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(E)-4-[(2-Carbamoylhydrazinylidene)methyl]-3-hydroxy-5-hydroxymethyl-2-methylpyridin-1-ium nitrate
dc.creator | Novaković, Slađana B. | |
dc.creator | Bogdanović, Goran A. | |
dc.creator | Leovac, Vukadin M. | |
dc.creator | Rodić, Marko V. | |
dc.creator | Vojinović-Ješić, Ljiljana S. | |
dc.creator | Ivkovic, Sonja | |
dc.date.accessioned | 2018-03-01T23:32:46Z | |
dc.date.available | 2018-03-01T23:32:46Z | |
dc.date.issued | 2013 | |
dc.identifier.issn | 0108-2701 | |
dc.identifier.uri | https://vinar.vin.bg.ac.rs/handle/123456789/5580 | |
dc.description.abstract | The title compound, C9H13N4O3+center dot NO3-, is the first structurally characterized Schiff base derived from semicarbazide and pyridoxal. Unusually for an unsubstituted semicarbazone, the compound adopts a syn conformation, in which the carbonyl O atom is in a cis disposition relative to the azomethine N atom. This arrangement is supported by a pair of hydrogen bonds between the organic cation and the nitrate anion. The cation is essentially planar, with only a hydroxymethyl O atom deviating significantly from the mean plane of the remaining atoms (r.m.s. deviation of the remaining non-H atoms = 0.01 angstrom). The molecules are linked into flat layers by N-H center dot center dot center dot O and C-H center dot center dot center dot O hydrogen bonds. O-H center dot center dot center dot O hydrogen bonds involving the hydroxymethyl group as a donor interconnect the layers into a three-dimensional structure. | en |
dc.relation | info:eu-repo/grantAgreement/MESTD/Basic Research (BR or ON)/172014/RS// | |
dc.rights | restrictedAccess | en |
dc.source | Acta Crystallographica. Section C: Crystal Structure Communications | en |
dc.title | (E)-4-[(2-Carbamoylhydrazinylidene)methyl]-3-hydroxy-5-hydroxymethyl-2-methylpyridin-1-ium nitrate | en |
dc.type | article | en |
dcterms.abstract | Војиновиц-Јесиц, Љиљана С.; Леовац, Вукадин М.; Ивковиц, Соња; Новаковић Слађана; Богдановић Горан; Родиц, Марко В.; | |
dc.citation.volume | 69 | |
dc.citation.spage | 761 | |
dc.citation.epage | + | |
dc.identifier.wos | 000321458200017 | |
dc.identifier.doi | 10.1107/S0108270113013929 | |
dc.citation.other | Part number: 7 | |
dc.citation.rank | M23 | |
dc.identifier.pmid | 23832038 | |
dc.identifier.scopus | 2-s2.0-84880179167 |
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