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Novel negatively-charged ultrafiltration membranes made by a combination of immersion precipitation and photopolymerization

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2013
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Authors
Radovanović, Filip
Tomković, Tanja
Nastasović, Aleksandra B.
Veličković, Sava J.
Nešić, Aleksandra
Onjia, Antonije E.
Contributors
Dekanski, Aleksandar B.
Sovilj, Sofija P.
Conference object (Published version)
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Abstract
Ultrafiltration (UF) membranes are currently used in industry for the concentration of proteins and other macromolecules. Performance of UF membranes is generally limited by a trade-off between permeability and selectivity [1]. However, electrically-charged ultrafiltration membranes can provide a dramatic improvement in ultrafiltration performance [2]. Novel UF membranes were made by combining traditional immersion precipitation process for making membranes with photopolymerization of the casting solution comprising polyethersulfone, glycidyl methacrylate and other reactive monomers. Negative charges were introduced either by initially using 2-acrylamido-2-methylpropane sulfonic acid as a reactive monomer, or were later created by epoxide ring opening of crosslinked glycidyl methacrylate. As shown in Fig. 1, selectivity of these membranes significantly improved as the concentration of negatively-charged groups in the membrane increased. The effects of membrane composition on the proper...ties and separation performance of these novel UF membranes will be presented.

Source:
8th International Conference of the Chemical Societies of the South-East European Countries - ICOSECS 8, Belgrade, Serbia, June 27-29, 2013: Book of Abstracts, 2013, 131-131
Publisher:
  • Belgrade : Serbian Chemical Society
Funding / projects:
  • Micro- Nanosystems and Sensors for Electric Power and Process Industry and Environmental Protection (RS-MESTD-Technological Development (TD or TR)-32008)
  • Advanced technologies for monitoring and environmental protection from chemical pollutants and radiation burden (RS-MESTD-Integrated and Interdisciplinary Research (IIR or III)-43009)
  • Synthesis and characterization of novel functional polymers and polymeric nanocomposites (RS-MESTD-Basic Research (BR or ON)-172062)
[ Google Scholar ]
Handle
https://hdl.handle.net/21.15107/rcub_vinar_7535
URI
https://vinar.vin.bg.ac.rs/handle/123456789/7535
Collections
  • DAIS Import
Institution/Community
Vinča
TY  - CONF
AU  - Radovanović, Filip
AU  - Tomković, Tanja
AU  - Nastasović, Aleksandra B.
AU  - Veličković, Sava J.
AU  - Nešić, Aleksandra
AU  - Onjia, Antonije E.
PY  - 2013
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/7535
AB  - Ultrafiltration (UF) membranes are currently used in industry for the concentration of proteins and other macromolecules. Performance of UF membranes is generally limited by a trade-off between permeability and selectivity [1]. However, electrically-charged ultrafiltration membranes can provide a dramatic improvement in ultrafiltration performance [2]. Novel UF membranes were made by combining traditional immersion precipitation process for making membranes with photopolymerization of the casting solution comprising polyethersulfone, glycidyl methacrylate and other reactive monomers. Negative charges were introduced either by initially using 2-acrylamido-2-methylpropane sulfonic acid as a reactive monomer, or were later created by epoxide ring opening of crosslinked glycidyl methacrylate. As shown in Fig. 1, selectivity of these membranes significantly improved as the concentration of negatively-charged groups in the membrane increased. The effects of membrane composition on the properties and separation performance of these novel UF membranes will be presented.
PB  - Belgrade : Serbian Chemical Society
C3  - 8th International Conference of the Chemical Societies of the South-East European Countries - ICOSECS 8, Belgrade, Serbia, June 27-29, 2013: Book of Abstracts
T1  - Novel negatively-charged ultrafiltration membranes made by a combination of immersion precipitation and photopolymerization
SP  - 131
EP  - 131
UR  - https://hdl.handle.net/21.15107/rcub_vinar_7535
ER  - 
@conference{
author = "Radovanović, Filip and Tomković, Tanja and Nastasović, Aleksandra B. and Veličković, Sava J. and Nešić, Aleksandra and Onjia, Antonije E.",
year = "2013",
abstract = "Ultrafiltration (UF) membranes are currently used in industry for the concentration of proteins and other macromolecules. Performance of UF membranes is generally limited by a trade-off between permeability and selectivity [1]. However, electrically-charged ultrafiltration membranes can provide a dramatic improvement in ultrafiltration performance [2]. Novel UF membranes were made by combining traditional immersion precipitation process for making membranes with photopolymerization of the casting solution comprising polyethersulfone, glycidyl methacrylate and other reactive monomers. Negative charges were introduced either by initially using 2-acrylamido-2-methylpropane sulfonic acid as a reactive monomer, or were later created by epoxide ring opening of crosslinked glycidyl methacrylate. As shown in Fig. 1, selectivity of these membranes significantly improved as the concentration of negatively-charged groups in the membrane increased. The effects of membrane composition on the properties and separation performance of these novel UF membranes will be presented.",
publisher = "Belgrade : Serbian Chemical Society",
journal = "8th International Conference of the Chemical Societies of the South-East European Countries - ICOSECS 8, Belgrade, Serbia, June 27-29, 2013: Book of Abstracts",
title = "Novel negatively-charged ultrafiltration membranes made by a combination of immersion precipitation and photopolymerization",
pages = "131-131",
url = "https://hdl.handle.net/21.15107/rcub_vinar_7535"
}
Radovanović, F., Tomković, T., Nastasović, A. B., Veličković, S. J., Nešić, A.,& Onjia, A. E.. (2013). Novel negatively-charged ultrafiltration membranes made by a combination of immersion precipitation and photopolymerization. in 8th International Conference of the Chemical Societies of the South-East European Countries - ICOSECS 8, Belgrade, Serbia, June 27-29, 2013: Book of Abstracts
Belgrade : Serbian Chemical Society., 131-131.
https://hdl.handle.net/21.15107/rcub_vinar_7535
Radovanović F, Tomković T, Nastasović AB, Veličković SJ, Nešić A, Onjia AE. Novel negatively-charged ultrafiltration membranes made by a combination of immersion precipitation and photopolymerization. in 8th International Conference of the Chemical Societies of the South-East European Countries - ICOSECS 8, Belgrade, Serbia, June 27-29, 2013: Book of Abstracts. 2013;:131-131.
https://hdl.handle.net/21.15107/rcub_vinar_7535 .
Radovanović, Filip, Tomković, Tanja, Nastasović, Aleksandra B., Veličković, Sava J., Nešić, Aleksandra, Onjia, Antonije E., "Novel negatively-charged ultrafiltration membranes made by a combination of immersion precipitation and photopolymerization" in 8th International Conference of the Chemical Societies of the South-East European Countries - ICOSECS 8, Belgrade, Serbia, June 27-29, 2013: Book of Abstracts (2013):131-131,
https://hdl.handle.net/21.15107/rcub_vinar_7535 .

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