TY  - JOUR
AU  - Miodragovic, Zoran M.
AU  - Bogdanović, Goran A.
AU  - Krajcinovic, Bojana B.
AU  - Drakulić, Branko J.
AU  - Kusigerski, Vladan
AU  - Miodragović Đenana U.
AU  - Spasojević, Vojislav
AU  - Hodzic, Ismet M.
AU  - Juranić, Ivan O.
PY  - 2006
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/3127
AB  - A new binuclear Cu(II) complex with an (E)-4-(2,4-diisopropylphenyl)-4-oxo-2-butenoato ligand (L) was successfully synthesized and characterized by elemental analysis and IR-spectroscopy. The structures of (E)-4-(2,4-diisopropylphenyl)-4-oxo-2-butenoic acid (HL), and the corresponding (tetrakis)-mu-[(E)-4-(2,4-diisopropylphenyl)-4-oxo-2-butenoato]-bis(ethanol)-copper(II) complex, [Cu2L4(C2H5OH)(2)], were determined by single crystal X-ray analyses and are preliminarily discussed. This is the first complex of a transition metal with ligand L. as well as the first determined crystal structure of a metal complex with this type of ligand. Analysis of the magnetic susceptibility measurements of the isolated [Cu2L4(C2H5OH)(2)]center dot H2O complex shows the existence of a strong anti-ferromagnetic intra-dimer coupling, with an exchange integral value 2J of -260 cm(-1). (C) 2006 Elsevier B.V. All rights reserved.
T2  - Inorganic Chemistry Communications
T1  - Synthesis, structure and magnetic properties of the first copper(II) complex with an (E)-4-aryl-4-oxo-2-butenoato ligand
VL  - 9
IS  - 12
SP  - 1173
EP  - 1177
DO  - 10.1016/j.inoche.2006.07.029
ER  - 

@article{
author = "Miodragovic, Zoran M. and Bogdanović, Goran A. and Krajcinovic, Bojana B. and Drakulić, Branko J. and Kusigerski, Vladan and Miodragović Đenana U. and Spasojević, Vojislav and Hodzic, Ismet M. and Juranić, Ivan O.",
year = "2006",
abstract = "A new binuclear Cu(II) complex with an (E)-4-(2,4-diisopropylphenyl)-4-oxo-2-butenoato ligand (L) was successfully synthesized and characterized by elemental analysis and IR-spectroscopy. The structures of (E)-4-(2,4-diisopropylphenyl)-4-oxo-2-butenoic acid (HL), and the corresponding (tetrakis)-mu-[(E)-4-(2,4-diisopropylphenyl)-4-oxo-2-butenoato]-bis(ethanol)-copper(II) complex, [Cu2L4(C2H5OH)(2)], were determined by single crystal X-ray analyses and are preliminarily discussed. This is the first complex of a transition metal with ligand L. as well as the first determined crystal structure of a metal complex with this type of ligand. Analysis of the magnetic susceptibility measurements of the isolated [Cu2L4(C2H5OH)(2)]center dot H2O complex shows the existence of a strong anti-ferromagnetic intra-dimer coupling, with an exchange integral value 2J of -260 cm(-1). (C) 2006 Elsevier B.V. All rights reserved.",
journal = "Inorganic Chemistry Communications",
title = "Synthesis, structure and magnetic properties of the first copper(II) complex with an (E)-4-aryl-4-oxo-2-butenoato ligand",
volume = "9",
number = "12",
pages = "1173-1177",
doi = "10.1016/j.inoche.2006.07.029"
}

Miodragovic, Z. M., Bogdanović, G. A., Krajcinovic, B. B., Drakulić, B. J., Kusigerski, V., Miodragović Đenana U., Spasojević, V., Hodzic, I. M.,& Juranić, I. O.. (2006). Synthesis, structure and magnetic properties of the first copper(II) complex with an (E)-4-aryl-4-oxo-2-butenoato ligand. in Inorganic Chemistry Communications, 9(12), 1173-1177.
https://doi.org/10.1016/j.inoche.2006.07.029

Miodragovic ZM, Bogdanović GA, Krajcinovic BB, Drakulić BJ, Kusigerski V, Miodragović Đenana U., Spasojević V, Hodzic IM, Juranić IO. Synthesis, structure and magnetic properties of the first copper(II) complex with an (E)-4-aryl-4-oxo-2-butenoato ligand. in Inorganic Chemistry Communications. 2006;9(12):1173-1177.
doi:10.1016/j.inoche.2006.07.029 .

Miodragovic, Zoran M., Bogdanović, Goran A., Krajcinovic, Bojana B., Drakulić, Branko J., Kusigerski, Vladan, Miodragović Đenana U., Spasojević, Vojislav, Hodzic, Ismet M., Juranić, Ivan O., "Synthesis, structure and magnetic properties of the first copper(II) complex with an (E)-4-aryl-4-oxo-2-butenoato ligand" in Inorganic Chemistry Communications, 9, no. 12 (2006):1173-1177,
https://doi.org/10.1016/j.inoche.2006.07.029 . .