TY  - JOUR
AU  - Elezovic, N. R.
AU  - Ercius, P.
AU  - Kovač, Janez
AU  - Radmilovíć, Velimir R.
AU  - Babić, Biljana M.
AU  - Krstajic, N. V.
PY  - 2015
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/420
AB  - Ruthenium oxide/titanium oxide, with a Ru:Ti atomic ratio of 7:3 was synthesized by modified sol-gel procedure and used as a support for platinum nanocatalyst for oxygen reduction reaction. The synthesized materials were characterized in terms of morphology, particle size distribution, chemical and phase composition by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), high angle annular dark filed scanning transmission electron microscopy (HAADF, STEM) and electron energy loss spectroscopy (EELS). XPS spectra revealed that Ru atoms were in mainly in Ru(4+) oxidation state, the Ti atoms in Ti(4+) oxidation state, whereas the Pt-atoms were in metallic state. TEM analysis proved that platinum nanoparticles nucleated at both oxide species and homogeneous distribution was observed. The average platinum nanoparticle size was 3.05 nm. Electrochemically active surface area of platinum was 32 m(2) g(-1). Kinetics of the oxygen reduction was studied at rotating disc electrode in 0.5 mol dm(-3) HClO4 solution, at 25 degrees C. The catalytic activities expressed in terms of specific activity (per electrochemically active surface area of platinum) and mass activity (per mass of platinum) were determined and compared to Pt catalyst on carbon support. The high catalytic activity was proven by electrochemical characterization. (C) 2014 Elsevier B.V. All rights reserved.
T2  - Journal of Electroanalytical Chemistry
T1  - Synthesis and characterization of Pt nanocatalyst on Ru0.7Ti0.3O2 support as a cathode for fuel cells application
VL  - 739
SP  - 164
EP  - 171
DO  - 10.1016/j.jelechem.2014.12.033
ER  - 

@article{
author = "Elezovic, N. R. and Ercius, P. and Kovač, Janez and Radmilovíć, Velimir R. and Babić, Biljana M. and Krstajic, N. V.",
year = "2015",
abstract = "Ruthenium oxide/titanium oxide, with a Ru:Ti atomic ratio of 7:3 was synthesized by modified sol-gel procedure and used as a support for platinum nanocatalyst for oxygen reduction reaction. The synthesized materials were characterized in terms of morphology, particle size distribution, chemical and phase composition by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), high angle annular dark filed scanning transmission electron microscopy (HAADF, STEM) and electron energy loss spectroscopy (EELS). XPS spectra revealed that Ru atoms were in mainly in Ru(4+) oxidation state, the Ti atoms in Ti(4+) oxidation state, whereas the Pt-atoms were in metallic state. TEM analysis proved that platinum nanoparticles nucleated at both oxide species and homogeneous distribution was observed. The average platinum nanoparticle size was 3.05 nm. Electrochemically active surface area of platinum was 32 m(2) g(-1). Kinetics of the oxygen reduction was studied at rotating disc electrode in 0.5 mol dm(-3) HClO4 solution, at 25 degrees C. The catalytic activities expressed in terms of specific activity (per electrochemically active surface area of platinum) and mass activity (per mass of platinum) were determined and compared to Pt catalyst on carbon support. The high catalytic activity was proven by electrochemical characterization. (C) 2014 Elsevier B.V. All rights reserved.",
journal = "Journal of Electroanalytical Chemistry",
title = "Synthesis and characterization of Pt nanocatalyst on Ru0.7Ti0.3O2 support as a cathode for fuel cells application",
volume = "739",
pages = "164-171",
doi = "10.1016/j.jelechem.2014.12.033"
}

Elezovic, N. R., Ercius, P., Kovač, J., Radmilovíć, V. R., Babić, B. M.,& Krstajic, N. V.. (2015). Synthesis and characterization of Pt nanocatalyst on Ru0.7Ti0.3O2 support as a cathode for fuel cells application. in Journal of Electroanalytical Chemistry, 739, 164-171.
https://doi.org/10.1016/j.jelechem.2014.12.033

Elezovic NR, Ercius P, Kovač J, Radmilovíć VR, Babić BM, Krstajic NV. Synthesis and characterization of Pt nanocatalyst on Ru0.7Ti0.3O2 support as a cathode for fuel cells application. in Journal of Electroanalytical Chemistry. 2015;739:164-171.
doi:10.1016/j.jelechem.2014.12.033 .

Elezovic, N. R., Ercius, P., Kovač, Janez, Radmilovíć, Velimir R., Babić, Biljana M., Krstajic, N. V., "Synthesis and characterization of Pt nanocatalyst on Ru0.7Ti0.3O2 support as a cathode for fuel cells application" in Journal of Electroanalytical Chemistry, 739 (2015):164-171,
https://doi.org/10.1016/j.jelechem.2014.12.033 . .