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Structural and photoluminescence properties of Y2O3 and Y2O3:Ln3+ (Ln = Eu, Er, Ho) films synthesized by plasma electrolytic oxidation of yttrium substrate

Authorized Users Only
2020
Authors
Ćirić, Aleksandar
Stojadinović, Stevan
Article (Published version)
Metadata
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Abstract
Plasma electrolytic oxidation (PEO) of yttrium is performed for the first time and is shown that Y2O3 and trivalent rare-earth ions (Eu3+, Er3+ or Ho3+) doped Y2O3 films can be formed by PEO in alkaline electrolyte without or with addition of rare-earth oxide particles (Eu2O3, Er2O3 or Ho2O3), respectively. The elements present in PEO micro-discharges were identified using optical emission spectroscopy technique. The gas plasma temperature of (3000 ± 300) K was estimated from the intensity distribution within a part of an OH spectrum. The morphology, chemical composition, crystal structure, formation process and photoluminescence (PL) properties of formed films were investigated. Diffraction patterns of formed films show well pronounced reflections inherent to pure cubic phase of Y2O3. PL characterization of Y2O3 and Y2O3:Ln3+ (Ln = Eu, Er, Ho) films is performed through excitation and emission spectra. An intense red PL emission was observed from the Y2O3:Eu3+ and a green emission was... observed from Y2O3:Er3+ and Y2O3:Ho3+ films.

Keywords:
Photoluminescence / Plasma electrolytic oxidation / Y2O3 / Rare-earth
Source:
Journal of Luminescence, 2020, 217, 116762-
Funding / projects:
  • Graphitic and Inorganic Low-dimensional Nanostructures (RS-MESTD-Basic Research (BR or ON)-171035)

DOI: 10.1016/j.jlumin.2019.116762

ISSN: 0022-2313

Scopus: 2-s2.0-85072624822
[ Google Scholar ]
URI
https://vinar.vin.bg.ac.rs/handle/123456789/15153
Collections
  • Radovi istraživača pre dolaska u INNV / Researchers' papers before joining INNV
Institution/Community
Vinča
TY  - JOUR
AU  - Ćirić, Aleksandar
AU  - Stojadinović, Stevan
PY  - 2020
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/15153
AB  - Plasma electrolytic oxidation (PEO) of yttrium is performed for the first time and is shown that Y2O3 and trivalent rare-earth ions (Eu3+, Er3+ or Ho3+) doped Y2O3 films can be formed by PEO in alkaline electrolyte without or with addition of rare-earth oxide particles (Eu2O3, Er2O3 or Ho2O3), respectively. The elements present in PEO micro-discharges were identified using optical emission spectroscopy technique. The gas plasma temperature of (3000 ± 300) K was estimated from the intensity distribution within a part of an OH spectrum. The morphology, chemical composition, crystal structure, formation process and photoluminescence (PL) properties of formed films were investigated. Diffraction patterns of formed films show well pronounced reflections inherent to pure cubic phase of Y2O3. PL characterization of Y2O3 and Y2O3:Ln3+ (Ln = Eu, Er, Ho) films is performed through excitation and emission spectra. An intense red PL emission was observed from the Y2O3:Eu3+ and a green emission was observed from Y2O3:Er3+ and Y2O3:Ho3+ films.
T2  - Journal of Luminescence
T1  - Structural and photoluminescence properties of Y2O3 and Y2O3:Ln3+ (Ln = Eu, Er, Ho) films synthesized by plasma electrolytic oxidation of yttrium substrate
VL  - 217
SP  - 116762
DO  - 10.1016/j.jlumin.2019.116762
ER  - 
@article{
author = "Ćirić, Aleksandar and Stojadinović, Stevan",
year = "2020",
abstract = "Plasma electrolytic oxidation (PEO) of yttrium is performed for the first time and is shown that Y2O3 and trivalent rare-earth ions (Eu3+, Er3+ or Ho3+) doped Y2O3 films can be formed by PEO in alkaline electrolyte without or with addition of rare-earth oxide particles (Eu2O3, Er2O3 or Ho2O3), respectively. The elements present in PEO micro-discharges were identified using optical emission spectroscopy technique. The gas plasma temperature of (3000 ± 300) K was estimated from the intensity distribution within a part of an OH spectrum. The morphology, chemical composition, crystal structure, formation process and photoluminescence (PL) properties of formed films were investigated. Diffraction patterns of formed films show well pronounced reflections inherent to pure cubic phase of Y2O3. PL characterization of Y2O3 and Y2O3:Ln3+ (Ln = Eu, Er, Ho) films is performed through excitation and emission spectra. An intense red PL emission was observed from the Y2O3:Eu3+ and a green emission was observed from Y2O3:Er3+ and Y2O3:Ho3+ films.",
journal = "Journal of Luminescence",
title = "Structural and photoluminescence properties of Y2O3 and Y2O3:Ln3+ (Ln = Eu, Er, Ho) films synthesized by plasma electrolytic oxidation of yttrium substrate",
volume = "217",
pages = "116762",
doi = "10.1016/j.jlumin.2019.116762"
}
Ćirić, A.,& Stojadinović, S.. (2020). Structural and photoluminescence properties of Y2O3 and Y2O3:Ln3+ (Ln = Eu, Er, Ho) films synthesized by plasma electrolytic oxidation of yttrium substrate. in Journal of Luminescence, 217, 116762.
https://doi.org/10.1016/j.jlumin.2019.116762
Ćirić A, Stojadinović S. Structural and photoluminescence properties of Y2O3 and Y2O3:Ln3+ (Ln = Eu, Er, Ho) films synthesized by plasma electrolytic oxidation of yttrium substrate. in Journal of Luminescence. 2020;217:116762.
doi:10.1016/j.jlumin.2019.116762 .
Ćirić, Aleksandar, Stojadinović, Stevan, "Structural and photoluminescence properties of Y2O3 and Y2O3:Ln3+ (Ln = Eu, Er, Ho) films synthesized by plasma electrolytic oxidation of yttrium substrate" in Journal of Luminescence, 217 (2020):116762,
https://doi.org/10.1016/j.jlumin.2019.116762 . .

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