New industrial and environmental application of chemical thermodynamics to the development of the chemical processes with multiphase and multicomponent systems

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New industrial and environmental application of chemical thermodynamics to the development of the chemical processes with multiphase and multicomponent systems (en)
Нови индустријски и еколошки аспекти примене хемијске термодинамике на унапређење хемијских процеса са вишефазним и вишекомпонентним системима (sr)
Novi industrijski i ekološki aspekti primene hemijske termodinamike na unapređenje hemijskih procesa sa višefaznim i višekomponentnim sistemima (sr_RS)
Authors

Publications

Volumetric and Viscometric Study of 1-Hexanol-Based Binary Systems: Experimental Determination and Modeling

Živković, Nikola V.; Majstorović, Divna M.; Kijevčanin, Mirjana Lj.; Živković, Emila M.

(2020)

TY  - JOUR
AU  - Živković, Nikola V.
AU  - Majstorović, Divna M.
AU  - Kijevčanin, Mirjana Lj.
AU  - Živković, Emila M.
PY  - 2020
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/9032
AB  - Density, viscosity, and refractive index of four binary mixtures with 1-hexanol are experimentally determined at seven temperatures, in the temperature range from 288.15 to 318.15 K and at atmospheric pressure. The choice of mixtures was based on their potential for applications in flue gas cleaning processes. From experimental data, excess molar volume, viscosity deviation, excess molar Gibbs free energy of activation of viscous flow, deviation in refractive index, and partial and excess partial molar volumes are calculated, correlated with the Redlich-Kister equation, and used for better understanding of molecular interactions between the mixture components. Since the mixtures were investigated both from the theoretical point of view and with the aspect for practical applications, modeling of two key properties, viscosity and excess molar volume, was performed with different models and approaches and the results are compared with experimental values.
T2  - Journal of Chemical & Engineering Data
T1  - Volumetric and Viscometric Study of 1-Hexanol-Based Binary Systems: Experimental Determination and Modeling
VL  - 65
IS  - 6
SP  - 3044
EP  - 3062
DO  - 10.1021/acs.jced.0c00083
ER  - 
@article{
author = "Živković, Nikola V. and Majstorović, Divna M. and Kijevčanin, Mirjana Lj. and Živković, Emila M.",
year = "2020",
abstract = "Density, viscosity, and refractive index of four binary mixtures with 1-hexanol are experimentally determined at seven temperatures, in the temperature range from 288.15 to 318.15 K and at atmospheric pressure. The choice of mixtures was based on their potential for applications in flue gas cleaning processes. From experimental data, excess molar volume, viscosity deviation, excess molar Gibbs free energy of activation of viscous flow, deviation in refractive index, and partial and excess partial molar volumes are calculated, correlated with the Redlich-Kister equation, and used for better understanding of molecular interactions between the mixture components. Since the mixtures were investigated both from the theoretical point of view and with the aspect for practical applications, modeling of two key properties, viscosity and excess molar volume, was performed with different models and approaches and the results are compared with experimental values.",
journal = "Journal of Chemical & Engineering Data",
title = "Volumetric and Viscometric Study of 1-Hexanol-Based Binary Systems: Experimental Determination and Modeling",
volume = "65",
number = "6",
pages = "3044-3062",
doi = "10.1021/acs.jced.0c00083"
}
Živković, N. V., Majstorović, D. M., Kijevčanin, M. Lj.,& Živković, E. M.. (2020). Volumetric and Viscometric Study of 1-Hexanol-Based Binary Systems: Experimental Determination and Modeling. in Journal of Chemical & Engineering Data, 65(6), 3044-3062.
https://doi.org/10.1021/acs.jced.0c00083
Živković NV, Majstorović DM, Kijevčanin ML, Živković EM. Volumetric and Viscometric Study of 1-Hexanol-Based Binary Systems: Experimental Determination and Modeling. in Journal of Chemical & Engineering Data. 2020;65(6):3044-3062.
doi:10.1021/acs.jced.0c00083 .
Živković, Nikola V., Majstorović, Divna M., Kijevčanin, Mirjana Lj., Živković, Emila M., "Volumetric and Viscometric Study of 1-Hexanol-Based Binary Systems: Experimental Determination and Modeling" in Journal of Chemical & Engineering Data, 65, no. 6 (2020):3044-3062,
https://doi.org/10.1021/acs.jced.0c00083 . .
4
2
3

Supporting information: Volumetric and Viscometric Study of 1-Hexanol-Based Binary Systems: Experimental Determination and Modeling

Živković, Nikola V.; Majstorović, Divna M.; Kijevčanin, Mirjana Lj.; Živković, Emila M.

(2020)

TY  - DATA
AU  - Živković, Nikola V.
AU  - Majstorović, Divna M.
AU  - Kijevčanin, Mirjana Lj.
AU  - Živković, Emila M.
PY  - 2020
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/9037
AB  - Supporting Information for the article: Živković, N. V., Majstorović, D. M., Kijevčanin, M. Lj.,& Živković, E. M. (2020). Volumetric and Viscometric Study of 1-Hexanol-Based Binary Systems: Experimental Determination and Modeling. Journal of Chemical & Engineering Data, 65(6), 3044-3062. [https://doi.org/10.1021/acs.jced.0c00083]
T2  - Journal of Chemical & Engineering Data
T1  - Supporting information: Volumetric and Viscometric Study of 1-Hexanol-Based Binary Systems: Experimental Determination and Modeling
VL  - 65
IS  - 6
SP  - 3044
EP  - 3062
DO  - 10.1021/acs.jced.0c00083
ER  - 
@misc{
author = "Živković, Nikola V. and Majstorović, Divna M. and Kijevčanin, Mirjana Lj. and Živković, Emila M.",
year = "2020",
abstract = "Supporting Information for the article: Živković, N. V., Majstorović, D. M., Kijevčanin, M. Lj.,& Živković, E. M. (2020). Volumetric and Viscometric Study of 1-Hexanol-Based Binary Systems: Experimental Determination and Modeling. Journal of Chemical & Engineering Data, 65(6), 3044-3062. [https://doi.org/10.1021/acs.jced.0c00083]",
journal = "Journal of Chemical & Engineering Data",
title = "Supporting information: Volumetric and Viscometric Study of 1-Hexanol-Based Binary Systems: Experimental Determination and Modeling",
volume = "65",
number = "6",
pages = "3044-3062",
doi = "10.1021/acs.jced.0c00083"
}
Živković, N. V., Majstorović, D. M., Kijevčanin, M. Lj.,& Živković, E. M.. (2020). Supporting information: Volumetric and Viscometric Study of 1-Hexanol-Based Binary Systems: Experimental Determination and Modeling. in Journal of Chemical & Engineering Data, 65(6), 3044-3062.
https://doi.org/10.1021/acs.jced.0c00083
Živković NV, Majstorović DM, Kijevčanin ML, Živković EM. Supporting information: Volumetric and Viscometric Study of 1-Hexanol-Based Binary Systems: Experimental Determination and Modeling. in Journal of Chemical & Engineering Data. 2020;65(6):3044-3062.
doi:10.1021/acs.jced.0c00083 .
Živković, Nikola V., Majstorović, Divna M., Kijevčanin, Mirjana Lj., Živković, Emila M., "Supporting information: Volumetric and Viscometric Study of 1-Hexanol-Based Binary Systems: Experimental Determination and Modeling" in Journal of Chemical & Engineering Data, 65, no. 6 (2020):3044-3062,
https://doi.org/10.1021/acs.jced.0c00083 . .
4
2
3

Instrument za određivanje toplotne provodljivosti tečnih fluida na atmosferskom pritisku

Stanimirović, Andrej; Živković, Emila; Majstorović, Divna; Kijevčanin, Mirjana; Živković, Nikola

(2019)


                                            

                                            
Stanimirović, A., Živković, E., Majstorović, D., Kijevčanin, M.,& Živković, N.. (2019). Instrument za određivanje toplotne provodljivosti tečnih fluida na atmosferskom pritisku. in Univerzitet u Beogradu : Tehnološko-metalurški fakultet : Katedra za hemijsko inženjerstvo.
https://hdl.handle.net/21.15107/rcub_vinar_12109
Stanimirović A, Živković E, Majstorović D, Kijevčanin M, Živković N. Instrument za određivanje toplotne provodljivosti tečnih fluida na atmosferskom pritisku. in Univerzitet u Beogradu : Tehnološko-metalurški fakultet : Katedra za hemijsko inženjerstvo. 2019;.
https://hdl.handle.net/21.15107/rcub_vinar_12109 .
Stanimirović, Andrej, Živković, Emila, Majstorović, Divna, Kijevčanin, Mirjana, Živković, Nikola, "Instrument za određivanje toplotne provodljivosti tečnih fluida na atmosferskom pritisku" in Univerzitet u Beogradu : Tehnološko-metalurški fakultet : Katedra za hemijsko inženjerstvo (2019),
https://hdl.handle.net/21.15107/rcub_vinar_12109 .

Viscosity of binary mixture DMA + 2-butanol with potential use as solvent for regenerative flue gas desulfurization processes

Majstorović, Divna; Živković, Nikola; Kijevčanin, Mirjana; Živković, Emila

(Beograd : Savez mašinskih i elektrotehničkih inženjera i tehničara Srbije (SMEITS), 2019)

TY  - CONF
AU  - Majstorović, Divna
AU  - Živković, Nikola
AU  - Kijevčanin, Mirjana
AU  - Živković, Emila
PY  - 2019
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/12116
AB  - Sulfur dioxide (SO2) is an environmental pollutant with multiple harmful effects on biological world. One of the main emission sources are industrial activities in thermal power plants, foundries and steel mills which involve combustion of fossil fuels containing sulfur, such as coal and oil. Initial step towards removal of SO2from flue gases was the so-called limestone process, a wet non-regenerative process that even today is the mostused flue gas desulfurization method. However, wet regenerative processes with gas absorption in liquid organic solvent and thermal regeneration recently have found practical application. Processes based on n,n-dimethylaniline (DMA) have alre-ady been patented and industrially applied. This solvent has high selectivity towards SO2in compa-rison  to  the  other  components  of  flue  gas  like  CO2,  and  excellent  binding  capability  by  the 214• 32ndINTERNATIONAL CONGRESS ON PROCESS INDUSTRYmechanisms of chemical absorption, but main disadvantage is its high toxicity. On the other hand, in more ambient friendly 2-butanol binding of sulfur-dioxide occurs by means of physical absorption. Investigations have shown that mixtures of physical and chemical solvents usually show better cha-racteristics regarding binding capacityand selectivity than traditionally used aqueous solutions of amines, due to the synergetic effect.One  of  the  most  important  thermophysical  properties  of  solvents,  necessary  for  process  and equipment  design  is  dynamic  viscosity.  In  this  investigation  viscosity  of  binary  mixture  DMA  +  2-butanol  is  experimentally  determined  in  temperature  and  concentration  range  and  correlated afterwards  using  different  literature  models.  These  correlations  present  useful  method  to  acquire reliable data necessary for fluid flow analysis and mass and heat transfer calculations, since experi-mental values for desired process conditions are often not available. In this study, two or three-pa-rameter  Eyring-UNIQUAC,  Eyring-NRTL  and  McAllister  models  were  used,  while  model  that  co-uples Eyring equation, Peng-Robinson equation of state and van der Waals mixing rule, was tested for simultaneous calculation of density and viscosity. The obtained results are presented and discu-ssed regarding potential application, limitations and complexity of used approach and models.
AB  - Sumpor dioksid (SO2) je zagađivač životne sredine sa višestrukim štetnim efektima na biološki svet. Jedan od glavnih izvora emisije su industrijske aktivnosti u termoelektranama, livnicama i železarama, koje uključuju sagorevanje fosilnih goriva koja sadrže sumpor, kao što su ugalj i nafta.   Početni korak u uklanjanju SO2 iz dimnih gasova bio je takozvani krečnjački postupak, mokri neregenerativni proces koji je i danas najčešće korišćen metod odsumporavanja dimnih gasova. Međutim, mokri regenerativni procesi sa apsorpcijom gasa u tečnom organskom rastvaraču i termalnom regeneracijom nedavno su našli praktičnu primenu. Procesi zasnovani na n,n-dimetilanilinu (DMA) su već patentirani i industrijski primenjeni. Ovaj rastvarač ima visoku selektivnost prema SO2 u poređenju sa drugim komponentama dimnog gasa kao što je CO2, i odličnu sposobnost vezivanja mehanizmima hemijske apsorpcije, ali glavni nedostatak je visoka toksičnost. S druge strane, u, sa stanovišta životne sredine prihvatljivijem, 2-butanolu do vezivanja sumpor-dioksida dolazi fizičkom apsorpcijom. Istraživanja su pokazala da smeše fizičkih i hemijskih rastvarača obično pokazuju bolje karakteristike u pogledu mogućnosti vezivanja i selektivnosti od tradicionalno korišćenih vodenih rastvora amina, zbog sinergetskog efekta.   Jedno od najvažnijih termofizičkih svojstava rastvarača, neophodno za simulaciju procesa i proračun opreme, je dinamička viskoznost. U ovom istraživanju, viskoznost binarne smeše DMA + 2-butanol eksperimentalno je određena u temperaturnom i koncentracionom opsegu i nakon toga korelisana korišćenjem različitih literaturnih modela. Ove korelacije predstavljaju korisnu metodu za dobijanje pouzdanih podataka potrebnih za analizu protoka fluida i proračune prenosa mase i toplote, jer eksperimentalne vrednosti za željene uslove procesa često nisu dostupne. U ovom istraživanju korišćeni su dvo- ili troparametarski modeli Eyring-UNIQUAC, Eyring-NRTL i McAllister, dok je model koji povezuje Eyring jednačinu, Peng-Robinson jednačinu stanja i van der Waals pravilo mešanja testiran za istovremeno izračunavanje gustine i viskoznosti. Dobijeni rezultati su prikazani i diskutovani u pogledu potencijalne primene, ograničenja i složenosti korišćenog pristupa i modela.
PB  - Beograd : Savez mašinskih i elektrotehničkih inženjera i tehničara Srbije (SMEITS)
PB  - Beograd : Društvo za procesnu tehniku
C3  - Processing '19 : zbornik radova za 32. Međunarodni kongres o procesnoj industriji
T1  - Viscosity of binary mixture DMA + 2-butanol with potential use as solvent  for regenerative flue gas desulfurization processes
T1  - Viskoznost binarne smeše DMA + 2-butanol za potencijalnu upotrebu kao rastvarača za regenerativne procese odsumporavanja dimnih gasova
SP  - 213
EP  - 218
DO  - 10.24094/ptk.019.32.1.213
ER  - 
@conference{
author = "Majstorović, Divna and Živković, Nikola and Kijevčanin, Mirjana and Živković, Emila",
year = "2019",
abstract = "Sulfur dioxide (SO2) is an environmental pollutant with multiple harmful effects on biological world. One of the main emission sources are industrial activities in thermal power plants, foundries and steel mills which involve combustion of fossil fuels containing sulfur, such as coal and oil. Initial step towards removal of SO2from flue gases was the so-called limestone process, a wet non-regenerative process that even today is the mostused flue gas desulfurization method. However, wet regenerative processes with gas absorption in liquid organic solvent and thermal regeneration recently have found practical application. Processes based on n,n-dimethylaniline (DMA) have alre-ady been patented and industrially applied. This solvent has high selectivity towards SO2in compa-rison  to  the  other  components  of  flue  gas  like  CO2,  and  excellent  binding  capability  by  the 214• 32ndINTERNATIONAL CONGRESS ON PROCESS INDUSTRYmechanisms of chemical absorption, but main disadvantage is its high toxicity. On the other hand, in more ambient friendly 2-butanol binding of sulfur-dioxide occurs by means of physical absorption. Investigations have shown that mixtures of physical and chemical solvents usually show better cha-racteristics regarding binding capacityand selectivity than traditionally used aqueous solutions of amines, due to the synergetic effect.One  of  the  most  important  thermophysical  properties  of  solvents,  necessary  for  process  and equipment  design  is  dynamic  viscosity.  In  this  investigation  viscosity  of  binary  mixture  DMA  +  2-butanol  is  experimentally  determined  in  temperature  and  concentration  range  and  correlated afterwards  using  different  literature  models.  These  correlations  present  useful  method  to  acquire reliable data necessary for fluid flow analysis and mass and heat transfer calculations, since experi-mental values for desired process conditions are often not available. In this study, two or three-pa-rameter  Eyring-UNIQUAC,  Eyring-NRTL  and  McAllister  models  were  used,  while  model  that  co-uples Eyring equation, Peng-Robinson equation of state and van der Waals mixing rule, was tested for simultaneous calculation of density and viscosity. The obtained results are presented and discu-ssed regarding potential application, limitations and complexity of used approach and models., Sumpor dioksid (SO2) je zagađivač životne sredine sa višestrukim štetnim efektima na biološki svet. Jedan od glavnih izvora emisije su industrijske aktivnosti u termoelektranama, livnicama i železarama, koje uključuju sagorevanje fosilnih goriva koja sadrže sumpor, kao što su ugalj i nafta.   Početni korak u uklanjanju SO2 iz dimnih gasova bio je takozvani krečnjački postupak, mokri neregenerativni proces koji je i danas najčešće korišćen metod odsumporavanja dimnih gasova. Međutim, mokri regenerativni procesi sa apsorpcijom gasa u tečnom organskom rastvaraču i termalnom regeneracijom nedavno su našli praktičnu primenu. Procesi zasnovani na n,n-dimetilanilinu (DMA) su već patentirani i industrijski primenjeni. Ovaj rastvarač ima visoku selektivnost prema SO2 u poređenju sa drugim komponentama dimnog gasa kao što je CO2, i odličnu sposobnost vezivanja mehanizmima hemijske apsorpcije, ali glavni nedostatak je visoka toksičnost. S druge strane, u, sa stanovišta životne sredine prihvatljivijem, 2-butanolu do vezivanja sumpor-dioksida dolazi fizičkom apsorpcijom. Istraživanja su pokazala da smeše fizičkih i hemijskih rastvarača obično pokazuju bolje karakteristike u pogledu mogućnosti vezivanja i selektivnosti od tradicionalno korišćenih vodenih rastvora amina, zbog sinergetskog efekta.   Jedno od najvažnijih termofizičkih svojstava rastvarača, neophodno za simulaciju procesa i proračun opreme, je dinamička viskoznost. U ovom istraživanju, viskoznost binarne smeše DMA + 2-butanol eksperimentalno je određena u temperaturnom i koncentracionom opsegu i nakon toga korelisana korišćenjem različitih literaturnih modela. Ove korelacije predstavljaju korisnu metodu za dobijanje pouzdanih podataka potrebnih za analizu protoka fluida i proračune prenosa mase i toplote, jer eksperimentalne vrednosti za željene uslove procesa često nisu dostupne. U ovom istraživanju korišćeni su dvo- ili troparametarski modeli Eyring-UNIQUAC, Eyring-NRTL i McAllister, dok je model koji povezuje Eyring jednačinu, Peng-Robinson jednačinu stanja i van der Waals pravilo mešanja testiran za istovremeno izračunavanje gustine i viskoznosti. Dobijeni rezultati su prikazani i diskutovani u pogledu potencijalne primene, ograničenja i složenosti korišćenog pristupa i modela.",
publisher = "Beograd : Savez mašinskih i elektrotehničkih inženjera i tehničara Srbije (SMEITS), Beograd : Društvo za procesnu tehniku",
journal = "Processing '19 : zbornik radova za 32. Međunarodni kongres o procesnoj industriji",
title = "Viscosity of binary mixture DMA + 2-butanol with potential use as solvent  for regenerative flue gas desulfurization processes, Viskoznost binarne smeše DMA + 2-butanol za potencijalnu upotrebu kao rastvarača za regenerativne procese odsumporavanja dimnih gasova",
pages = "213-218",
doi = "10.24094/ptk.019.32.1.213"
}
Majstorović, D., Živković, N., Kijevčanin, M.,& Živković, E.. (2019). Viscosity of binary mixture DMA + 2-butanol with potential use as solvent  for regenerative flue gas desulfurization processes. in Processing '19 : zbornik radova za 32. Međunarodni kongres o procesnoj industriji
Beograd : Savez mašinskih i elektrotehničkih inženjera i tehničara Srbije (SMEITS)., 213-218.
https://doi.org/10.24094/ptk.019.32.1.213
Majstorović D, Živković N, Kijevčanin M, Živković E. Viscosity of binary mixture DMA + 2-butanol with potential use as solvent  for regenerative flue gas desulfurization processes. in Processing '19 : zbornik radova za 32. Međunarodni kongres o procesnoj industriji. 2019;:213-218.
doi:10.24094/ptk.019.32.1.213 .
Majstorović, Divna, Živković, Nikola, Kijevčanin, Mirjana, Živković, Emila, "Viscosity of binary mixture DMA + 2-butanol with potential use as solvent  for regenerative flue gas desulfurization processes" in Processing '19 : zbornik radova za 32. Međunarodni kongres o procesnoj industriji (2019):213-218,
https://doi.org/10.24094/ptk.019.32.1.213 . .

Volumetric and transport properties of binary liquid mixtures with 1-ethyl-3-methylimidazolium ethyl sulfate as candidate solvents for regenerative flue gas desulfurization processes

(2018)

TY  - JOUR
PY  - 2018
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/7579
AB  - This paper presents novel data on density, viscosity and refractive index of four binary mixtures constituted of ionic liquid 1-ethyl-3-methylimidazolium ethyl sulfate and N-methyl-2-pyrrolidone/or 1-hexanol/or liquid polyethylene glycols with molar mass 200/or 400, in the temperature range from T = 288.15 K to 333.15 K and at pressure of p =.1 MPa. Thermal conductivity has been measured for mixtures of ionic liquid and polyethylene glycol 200/or polyethylene glycol 400 in the temperature range from T = 303.15 to 323.15 K and at a pressure of p =.1 MPa. All these solutions have the potential for application in regenerative flue gas desulfurization processes. From experimental values of densities, viscosities, thermal conductivities and refractive indices, excess molar volumes and deviations in viscosity, thermal conductivity and refractive index have been calculated and correlated with Redlich-Kister polynomial equation. The values of excess and deviation functions were used for analysis of molecular interactions present in the investigated solutions. In addition, modeling of transport properties, viscosity and thermal conductivity, was carried out and the obtained results were interpreted taking into account the applied approaches and models. (C) 2018 Elsevier Ltd.
T2  - Journal of Chemical Thermodynamics
T1  - Volumetric and transport properties of binary liquid mixtures with 1-ethyl-3-methylimidazolium ethyl sulfate as candidate solvents for regenerative flue gas desulfurization processes
VL  - 119
SP  - 135
EP  - 154
DO  - 10.1016/j.jct.2017.12.023
ER  - 
@article{
year = "2018",
abstract = "This paper presents novel data on density, viscosity and refractive index of four binary mixtures constituted of ionic liquid 1-ethyl-3-methylimidazolium ethyl sulfate and N-methyl-2-pyrrolidone/or 1-hexanol/or liquid polyethylene glycols with molar mass 200/or 400, in the temperature range from T = 288.15 K to 333.15 K and at pressure of p =.1 MPa. Thermal conductivity has been measured for mixtures of ionic liquid and polyethylene glycol 200/or polyethylene glycol 400 in the temperature range from T = 303.15 to 323.15 K and at a pressure of p =.1 MPa. All these solutions have the potential for application in regenerative flue gas desulfurization processes. From experimental values of densities, viscosities, thermal conductivities and refractive indices, excess molar volumes and deviations in viscosity, thermal conductivity and refractive index have been calculated and correlated with Redlich-Kister polynomial equation. The values of excess and deviation functions were used for analysis of molecular interactions present in the investigated solutions. In addition, modeling of transport properties, viscosity and thermal conductivity, was carried out and the obtained results were interpreted taking into account the applied approaches and models. (C) 2018 Elsevier Ltd.",
journal = "Journal of Chemical Thermodynamics",
title = "Volumetric and transport properties of binary liquid mixtures with 1-ethyl-3-methylimidazolium ethyl sulfate as candidate solvents for regenerative flue gas desulfurization processes",
volume = "119",
pages = "135-154",
doi = "10.1016/j.jct.2017.12.023"
}
(2018). Volumetric and transport properties of binary liquid mixtures with 1-ethyl-3-methylimidazolium ethyl sulfate as candidate solvents for regenerative flue gas desulfurization processes. in Journal of Chemical Thermodynamics, 119, 135-154.
https://doi.org/10.1016/j.jct.2017.12.023
Volumetric and transport properties of binary liquid mixtures with 1-ethyl-3-methylimidazolium ethyl sulfate as candidate solvents for regenerative flue gas desulfurization processes. in Journal of Chemical Thermodynamics. 2018;119:135-154.
doi:10.1016/j.jct.2017.12.023 .
"Volumetric and transport properties of binary liquid mixtures with 1-ethyl-3-methylimidazolium ethyl sulfate as candidate solvents for regenerative flue gas desulfurization processes" in Journal of Chemical Thermodynamics, 119 (2018):135-154,
https://doi.org/10.1016/j.jct.2017.12.023 . .
21
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The friction theory for estimating viscosity of candidate solvents for flue gas desulfurization processes

Jovanović, Jovan D.; Majstorović, Divna M.; Živković, Nikola V.; Kijevčanin, Mirjana Lj.; Živković, Emila M.

(2018)

TY  - JOUR
AU  - Jovanović, Jovan D.
AU  - Majstorović, Divna M.
AU  - Živković, Nikola V.
AU  - Kijevčanin, Mirjana Lj.
AU  - Živković, Emila M.
PY  - 2018
UR  - https://linkinghub.elsevier.com/retrieve/pii/S0167732218329441
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/7885
AB  - In this study, applicability of the friction theory for the viscosity estimation of pure substances and binary liquid mixtures, used in regenerative flue gas desulphurization processes, was investigated. Theory was tested on the selected solvents that have already found commercial application, tetraethylene glycol dimethyl ether, n‑methyl‑2‑pyrrolidone and n,n‑dimethylaniline, in mixtures with alcohols 1‑butanol, 2‑butanol or 1‑hexanol. The results were compared with experimental viscosity data for eleven systems. In the calculation procedure, friction theory was coupled both with the Peng-Robinson (PR) and Soave-Redlich-Kwong (SRK) equations of state (EoS). Almost identical deviations, under 0.2% with both EoS, were obtained for pure compounds. For viscosity of mixtures, in almost all cases, better results were obtained using PR EoS, with values of percentage deviations less than 4%. Additionally, the possibility of simultaneous density calculations was checked and the obtained values were compared with experimental data. Application of this model for viscosity modeling of the investigated systems was justified by comparison of the obtained results with other commonly used predictive models, UNIFAC-VISCO and ASOG-VISCO. © 2018 Elsevier B.V.
T2  - Journal of Molecular Liquids
T1  - The friction theory for estimating viscosity of candidate solvents for flue gas desulfurization processes
VL  - 271
SP  - 696
EP  - 703
DO  - 10.1016/j.molliq.2018.09.043
ER  - 
@article{
author = "Jovanović, Jovan D. and Majstorović, Divna M. and Živković, Nikola V. and Kijevčanin, Mirjana Lj. and Živković, Emila M.",
year = "2018",
abstract = "In this study, applicability of the friction theory for the viscosity estimation of pure substances and binary liquid mixtures, used in regenerative flue gas desulphurization processes, was investigated. Theory was tested on the selected solvents that have already found commercial application, tetraethylene glycol dimethyl ether, n‑methyl‑2‑pyrrolidone and n,n‑dimethylaniline, in mixtures with alcohols 1‑butanol, 2‑butanol or 1‑hexanol. The results were compared with experimental viscosity data for eleven systems. In the calculation procedure, friction theory was coupled both with the Peng-Robinson (PR) and Soave-Redlich-Kwong (SRK) equations of state (EoS). Almost identical deviations, under 0.2% with both EoS, were obtained for pure compounds. For viscosity of mixtures, in almost all cases, better results were obtained using PR EoS, with values of percentage deviations less than 4%. Additionally, the possibility of simultaneous density calculations was checked and the obtained values were compared with experimental data. Application of this model for viscosity modeling of the investigated systems was justified by comparison of the obtained results with other commonly used predictive models, UNIFAC-VISCO and ASOG-VISCO. © 2018 Elsevier B.V.",
journal = "Journal of Molecular Liquids",
title = "The friction theory for estimating viscosity of candidate solvents for flue gas desulfurization processes",
volume = "271",
pages = "696-703",
doi = "10.1016/j.molliq.2018.09.043"
}
Jovanović, J. D., Majstorović, D. M., Živković, N. V., Kijevčanin, M. Lj.,& Živković, E. M.. (2018). The friction theory for estimating viscosity of candidate solvents for flue gas desulfurization processes. in Journal of Molecular Liquids, 271, 696-703.
https://doi.org/10.1016/j.molliq.2018.09.043
Jovanović JD, Majstorović DM, Živković NV, Kijevčanin ML, Živković EM. The friction theory for estimating viscosity of candidate solvents for flue gas desulfurization processes. in Journal of Molecular Liquids. 2018;271:696-703.
doi:10.1016/j.molliq.2018.09.043 .
Jovanović, Jovan D., Majstorović, Divna M., Živković, Nikola V., Kijevčanin, Mirjana Lj., Živković, Emila M., "The friction theory for estimating viscosity of candidate solvents for flue gas desulfurization processes" in Journal of Molecular Liquids, 271 (2018):696-703,
https://doi.org/10.1016/j.molliq.2018.09.043 . .
1
1

Application and Testing of a New Simple Experimental Set-Up for Thermal Conductivity Measurements of Liquids

Stanimirović, Andrej M.; Živković, Emila M.; Milošević, Nenad D.; Kijevčanin, Mirjana Lj.

(2017)

TY  - JOUR
AU  - Stanimirović, Andrej M.
AU  - Živković, Emila M.
AU  - Milošević, Nenad D.
AU  - Kijevčanin, Mirjana Lj.
PY  - 2017
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/1629
AB  - Transient hot wire method is considered a reliable and precise technique for measuring the thermal conductivity of liquids. The present paper describes a new transient hot wire experimental set-up and its initial testing. The new apparatus was tested by performing thermal conductivity measurements on substances whose reference thermophysical properties data existed in literature, namely on pure toluene and double distilled deionized water. The values of thermal conductivity measured in the temperature range 25 to 45 degrees C deviated +2.2% to +3% from the literature data, while the expanded measurement uncertainty was estimated to be +/- 4%.
T2  - Thermal Science
T1  - Application and Testing of a New Simple Experimental Set-Up for Thermal Conductivity Measurements of Liquids
VL  - 21
IS  - 3
SP  - 1195
EP  - 1202
DO  - 10.2298/TSCI160324219S
ER  - 
@article{
author = "Stanimirović, Andrej M. and Živković, Emila M. and Milošević, Nenad D. and Kijevčanin, Mirjana Lj.",
year = "2017",
abstract = "Transient hot wire method is considered a reliable and precise technique for measuring the thermal conductivity of liquids. The present paper describes a new transient hot wire experimental set-up and its initial testing. The new apparatus was tested by performing thermal conductivity measurements on substances whose reference thermophysical properties data existed in literature, namely on pure toluene and double distilled deionized water. The values of thermal conductivity measured in the temperature range 25 to 45 degrees C deviated +2.2% to +3% from the literature data, while the expanded measurement uncertainty was estimated to be +/- 4%.",
journal = "Thermal Science",
title = "Application and Testing of a New Simple Experimental Set-Up for Thermal Conductivity Measurements of Liquids",
volume = "21",
number = "3",
pages = "1195-1202",
doi = "10.2298/TSCI160324219S"
}
Stanimirović, A. M., Živković, E. M., Milošević, N. D.,& Kijevčanin, M. Lj.. (2017). Application and Testing of a New Simple Experimental Set-Up for Thermal Conductivity Measurements of Liquids. in Thermal Science, 21(3), 1195-1202.
https://doi.org/10.2298/TSCI160324219S
Stanimirović AM, Živković EM, Milošević ND, Kijevčanin ML. Application and Testing of a New Simple Experimental Set-Up for Thermal Conductivity Measurements of Liquids. in Thermal Science. 2017;21(3):1195-1202.
doi:10.2298/TSCI160324219S .
Stanimirović, Andrej M., Živković, Emila M., Milošević, Nenad D., Kijevčanin, Mirjana Lj., "Application and Testing of a New Simple Experimental Set-Up for Thermal Conductivity Measurements of Liquids" in Thermal Science, 21, no. 3 (2017):1195-1202,
https://doi.org/10.2298/TSCI160324219S . .
4
2
4

Volumetric and viscometric properties of binary liquid mixtures as potential solvents for flue gas desulfurization processes

Živković, Nikola V.; Zivkovic, Emila M.; Šerbanović, Slobodan P.; Majstorović, Divna M.; Kijevčanin, Mirjana Lj.

(2017)

TY  - JOUR
AU  - Živković, Nikola V.
AU  - Zivkovic, Emila M.
AU  - Šerbanović, Slobodan P.
AU  - Majstorović, Divna M.
AU  - Kijevčanin, Mirjana Lj.
PY  - 2017
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/1443
AB  - Desulphurization processes (FGD) of flue gases from the thermal power and industrial plants, based on organic liquid solvents with mechanism of physical absorption (tetraethylene glycol dimethyl ether) or combination of physical and chemical absorption (N-methyl-2-pyrrolidone), recently gained its significance. The research results presented in this paper include density and dynamic viscosity measurements of following binary systems at atmospheric pressure: polyethylene glycol 200 + tetraethylene glycol dimethyl ether, polyethylene glycol 400 + tetraethylene glycol dimethyl ether, in temperature range from 288.15 to 333.15 K, and binary systems polyethylene glycol 200 + N-methyl-2-pyrrolidone and polyethylene glycol 400 + N-methyl-2-pyrrolidone, in temperature range from 288.15 to 323.15 K. In order to analyze and comment intermolecular interactions, calculated values of excess molar volumes and viscosity deviations were used. Strong, physical interactions of dipole-dipole type or formation of intermolecular hydrogen bonds lead and contribute to negative V-E values that occur in these systems. Calculated values of excess and deviation properties were interpolated using the Redlich-Kister polynomial equation. Viscosity modeling has been performed, using predictive, group contribution models (UNIFAC - VISCO and ASOG- VISCO) as well as correlative models (McAlister, Eyring - UNIQUAC and Eyring - NRTL). For simultaneous modeling of excess molar volumes and viscosities, model based on the equation of state was used. For investigated systems, correlative McAllister models gave the best results and can be used for viscosity calculations. (C) 2017 Elsevier Ltd.
T2  - Journal of Chemical Thermodynamics
T1  - Volumetric and viscometric properties of binary liquid mixtures as potential solvents for flue gas desulfurization processes
VL  - 108
SP  - 162
EP  - 180
DO  - 10.1016/j.jct.2017.01.018
ER  - 
@article{
author = "Živković, Nikola V. and Zivkovic, Emila M. and Šerbanović, Slobodan P. and Majstorović, Divna M. and Kijevčanin, Mirjana Lj.",
year = "2017",
abstract = "Desulphurization processes (FGD) of flue gases from the thermal power and industrial plants, based on organic liquid solvents with mechanism of physical absorption (tetraethylene glycol dimethyl ether) or combination of physical and chemical absorption (N-methyl-2-pyrrolidone), recently gained its significance. The research results presented in this paper include density and dynamic viscosity measurements of following binary systems at atmospheric pressure: polyethylene glycol 200 + tetraethylene glycol dimethyl ether, polyethylene glycol 400 + tetraethylene glycol dimethyl ether, in temperature range from 288.15 to 333.15 K, and binary systems polyethylene glycol 200 + N-methyl-2-pyrrolidone and polyethylene glycol 400 + N-methyl-2-pyrrolidone, in temperature range from 288.15 to 323.15 K. In order to analyze and comment intermolecular interactions, calculated values of excess molar volumes and viscosity deviations were used. Strong, physical interactions of dipole-dipole type or formation of intermolecular hydrogen bonds lead and contribute to negative V-E values that occur in these systems. Calculated values of excess and deviation properties were interpolated using the Redlich-Kister polynomial equation. Viscosity modeling has been performed, using predictive, group contribution models (UNIFAC - VISCO and ASOG- VISCO) as well as correlative models (McAlister, Eyring - UNIQUAC and Eyring - NRTL). For simultaneous modeling of excess molar volumes and viscosities, model based on the equation of state was used. For investigated systems, correlative McAllister models gave the best results and can be used for viscosity calculations. (C) 2017 Elsevier Ltd.",
journal = "Journal of Chemical Thermodynamics",
title = "Volumetric and viscometric properties of binary liquid mixtures as potential solvents for flue gas desulfurization processes",
volume = "108",
pages = "162-180",
doi = "10.1016/j.jct.2017.01.018"
}
Živković, N. V., Zivkovic, E. M., Šerbanović, S. P., Majstorović, D. M.,& Kijevčanin, M. Lj.. (2017). Volumetric and viscometric properties of binary liquid mixtures as potential solvents for flue gas desulfurization processes. in Journal of Chemical Thermodynamics, 108, 162-180.
https://doi.org/10.1016/j.jct.2017.01.018
Živković NV, Zivkovic EM, Šerbanović SP, Majstorović DM, Kijevčanin ML. Volumetric and viscometric properties of binary liquid mixtures as potential solvents for flue gas desulfurization processes. in Journal of Chemical Thermodynamics. 2017;108:162-180.
doi:10.1016/j.jct.2017.01.018 .
Živković, Nikola V., Zivkovic, Emila M., Šerbanović, Slobodan P., Majstorović, Divna M., Kijevčanin, Mirjana Lj., "Volumetric and viscometric properties of binary liquid mixtures as potential solvents for flue gas desulfurization processes" in Journal of Chemical Thermodynamics, 108 (2017):162-180,
https://doi.org/10.1016/j.jct.2017.01.018 . .
5
4
5

Review of techological methods and experimental determination of thermodynamic and transport properties of reagents for carbon dioxide removal from flue gases

Spasojević, Vuk D.; Šerbanović, Slobodan P.; Stefanović, Predrag Lj.; Kijevčanin, Mirjana Lj.

(2014)

TY  - JOUR
AU  - Spasojević, Vuk D.
AU  - Šerbanović, Slobodan P.
AU  - Stefanović, Predrag Lj.
AU  - Kijevčanin, Mirjana Lj.
PY  - 2014
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/5980
AB  - In this work a review of the currently available methods for carbon dioxide removal from flue gasses is given. Some of them are commercially available, while others are still under development. Special attention is given to detailed description of the methods based on hemi sorption by aqueous solutions of alkanolamines, which found wide commercial use in industry. Selection of appropriate absorbent, process equipment, methods, working parameters, combustion processes, etc., are some of the key points that will be reviewed within this work in order to present advantages and limitations of carbon dioxide removal methods. In the experimental section we have provided data on density, viscosity and refractive index of insufficiently investigated carbon dioxide removal agents, such as monoisopropanolamine (MIPA), diisopropanolamine (DIPA), triisopropanolamine (TIPA) and currently widely used dietanolamine (DEA). The data obtained are crucial for the equipment design and process optimization.
T2  - Hemijska industrija
T1  - Review of techological methods and experimental determination of thermodynamic and transport properties of reagents for carbon dioxide removal from flue gases
VL  - 68
IS  - 1
SP  - 123
EP  - 134
DO  - 10.2298/HEMIND130312039S
ER  - 
@article{
author = "Spasojević, Vuk D. and Šerbanović, Slobodan P. and Stefanović, Predrag Lj. and Kijevčanin, Mirjana Lj.",
year = "2014",
abstract = "In this work a review of the currently available methods for carbon dioxide removal from flue gasses is given. Some of them are commercially available, while others are still under development. Special attention is given to detailed description of the methods based on hemi sorption by aqueous solutions of alkanolamines, which found wide commercial use in industry. Selection of appropriate absorbent, process equipment, methods, working parameters, combustion processes, etc., are some of the key points that will be reviewed within this work in order to present advantages and limitations of carbon dioxide removal methods. In the experimental section we have provided data on density, viscosity and refractive index of insufficiently investigated carbon dioxide removal agents, such as monoisopropanolamine (MIPA), diisopropanolamine (DIPA), triisopropanolamine (TIPA) and currently widely used dietanolamine (DEA). The data obtained are crucial for the equipment design and process optimization.",
journal = "Hemijska industrija",
title = "Review of techological methods and experimental determination of thermodynamic and transport properties of reagents for carbon dioxide removal from flue gases",
volume = "68",
number = "1",
pages = "123-134",
doi = "10.2298/HEMIND130312039S"
}
Spasojević, V. D., Šerbanović, S. P., Stefanović, P. Lj.,& Kijevčanin, M. Lj.. (2014). Review of techological methods and experimental determination of thermodynamic and transport properties of reagents for carbon dioxide removal from flue gases. in Hemijska industrija, 68(1), 123-134.
https://doi.org/10.2298/HEMIND130312039S
Spasojević VD, Šerbanović SP, Stefanović PL, Kijevčanin ML. Review of techological methods and experimental determination of thermodynamic and transport properties of reagents for carbon dioxide removal from flue gases. in Hemijska industrija. 2014;68(1):123-134.
doi:10.2298/HEMIND130312039S .
Spasojević, Vuk D., Šerbanović, Slobodan P., Stefanović, Predrag Lj., Kijevčanin, Mirjana Lj., "Review of techological methods and experimental determination of thermodynamic and transport properties of reagents for carbon dioxide removal from flue gases" in Hemijska industrija, 68, no. 1 (2014):123-134,
https://doi.org/10.2298/HEMIND130312039S . .
1
1

Wet flue gas desulphurisation procedures and relevant solvents thermophysical properties determination

Živković, Nikola V.; Šerbanović, Slobodan P.; Zivkovic, Emila M.; Kijevčanin, Mirjana Lj.; Stefanović, Predrag Lj.

(2014)

TY  - JOUR
AU  - Živković, Nikola V.
AU  - Šerbanović, Slobodan P.
AU  - Zivkovic, Emila M.
AU  - Kijevčanin, Mirjana Lj.
AU  - Stefanović, Predrag Lj.
PY  - 2014
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/162
AB  - In order to mitigate climate change, the priority task is to reduce emissions of greenhouse gases, including sulfur oxides, from stationary power plants. The legal framework of the European Union has limited the allowable emissions of gases with harmful effects and fulfillment of this obligation is also ahead of the Republic of Serbia in the following years. In this paper the categorization of wet procedures for sulfur oxides removal is given. Wet procedure with the most widespread industrial application, lime/limestone process, has been described in detail. In addition, the procedures with chemical and physical absorption and solvent thermal regeneration, which recently gained more importance, have been presented. Experimentally determined thermophysical and transport properties of commercially used and alternative solvents, necessary for the equipment design and process optimization, are also given in the paper. The obtained values of densities and viscosities of pure chemicals - solvents, polyethylene glycol 200 (PEG 200), polyethylene glycol 400 (PEG 400), tetraethylene glycol dimethyl ether (TEGDMA), N-methyl-2-pyrolidon (NMP) and dimethylaniline (DMA), measured at the atmospheric pressure, are presented as a function of temperature.
T2  - Hemijska industrija
T1  - Wet flue gas desulphurisation procedures and relevant solvents thermophysical properties determination
VL  - 68
IS  - 4
SP  - 491
EP  - 500
DO  - 10.2298/HEMIND130610074Z
ER  - 
@article{
author = "Živković, Nikola V. and Šerbanović, Slobodan P. and Zivkovic, Emila M. and Kijevčanin, Mirjana Lj. and Stefanović, Predrag Lj.",
year = "2014",
abstract = "In order to mitigate climate change, the priority task is to reduce emissions of greenhouse gases, including sulfur oxides, from stationary power plants. The legal framework of the European Union has limited the allowable emissions of gases with harmful effects and fulfillment of this obligation is also ahead of the Republic of Serbia in the following years. In this paper the categorization of wet procedures for sulfur oxides removal is given. Wet procedure with the most widespread industrial application, lime/limestone process, has been described in detail. In addition, the procedures with chemical and physical absorption and solvent thermal regeneration, which recently gained more importance, have been presented. Experimentally determined thermophysical and transport properties of commercially used and alternative solvents, necessary for the equipment design and process optimization, are also given in the paper. The obtained values of densities and viscosities of pure chemicals - solvents, polyethylene glycol 200 (PEG 200), polyethylene glycol 400 (PEG 400), tetraethylene glycol dimethyl ether (TEGDMA), N-methyl-2-pyrolidon (NMP) and dimethylaniline (DMA), measured at the atmospheric pressure, are presented as a function of temperature.",
journal = "Hemijska industrija",
title = "Wet flue gas desulphurisation procedures and relevant solvents thermophysical properties determination",
volume = "68",
number = "4",
pages = "491-500",
doi = "10.2298/HEMIND130610074Z"
}
Živković, N. V., Šerbanović, S. P., Zivkovic, E. M., Kijevčanin, M. Lj.,& Stefanović, P. Lj.. (2014). Wet flue gas desulphurisation procedures and relevant solvents thermophysical properties determination. in Hemijska industrija, 68(4), 491-500.
https://doi.org/10.2298/HEMIND130610074Z
Živković NV, Šerbanović SP, Zivkovic EM, Kijevčanin ML, Stefanović PL. Wet flue gas desulphurisation procedures and relevant solvents thermophysical properties determination. in Hemijska industrija. 2014;68(4):491-500.
doi:10.2298/HEMIND130610074Z .
Živković, Nikola V., Šerbanović, Slobodan P., Zivkovic, Emila M., Kijevčanin, Mirjana Lj., Stefanović, Predrag Lj., "Wet flue gas desulphurisation procedures and relevant solvents thermophysical properties determination" in Hemijska industrija, 68, no. 4 (2014):491-500,
https://doi.org/10.2298/HEMIND130610074Z . .
2
2

Densities, Refractive Indices, Viscosities, and Spectroscopic Study of 1-Amino-2-propanol+1-Butanol and+2-Butanol Solutions at (288.15 to 333.15) K

Spasojević, Vuk D.; Djordjevic, Bojan D.; Šerbanović, Slobodan P.; Radović, Ivona R.; Kijevčanin, Mirjana Lj.

(2014)

TY  - JOUR
AU  - Spasojević, Vuk D.
AU  - Djordjevic, Bojan D.
AU  - Šerbanović, Slobodan P.
AU  - Radović, Ivona R.
AU  - Kijevčanin, Mirjana Lj.
PY  - 2014
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/6039
AB  - Densities, refractive indices, and viscosities of 1-amino-2-propanol (monoisopropanolamine (MIPA)) + 1-butanol and 1-amino-2-propanol + 2-butanol solutions are reported over the entire range of mole fractions and the temperature range from (288.15 to 333.15) K. The Redlich-Kister relation was used for correlation of measured results of excess molar volumes, viscosities, and refractive indices as a function of temperature and composition. Partial molar volumes at infinite dilution were determined from apparent molar volumes. Negative values for excess molar volumes, refractive indices, and viscosity deviations are observed over the entire composition range. The viscosities of 1-amino-2-propanol with 1-butanol and 1-amino-2-propanol with 2-butanol are well represented by an Arrhenius equation. Activation energies for viscous flows are determined by linearization of the Arrhenius equation, providing a clear explanation of the influence on hydrogen bonding. In order to confirm molecular interactions between compounds obtained by analysis of infinite dilution of solute, a FT-IR spectroscopy study was performed at T = 298.15 K. Interactional and structural effects were investigated through calculations of excess Gibbs free energy of activation of viscous flow.
T2  - Journal of Chemical and Engineering Data
T1  - Densities, Refractive Indices, Viscosities, and Spectroscopic Study of 1-Amino-2-propanol+1-Butanol and+2-Butanol Solutions at (288.15 to 333.15) K
VL  - 59
IS  - 6
SP  - 1817
EP  - 1829
DO  - 10.1021/je401036f
ER  - 
@article{
author = "Spasojević, Vuk D. and Djordjevic, Bojan D. and Šerbanović, Slobodan P. and Radović, Ivona R. and Kijevčanin, Mirjana Lj.",
year = "2014",
abstract = "Densities, refractive indices, and viscosities of 1-amino-2-propanol (monoisopropanolamine (MIPA)) + 1-butanol and 1-amino-2-propanol + 2-butanol solutions are reported over the entire range of mole fractions and the temperature range from (288.15 to 333.15) K. The Redlich-Kister relation was used for correlation of measured results of excess molar volumes, viscosities, and refractive indices as a function of temperature and composition. Partial molar volumes at infinite dilution were determined from apparent molar volumes. Negative values for excess molar volumes, refractive indices, and viscosity deviations are observed over the entire composition range. The viscosities of 1-amino-2-propanol with 1-butanol and 1-amino-2-propanol with 2-butanol are well represented by an Arrhenius equation. Activation energies for viscous flows are determined by linearization of the Arrhenius equation, providing a clear explanation of the influence on hydrogen bonding. In order to confirm molecular interactions between compounds obtained by analysis of infinite dilution of solute, a FT-IR spectroscopy study was performed at T = 298.15 K. Interactional and structural effects were investigated through calculations of excess Gibbs free energy of activation of viscous flow.",
journal = "Journal of Chemical and Engineering Data",
title = "Densities, Refractive Indices, Viscosities, and Spectroscopic Study of 1-Amino-2-propanol+1-Butanol and+2-Butanol Solutions at (288.15 to 333.15) K",
volume = "59",
number = "6",
pages = "1817-1829",
doi = "10.1021/je401036f"
}
Spasojević, V. D., Djordjevic, B. D., Šerbanović, S. P., Radović, I. R.,& Kijevčanin, M. Lj.. (2014). Densities, Refractive Indices, Viscosities, and Spectroscopic Study of 1-Amino-2-propanol+1-Butanol and+2-Butanol Solutions at (288.15 to 333.15) K. in Journal of Chemical and Engineering Data, 59(6), 1817-1829.
https://doi.org/10.1021/je401036f
Spasojević VD, Djordjevic BD, Šerbanović SP, Radović IR, Kijevčanin ML. Densities, Refractive Indices, Viscosities, and Spectroscopic Study of 1-Amino-2-propanol+1-Butanol and+2-Butanol Solutions at (288.15 to 333.15) K. in Journal of Chemical and Engineering Data. 2014;59(6):1817-1829.
doi:10.1021/je401036f .
Spasojević, Vuk D., Djordjevic, Bojan D., Šerbanović, Slobodan P., Radović, Ivona R., Kijevčanin, Mirjana Lj., "Densities, Refractive Indices, Viscosities, and Spectroscopic Study of 1-Amino-2-propanol+1-Butanol and+2-Butanol Solutions at (288.15 to 333.15) K" in Journal of Chemical and Engineering Data, 59, no. 6 (2014):1817-1829,
https://doi.org/10.1021/je401036f . .
58
42
56

Volumetric Properties, Viscosities, and Refractive Indices of the Binary Systems 1-Butanol + PEG 200, + PEG 400, and + TEGDME

Živković, Nikola V.; Serbanovic, S.; Kijevčanin, Mirjana Lj.; Zivkovic, E.

(2013)

TY  - JOUR
AU  - Živković, Nikola V.
AU  - Serbanovic, S.
AU  - Kijevčanin, Mirjana Lj.
AU  - Zivkovic, E.
PY  - 2013
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/5586
AB  - Densities, viscosities, and refractive indices of three binary systems consisting of 1-butanol with polyethylene glycols of different molecular weights (PEG 200 and PEG 400) or tetraethylene glycol dimethyl ether (TEGDME) were measured at ten temperatures (288.15, 293.15, 298.15, 303.15, 308.15, 313.15, 318.15, 323.15, 328.15, and 333.15) K and atmospheric pressure. Densities of the selected binary mixtures were measured with an Anton Paar DMA 5000 digital vibrating U-tube densimeter, refractive indices were measured with an automatic Anton Paar RXA-156 refractometer, while for viscosity measurements, a digital Stabinger SVM 3000/G2 viscometer was used. From these data, excess molar volumes were calculated and fitted to the Redlich-Kister equation. The obtained results have been analyzed in terms of specific molecular interactions and mixing behavior between mixture components, as well as the influence of temperature on them. Viscosity data were also correlated by Grunberg-Nissan, Eyring-UNIQUAC, three-body McAlister, and Eyring-NRTL models.
T2  - International Journal of Thermophysics
T1  - Volumetric Properties, Viscosities, and Refractive Indices of the Binary Systems 1-Butanol + PEG 200, + PEG 400, and + TEGDME
VL  - 34
IS  - 6
SP  - 1002
EP  - 1020
DO  - 10.1007/s10765-013-1469-0
ER  - 
@article{
author = "Živković, Nikola V. and Serbanovic, S. and Kijevčanin, Mirjana Lj. and Zivkovic, E.",
year = "2013",
abstract = "Densities, viscosities, and refractive indices of three binary systems consisting of 1-butanol with polyethylene glycols of different molecular weights (PEG 200 and PEG 400) or tetraethylene glycol dimethyl ether (TEGDME) were measured at ten temperatures (288.15, 293.15, 298.15, 303.15, 308.15, 313.15, 318.15, 323.15, 328.15, and 333.15) K and atmospheric pressure. Densities of the selected binary mixtures were measured with an Anton Paar DMA 5000 digital vibrating U-tube densimeter, refractive indices were measured with an automatic Anton Paar RXA-156 refractometer, while for viscosity measurements, a digital Stabinger SVM 3000/G2 viscometer was used. From these data, excess molar volumes were calculated and fitted to the Redlich-Kister equation. The obtained results have been analyzed in terms of specific molecular interactions and mixing behavior between mixture components, as well as the influence of temperature on them. Viscosity data were also correlated by Grunberg-Nissan, Eyring-UNIQUAC, three-body McAlister, and Eyring-NRTL models.",
journal = "International Journal of Thermophysics",
title = "Volumetric Properties, Viscosities, and Refractive Indices of the Binary Systems 1-Butanol + PEG 200, + PEG 400, and + TEGDME",
volume = "34",
number = "6",
pages = "1002-1020",
doi = "10.1007/s10765-013-1469-0"
}
Živković, N. V., Serbanovic, S., Kijevčanin, M. Lj.,& Zivkovic, E.. (2013). Volumetric Properties, Viscosities, and Refractive Indices of the Binary Systems 1-Butanol + PEG 200, + PEG 400, and + TEGDME. in International Journal of Thermophysics, 34(6), 1002-1020.
https://doi.org/10.1007/s10765-013-1469-0
Živković NV, Serbanovic S, Kijevčanin ML, Zivkovic E. Volumetric Properties, Viscosities, and Refractive Indices of the Binary Systems 1-Butanol + PEG 200, + PEG 400, and + TEGDME. in International Journal of Thermophysics. 2013;34(6):1002-1020.
doi:10.1007/s10765-013-1469-0 .
Živković, Nikola V., Serbanovic, S., Kijevčanin, Mirjana Lj., Zivkovic, E., "Volumetric Properties, Viscosities, and Refractive Indices of the Binary Systems 1-Butanol + PEG 200, + PEG 400, and + TEGDME" in International Journal of Thermophysics, 34, no. 6 (2013):1002-1020,
https://doi.org/10.1007/s10765-013-1469-0 . .
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Volumetric and Viscometric Behavior of Binary Systems 2-Butanol + PEG 200, + PEG 400, + Tetraethylene Glycol Dimethyl Ether, and plus N-Methyl-2-pyrrolidone

Živković, Nikola V.; Serbanovic, Slobodanh S.; Kijevčanin, Mirjana Lj.; Zivkovic, E. M.

(2013)

TY  - JOUR
AU  - Živković, Nikola V.
AU  - Serbanovic, Slobodanh S.
AU  - Kijevčanin, Mirjana Lj.
AU  - Zivkovic, E. M.
PY  - 2013
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/5805
AB  - Experimental data on densities, viscosities, and refractive indices of binary mixtures with 2-butanol and polyethylene glycols of different molecular weights, tetraethylene glycol dimethyl ether, or N-methyl-2-pyrrolidone, were determined in the temperature interval from 288.15 K to 323.15 K and at atmospheric pressure. Excess molar volumes, viscosity deviations, and deviations in refractive indices were computed from these data and correlated with the Redlich-Kister polynomial equation. The obtained results allowed the interpretation of specific inter- and intramolecular interactions.
T2  - Journal of Chemical and Engineering Data
T1  - Volumetric and Viscometric Behavior of Binary Systems 2-Butanol + PEG 200, + PEG 400, + Tetraethylene Glycol Dimethyl Ether, and plus N-Methyl-2-pyrrolidone
VL  - 58
IS  - 12
SP  - 3332
EP  - 3341
DO  - 10.1021/je400486p
ER  - 
@article{
author = "Živković, Nikola V. and Serbanovic, Slobodanh S. and Kijevčanin, Mirjana Lj. and Zivkovic, E. M.",
year = "2013",
abstract = "Experimental data on densities, viscosities, and refractive indices of binary mixtures with 2-butanol and polyethylene glycols of different molecular weights, tetraethylene glycol dimethyl ether, or N-methyl-2-pyrrolidone, were determined in the temperature interval from 288.15 K to 323.15 K and at atmospheric pressure. Excess molar volumes, viscosity deviations, and deviations in refractive indices were computed from these data and correlated with the Redlich-Kister polynomial equation. The obtained results allowed the interpretation of specific inter- and intramolecular interactions.",
journal = "Journal of Chemical and Engineering Data",
title = "Volumetric and Viscometric Behavior of Binary Systems 2-Butanol + PEG 200, + PEG 400, + Tetraethylene Glycol Dimethyl Ether, and plus N-Methyl-2-pyrrolidone",
volume = "58",
number = "12",
pages = "3332-3341",
doi = "10.1021/je400486p"
}
Živković, N. V., Serbanovic, S. S., Kijevčanin, M. Lj.,& Zivkovic, E. M.. (2013). Volumetric and Viscometric Behavior of Binary Systems 2-Butanol + PEG 200, + PEG 400, + Tetraethylene Glycol Dimethyl Ether, and plus N-Methyl-2-pyrrolidone. in Journal of Chemical and Engineering Data, 58(12), 3332-3341.
https://doi.org/10.1021/je400486p
Živković NV, Serbanovic SS, Kijevčanin ML, Zivkovic EM. Volumetric and Viscometric Behavior of Binary Systems 2-Butanol + PEG 200, + PEG 400, + Tetraethylene Glycol Dimethyl Ether, and plus N-Methyl-2-pyrrolidone. in Journal of Chemical and Engineering Data. 2013;58(12):3332-3341.
doi:10.1021/je400486p .
Živković, Nikola V., Serbanovic, Slobodanh S., Kijevčanin, Mirjana Lj., Zivkovic, E. M., "Volumetric and Viscometric Behavior of Binary Systems 2-Butanol + PEG 200, + PEG 400, + Tetraethylene Glycol Dimethyl Ether, and plus N-Methyl-2-pyrrolidone" in Journal of Chemical and Engineering Data, 58, no. 12 (2013):3332-3341,
https://doi.org/10.1021/je400486p . .
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