Synthesis, crystal structure and biological activity of copper(II) complex with 4-nitro-3-pyrazolecarboxylic ligand
Аутори
Kosović, MilicaNovaković, Slađana B.
Jaćimović, Željko
Latinović, Nedeljko
Marković, Nada
Đorđević, Tamara
Libowitzky, Eugen
Giester, Gerald
Чланак у часопису (Објављена верзија)
Метаподаци
Приказ свих података о документуАпстракт
The reaction of 4-nitro-3-pyrazolecarboxylic acid and Cu(OAc)2⋅H2O in ethanol resulted in a new coordination compound [Cu2(4-nitro-3- -pzc)2(H2O)6]2H2O (4nitro-3pzc = 4-nitro-3-pyrazolecarboxylate). The compound was investigated by means of single-crystal X-ray diffraction and infrared spectroscopy. The biological activity of the complex was also tested. In the crystal structure of [Cu2(4nitro-3-pzc)2(H2O)6]2H2O, the Cu(II) ion is in a distorted [4+2] octahedral coordination due to the Jan–Teller effect. A survey of the Cambridge Structural Database showed that the octahedral coordination geometry is generally rare for pyrazole-bridged Cu(II) complexes. In the case of Cu(II) complexes with the 3-pyrazolecarboxylato ligands, no complexes with a similar octahedral coordination geometry have been reported. Biological research based on determination of the inhibition effect of the commercial fungicide Cabrio top and the newly synthesized complex on Ph. viticola were performed using the phy...tosanitary method.
Кључне речи:
pyrazole / copper(II) / coordination complexes / crystal structure / infrared spectra / inhibition effectИзвор:
Journal of the Serbian Chemical Society, 2020, 85, 7, 885-895Финансирање / пројекти:
- Ministry of Education, Science and Technological Development of the Republic of Serbia
- Ministry of Science of the Republic of Montenegro
DOI: 10.2298/JSC190724133K
ISSN: 0352-5139
WoS: 000550645700001
Scopus: 2-s2.0-85090465280
Колекције
Институција/група
VinčaTY - JOUR AU - Kosović, Milica AU - Novaković, Slađana B. AU - Jaćimović, Željko AU - Latinović, Nedeljko AU - Marković, Nada AU - Đorđević, Tamara AU - Libowitzky, Eugen AU - Giester, Gerald PY - 2020 UR - https://vinar.vin.bg.ac.rs/handle/123456789/9643 AB - The reaction of 4-nitro-3-pyrazolecarboxylic acid and Cu(OAc)2⋅H2O in ethanol resulted in a new coordination compound [Cu2(4-nitro-3- -pzc)2(H2O)6]2H2O (4nitro-3pzc = 4-nitro-3-pyrazolecarboxylate). The compound was investigated by means of single-crystal X-ray diffraction and infrared spectroscopy. The biological activity of the complex was also tested. In the crystal structure of [Cu2(4nitro-3-pzc)2(H2O)6]2H2O, the Cu(II) ion is in a distorted [4+2] octahedral coordination due to the Jan–Teller effect. A survey of the Cambridge Structural Database showed that the octahedral coordination geometry is generally rare for pyrazole-bridged Cu(II) complexes. In the case of Cu(II) complexes with the 3-pyrazolecarboxylato ligands, no complexes with a similar octahedral coordination geometry have been reported. Biological research based on determination of the inhibition effect of the commercial fungicide Cabrio top and the newly synthesized complex on Ph. viticola were performed using the phytosanitary method. T2 - Journal of the Serbian Chemical Society T1 - Synthesis, crystal structure and biological activity of copper(II) complex with 4-nitro-3-pyrazolecarboxylic ligand VL - 85 IS - 7 SP - 885 EP - 895 DO - 10.2298/JSC190724133K ER -
@article{ author = "Kosović, Milica and Novaković, Slađana B. and Jaćimović, Željko and Latinović, Nedeljko and Marković, Nada and Đorđević, Tamara and Libowitzky, Eugen and Giester, Gerald", year = "2020", abstract = "The reaction of 4-nitro-3-pyrazolecarboxylic acid and Cu(OAc)2⋅H2O in ethanol resulted in a new coordination compound [Cu2(4-nitro-3- -pzc)2(H2O)6]2H2O (4nitro-3pzc = 4-nitro-3-pyrazolecarboxylate). The compound was investigated by means of single-crystal X-ray diffraction and infrared spectroscopy. The biological activity of the complex was also tested. In the crystal structure of [Cu2(4nitro-3-pzc)2(H2O)6]2H2O, the Cu(II) ion is in a distorted [4+2] octahedral coordination due to the Jan–Teller effect. A survey of the Cambridge Structural Database showed that the octahedral coordination geometry is generally rare for pyrazole-bridged Cu(II) complexes. In the case of Cu(II) complexes with the 3-pyrazolecarboxylato ligands, no complexes with a similar octahedral coordination geometry have been reported. Biological research based on determination of the inhibition effect of the commercial fungicide Cabrio top and the newly synthesized complex on Ph. viticola were performed using the phytosanitary method.", journal = "Journal of the Serbian Chemical Society", title = "Synthesis, crystal structure and biological activity of copper(II) complex with 4-nitro-3-pyrazolecarboxylic ligand", volume = "85", number = "7", pages = "885-895", doi = "10.2298/JSC190724133K" }
Kosović, M., Novaković, S. B., Jaćimović, Ž., Latinović, N., Marković, N., Đorđević, T., Libowitzky, E.,& Giester, G.. (2020). Synthesis, crystal structure and biological activity of copper(II) complex with 4-nitro-3-pyrazolecarboxylic ligand. in Journal of the Serbian Chemical Society, 85(7), 885-895. https://doi.org/10.2298/JSC190724133K
Kosović M, Novaković SB, Jaćimović Ž, Latinović N, Marković N, Đorđević T, Libowitzky E, Giester G. Synthesis, crystal structure and biological activity of copper(II) complex with 4-nitro-3-pyrazolecarboxylic ligand. in Journal of the Serbian Chemical Society. 2020;85(7):885-895. doi:10.2298/JSC190724133K .
Kosović, Milica, Novaković, Slađana B., Jaćimović, Željko, Latinović, Nedeljko, Marković, Nada, Đorđević, Tamara, Libowitzky, Eugen, Giester, Gerald, "Synthesis, crystal structure and biological activity of copper(II) complex with 4-nitro-3-pyrazolecarboxylic ligand" in Journal of the Serbian Chemical Society, 85, no. 7 (2020):885-895, https://doi.org/10.2298/JSC190724133K . .