TY  - JOUR
AU  - Kosović, Milica
AU  - Novaković, Slađana B.
AU  - Jaćimović, Željko
AU  - Latinović, Nedeljko
AU  - Marković, Nada
AU  - Đorđević, Tamara
AU  - Libowitzky, Eugen
AU  - Giester, Gerald
PY  - 2020
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/9643
AB  - The reaction of 4-nitro-3-pyrazolecarboxylic acid and Cu(OAc)2⋅H2O in ethanol resulted in a new coordination compound [Cu2(4-nitro-3- -pzc)2(H2O)6]2H2O (4nitro-3pzc = 4-nitro-3-pyrazolecarboxylate). The compound was investigated by means of single-crystal X-ray diffraction and infrared spectroscopy. The biological activity of the complex was also tested. In the crystal structure of [Cu2(4nitro-3-pzc)2(H2O)6]2H2O, the Cu(II) ion is in a distorted [4+2] octahedral coordination due to the Jan–Teller effect. A survey of the Cambridge Structural Database showed that the octahedral coordination geometry is generally rare for pyrazole-bridged Cu(II) complexes. In the case of Cu(II) complexes with the 3-pyrazolecarboxylato ligands, no complexes with a similar octahedral coordination geometry have been reported. Biological research based on determination of the inhibition effect of the commercial fungicide Cabrio top and the newly synthesized complex on Ph. viticola were performed using the phytosanitary method.
T2  - Journal of the Serbian Chemical Society
T1  - Synthesis, crystal structure and biological activity of copper(II) complex with 4-nitro-3-pyrazolecarboxylic ligand
VL  - 85
IS  - 7
SP  - 885
EP  - 895
DO  - 10.2298/JSC190724133K
ER  - 

@article{
author = "Kosović, Milica and Novaković, Slađana B. and Jaćimović, Željko and Latinović, Nedeljko and Marković, Nada and Đorđević, Tamara and Libowitzky, Eugen and Giester, Gerald",
year = "2020",
abstract = "The reaction of 4-nitro-3-pyrazolecarboxylic acid and Cu(OAc)2⋅H2O in ethanol resulted in a new coordination compound [Cu2(4-nitro-3- -pzc)2(H2O)6]2H2O (4nitro-3pzc = 4-nitro-3-pyrazolecarboxylate). The compound was investigated by means of single-crystal X-ray diffraction and infrared spectroscopy. The biological activity of the complex was also tested. In the crystal structure of [Cu2(4nitro-3-pzc)2(H2O)6]2H2O, the Cu(II) ion is in a distorted [4+2] octahedral coordination due to the Jan–Teller effect. A survey of the Cambridge Structural Database showed that the octahedral coordination geometry is generally rare for pyrazole-bridged Cu(II) complexes. In the case of Cu(II) complexes with the 3-pyrazolecarboxylato ligands, no complexes with a similar octahedral coordination geometry have been reported. Biological research based on determination of the inhibition effect of the commercial fungicide Cabrio top and the newly synthesized complex on Ph. viticola were performed using the phytosanitary method.",
journal = "Journal of the Serbian Chemical Society",
title = "Synthesis, crystal structure and biological activity of copper(II) complex with 4-nitro-3-pyrazolecarboxylic ligand",
volume = "85",
number = "7",
pages = "885-895",
doi = "10.2298/JSC190724133K"
}

Kosović, M., Novaković, S. B., Jaćimović, Ž., Latinović, N., Marković, N., Đorđević, T., Libowitzky, E.,& Giester, G.. (2020). Synthesis, crystal structure and biological activity of copper(II) complex with 4-nitro-3-pyrazolecarboxylic ligand. in Journal of the Serbian Chemical Society, 85(7), 885-895.
https://doi.org/10.2298/JSC190724133K

Kosović M, Novaković SB, Jaćimović Ž, Latinović N, Marković N, Đorđević T, Libowitzky E, Giester G. Synthesis, crystal structure and biological activity of copper(II) complex with 4-nitro-3-pyrazolecarboxylic ligand. in Journal of the Serbian Chemical Society. 2020;85(7):885-895.
doi:10.2298/JSC190724133K .

Kosović, Milica, Novaković, Slađana B., Jaćimović, Željko, Latinović, Nedeljko, Marković, Nada, Đorđević, Tamara, Libowitzky, Eugen, Giester, Gerald, "Synthesis, crystal structure and biological activity of copper(II) complex with 4-nitro-3-pyrazolecarboxylic ligand" in Journal of the Serbian Chemical Society, 85, no. 7 (2020):885-895,
https://doi.org/10.2298/JSC190724133K . .