conditions that lead to obtaining graphene with different sizes and oxygen content [4]. RESULTS AND DISCUSSION: The GrInShield project aims to produce composites of GO with silver nanowires (AgNWs) to develop GO-AgNW composites for EMI shielding applications. To achieve these goals, the project gathers experts from the chemistry of nanomaterials, and polymer processing, along with specialists for near-field microscopy tools and radiofrequency (RF) characterization of materials. CONCLUSIONS: The GrInShield project is developing new nanomaterials for EMI shielding based on carbon nanomaterials, metallic nanomaterials, and polymers. The fabrication of low-cost, sustainable, eco-friendly, durable EMI shielding material should be achieved.
PB  - Belgrade : Association of Chemical Engineers of Serbia
C3  - Hemijska Industrija
T1  - Twinning for graphene-based composites in EMI shielding
VL  - 78
IS  - 1S
SP  - 79
UR  - https://hdl.handle.net/21.15107/rcub_vinar_13188
ER  - 
@conference{
author = "Jovanović, Svetlana and Kepić, Dejan and Huskić, Miroslav and Yasir, Muhammad and Haddadi, Kamel",
year = "2024",
abstract = "In the era of intensive development of microelectronics, energy, and car industries along with Radio-Frequency (RF) telecommunications, the pollution caused by Electromagnetic Waves (EWs) is ever-present. EW interferences (Electromagnetic Interference-EMI) exhibit perturbation and negative impact on devices and systems including those used in everyday life as well as on the specialized, sensitive, and sophisticated instruments used in research laboratories. EMI could cause untrusted signals and RF noise. To prevent these issues, materials able to block or absorb the radiated EWs are urgently required. The GrInShield project is focused on developing new graphene-based shielding nano-materials and increasing researchers' expertise in EMI shielding measuring, protective materials, and possibilities to bring these new products to the market. INTRODUCTION: The GrInShield project uses graphene oxide (GO) obtained by Hummers' reaction and electrochemical exfoliation of graphite [1,2]. We have analysed the factors that affect the shielding efficiency of materials [3] and studied the reaction conditions that lead to obtaining graphene with different sizes and oxygen content [4]. RESULTS AND DISCUSSION: The GrInShield project aims to produce composites of GO with silver nanowires (AgNWs) to develop GO-AgNW composites for EMI shielding applications. To achieve these goals, the project gathers experts from the chemistry of nanomaterials, and polymer processing, along with specialists for near-field microscopy tools and radiofrequency (RF) characterization of materials. CONCLUSIONS: The GrInShield project is developing new nanomaterials for EMI shielding based on carbon nanomaterials, metallic nanomaterials, and polymers. The fabrication of low-cost, sustainable, eco-friendly, durable EMI shielding material should be achieved.",
publisher = "Belgrade : Association of Chemical Engineers of Serbia",
journal = "Hemijska Industrija",
title = "Twinning for graphene-based composites in EMI shielding",
volume = "78",
number = "1S",
pages = "79",
url = "https://hdl.handle.net/21.15107/rcub_vinar_13188"
}
Jovanović, S., Kepić, D., Huskić, M., Yasir, M.,& Haddadi, K.. (2024). Twinning for graphene-based composites in EMI shielding. in Hemijska Industrija
Belgrade : Association of Chemical Engineers of Serbia., 78(1S), 79.
https://hdl.handle.net/21.15107/rcub_vinar_13188
Jovanović S, Kepić D, Huskić M, Yasir M, Haddadi K. Twinning for graphene-based composites in EMI shielding. in Hemijska Industrija. 2024;78(1S):79.
https://hdl.handle.net/21.15107/rcub_vinar_13188 .
Jovanović, Svetlana, Kepić, Dejan, Huskić, Miroslav, Yasir, Muhammad, Haddadi, Kamel, "Twinning for graphene-based composites in EMI shielding" in Hemijska Industrija, 78, no. 1S (2024):79,
https://hdl.handle.net/21.15107/rcub_vinar_13188 .

The Influence of Reaction Conditions on the Properties of Graphene Oxide

Huskić, Miroslav; Kepić, Dejan; Kleut, Duška; Mozetič, Miran; Vesel, Alenka; Anžlovar, Alojz; Bajuk Bogdanović, Danica; Jovanović, Svetlana

(2024)

TY  - JOUR
AU  - Huskić, Miroslav
AU  - Kepić, Dejan
AU  - Kleut, Duška
AU  - Mozetič, Miran
AU  - Vesel, Alenka
AU  - Anžlovar, Alojz
AU  - Bajuk Bogdanović, Danica
AU  - Jovanović, Svetlana
PY  - 2024
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/12874
AB  - The present study focuses on correlations between three parameters: (1) graphite particle
size, (2) the ratio of graphite to oxidizing agent (KMnO4
), and (3) the ratio of graphite to acid
(H2SO4 and H3PO4
), with the reaction yield, structure, and properties of graphene oxide (GO). The
correlations are a challenge, as these three parameters can hardly be separated from each other due to
the variations in the viscosity of the system. The larger the graphite particles, the higher the viscosity
of GO. Decreasing the ratio of graphite to KMnO4
from 1:4 to 1:6 generally leads to a higher degree
of oxidation and a higher reaction yield. However, the differences are very small. Increasing the
graphite-to-acid-volume ratio from 1 g/60 mL to 1 g/80 mL, except for the smallest particles, reduced
the degree of oxidation and slightly reduced the reaction yield. However, the reaction yield mainly
depends on the extent of purification of GO by water, not on the reaction conditions. The large
differences in the thermal decomposition of GO are mainly due to the bulk particle size and less to
other parameters
T2  - Nanomaterials
T1  - The Influence of Reaction Conditions on the Properties of Graphene Oxide
VL  - 14
IS  - 3
SP  - 281
DO  - 10.3390/nano14030281
ER  - 
@article{
author = "Huskić, Miroslav and Kepić, Dejan and Kleut, Duška and Mozetič, Miran and Vesel, Alenka and Anžlovar, Alojz and Bajuk Bogdanović, Danica and Jovanović, Svetlana",
year = "2024",
abstract = "The present study focuses on correlations between three parameters: (1) graphite particle
size, (2) the ratio of graphite to oxidizing agent (KMnO4
), and (3) the ratio of graphite to acid
(H2SO4 and H3PO4
), with the reaction yield, structure, and properties of graphene oxide (GO). The
correlations are a challenge, as these three parameters can hardly be separated from each other due to
the variations in the viscosity of the system. The larger the graphite particles, the higher the viscosity
of GO. Decreasing the ratio of graphite to KMnO4
from 1:4 to 1:6 generally leads to a higher degree
of oxidation and a higher reaction yield. However, the differences are very small. Increasing the
graphite-to-acid-volume ratio from 1 g/60 mL to 1 g/80 mL, except for the smallest particles, reduced
the degree of oxidation and slightly reduced the reaction yield. However, the reaction yield mainly
depends on the extent of purification of GO by water, not on the reaction conditions. The large
differences in the thermal decomposition of GO are mainly due to the bulk particle size and less to
other parameters",
journal = "Nanomaterials",
title = "The Influence of Reaction Conditions on the Properties of Graphene Oxide",
volume = "14",
number = "3",
pages = "281",
doi = "10.3390/nano14030281"
}
Huskić, M., Kepić, D., Kleut, D., Mozetič, M., Vesel, A., Anžlovar, A., Bajuk Bogdanović, D.,& Jovanović, S.. (2024). The Influence of Reaction Conditions on the Properties of Graphene Oxide. in Nanomaterials, 14(3), 281.
https://doi.org/10.3390/nano14030281
Huskić M, Kepić D, Kleut D, Mozetič M, Vesel A, Anžlovar A, Bajuk Bogdanović D, Jovanović S. The Influence of Reaction Conditions on the Properties of Graphene Oxide. in Nanomaterials. 2024;14(3):281.
doi:10.3390/nano14030281 .
Huskić, Miroslav, Kepić, Dejan, Kleut, Duška, Mozetič, Miran, Vesel, Alenka, Anžlovar, Alojz, Bajuk Bogdanović, Danica, Jovanović, Svetlana, "The Influence of Reaction Conditions on the Properties of Graphene Oxide" in Nanomaterials, 14, no. 3 (2024):281,
https://doi.org/10.3390/nano14030281 . .
2

The involvement of Akt, mTOR, and S6K in the in vivo effect of IGF-1 on the regulation of rat cardiac Na+/K+-ATPase

Banjac, Katarina; Obradović, Milan; Zafirović, Sonja; Essack, Magbubah; Gluvić, Zoran; Šunderić, Miloš; Nedić, Olgica; Isenović, Esma R.

(2024)

TY  - JOUR
AU  - Banjac, Katarina
AU  - Obradović, Milan
AU  - Zafirović, Sonja
AU  - Essack, Magbubah
AU  - Gluvić, Zoran
AU  - Šunderić, Miloš
AU  - Nedić, Olgica
AU  - Isenović, Esma R.
PY  - 2024
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/13184
AB  - Background We previously demonstrated that insulin-like growth factor-1 (IGF-1) regulates sodium/potassium adenosine triphosphatase (Na+/K+-ATPase) in vascular smooth muscle cells (VSMC) via phosphatidylinositol-3 kinase (PI3K). Taking into account that others’ work show that IGF-1 activates the PI3K/protein kinase B (Akt) signaling pathway in many different cells, we here further questioned if the Akt/mammalian target of rapamycin (mTOR)/ribosomal protein p70 S6 kinase (S6K) pathway stimulates Na+/K+-ATPase, an essential protein for maintaining normal heart function. Methods and results There were 14 adult male Wistar rats, half of whom received bolus injections of IGF-1 (50 μg/kg) for 24 h. We evaluated cardiac Na+/K+-ATPase expression, activity, and serum IGF-1 levels. Additionally, we examined the phosphorylated forms of the following proteins: insulin receptor substrate (IRS), phosphoinositide-dependent kinase-1 (PDK-1), Akt, mTOR, S6K, and α subunit of Na+/K+-ATPase. Additionally, the mRNA expression of the Na+/K+-ATPase α1 subunit was evaluated. Treatment with IGF-1 increases levels of serum IGF-1 and stimulates Na+/K+-ATPase activity, phosphorylation of α subunit of Na+/K+-ATPase on Ser23, and protein expression of α2 subunit. Furthermore, IGF-1 treatment increased phosphorylation of IRS-1 on Tyr1222, Akt on Ser473, PDK-1 on Ser241, mTOR on Ser2481 and Ser2448, and S6K on Thr421/Ser424. The concentration of IGF-1 in serum positively correlates with Na+/K+-ATPase activity and the phosphorylated form of mTOR (Ser2448), while Na+/K+-ATPase activity positively correlates with the phosphorylated form of IRS-1 (Tyr1222) and mTOR (Ser2448). Conclusion These results indicate that the Akt/mTOR/S6K signalling pathway may be involved in the IGF-1 regulating cardiac Na+/K+-ATPase expression and activity
T2  - Molecular Biology Reports
T1  - The involvement of Akt, mTOR, and S6K in the in vivo effect of IGF-1 on the regulation of rat cardiac Na+/K+-ATPase
VL  - 51
IS  - 1
DO  - 10.1007/s11033-024-09451-3
ER  - 
@article{
author = "Banjac, Katarina and Obradović, Milan and Zafirović, Sonja and Essack, Magbubah and Gluvić, Zoran and Šunderić, Miloš and Nedić, Olgica and Isenović, Esma R.",
year = "2024",
abstract = "Background We previously demonstrated that insulin-like growth factor-1 (IGF-1) regulates sodium/potassium adenosine triphosphatase (Na+/K+-ATPase) in vascular smooth muscle cells (VSMC) via phosphatidylinositol-3 kinase (PI3K). Taking into account that others’ work show that IGF-1 activates the PI3K/protein kinase B (Akt) signaling pathway in many different cells, we here further questioned if the Akt/mammalian target of rapamycin (mTOR)/ribosomal protein p70 S6 kinase (S6K) pathway stimulates Na+/K+-ATPase, an essential protein for maintaining normal heart function. Methods and results There were 14 adult male Wistar rats, half of whom received bolus injections of IGF-1 (50 μg/kg) for 24 h. We evaluated cardiac Na+/K+-ATPase expression, activity, and serum IGF-1 levels. Additionally, we examined the phosphorylated forms of the following proteins: insulin receptor substrate (IRS), phosphoinositide-dependent kinase-1 (PDK-1), Akt, mTOR, S6K, and α subunit of Na+/K+-ATPase. Additionally, the mRNA expression of the Na+/K+-ATPase α1 subunit was evaluated. Treatment with IGF-1 increases levels of serum IGF-1 and stimulates Na+/K+-ATPase activity, phosphorylation of α subunit of Na+/K+-ATPase on Ser23, and protein expression of α2 subunit. Furthermore, IGF-1 treatment increased phosphorylation of IRS-1 on Tyr1222, Akt on Ser473, PDK-1 on Ser241, mTOR on Ser2481 and Ser2448, and S6K on Thr421/Ser424. The concentration of IGF-1 in serum positively correlates with Na+/K+-ATPase activity and the phosphorylated form of mTOR (Ser2448), while Na+/K+-ATPase activity positively correlates with the phosphorylated form of IRS-1 (Tyr1222) and mTOR (Ser2448). Conclusion These results indicate that the Akt/mTOR/S6K signalling pathway may be involved in the IGF-1 regulating cardiac Na+/K+-ATPase expression and activity",
journal = "Molecular Biology Reports",
title = "The involvement of Akt, mTOR, and S6K in the in vivo effect of IGF-1 on the regulation of rat cardiac Na+/K+-ATPase",
volume = "51",
number = "1",
doi = "10.1007/s11033-024-09451-3"
}
Banjac, K., Obradović, M., Zafirović, S., Essack, M., Gluvić, Z., Šunderić, M., Nedić, O.,& Isenović, E. R.. (2024). The involvement of Akt, mTOR, and S6K in the in vivo effect of IGF-1 on the regulation of rat cardiac Na+/K+-ATPase. in Molecular Biology Reports, 51(1).
https://doi.org/10.1007/s11033-024-09451-3
Banjac K, Obradović M, Zafirović S, Essack M, Gluvić Z, Šunderić M, Nedić O, Isenović ER. The involvement of Akt, mTOR, and S6K in the in vivo effect of IGF-1 on the regulation of rat cardiac Na+/K+-ATPase. in Molecular Biology Reports. 2024;51(1).
doi:10.1007/s11033-024-09451-3 .
Banjac, Katarina, Obradović, Milan, Zafirović, Sonja, Essack, Magbubah, Gluvić, Zoran, Šunderić, Miloš, Nedić, Olgica, Isenović, Esma R., "The involvement of Akt, mTOR, and S6K in the in vivo effect of IGF-1 on the regulation of rat cardiac Na+/K+-ATPase" in Molecular Biology Reports, 51, no. 1 (2024),
https://doi.org/10.1007/s11033-024-09451-3 . .

Mineralogical Characterization of Raw Clay from Rujište (Serbia) Used in Traditional Pottery Manufacture

Milošević, Maja; Dabić, Predrag; Gulicovski, Jelena; Dodevski, Vladimir; Rosić, Milena

(2024)

TY  - JOUR
AU  - Milošević, Maja
AU  - Dabić, Predrag
AU  - Gulicovski, Jelena
AU  - Dodevski, Vladimir
AU  - Rosić, Milena
PY  - 2024
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/13245
AB  - The pottery produced from the Rujište deposit in Serbia has been protected under the guidance of UNESCO and the Sector for Intangible Cultural Heritage of Serbia since 2019. A study was conducted to evaluate the mineralogical characteristics of the raw clay from this deposit. This study used various techniques, such as X-ray diffraction (XRD), infrared (IR) spectroscopy, X-ray fluorescence (XRF), and differential thermal analysis (DTA) to characterize the clay. This study found that the clay contained mostly clay minerals (56.3%–41.9%), with illite, smectite, and chlorite as the predominant phases. Other phases identified were quartz, feldspars, carbonates, and iron-bearing minerals (43.8%–58.1%). The chemical analyses revealed a high abundance of silica (>52 wt.%) and alumina (~16 wt.%), with Fe2O3 (~6 wt.%), K2O (~2.8 wt.%), and a similar content of MgO as the main constituents. The physical features that were investigated included the granulometry (clay: ~31%–44%, silt: ~ 26%–23%, and sand: ~ 42%–32%), specific surface area (97 to 107 m2 g−1), cation exchange capacity (12.5–13.7 mmol 100 g−1), and color (yellowish to moderate brown). The preliminary results suggest that most of the raw clay from the Rujište deposit might be suitable for use in traditional pottery manufacture.
T2  - Minerals
T1  - Mineralogical Characterization of Raw Clay from Rujište (Serbia) Used in Traditional Pottery Manufacture
VL  - 14
IS  - 5
SP  - 469
DO  - 10.3390/min14050469
ER  - 
@article{
author = "Milošević, Maja and Dabić, Predrag and Gulicovski, Jelena and Dodevski, Vladimir and Rosić, Milena",
year = "2024",
abstract = "The pottery produced from the Rujište deposit in Serbia has been protected under the guidance of UNESCO and the Sector for Intangible Cultural Heritage of Serbia since 2019. A study was conducted to evaluate the mineralogical characteristics of the raw clay from this deposit. This study used various techniques, such as X-ray diffraction (XRD), infrared (IR) spectroscopy, X-ray fluorescence (XRF), and differential thermal analysis (DTA) to characterize the clay. This study found that the clay contained mostly clay minerals (56.3%–41.9%), with illite, smectite, and chlorite as the predominant phases. Other phases identified were quartz, feldspars, carbonates, and iron-bearing minerals (43.8%–58.1%). The chemical analyses revealed a high abundance of silica (>52 wt.%) and alumina (~16 wt.%), with Fe2O3 (~6 wt.%), K2O (~2.8 wt.%), and a similar content of MgO as the main constituents. The physical features that were investigated included the granulometry (clay: ~31%–44%, silt: ~ 26%–23%, and sand: ~ 42%–32%), specific surface area (97 to 107 m2 g−1), cation exchange capacity (12.5–13.7 mmol 100 g−1), and color (yellowish to moderate brown). The preliminary results suggest that most of the raw clay from the Rujište deposit might be suitable for use in traditional pottery manufacture.",
journal = "Minerals",
title = "Mineralogical Characterization of Raw Clay from Rujište (Serbia) Used in Traditional Pottery Manufacture",
volume = "14",
number = "5",
pages = "469",
doi = "10.3390/min14050469"
}
Milošević, M., Dabić, P., Gulicovski, J., Dodevski, V.,& Rosić, M.. (2024). Mineralogical Characterization of Raw Clay from Rujište (Serbia) Used in Traditional Pottery Manufacture. in Minerals, 14(5), 469.
https://doi.org/10.3390/min14050469
Milošević M, Dabić P, Gulicovski J, Dodevski V, Rosić M. Mineralogical Characterization of Raw Clay from Rujište (Serbia) Used in Traditional Pottery Manufacture. in Minerals. 2024;14(5):469.
doi:10.3390/min14050469 .
Milošević, Maja, Dabić, Predrag, Gulicovski, Jelena, Dodevski, Vladimir, Rosić, Milena, "Mineralogical Characterization of Raw Clay from Rujište (Serbia) Used in Traditional Pottery Manufacture" in Minerals, 14, no. 5 (2024):469,
https://doi.org/10.3390/min14050469 . .

Adsorption Efficiency of Cadmium (II) by Different Alkali-Activated Materials

Mladenović Nikolić, Nataša; Kljajević, Ljiljana; Nenadović, Snežana S.; Potočnik, Jelena; Knežević, Sanja; Dolenec, Sabina; Trivunac, Katarina

(2024)

TY  - JOUR
AU  - Mladenović Nikolić, Nataša
AU  - Kljajević, Ljiljana
AU  - Nenadović, Snežana S.
AU  - Potočnik, Jelena
AU  - Knežević, Sanja
AU  - Dolenec, Sabina
AU  - Trivunac, Katarina
PY  - 2024
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/13247
AB  - The objective of this study was to demonstrate the potential utilization of fly ash (FA), wood ash (WA), and metakaolin (MK) in developing new alkali-activated materials (AAMs) for the removal of cadmium ions from waste water. The synthesis of AAMs involved the dissolution of solid precursors, FA, WA, and MK, by a liquid activator (Na2SiO3 and NaOH). In concentrated solutions of the activator, the formation of an aluminosilicate gel structure occurred. DRIFT spectroscopy of the AAMs indicated main vibration bands between 1036 cm−1 and 996 cm−1, corresponding to Si-O-Si/Si-O-Al bands. Shifting vibration bands were seen at 1028 cm−1 to 1021 cm−1, indicating that the Si-O-Si/Si-O-Al bond is elongating, and the bond angle is decreasing. Based on the X-ray diffraction results, alkali-activated samples consist of an amorphous phase and residual mineral phases. The characteristic “hump” of an amorphous phase in the range from 20 to 40° 2θ was observed in FA and in all AWAFA samples. By the XRD patterns of the AAMs obtained by the activation of a solid three-component system, a new crystalline phase, gehlenite, was identified. The efficiency of AAMs in removing cadmium ions from aqueous solutions was tested under various conditions. The highest values of adsorption capacity, 64.76 mg/g (AWAFA6), 67.02 mg/g (AWAFAMK6), and 72.84 mg/g mg/g (AWAMK6), were obtained for materials activated with a 6 M NaOH solution in the alkali activator. The Langmuir adsorption isotherm and pseudo-second kinetic order provided the best fit for all investigated AAMs.
T2  - Gels
T1  - Adsorption Efficiency of Cadmium (II) by Different Alkali-Activated Materials
VL  - 10
IS  - 5
SP  - 317
DO  - 10.3390/gels10050317
ER  - 
@article{
author = "Mladenović Nikolić, Nataša and Kljajević, Ljiljana and Nenadović, Snežana S. and Potočnik, Jelena and Knežević, Sanja and Dolenec, Sabina and Trivunac, Katarina",
year = "2024",
abstract = "The objective of this study was to demonstrate the potential utilization of fly ash (FA), wood ash (WA), and metakaolin (MK) in developing new alkali-activated materials (AAMs) for the removal of cadmium ions from waste water. The synthesis of AAMs involved the dissolution of solid precursors, FA, WA, and MK, by a liquid activator (Na2SiO3 and NaOH). In concentrated solutions of the activator, the formation of an aluminosilicate gel structure occurred. DRIFT spectroscopy of the AAMs indicated main vibration bands between 1036 cm−1 and 996 cm−1, corresponding to Si-O-Si/Si-O-Al bands. Shifting vibration bands were seen at 1028 cm−1 to 1021 cm−1, indicating that the Si-O-Si/Si-O-Al bond is elongating, and the bond angle is decreasing. Based on the X-ray diffraction results, alkali-activated samples consist of an amorphous phase and residual mineral phases. The characteristic “hump” of an amorphous phase in the range from 20 to 40° 2θ was observed in FA and in all AWAFA samples. By the XRD patterns of the AAMs obtained by the activation of a solid three-component system, a new crystalline phase, gehlenite, was identified. The efficiency of AAMs in removing cadmium ions from aqueous solutions was tested under various conditions. The highest values of adsorption capacity, 64.76 mg/g (AWAFA6), 67.02 mg/g (AWAFAMK6), and 72.84 mg/g mg/g (AWAMK6), were obtained for materials activated with a 6 M NaOH solution in the alkali activator. The Langmuir adsorption isotherm and pseudo-second kinetic order provided the best fit for all investigated AAMs.",
journal = "Gels",
title = "Adsorption Efficiency of Cadmium (II) by Different Alkali-Activated Materials",
volume = "10",
number = "5",
pages = "317",
doi = "10.3390/gels10050317"
}
Mladenović Nikolić, N., Kljajević, L., Nenadović, S. S., Potočnik, J., Knežević, S., Dolenec, S.,& Trivunac, K.. (2024). Adsorption Efficiency of Cadmium (II) by Different Alkali-Activated Materials. in Gels, 10(5), 317.
https://doi.org/10.3390/gels10050317
Mladenović Nikolić N, Kljajević L, Nenadović SS, Potočnik J, Knežević S, Dolenec S, Trivunac K. Adsorption Efficiency of Cadmium (II) by Different Alkali-Activated Materials. in Gels. 2024;10(5):317.
doi:10.3390/gels10050317 .
Mladenović Nikolić, Nataša, Kljajević, Ljiljana, Nenadović, Snežana S., Potočnik, Jelena, Knežević, Sanja, Dolenec, Sabina, Trivunac, Katarina, "Adsorption Efficiency of Cadmium (II) by Different Alkali-Activated Materials" in Gels, 10, no. 5 (2024):317,
https://doi.org/10.3390/gels10050317 . .

Agates of the Lece Volcanic Complex (Serbia): Mineralogical and Geochemical Characteristics

Miladinović, Zoran; Simić, Vladimir; Nikolić, Nenad; Jović Orsini, Nataša; Rosić, Milena

(2024)

TY  - JOUR
AU  - Miladinović, Zoran
AU  - Simić, Vladimir
AU  - Nikolić, Nenad
AU  - Jović Orsini, Nataša
AU  - Rosić, Milena
PY  - 2024
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/13248
AB  - Agate veins and nodules occur in the Lece Volcanic Complex (Oligocene-Miocene) situated in the south of Serbia and occupying an area of 700 km2. This volcanic complex is composed predominantly of andesites, with sporadic occurrences of andesite-basalts, dacites and latites, and features agate formations that have been very little investigated. This study focuses on five selected agate occurrences within the Lece Volcanic Complex, employing optical microscopy, scanning electron microscopy (SEM), X-ray powder diffraction analysis, inductively coupled plasma mass spectrometry (ICP-MS), and Fourier transform infrared spectroscopy (FTIR). In three localities (Rasovača, Mehane, and Ždraljevići), agate mineralization is directly related to distinct fault zones with strong local brecciation. In the other two localities (Vlasovo and Sokolov Vis), the agate is found in nodular form and does not show any connection with fracture zones. The silica phases of the Lece volcanic agates consist of cristobalite and tridymite, length-fast chalcedony, quartzine (length-slow chalcedony), and macrocrystalline quartz. Vein agates show a frequent alternation between length-fast chalcedony and quartz bands. Nodular agates consist primarily of length-fast chalcedony, occasionally containing notable quantities of opal-CT, absent in vein agates. Microtextures present in vein agates include crustiform, colloform, comb, mosaic, flamboyant, and pseudo-bladed. Jigsaw puzzle quartz microtexture supports the recrystallization of previously deposited silica in the form of opal or chalcedony from hydrothermal fluids. Growth lines in euhedral quartz (Bambauer quartz) point to agate formations in varying physicochemical conditions. These features indicate epithermal conditions during the formation of hydrothermal vein agates. Due to intense hydrothermal activity, vein agate host rocks are intensively silicified. Vein agates are also enriched with typical ore metallic elements (especially Pb, Co, As, Sb, and W), indicating genetic relation with the formation of polymetallic ore deposits of the Lece Volcanic Complex. In contrast, nodular agates have a higher content of major elements of host rocks (Al2O3, MgO, CaO, Na2O, and K2O), most probably mobilized from volcanic host rocks. Organic matter, present in both vein and nodular agate with filamentous forms found only in nodular agate, suggests formation in near-surface conditions.
T2  - Minerals
T1  - Agates of the Lece Volcanic Complex (Serbia): Mineralogical and Geochemical Characteristics
VL  - 14
IS  - 5
SP  - 511
DO  - 10.3390/min14050511
ER  - 
@article{
author = "Miladinović, Zoran and Simić, Vladimir and Nikolić, Nenad and Jović Orsini, Nataša and Rosić, Milena",
year = "2024",
abstract = "Agate veins and nodules occur in the Lece Volcanic Complex (Oligocene-Miocene) situated in the south of Serbia and occupying an area of 700 km2. This volcanic complex is composed predominantly of andesites, with sporadic occurrences of andesite-basalts, dacites and latites, and features agate formations that have been very little investigated. This study focuses on five selected agate occurrences within the Lece Volcanic Complex, employing optical microscopy, scanning electron microscopy (SEM), X-ray powder diffraction analysis, inductively coupled plasma mass spectrometry (ICP-MS), and Fourier transform infrared spectroscopy (FTIR). In three localities (Rasovača, Mehane, and Ždraljevići), agate mineralization is directly related to distinct fault zones with strong local brecciation. In the other two localities (Vlasovo and Sokolov Vis), the agate is found in nodular form and does not show any connection with fracture zones. The silica phases of the Lece volcanic agates consist of cristobalite and tridymite, length-fast chalcedony, quartzine (length-slow chalcedony), and macrocrystalline quartz. Vein agates show a frequent alternation between length-fast chalcedony and quartz bands. Nodular agates consist primarily of length-fast chalcedony, occasionally containing notable quantities of opal-CT, absent in vein agates. Microtextures present in vein agates include crustiform, colloform, comb, mosaic, flamboyant, and pseudo-bladed. Jigsaw puzzle quartz microtexture supports the recrystallization of previously deposited silica in the form of opal or chalcedony from hydrothermal fluids. Growth lines in euhedral quartz (Bambauer quartz) point to agate formations in varying physicochemical conditions. These features indicate epithermal conditions during the formation of hydrothermal vein agates. Due to intense hydrothermal activity, vein agate host rocks are intensively silicified. Vein agates are also enriched with typical ore metallic elements (especially Pb, Co, As, Sb, and W), indicating genetic relation with the formation of polymetallic ore deposits of the Lece Volcanic Complex. In contrast, nodular agates have a higher content of major elements of host rocks (Al2O3, MgO, CaO, Na2O, and K2O), most probably mobilized from volcanic host rocks. Organic matter, present in both vein and nodular agate with filamentous forms found only in nodular agate, suggests formation in near-surface conditions.",
journal = "Minerals",
title = "Agates of the Lece Volcanic Complex (Serbia): Mineralogical and Geochemical Characteristics",
volume = "14",
number = "5",
pages = "511",
doi = "10.3390/min14050511"
}
Miladinović, Z., Simić, V., Nikolić, N., Jović Orsini, N.,& Rosić, M.. (2024). Agates of the Lece Volcanic Complex (Serbia): Mineralogical and Geochemical Characteristics. in Minerals, 14(5), 511.
https://doi.org/10.3390/min14050511
Miladinović Z, Simić V, Nikolić N, Jović Orsini N, Rosić M. Agates of the Lece Volcanic Complex (Serbia): Mineralogical and Geochemical Characteristics. in Minerals. 2024;14(5):511.
doi:10.3390/min14050511 .
Miladinović, Zoran, Simić, Vladimir, Nikolić, Nenad, Jović Orsini, Nataša, Rosić, Milena, "Agates of the Lece Volcanic Complex (Serbia): Mineralogical and Geochemical Characteristics" in Minerals, 14, no. 5 (2024):511,
https://doi.org/10.3390/min14050511 . .

Carbon nitride impregnated non-woven jute post-industrial waste in photocatalytic degradation of textile dyes

Carević, Milica; Vulić, Tatjana; Šaponjić, Zoran; Mojović, Zorica D.; Abazović, Nadica; Čomor, Mirjana

(2024)

TY  - JOUR
AU  - Carević, Milica
AU  - Vulić, Tatjana
AU  - Šaponjić, Zoran
AU  - Mojović, Zorica D.
AU  - Abazović, Nadica
AU  - Čomor, Mirjana
PY  - 2024
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/13240
AB  - Textile dye effluents and textile waste disposal represent two significant environmental challenges. Here, we present possible combined solution for both. Urea-derived graphitic carbon nitride g-C3N4 is thermally exfoliated to nano n-C3N4. Both obtained materials are characterized in detail, and their photocatalytic efficacies in photodegradation of three textile azo dyes under simulated solar light irradiation are compared. n-C3N4 exhibited superior performance over g-C3N4 under given experimental conditions. Novelty of the work is the subsequent usage of the non-woven jute post-industrial waste as a photocatalyst support. It was shown that NW jute impregnated with n-C3N4 can be successfully used in three consecutive photocatalytic cycles, keeping high photodegradation efficacy (~ 90% in the case of Acid Orange 7, and 55% in the case of Acid Blue 113). Additionally, possibility of usage of NW jute post-industrial waste as textile dye sorbent is presented in the case of Basic Yellow 28.
T2  - Cellulose
T1  - Carbon nitride impregnated non-woven jute post-industrial waste in photocatalytic degradation of textile dyes
DO  - 10.1007/s10570-024-05908-7
ER  - 
@article{
author = "Carević, Milica and Vulić, Tatjana and Šaponjić, Zoran and Mojović, Zorica D. and Abazović, Nadica and Čomor, Mirjana",
year = "2024",
abstract = "Textile dye effluents and textile waste disposal represent two significant environmental challenges. Here, we present possible combined solution for both. Urea-derived graphitic carbon nitride g-C3N4 is thermally exfoliated to nano n-C3N4. Both obtained materials are characterized in detail, and their photocatalytic efficacies in photodegradation of three textile azo dyes under simulated solar light irradiation are compared. n-C3N4 exhibited superior performance over g-C3N4 under given experimental conditions. Novelty of the work is the subsequent usage of the non-woven jute post-industrial waste as a photocatalyst support. It was shown that NW jute impregnated with n-C3N4 can be successfully used in three consecutive photocatalytic cycles, keeping high photodegradation efficacy (~ 90% in the case of Acid Orange 7, and 55% in the case of Acid Blue 113). Additionally, possibility of usage of NW jute post-industrial waste as textile dye sorbent is presented in the case of Basic Yellow 28.",
journal = "Cellulose",
title = "Carbon nitride impregnated non-woven jute post-industrial waste in photocatalytic degradation of textile dyes",
doi = "10.1007/s10570-024-05908-7"
}
Carević, M., Vulić, T., Šaponjić, Z., Mojović, Z. D., Abazović, N.,& Čomor, M.. (2024). Carbon nitride impregnated non-woven jute post-industrial waste in photocatalytic degradation of textile dyes. in Cellulose.
https://doi.org/10.1007/s10570-024-05908-7
Carević M, Vulić T, Šaponjić Z, Mojović ZD, Abazović N, Čomor M. Carbon nitride impregnated non-woven jute post-industrial waste in photocatalytic degradation of textile dyes. in Cellulose. 2024;.
doi:10.1007/s10570-024-05908-7 .
Carević, Milica, Vulić, Tatjana, Šaponjić, Zoran, Mojović, Zorica D., Abazović, Nadica, Čomor, Mirjana, "Carbon nitride impregnated non-woven jute post-industrial waste in photocatalytic degradation of textile dyes" in Cellulose (2024),
https://doi.org/10.1007/s10570-024-05908-7 . .

Comparison of some of the analytical techniques and their applications to environmental radiostrontium determination

Sarap, Nataša; Nodilo, Marijana; Štrok, Marko; Grahek, Željko; Janković, Marija

(2024)

TY  - JOUR
AU  - Sarap, Nataša
AU  - Nodilo, Marijana
AU  - Štrok, Marko
AU  - Grahek, Željko
AU  - Janković, Marija
PY  - 2024
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/13241
AB  - he knowledge about behavior of 90Sr in environment is of importance to prevent and control contamination. A large number of analytical methods have been developed for the determination of 90Sr in environmental samples. The conducted study was focused on interpretation and evaluation of the results obtained using three radiochemical procedures for the separation of 90Sr and/or 90Y including the classical procedures based on a series of semi-selective precipitations, the ion-exchange procedure and the use of fuming nitric acid. The acquired results showed a good agreement between the compared methods within the terms of accuracy and precision.
T2  - Journal of Radioanalytical and Nuclear Chemistry
T1  - Comparison of some of the analytical techniques and their applications to environmental radiostrontium determination
DO  - 10.1007/s10967-024-09499-2
ER  - 
@article{
author = "Sarap, Nataša and Nodilo, Marijana and Štrok, Marko and Grahek, Željko and Janković, Marija",
year = "2024",
abstract = "he knowledge about behavior of 90Sr in environment is of importance to prevent and control contamination. A large number of analytical methods have been developed for the determination of 90Sr in environmental samples. The conducted study was focused on interpretation and evaluation of the results obtained using three radiochemical procedures for the separation of 90Sr and/or 90Y including the classical procedures based on a series of semi-selective precipitations, the ion-exchange procedure and the use of fuming nitric acid. The acquired results showed a good agreement between the compared methods within the terms of accuracy and precision.",
journal = "Journal of Radioanalytical and Nuclear Chemistry",
title = "Comparison of some of the analytical techniques and their applications to environmental radiostrontium determination",
doi = "10.1007/s10967-024-09499-2"
}
Sarap, N., Nodilo, M., Štrok, M., Grahek, Ž.,& Janković, M.. (2024). Comparison of some of the analytical techniques and their applications to environmental radiostrontium determination. in Journal of Radioanalytical and Nuclear Chemistry.
https://doi.org/10.1007/s10967-024-09499-2
Sarap N, Nodilo M, Štrok M, Grahek Ž, Janković M. Comparison of some of the analytical techniques and their applications to environmental radiostrontium determination. in Journal of Radioanalytical and Nuclear Chemistry. 2024;.
doi:10.1007/s10967-024-09499-2 .
Sarap, Nataša, Nodilo, Marijana, Štrok, Marko, Grahek, Željko, Janković, Marija, "Comparison of some of the analytical techniques and their applications to environmental radiostrontium determination" in Journal of Radioanalytical and Nuclear Chemistry (2024),
https://doi.org/10.1007/s10967-024-09499-2 . .

Bipyraloxifene – a modified raloxifene vector against triple-negative breast cancer

Kazimir, Aleksandr; Götze, Tom; Murganić, Blagoje; Mijatović, Sanja; Maksimović-Ivanić, Danijela; Hey-Hawkins, Evamarie

(2024)

TY  - JOUR
AU  - Kazimir, Aleksandr
AU  - Götze, Tom
AU  - Murganić, Blagoje
AU  - Mijatović, Sanja
AU  - Maksimović-Ivanić, Danijela
AU  - Hey-Hawkins, Evamarie
PY  - 2024
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/13242
AB  - Raloxifene, a selective oestrogen receptor modulator (SERM), has demonstrated efficacy in the prevention and therapy of oestrogen receptor-positive (ER+) breast cancer, with some degree of effectiveness against triple-negative forms. This suggests the presence of oestrogen receptor-independent pathways in raloxifene-mediated anticancer activity. To enhance the potential of raloxifene against the most aggressive breast cancer cells, hybrid molecules combining the drug with a metal chelator moiety have been developed. In this study, we synthetically modified the structure of raloxifene by incorporating a 2,2′-bipyridine (2,2′-bipy) moiety, resulting in [6-methoxy-2-(4-hydroxyphenyl)benzo[b]thiophen-3-yl]-[4-(2,2′-bipyridin-4′-yl-methoxy)phenyl]methanone (bipyraloxifene). We investigated the cytotoxic activity of both raloxifene and bipyraloxifene against ER+ breast adenocarcinomas, glioblastomas, and a triple-negative breast cancer (TNBC) cell line, elucidating their mode of action against TNBC. Bipyraloxifene maintained a mechanism based on caspase-mediated apoptosis but exhibited significantly higher activity and selectivity compared to the original drug, particularly evident in triple-negative stem-like MDA-MB-231 cells.
T2  - RSC Medicinal Chemistry
T1  - Bipyraloxifene – a modified raloxifene vector against triple-negative breast cancer
DO  - 10.1039/D4MD00051J
ER  - 
@article{
author = "Kazimir, Aleksandr and Götze, Tom and Murganić, Blagoje and Mijatović, Sanja and Maksimović-Ivanić, Danijela and Hey-Hawkins, Evamarie",
year = "2024",
abstract = "Raloxifene, a selective oestrogen receptor modulator (SERM), has demonstrated efficacy in the prevention and therapy of oestrogen receptor-positive (ER+) breast cancer, with some degree of effectiveness against triple-negative forms. This suggests the presence of oestrogen receptor-independent pathways in raloxifene-mediated anticancer activity. To enhance the potential of raloxifene against the most aggressive breast cancer cells, hybrid molecules combining the drug with a metal chelator moiety have been developed. In this study, we synthetically modified the structure of raloxifene by incorporating a 2,2′-bipyridine (2,2′-bipy) moiety, resulting in [6-methoxy-2-(4-hydroxyphenyl)benzo[b]thiophen-3-yl]-[4-(2,2′-bipyridin-4′-yl-methoxy)phenyl]methanone (bipyraloxifene). We investigated the cytotoxic activity of both raloxifene and bipyraloxifene against ER+ breast adenocarcinomas, glioblastomas, and a triple-negative breast cancer (TNBC) cell line, elucidating their mode of action against TNBC. Bipyraloxifene maintained a mechanism based on caspase-mediated apoptosis but exhibited significantly higher activity and selectivity compared to the original drug, particularly evident in triple-negative stem-like MDA-MB-231 cells.",
journal = "RSC Medicinal Chemistry",
title = "Bipyraloxifene – a modified raloxifene vector against triple-negative breast cancer",
doi = "10.1039/D4MD00051J"
}
Kazimir, A., Götze, T., Murganić, B., Mijatović, S., Maksimović-Ivanić, D.,& Hey-Hawkins, E.. (2024). Bipyraloxifene – a modified raloxifene vector against triple-negative breast cancer. in RSC Medicinal Chemistry.
https://doi.org/10.1039/D4MD00051J
Kazimir A, Götze T, Murganić B, Mijatović S, Maksimović-Ivanić D, Hey-Hawkins E. Bipyraloxifene – a modified raloxifene vector against triple-negative breast cancer. in RSC Medicinal Chemistry. 2024;.
doi:10.1039/D4MD00051J .
Kazimir, Aleksandr, Götze, Tom, Murganić, Blagoje, Mijatović, Sanja, Maksimović-Ivanić, Danijela, Hey-Hawkins, Evamarie, "Bipyraloxifene – a modified raloxifene vector against triple-negative breast cancer" in RSC Medicinal Chemistry (2024),
https://doi.org/10.1039/D4MD00051J . .

POV-based molecular catalysts for highly efficient esterification of alcohols with aldehydes as acylating agents

Wu, Zhikang; Dai, Guoyong; Li, Qi; Wei, Zheyu; Ru, Shi; Li, Jianda; Jia, Hongli; Zang, Dejin; Čolović, Mirjana; Wei, Yongge

(2024)

TY  - JOUR
AU  - Wu, Zhikang
AU  - Dai, Guoyong
AU  - Li, Qi
AU  - Wei, Zheyu
AU  - Ru, Shi
AU  - Li, Jianda
AU  - Jia, Hongli
AU  - Zang, Dejin
AU  - Čolović, Mirjana
AU  - Wei, Yongge
PY  - 2024
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/12920
AB  - The selective oxidative esterification of aldehydes with alcohols to the corresponding esters has been one of the hot spots in scientific research and industrial synthesis. However, the application of precious metal catalytic systems is limited by their complicated synthetic steps and high cost. Thus a highly efficient, green, recyclable selective synthesis method of esters catalyzed by POV(polyoxovanadate)-based molecular catalysts has been developed in this paper. The results show that supramolecular interaction between POV and 1,3-dibenzylimidazolium bromide (Act2Im) can efficiently convert alcohols and aldehydes to the corresponding esters in high yield under much milder conditions. Mechanistic insight is also provided based on the control experiments, single crystal X-ray diffraction and cyclic voltammetry studies.
T2  - Chinese Chemical Letters
T1  - POV-based molecular catalysts for highly efficient esterification of alcohols with aldehydes as acylating agents
VL  - 35
IS  - 8
SP  - 109061
DO  - 10.1016/j.cclet.2023.109061
ER  - 
@article{
author = "Wu, Zhikang and Dai, Guoyong and Li, Qi and Wei, Zheyu and Ru, Shi and Li, Jianda and Jia, Hongli and Zang, Dejin and Čolović, Mirjana and Wei, Yongge",
year = "2024",
abstract = "The selective oxidative esterification of aldehydes with alcohols to the corresponding esters has been one of the hot spots in scientific research and industrial synthesis. However, the application of precious metal catalytic systems is limited by their complicated synthetic steps and high cost. Thus a highly efficient, green, recyclable selective synthesis method of esters catalyzed by POV(polyoxovanadate)-based molecular catalysts has been developed in this paper. The results show that supramolecular interaction between POV and 1,3-dibenzylimidazolium bromide (Act2Im) can efficiently convert alcohols and aldehydes to the corresponding esters in high yield under much milder conditions. Mechanistic insight is also provided based on the control experiments, single crystal X-ray diffraction and cyclic voltammetry studies.",
journal = "Chinese Chemical Letters",
title = "POV-based molecular catalysts for highly efficient esterification of alcohols with aldehydes as acylating agents",
volume = "35",
number = "8",
pages = "109061",
doi = "10.1016/j.cclet.2023.109061"
}
Wu, Z., Dai, G., Li, Q., Wei, Z., Ru, S., Li, J., Jia, H., Zang, D., Čolović, M.,& Wei, Y.. (2024). POV-based molecular catalysts for highly efficient esterification of alcohols with aldehydes as acylating agents. in Chinese Chemical Letters, 35(8), 109061.
https://doi.org/10.1016/j.cclet.2023.109061
Wu Z, Dai G, Li Q, Wei Z, Ru S, Li J, Jia H, Zang D, Čolović M, Wei Y. POV-based molecular catalysts for highly efficient esterification of alcohols with aldehydes as acylating agents. in Chinese Chemical Letters. 2024;35(8):109061.
doi:10.1016/j.cclet.2023.109061 .
Wu, Zhikang, Dai, Guoyong, Li, Qi, Wei, Zheyu, Ru, Shi, Li, Jianda, Jia, Hongli, Zang, Dejin, Čolović, Mirjana, Wei, Yongge, "POV-based molecular catalysts for highly efficient esterification of alcohols with aldehydes as acylating agents" in Chinese Chemical Letters, 35, no. 8 (2024):109061,
https://doi.org/10.1016/j.cclet.2023.109061 . .
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