Synthesis, structure and magnetic properties of the first copper(II) complex with an (E)-4-aryl-4-oxo-2-butenoato ligand
АуториMiodragovic, Zoran M.
Bogdanović, Goran A.
Krajcinovic, Bojana B.
Drakulić, Branko J.
Miodragovic, Djenana U.
Hodzic, Ismet M.
Juranic, Ivan O.
Чланак у часопису
МетаподациПриказ свих података о документу
A new binuclear Cu(II) complex with an (E)-4-(2,4-diisopropylphenyl)-4-oxo-2-butenoato ligand (L) was successfully synthesized and characterized by elemental analysis and IR-spectroscopy. The structures of (E)-4-(2,4-diisopropylphenyl)-4-oxo-2-butenoic acid (HL), and the corresponding (tetrakis)-mu-[(E)-4-(2,4-diisopropylphenyl)-4-oxo-2-butenoato]-bis(ethanol)-copper(II) complex, [Cu2L4(C2H5OH)(2)], were determined by single crystal X-ray analyses and are preliminarily discussed. This is the first complex of a transition metal with ligand L. as well as the first determined crystal structure of a metal complex with this type of ligand. Analysis of the magnetic susceptibility measurements of the isolated [Cu2L4(C2H5OH)(2)]center dot H2O complex shows the existence of a strong anti-ferromagnetic intra-dimer coupling, with an exchange integral value 2J of -260 cm(-1). (C) 2006 Elsevier B.V. All rights reserved.
Кључне речи:(E)-4-(2,4-diisopropylphenyl)-4-oxo-2-butenoato ligand / Cu(II) complexes / X-ray analysis / magnetic properties
Извор:Inorganic Chemistry Communications, 2006, 9, 12, 1173-1177
ISSN: 1387-7003 (print)