Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200017 (University of Belgrade, Institute of Nuclear Sciences 'Vinča', Belgrade-Vinča)

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Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200017 (University of Belgrade, Institute of Nuclear Sciences 'Vinča', Belgrade-Vinča) (en)
Ministarstvo prosvete, nauke i tehnološkog razvoja Republike Srbije, Ugovor br. 451-03-68/2020-14/200017 (Univerzitet u Beogradu, Institut za nuklearne nauke Vinča, Beograd-Vinča) (sr_RS)
Министарство просвете, науке и технолошког развоја Републике Србије, Уговор бр. 451-03-68/2020-14/200017 (Универзитет у Београду, Институт за нуклеарне науке Винча, Београд-Винча) (sr)
Authors

Publications

Enthalpy–entropy compensation and isoequilibrium relationship in thermo-chemical conversion of cigarette butt filters (CBFs) based on cellulose acetate (CA): causes and effects

Janković, Bojan; Marinović-Cincović, Milena; Manić, Nebojša; Janković, Marija; Waisi, Hadi; Dodevski, Vladimir

(2024)

TY  - JOUR
AU  - Janković, Bojan
AU  - Marinović-Cincović, Milena
AU  - Manić, Nebojša
AU  - Janković, Marija
AU  - Waisi, Hadi
AU  - Dodevski, Vladimir
PY  - 2024
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/13370
AB  - The aim of this study is to explain the consequences of the occurrence of enthalpy–entropy compensation (EEC) and isoequilibrium relationship during slow pyrolysis of cigarette butt filters (CBFs), consisting cellulose acetate (AC) as the main component. By using model-free and model-based kinetic methods and thermodynamic calculations, the complete reaction mechanism and extrathermodynamic issues about investigated process are completely resolved. It was established that compensation phenomenon where isoequilibrium temperature occurs is a consequence of formation of low-entropy molecular structure (cellulose II) and breaking of hydrogen bonds. Consequently, it was concluded that mechanisms which include a formation of low-entropy molecular structure and H-bonds breakage enter the changes in both enthalpy and entropy, which compensate each other. For the cellulose II generation, it was necessary to invest energy which represents use up energy. This “wasted” energy turns into work for creation of cellulose II molecular structures, whereby additional energy was provided from “local” decomposition reactions (which were identified in the established process mechanism) that arise from pyrolysis of starting material. Therefore, it was concluded that for “local reactions”, a negative ΔS° value was identified, but for the global process, the entropy change retained a positive value. Considering thermodynamic effects manifested through compensation temperature found below glass transition temperature (Tg) in the undercooling conditions, it was concluded that small amounts of plasticizers affect reduction of free volume in the glassy state. Obtained results indicated a decrease in β-relaxation mode of cellulose acetate by an abatement of the polymer free volume.
T2  - Polymer Bulletin
T1  - Enthalpy–entropy compensation and isoequilibrium relationship in thermo-chemical conversion of cigarette butt filters (CBFs) based on cellulose acetate (CA): causes and effects
DO  - 10.1007/s00289-024-05343-5
ER  - 
@article{
author = "Janković, Bojan and Marinović-Cincović, Milena and Manić, Nebojša and Janković, Marija and Waisi, Hadi and Dodevski, Vladimir",
year = "2024",
abstract = "The aim of this study is to explain the consequences of the occurrence of enthalpy–entropy compensation (EEC) and isoequilibrium relationship during slow pyrolysis of cigarette butt filters (CBFs), consisting cellulose acetate (AC) as the main component. By using model-free and model-based kinetic methods and thermodynamic calculations, the complete reaction mechanism and extrathermodynamic issues about investigated process are completely resolved. It was established that compensation phenomenon where isoequilibrium temperature occurs is a consequence of formation of low-entropy molecular structure (cellulose II) and breaking of hydrogen bonds. Consequently, it was concluded that mechanisms which include a formation of low-entropy molecular structure and H-bonds breakage enter the changes in both enthalpy and entropy, which compensate each other. For the cellulose II generation, it was necessary to invest energy which represents use up energy. This “wasted” energy turns into work for creation of cellulose II molecular structures, whereby additional energy was provided from “local” decomposition reactions (which were identified in the established process mechanism) that arise from pyrolysis of starting material. Therefore, it was concluded that for “local reactions”, a negative ΔS° value was identified, but for the global process, the entropy change retained a positive value. Considering thermodynamic effects manifested through compensation temperature found below glass transition temperature (Tg) in the undercooling conditions, it was concluded that small amounts of plasticizers affect reduction of free volume in the glassy state. Obtained results indicated a decrease in β-relaxation mode of cellulose acetate by an abatement of the polymer free volume.",
journal = "Polymer Bulletin",
title = "Enthalpy–entropy compensation and isoequilibrium relationship in thermo-chemical conversion of cigarette butt filters (CBFs) based on cellulose acetate (CA): causes and effects",
doi = "10.1007/s00289-024-05343-5"
}
Janković, B., Marinović-Cincović, M., Manić, N., Janković, M., Waisi, H.,& Dodevski, V.. (2024). Enthalpy–entropy compensation and isoequilibrium relationship in thermo-chemical conversion of cigarette butt filters (CBFs) based on cellulose acetate (CA): causes and effects. in Polymer Bulletin.
https://doi.org/10.1007/s00289-024-05343-5
Janković B, Marinović-Cincović M, Manić N, Janković M, Waisi H, Dodevski V. Enthalpy–entropy compensation and isoequilibrium relationship in thermo-chemical conversion of cigarette butt filters (CBFs) based on cellulose acetate (CA): causes and effects. in Polymer Bulletin. 2024;.
doi:10.1007/s00289-024-05343-5 .
Janković, Bojan, Marinović-Cincović, Milena, Manić, Nebojša, Janković, Marija, Waisi, Hadi, Dodevski, Vladimir, "Enthalpy–entropy compensation and isoequilibrium relationship in thermo-chemical conversion of cigarette butt filters (CBFs) based on cellulose acetate (CA): causes and effects" in Polymer Bulletin (2024),
https://doi.org/10.1007/s00289-024-05343-5 . .

Novel insights into the problem of enthalpy and entropy convergence in thermal decomposition of coal slag using the data from non-isothermal kinetic measurements

Janković, Bojan; Janković, Marija; Smičiklas, Ivana; Jović, Mihajlo; Vukanac, Ivana; Mraković, Ana; Manić, Nebojša

(2024)

TY  - JOUR
AU  - Janković, Bojan
AU  - Janković, Marija
AU  - Smičiklas, Ivana
AU  - Jović, Mihajlo
AU  - Vukanac, Ivana
AU  - Mraković, Ana
AU  - Manić, Nebojša
PY  - 2024
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/13237
AB  - This study provides insight into benefits of thermo-chemical conversion of coal slag as recovery process into value-added products. This research involves kinetic analysis of process conducted through non-isothermal thermal analysis measurements, with additional raw material characterization. Kinetic results showed that decomposition proceeds through two consecutive reactions steps (first one, including anorthite P1‾ → I1‾ phase transition, and then production of incongruent melting product (ternary system: CaO⋅Al2O3⋅2SiO2 (CAS2), where viscosity of slag changes), and second one including dehydration and formation of meta-muscovite, and subsequently, thermal disruption of muscovite de-hydroxylated phase, which proceeds with breaking of octahedral Al–O bonds), and one single-step reaction (attributed to CO-reduction of hematite to magnetite). Thermodynamic results showed an existence of physically meaningful isokinetic temperature (Tiso), which corresponds to active vibrational frequency of surroundings of SiO2 reaction site, manifested through Si‒O bond weakening by catalytic reaction of freed hydroxide ion (OH􀀀 ). It was concluded that at temperature T = Tiso, the course of process loses its dependence on temperature and pressure, regulating changes between thermodynamic parameters, through enthalpy-entropy compensation (EEC) effect.
T2  - Thermochimica Acta
T1  - Novel insights into the problem of enthalpy and entropy convergence in thermal decomposition of coal slag using the data from non-isothermal kinetic measurements
VL  - 736
SP  - 179763
DO  - 10.1016/j.tca.2024.179763
ER  - 
@article{
author = "Janković, Bojan and Janković, Marija and Smičiklas, Ivana and Jović, Mihajlo and Vukanac, Ivana and Mraković, Ana and Manić, Nebojša",
year = "2024",
abstract = "This study provides insight into benefits of thermo-chemical conversion of coal slag as recovery process into value-added products. This research involves kinetic analysis of process conducted through non-isothermal thermal analysis measurements, with additional raw material characterization. Kinetic results showed that decomposition proceeds through two consecutive reactions steps (first one, including anorthite P1‾ → I1‾ phase transition, and then production of incongruent melting product (ternary system: CaO⋅Al2O3⋅2SiO2 (CAS2), where viscosity of slag changes), and second one including dehydration and formation of meta-muscovite, and subsequently, thermal disruption of muscovite de-hydroxylated phase, which proceeds with breaking of octahedral Al–O bonds), and one single-step reaction (attributed to CO-reduction of hematite to magnetite). Thermodynamic results showed an existence of physically meaningful isokinetic temperature (Tiso), which corresponds to active vibrational frequency of surroundings of SiO2 reaction site, manifested through Si‒O bond weakening by catalytic reaction of freed hydroxide ion (OH􀀀 ). It was concluded that at temperature T = Tiso, the course of process loses its dependence on temperature and pressure, regulating changes between thermodynamic parameters, through enthalpy-entropy compensation (EEC) effect.",
journal = "Thermochimica Acta",
title = "Novel insights into the problem of enthalpy and entropy convergence in thermal decomposition of coal slag using the data from non-isothermal kinetic measurements",
volume = "736",
pages = "179763",
doi = "10.1016/j.tca.2024.179763"
}
Janković, B., Janković, M., Smičiklas, I., Jović, M., Vukanac, I., Mraković, A.,& Manić, N.. (2024). Novel insights into the problem of enthalpy and entropy convergence in thermal decomposition of coal slag using the data from non-isothermal kinetic measurements. in Thermochimica Acta, 736, 179763.
https://doi.org/10.1016/j.tca.2024.179763
Janković B, Janković M, Smičiklas I, Jović M, Vukanac I, Mraković A, Manić N. Novel insights into the problem of enthalpy and entropy convergence in thermal decomposition of coal slag using the data from non-isothermal kinetic measurements. in Thermochimica Acta. 2024;736:179763.
doi:10.1016/j.tca.2024.179763 .
Janković, Bojan, Janković, Marija, Smičiklas, Ivana, Jović, Mihajlo, Vukanac, Ivana, Mraković, Ana, Manić, Nebojša, "Novel insights into the problem of enthalpy and entropy convergence in thermal decomposition of coal slag using the data from non-isothermal kinetic measurements" in Thermochimica Acta, 736 (2024):179763,
https://doi.org/10.1016/j.tca.2024.179763 . .

Application of Model-Free and Model-Based Kinetic Methods in Evaluation of Reactions Complexity during Thermo-Oxidative Degradation Process: Case Study of [4-(Hydroxymethyl)phenoxymethyl] Polystyrene Resin

Janković, Bojan Ž.; Dodevski, Vladimir; Veljković, Filip M.; Janković, Marija M.; Manić, Nebojša

(2024)

TY  - JOUR
AU  - Janković, Bojan Ž.
AU  - Dodevski, Vladimir
AU  - Veljković, Filip M.
AU  - Janković, Marija M.
AU  - Manić, Nebojša
PY  - 2024
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/13254
AB  - This work examined the possibilities and limitations of model-free and model-based methods related to decrypting the kinetic complexity of multi-step thermo-oxidative degradation processes (as a testing system, a [4-(hydroxymethyl)phenoxymethyl] polystyrene resin was used), monitored by thermal analysis (TGA-DTG-DTA) techniques. It was found that isoconversional methods could successfully determine the correct number of process stages and presence of multiple reactions based on derived Ea(α) profiles and identify the negative dependence of the rate constant on the temperature. These methods could not overcome the problem that arose due to mass transfer limitations. The model-based method overcame more successfully the problem associated with mass transfer because its calculation machinery had capabilities for the correct solution of the total mass balance equation. However, a perfect fit with the experimental data was not achieved due to the dependence on the thermal history of the contribution (ctb.) of a given reaction step inside a fitting procedure cycle. On the other hand, through this approach, it was possible to estimate the rate-controlling steps of the process regarding the influence of the heating rate. It was found that for consecutive reaction mechanisms, the production of benzaldehyde and gases in high yields was controlled by the heating rate, where low heating rates were strongly recommended (≤10 K/min). Also, it was shown that the transport phenomenon may be also the rate-determining step (within the set of “intrinsic” kinetic parameters). It was also established that external heat transfer controls the overall rate, where the “pure” kinetic control regime had not been reached but was approached when lowering the temperature and size of the resin particles.
T2  - Fire
T1  - Application of Model-Free and Model-Based Kinetic Methods in Evaluation of Reactions Complexity during Thermo-Oxidative Degradation Process: Case Study of [4-(Hydroxymethyl)phenoxymethyl] Polystyrene Resin
VL  - 7
IS  - 5
SP  - 165
DO  - 10.3390/fire7050165
ER  - 
@article{
author = "Janković, Bojan Ž. and Dodevski, Vladimir and Veljković, Filip M. and Janković, Marija M. and Manić, Nebojša",
year = "2024",
abstract = "This work examined the possibilities and limitations of model-free and model-based methods related to decrypting the kinetic complexity of multi-step thermo-oxidative degradation processes (as a testing system, a [4-(hydroxymethyl)phenoxymethyl] polystyrene resin was used), monitored by thermal analysis (TGA-DTG-DTA) techniques. It was found that isoconversional methods could successfully determine the correct number of process stages and presence of multiple reactions based on derived Ea(α) profiles and identify the negative dependence of the rate constant on the temperature. These methods could not overcome the problem that arose due to mass transfer limitations. The model-based method overcame more successfully the problem associated with mass transfer because its calculation machinery had capabilities for the correct solution of the total mass balance equation. However, a perfect fit with the experimental data was not achieved due to the dependence on the thermal history of the contribution (ctb.) of a given reaction step inside a fitting procedure cycle. On the other hand, through this approach, it was possible to estimate the rate-controlling steps of the process regarding the influence of the heating rate. It was found that for consecutive reaction mechanisms, the production of benzaldehyde and gases in high yields was controlled by the heating rate, where low heating rates were strongly recommended (≤10 K/min). Also, it was shown that the transport phenomenon may be also the rate-determining step (within the set of “intrinsic” kinetic parameters). It was also established that external heat transfer controls the overall rate, where the “pure” kinetic control regime had not been reached but was approached when lowering the temperature and size of the resin particles.",
journal = "Fire",
title = "Application of Model-Free and Model-Based Kinetic Methods in Evaluation of Reactions Complexity during Thermo-Oxidative Degradation Process: Case Study of [4-(Hydroxymethyl)phenoxymethyl] Polystyrene Resin",
volume = "7",
number = "5",
pages = "165",
doi = "10.3390/fire7050165"
}
Janković, B. Ž., Dodevski, V., Veljković, F. M., Janković, M. M.,& Manić, N.. (2024). Application of Model-Free and Model-Based Kinetic Methods in Evaluation of Reactions Complexity during Thermo-Oxidative Degradation Process: Case Study of [4-(Hydroxymethyl)phenoxymethyl] Polystyrene Resin. in Fire, 7(5), 165.
https://doi.org/10.3390/fire7050165
Janković BŽ, Dodevski V, Veljković FM, Janković MM, Manić N. Application of Model-Free and Model-Based Kinetic Methods in Evaluation of Reactions Complexity during Thermo-Oxidative Degradation Process: Case Study of [4-(Hydroxymethyl)phenoxymethyl] Polystyrene Resin. in Fire. 2024;7(5):165.
doi:10.3390/fire7050165 .
Janković, Bojan Ž., Dodevski, Vladimir, Veljković, Filip M., Janković, Marija M., Manić, Nebojša, "Application of Model-Free and Model-Based Kinetic Methods in Evaluation of Reactions Complexity during Thermo-Oxidative Degradation Process: Case Study of [4-(Hydroxymethyl)phenoxymethyl] Polystyrene Resin" in Fire, 7, no. 5 (2024):165,
https://doi.org/10.3390/fire7050165 . .

Complete removal of organophosphate pesticides from wastewaters with sustainable ionic liquid-based aqueous two-phase strategy

Jocić, Ana; Marić, Slađana; Tekić, Danijela; Lazarević-Pašti, Tamara; Mušović, Jasmina; Filipović Tričković, Jelena; Dimitrijević, Aleksandra

(2024)

TY  - JOUR
AU  - Jocić, Ana
AU  - Marić, Slađana
AU  - Tekić, Danijela
AU  - Lazarević-Pašti, Tamara
AU  - Mušović, Jasmina
AU  - Filipović Tričković, Jelena
AU  - Dimitrijević, Aleksandra
PY  - 2024
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/13329
AB  - Due to extensive food production, organophosphate pesticides (OPs) are widely utilized for crop protection, leading to their presence in the environment. The focus of this study was the design of an efficient aqueous biphasic system (ABS) strategy for OP removal, namely, malathion (MAL), azinphos-methyl (AZM), and chlorpyrifos (CHP) from water. Different ionic liquids (ILs) with symmetrical cations were selected as ABS phase- formers (tetrabutylphosphonium salicylate, tetrabutylammonium salicylate, 1,3-dibutylimidazolium dicyanamide, 1,3-dibutylimidazolium salicylate and 1,3-dibutylimidazolium bromide) with citrate salt as a salting-out agent. Initially, phase diagrams were determined, followed by partition studies revealing that the partition of MAL and CHP aligns with the IL- ABS formation trend, while the AZM partition is governed by specific interactions with ILs. For optimization studies, tetrabutylphosphonium-salicylate i.e. [TBP][Sal]-based ABS was chosen, due to obtained high extraction efficiencies of over 99.3 %. After establishing the effects of pH, temperature, tie-line length, and phase ratio on extraction performance, extraction of OPs from a real wastewater sample further confirmed the effectiveness of the designed method achieving complete removal of each pesticide. Furthermore, recovery of IL was achieved using an antisolvent method to precipitate CHP followed by IL-reuse in three consecutive cycles without efficiency decreased. Finally, it was demonstrated that [TBP][Sal] exhibits low cytotoxic potential, indicating that the presence of low amounts of this IL in aqueous media could be acceptable from ecotoxicological standpoint. This study showcased the exceptional potential of the proposed technology for the efficient and sustainable treatment of wastewater contaminated with OPs, affirming its capability to treat significant wastewater volumes.
T2  - Journal of Water Process Engineering
T1  - Complete removal of organophosphate pesticides from wastewaters with sustainable ionic liquid-based aqueous two-phase strategy
VL  - 64
SP  - 105621
DO  - 10.1016/j.jwpe.2024.105621
ER  - 
@article{
author = "Jocić, Ana and Marić, Slađana and Tekić, Danijela and Lazarević-Pašti, Tamara and Mušović, Jasmina and Filipović Tričković, Jelena and Dimitrijević, Aleksandra",
year = "2024",
abstract = "Due to extensive food production, organophosphate pesticides (OPs) are widely utilized for crop protection, leading to their presence in the environment. The focus of this study was the design of an efficient aqueous biphasic system (ABS) strategy for OP removal, namely, malathion (MAL), azinphos-methyl (AZM), and chlorpyrifos (CHP) from water. Different ionic liquids (ILs) with symmetrical cations were selected as ABS phase- formers (tetrabutylphosphonium salicylate, tetrabutylammonium salicylate, 1,3-dibutylimidazolium dicyanamide, 1,3-dibutylimidazolium salicylate and 1,3-dibutylimidazolium bromide) with citrate salt as a salting-out agent. Initially, phase diagrams were determined, followed by partition studies revealing that the partition of MAL and CHP aligns with the IL- ABS formation trend, while the AZM partition is governed by specific interactions with ILs. For optimization studies, tetrabutylphosphonium-salicylate i.e. [TBP][Sal]-based ABS was chosen, due to obtained high extraction efficiencies of over 99.3 %. After establishing the effects of pH, temperature, tie-line length, and phase ratio on extraction performance, extraction of OPs from a real wastewater sample further confirmed the effectiveness of the designed method achieving complete removal of each pesticide. Furthermore, recovery of IL was achieved using an antisolvent method to precipitate CHP followed by IL-reuse in three consecutive cycles without efficiency decreased. Finally, it was demonstrated that [TBP][Sal] exhibits low cytotoxic potential, indicating that the presence of low amounts of this IL in aqueous media could be acceptable from ecotoxicological standpoint. This study showcased the exceptional potential of the proposed technology for the efficient and sustainable treatment of wastewater contaminated with OPs, affirming its capability to treat significant wastewater volumes.",
journal = "Journal of Water Process Engineering",
title = "Complete removal of organophosphate pesticides from wastewaters with sustainable ionic liquid-based aqueous two-phase strategy",
volume = "64",
pages = "105621",
doi = "10.1016/j.jwpe.2024.105621"
}
Jocić, A., Marić, S., Tekić, D., Lazarević-Pašti, T., Mušović, J., Filipović Tričković, J.,& Dimitrijević, A.. (2024). Complete removal of organophosphate pesticides from wastewaters with sustainable ionic liquid-based aqueous two-phase strategy. in Journal of Water Process Engineering, 64, 105621.
https://doi.org/10.1016/j.jwpe.2024.105621
Jocić A, Marić S, Tekić D, Lazarević-Pašti T, Mušović J, Filipović Tričković J, Dimitrijević A. Complete removal of organophosphate pesticides from wastewaters with sustainable ionic liquid-based aqueous two-phase strategy. in Journal of Water Process Engineering. 2024;64:105621.
doi:10.1016/j.jwpe.2024.105621 .
Jocić, Ana, Marić, Slađana, Tekić, Danijela, Lazarević-Pašti, Tamara, Mušović, Jasmina, Filipović Tričković, Jelena, Dimitrijević, Aleksandra, "Complete removal of organophosphate pesticides from wastewaters with sustainable ionic liquid-based aqueous two-phase strategy" in Journal of Water Process Engineering, 64 (2024):105621,
https://doi.org/10.1016/j.jwpe.2024.105621 . .

Time-resolved photoacoustic response of thin solids measured using minimal volume cell

Galović, Slobodanka; Stanimirović, Zdravko; Stanimirović, Ivanka; Đorđević, Katarina Lj.; Miličević, Dejan; Suljovrujić, Edin H.

(2024)

TY  - JOUR
AU  - Galović, Slobodanka
AU  - Stanimirović, Zdravko
AU  - Stanimirović, Ivanka
AU  - Đorđević, Katarina Lj.
AU  - Miličević, Dejan
AU  - Suljovrujić, Edin H.
PY  - 2024
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/13250
AB  - The photoacoustic effect was explained more than half a century ago and has since been used to develop non-destructive and non-contact techniques for testing materials. Most existing experimental setups are time-consuming. In this paper, we deal with the development of time-resolved photoacoustics to use all the advantages of photoacoustic techniques in the development of real-time characterization of various samples. We propose a model for a time-resolved photoacoustic signal of thin samples measured in a gas-microphone setup with a minimal volume cell, assuming that the gas column in the cell can be shorter than the thermal diffusion length in air. The derived model additionally includes the influence of thermal relaxations and detector transfer function. We also suggest a methodology for inverse problem solving, i.e., to determine the sample properties from measured signals using the presented model. The model has been validated by comparing the model predictions with an experimentally measured signal for a thin metallic sample excited by an optical pulse train of a repetition rate of 12 Hz. The results obtained by the suggested inverse-problem solving methodology are in accordance with the literature, thus confirming the validity of the proposed methodology. We have shown that the proposed model and the methodology of inverse time-resolved photoacoustic problems give the same results as the widespread time-consuming frequency photoacoustic measurements. This means that the presented model and methodology enable the employment of low-frequency time-resolved gas-microphone photoacoustics in the real-time characterization of thin solids.
T2  - International Communications in Heat and Mass Transfer
T1  - Time-resolved photoacoustic response of thin solids measured using minimal volume cell
VL  - 155
SP  - 107574
DO  - 10.1016/j.icheatmasstransfer.2024.107574
ER  - 
@article{
author = "Galović, Slobodanka and Stanimirović, Zdravko and Stanimirović, Ivanka and Đorđević, Katarina Lj. and Miličević, Dejan and Suljovrujić, Edin H.",
year = "2024",
abstract = "The photoacoustic effect was explained more than half a century ago and has since been used to develop non-destructive and non-contact techniques for testing materials. Most existing experimental setups are time-consuming. In this paper, we deal with the development of time-resolved photoacoustics to use all the advantages of photoacoustic techniques in the development of real-time characterization of various samples. We propose a model for a time-resolved photoacoustic signal of thin samples measured in a gas-microphone setup with a minimal volume cell, assuming that the gas column in the cell can be shorter than the thermal diffusion length in air. The derived model additionally includes the influence of thermal relaxations and detector transfer function. We also suggest a methodology for inverse problem solving, i.e., to determine the sample properties from measured signals using the presented model. The model has been validated by comparing the model predictions with an experimentally measured signal for a thin metallic sample excited by an optical pulse train of a repetition rate of 12 Hz. The results obtained by the suggested inverse-problem solving methodology are in accordance with the literature, thus confirming the validity of the proposed methodology. We have shown that the proposed model and the methodology of inverse time-resolved photoacoustic problems give the same results as the widespread time-consuming frequency photoacoustic measurements. This means that the presented model and methodology enable the employment of low-frequency time-resolved gas-microphone photoacoustics in the real-time characterization of thin solids.",
journal = "International Communications in Heat and Mass Transfer",
title = "Time-resolved photoacoustic response of thin solids measured using minimal volume cell",
volume = "155",
pages = "107574",
doi = "10.1016/j.icheatmasstransfer.2024.107574"
}
Galović, S., Stanimirović, Z., Stanimirović, I., Đorđević, K. Lj., Miličević, D.,& Suljovrujić, E. H.. (2024). Time-resolved photoacoustic response of thin solids measured using minimal volume cell. in International Communications in Heat and Mass Transfer, 155, 107574.
https://doi.org/10.1016/j.icheatmasstransfer.2024.107574
Galović S, Stanimirović Z, Stanimirović I, Đorđević KL, Miličević D, Suljovrujić EH. Time-resolved photoacoustic response of thin solids measured using minimal volume cell. in International Communications in Heat and Mass Transfer. 2024;155:107574.
doi:10.1016/j.icheatmasstransfer.2024.107574 .
Galović, Slobodanka, Stanimirović, Zdravko, Stanimirović, Ivanka, Đorđević, Katarina Lj., Miličević, Dejan, Suljovrujić, Edin H., "Time-resolved photoacoustic response of thin solids measured using minimal volume cell" in International Communications in Heat and Mass Transfer, 155 (2024):107574,
https://doi.org/10.1016/j.icheatmasstransfer.2024.107574 . .

Application of neural network to study of frequency range effect to photoacoustic measurement of thermoelastic properties of thin aluminum samples

Đorđević, Katarina Lj.; Stoisavljević, Z.Z.; Dragaš, M.A.; Stanimirović, I.; Stanimirović, Z.; Suljovrujić, Edin; Galović, Slobodanka

(2024)

TY  - JOUR
AU  - Đorđević, Katarina Lj.
AU  - Stoisavljević, Z.Z.
AU  - Dragaš, M.A.
AU  - Stanimirović, I.
AU  - Stanimirović, Z.
AU  - Suljovrujić, Edin
AU  - Galović, Slobodanka
PY  - 2024
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/13368
AB  - In this paper, the influence of the measurement range on the prediction of thermoelastic and geometric properties of a thin aluminum sample obtained by solving the inverse photoacoustic problem using neural networks was analyzed. Tests of neural networks on theoretical photoacoustic signals showed that the accuracy of solving the inverse problem increases with the increase of the measurement range, which is in accordance with the theory of solving inverse problems. Tests on experimentally measured signals in a transmission experimental setup with an open photoacoustic cell, from which the influence of the transmission characteristic of the detector was removed, show the advantages of using narrow frequency bands. This result indicates the need for further investigations of both: the influence of the measuring chain on the recorded signal and the influence of additional processes and sample properties on the thermoelastic behavior of thin metal films.
T2  - Measurement
T1  - Application of neural network to study of frequency range effect to photoacoustic measurement of thermoelastic properties of thin aluminum samples
VL  - 236
SP  - 115043
DO  - 10.1016/j.measurement.2024.115043
ER  - 
@article{
author = "Đorđević, Katarina Lj. and Stoisavljević, Z.Z. and Dragaš, M.A. and Stanimirović, I. and Stanimirović, Z. and Suljovrujić, Edin and Galović, Slobodanka",
year = "2024",
abstract = "In this paper, the influence of the measurement range on the prediction of thermoelastic and geometric properties of a thin aluminum sample obtained by solving the inverse photoacoustic problem using neural networks was analyzed. Tests of neural networks on theoretical photoacoustic signals showed that the accuracy of solving the inverse problem increases with the increase of the measurement range, which is in accordance with the theory of solving inverse problems. Tests on experimentally measured signals in a transmission experimental setup with an open photoacoustic cell, from which the influence of the transmission characteristic of the detector was removed, show the advantages of using narrow frequency bands. This result indicates the need for further investigations of both: the influence of the measuring chain on the recorded signal and the influence of additional processes and sample properties on the thermoelastic behavior of thin metal films.",
journal = "Measurement",
title = "Application of neural network to study of frequency range effect to photoacoustic measurement of thermoelastic properties of thin aluminum samples",
volume = "236",
pages = "115043",
doi = "10.1016/j.measurement.2024.115043"
}
Đorđević, K. Lj., Stoisavljević, Z.Z., Dragaš, M.A., Stanimirović, I., Stanimirović, Z., Suljovrujić, E.,& Galović, S.. (2024). Application of neural network to study of frequency range effect to photoacoustic measurement of thermoelastic properties of thin aluminum samples. in Measurement, 236, 115043.
https://doi.org/10.1016/j.measurement.2024.115043
Đorđević KL, Stoisavljević Z, Dragaš M, Stanimirović I, Stanimirović Z, Suljovrujić E, Galović S. Application of neural network to study of frequency range effect to photoacoustic measurement of thermoelastic properties of thin aluminum samples. in Measurement. 2024;236:115043.
doi:10.1016/j.measurement.2024.115043 .
Đorđević, Katarina Lj., Stoisavljević, Z.Z., Dragaš, M.A., Stanimirović, I., Stanimirović, Z., Suljovrujić, Edin, Galović, Slobodanka, "Application of neural network to study of frequency range effect to photoacoustic measurement of thermoelastic properties of thin aluminum samples" in Measurement, 236 (2024):115043,
https://doi.org/10.1016/j.measurement.2024.115043 . .

Medical application of polylactide (PLA)

Stoisavljević, Zorana; Galović, Slobodanka; Đorđević, Katarina Lj.

(2024)

TY  - JOUR
AU  - Stoisavljević, Zorana
AU  - Galović, Slobodanka
AU  - Đorđević, Katarina Lj.
PY  - 2024
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/12953
AB  - In this paper, the possibilities of using polylactide (PLA) in various fields of medicine are briefly mentioned. Also, the most important characteristics of this biomaterial are described and examples of the two most common polymers that have significant medical applications are given.
AB  - U ovom radu su ukratko navedene mogućnosti primene polilaktida (PLA) u različitim oblastima medicine. Takođe, opisane su najznačajnije karakteristike ovog biomaterijala i dati primeri dva najzastupljenija polimera koja imaju značajnu medicinsku primenu.
T2  - Tehnika
T1  - Medical application of polylactide (PLA)
T1  - Medicinska primena polilaktida (PLA)
VL  - 79
IS  - 1
SP  - 14
EP  - 19
DO  - 10.5937/tehnika2401014S
ER  - 
@article{
author = "Stoisavljević, Zorana and Galović, Slobodanka and Đorđević, Katarina Lj.",
year = "2024",
abstract = "In this paper, the possibilities of using polylactide (PLA) in various fields of medicine are briefly mentioned. Also, the most important characteristics of this biomaterial are described and examples of the two most common polymers that have significant medical applications are given., U ovom radu su ukratko navedene mogućnosti primene polilaktida (PLA) u različitim oblastima medicine. Takođe, opisane su najznačajnije karakteristike ovog biomaterijala i dati primeri dva najzastupljenija polimera koja imaju značajnu medicinsku primenu.",
journal = "Tehnika",
title = "Medical application of polylactide (PLA), Medicinska primena polilaktida (PLA)",
volume = "79",
number = "1",
pages = "14-19",
doi = "10.5937/tehnika2401014S"
}
Stoisavljević, Z., Galović, S.,& Đorđević, K. Lj.. (2024). Medical application of polylactide (PLA). in Tehnika, 79(1), 14-19.
https://doi.org/10.5937/tehnika2401014S
Stoisavljević Z, Galović S, Đorđević KL. Medical application of polylactide (PLA). in Tehnika. 2024;79(1):14-19.
doi:10.5937/tehnika2401014S .
Stoisavljević, Zorana, Galović, Slobodanka, Đorđević, Katarina Lj., "Medical application of polylactide (PLA)" in Tehnika, 79, no. 1 (2024):14-19,
https://doi.org/10.5937/tehnika2401014S . .

Velocity Map Imaging Photoelectron Spectroscopy of Silver Iodide Aerosol Particles

Danilović, Danijela; Nahon, Laurent; Garcia, Gustavo A; Milosavljević, Aleksandar R.; Vukmirović, Nenad; Dojčilović, Radovan; Tošić, Dragana; Đoković, Vladimir; Božanić, Dušan

(2024)

TY  - JOUR
AU  - Danilović, Danijela
AU  - Nahon, Laurent
AU  - Garcia, Gustavo A
AU  - Milosavljević, Aleksandar R.
AU  - Vukmirović, Nenad
AU  - Dojčilović, Radovan
AU  - Tošić, Dragana
AU  - Đoković, Vladimir
AU  - Božanić, Dušan
PY  - 2024
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/13365
AB  - The valence band electronic structure of isolated silveriodide nanoparticles (AgI NP) was investigated by vacuum-ultravioletaerosol photoelectron spectroscopy using the velocity map imagingtechnique (VUV VMI-PES). The VUV VMI-PES results were obtainedfor polydisperse aerosol produced by aggregation of hydrocolloid ofsilver iodide particles 8 - 15 nm in size. The ionization energy of theAgI particles was found to be 6.0 ± 0.1 eV with respect to the vacuumlevel. The DFT calculations showed that the main contribution to thedensity of AgI electronic states in the valence region originates from I5p orbitals. The dependence of the asymmetry parameter on theelectron energy showed that the value of the characteristic energyloss of excited photoelectrons was 2.7 eV, which coincided with theband gap of the nanomaterial.
T2  - ChemPhysChem
T1  - Velocity Map Imaging Photoelectron Spectroscopy of Silver Iodide Aerosol Particles
DO  - 10.1002/cphc.202400328
ER  - 
@article{
author = "Danilović, Danijela and Nahon, Laurent and Garcia, Gustavo A and Milosavljević, Aleksandar R. and Vukmirović, Nenad and Dojčilović, Radovan and Tošić, Dragana and Đoković, Vladimir and Božanić, Dušan",
year = "2024",
abstract = "The valence band electronic structure of isolated silveriodide nanoparticles (AgI NP) was investigated by vacuum-ultravioletaerosol photoelectron spectroscopy using the velocity map imagingtechnique (VUV VMI-PES). The VUV VMI-PES results were obtainedfor polydisperse aerosol produced by aggregation of hydrocolloid ofsilver iodide particles 8 - 15 nm in size. The ionization energy of theAgI particles was found to be 6.0 ± 0.1 eV with respect to the vacuumlevel. The DFT calculations showed that the main contribution to thedensity of AgI electronic states in the valence region originates from I5p orbitals. The dependence of the asymmetry parameter on theelectron energy showed that the value of the characteristic energyloss of excited photoelectrons was 2.7 eV, which coincided with theband gap of the nanomaterial.",
journal = "ChemPhysChem",
title = "Velocity Map Imaging Photoelectron Spectroscopy of Silver Iodide Aerosol Particles",
doi = "10.1002/cphc.202400328"
}
Danilović, D., Nahon, L., Garcia, G. A., Milosavljević, A. R., Vukmirović, N., Dojčilović, R., Tošić, D., Đoković, V.,& Božanić, D.. (2024). Velocity Map Imaging Photoelectron Spectroscopy of Silver Iodide Aerosol Particles. in ChemPhysChem.
https://doi.org/10.1002/cphc.202400328
Danilović D, Nahon L, Garcia GA, Milosavljević AR, Vukmirović N, Dojčilović R, Tošić D, Đoković V, Božanić D. Velocity Map Imaging Photoelectron Spectroscopy of Silver Iodide Aerosol Particles. in ChemPhysChem. 2024;.
doi:10.1002/cphc.202400328 .
Danilović, Danijela, Nahon, Laurent, Garcia, Gustavo A, Milosavljević, Aleksandar R., Vukmirović, Nenad, Dojčilović, Radovan, Tošić, Dragana, Đoković, Vladimir, Božanić, Dušan, "Velocity Map Imaging Photoelectron Spectroscopy of Silver Iodide Aerosol Particles" in ChemPhysChem (2024),
https://doi.org/10.1002/cphc.202400328 . .

Velocity Map Imaging Photoelectron Spectroscopy of Silver Iodide Aerosol Particles

Danilović, Danijela; Nahon, Laurent; Garcia, Gustavo A; Milosavljević, Aleksandar R.; Vukmirović, Nenad; Dojčilović, Radovan; Tošić, Dragana; Đoković, Vladimir; Božanić, Dušan

(2024)

TY  - JOUR
AU  - Danilović, Danijela
AU  - Nahon, Laurent
AU  - Garcia, Gustavo A
AU  - Milosavljević, Aleksandar R.
AU  - Vukmirović, Nenad
AU  - Dojčilović, Radovan
AU  - Tošić, Dragana
AU  - Đoković, Vladimir
AU  - Božanić, Dušan
PY  - 2024
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/13366
AB  - The valence band electronic structure of isolated silveriodide nanoparticles (AgI NP) was investigated by vacuum-ultravioletaerosol photoelectron spectroscopy using the velocity map imagingtechnique (VUV VMI-PES). The VUV VMI-PES results were obtainedfor polydisperse aerosol produced by aggregation of hydrocolloid ofsilver iodide particles 8 - 15 nm in size. The ionization energy of theAgI particles was found to be 6.0 ± 0.1 eV with respect to the vacuumlevel. The DFT calculations showed that the main contribution to thedensity of AgI electronic states in the valence region originates from I5p orbitals. The dependence of the asymmetry parameter on theelectron energy showed that the value of the characteristic energyloss of excited photoelectrons was 2.7 eV, which coincided with theband gap of the nanomaterial.
T2  - ChemPhysChem
T1  - Velocity Map Imaging Photoelectron Spectroscopy of Silver Iodide Aerosol Particles
IS  - InPress
SP  - e202400328
ER  - 
@article{
author = "Danilović, Danijela and Nahon, Laurent and Garcia, Gustavo A and Milosavljević, Aleksandar R. and Vukmirović, Nenad and Dojčilović, Radovan and Tošić, Dragana and Đoković, Vladimir and Božanić, Dušan",
year = "2024",
abstract = "The valence band electronic structure of isolated silveriodide nanoparticles (AgI NP) was investigated by vacuum-ultravioletaerosol photoelectron spectroscopy using the velocity map imagingtechnique (VUV VMI-PES). The VUV VMI-PES results were obtainedfor polydisperse aerosol produced by aggregation of hydrocolloid ofsilver iodide particles 8 - 15 nm in size. The ionization energy of theAgI particles was found to be 6.0 ± 0.1 eV with respect to the vacuumlevel. The DFT calculations showed that the main contribution to thedensity of AgI electronic states in the valence region originates from I5p orbitals. The dependence of the asymmetry parameter on theelectron energy showed that the value of the characteristic energyloss of excited photoelectrons was 2.7 eV, which coincided with theband gap of the nanomaterial.",
journal = "ChemPhysChem",
title = "Velocity Map Imaging Photoelectron Spectroscopy of Silver Iodide Aerosol Particles",
number = "InPress",
pages = "e202400328"
}
Danilović, D., Nahon, L., Garcia, G. A., Milosavljević, A. R., Vukmirović, N., Dojčilović, R., Tošić, D., Đoković, V.,& Božanić, D.. (2024). Velocity Map Imaging Photoelectron Spectroscopy of Silver Iodide Aerosol Particles. in ChemPhysChem(InPress), e202400328.
Danilović D, Nahon L, Garcia GA, Milosavljević AR, Vukmirović N, Dojčilović R, Tošić D, Đoković V, Božanić D. Velocity Map Imaging Photoelectron Spectroscopy of Silver Iodide Aerosol Particles. in ChemPhysChem. 2024;(InPress):e202400328..
Danilović, Danijela, Nahon, Laurent, Garcia, Gustavo A, Milosavljević, Aleksandar R., Vukmirović, Nenad, Dojčilović, Radovan, Tošić, Dragana, Đoković, Vladimir, Božanić, Dušan, "Velocity Map Imaging Photoelectron Spectroscopy of Silver Iodide Aerosol Particles" in ChemPhysChem, no. InPress (2024):e202400328.

Metals on the Menu—Analyzing the Presence, Importance, and Consequences

Milanković, Vedran; Tasić, Tamara; Leskovac, Andreja; Petrović, Sandra; Mitić, Miloš; Lazarević-Pašti, Tamara; Novaković, Mirjana; Potkonjak, Nebojša

(2024)

TY  - JOUR
AU  - Milanković, Vedran
AU  - Tasić, Tamara
AU  - Leskovac, Andreja
AU  - Petrović, Sandra
AU  - Mitić, Miloš
AU  - Lazarević-Pašti, Tamara
AU  - Novaković, Mirjana
AU  - Potkonjak, Nebojša
PY  - 2024
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/13362
AB  - Metals are integral components of the natural environment, and their presence in the food supply is inevitable and complex. While essential metals such as sodium, potassium, magnesium, calcium, iron, zinc, and copper are crucial for various physiological functions and must be consumed through the diet, others, like lead, mercury, and cadmium, are toxic even at low concentrations and pose serious health risks. This study comprehensively analyzes the presence, importance, and consequences of metals in the food chain. We explore the pathways through which metals enter the food supply, their distribution across different food types, and the associated health implications. By examining current regulatory standards for maximum allowable levels of various metals, we highlight the importance of ensuring food safety and protecting public health. Furthermore, this research underscores the need for continuous monitoring and management of metal content in food, especially as global agricultural and food production practices evolve. Our findings aim to inform dietary recommendations, food fortification strategies, and regulatory policies, ultimately contributing to safer and more nutritionally balanced diets.
T2  - Foods
T1  - Metals on the Menu—Analyzing the Presence, Importance, and Consequences
VL  - 13
IS  - 12
SP  - 1890
DO  - 10.3390/foods13121890
ER  - 
@article{
author = "Milanković, Vedran and Tasić, Tamara and Leskovac, Andreja and Petrović, Sandra and Mitić, Miloš and Lazarević-Pašti, Tamara and Novaković, Mirjana and Potkonjak, Nebojša",
year = "2024",
abstract = "Metals are integral components of the natural environment, and their presence in the food supply is inevitable and complex. While essential metals such as sodium, potassium, magnesium, calcium, iron, zinc, and copper are crucial for various physiological functions and must be consumed through the diet, others, like lead, mercury, and cadmium, are toxic even at low concentrations and pose serious health risks. This study comprehensively analyzes the presence, importance, and consequences of metals in the food chain. We explore the pathways through which metals enter the food supply, their distribution across different food types, and the associated health implications. By examining current regulatory standards for maximum allowable levels of various metals, we highlight the importance of ensuring food safety and protecting public health. Furthermore, this research underscores the need for continuous monitoring and management of metal content in food, especially as global agricultural and food production practices evolve. Our findings aim to inform dietary recommendations, food fortification strategies, and regulatory policies, ultimately contributing to safer and more nutritionally balanced diets.",
journal = "Foods",
title = "Metals on the Menu—Analyzing the Presence, Importance, and Consequences",
volume = "13",
number = "12",
pages = "1890",
doi = "10.3390/foods13121890"
}
Milanković, V., Tasić, T., Leskovac, A., Petrović, S., Mitić, M., Lazarević-Pašti, T., Novaković, M.,& Potkonjak, N.. (2024). Metals on the Menu—Analyzing the Presence, Importance, and Consequences. in Foods, 13(12), 1890.
https://doi.org/10.3390/foods13121890
Milanković V, Tasić T, Leskovac A, Petrović S, Mitić M, Lazarević-Pašti T, Novaković M, Potkonjak N. Metals on the Menu—Analyzing the Presence, Importance, and Consequences. in Foods. 2024;13(12):1890.
doi:10.3390/foods13121890 .
Milanković, Vedran, Tasić, Tamara, Leskovac, Andreja, Petrović, Sandra, Mitić, Miloš, Lazarević-Pašti, Tamara, Novaković, Mirjana, Potkonjak, Nebojša, "Metals on the Menu—Analyzing the Presence, Importance, and Consequences" in Foods, 13, no. 12 (2024):1890,
https://doi.org/10.3390/foods13121890 . .

Thickness-dependent growth of Ni vertical columns deposited by GLAD method: Study on the microstructural and optical properties

Potočnik, Jelena; Novaković, Mirjana; Popović, Maja

(2024)

TY  - JOUR
AU  - Potočnik, Jelena
AU  - Novaković, Mirjana
AU  - Popović, Maja
PY  - 2024
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/13361
AB  - The paper presents a study on the structural and optical properties of nickel (Ni) thin films in the shape of vertical columns obtained by using the glancing angle deposition method. The films are deposited onto glass substrates at a fixed deposition angle of 85° to the different thicknesses of 50 nm, 80 nm, 110 nm, and 140 nm. Field emission scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS), and high resolution transmission electron microscopy (HR-TEM) were utilized to analyze the morphological, chemical, and microstructural properties of the films. SEM and TEM analyses are showing well-defined columnar structures, where the increase in thickness leads to more porous films and larger column diameters. The results of the surface examination of the XPS confirm that metallic Ni is a major phase in the deposited structures, but all samples also exhibit a certain amount of oxide phases. The optical measurements of the effective dielectric function reveal that both real and imaginary parts are strongly influenced by the changes in the film thickness. The surface plasmon resonance (SPR) peak is significantly shifted from 585.6 nm, as obtained for a 50 nm thick film, to 1291.8 nm in the case of a thickness of 140 nm. The variation in SPR peak position can be related to the differences in the film's morphology, and it is attributed to the changes in the size of the formed Ni nanoparticles. Finally, the experimental results show that with increasing film thickness, the electrical resistivity decreases. Both optical and electrical properties are found to be determined by the growth mechanism, and they are discussed on the basis of the defect concentration of the films.
T2  - Optical Materials
T1  - Thickness-dependent growth of Ni vertical columns deposited by GLAD method: Study on the microstructural and optical properties
VL  - 154
SP  - 115665
DO  - 10.1016/j.optmat.2024.115665
ER  - 
@article{
author = "Potočnik, Jelena and Novaković, Mirjana and Popović, Maja",
year = "2024",
abstract = "The paper presents a study on the structural and optical properties of nickel (Ni) thin films in the shape of vertical columns obtained by using the glancing angle deposition method. The films are deposited onto glass substrates at a fixed deposition angle of 85° to the different thicknesses of 50 nm, 80 nm, 110 nm, and 140 nm. Field emission scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS), and high resolution transmission electron microscopy (HR-TEM) were utilized to analyze the morphological, chemical, and microstructural properties of the films. SEM and TEM analyses are showing well-defined columnar structures, where the increase in thickness leads to more porous films and larger column diameters. The results of the surface examination of the XPS confirm that metallic Ni is a major phase in the deposited structures, but all samples also exhibit a certain amount of oxide phases. The optical measurements of the effective dielectric function reveal that both real and imaginary parts are strongly influenced by the changes in the film thickness. The surface plasmon resonance (SPR) peak is significantly shifted from 585.6 nm, as obtained for a 50 nm thick film, to 1291.8 nm in the case of a thickness of 140 nm. The variation in SPR peak position can be related to the differences in the film's morphology, and it is attributed to the changes in the size of the formed Ni nanoparticles. Finally, the experimental results show that with increasing film thickness, the electrical resistivity decreases. Both optical and electrical properties are found to be determined by the growth mechanism, and they are discussed on the basis of the defect concentration of the films.",
journal = "Optical Materials",
title = "Thickness-dependent growth of Ni vertical columns deposited by GLAD method: Study on the microstructural and optical properties",
volume = "154",
pages = "115665",
doi = "10.1016/j.optmat.2024.115665"
}
Potočnik, J., Novaković, M.,& Popović, M.. (2024). Thickness-dependent growth of Ni vertical columns deposited by GLAD method: Study on the microstructural and optical properties. in Optical Materials, 154, 115665.
https://doi.org/10.1016/j.optmat.2024.115665
Potočnik J, Novaković M, Popović M. Thickness-dependent growth of Ni vertical columns deposited by GLAD method: Study on the microstructural and optical properties. in Optical Materials. 2024;154:115665.
doi:10.1016/j.optmat.2024.115665 .
Potočnik, Jelena, Novaković, Mirjana, Popović, Maja, "Thickness-dependent growth of Ni vertical columns deposited by GLAD method: Study on the microstructural and optical properties" in Optical Materials, 154 (2024):115665,
https://doi.org/10.1016/j.optmat.2024.115665 . .

Instrumentation Development Based on Reduce and Reuse Principles

Stolić, P.; Petrović, S.; Mravik, Ž.; Radovanović, I.; Petronić, S.; Dimitrijević, S.; Stević, Z.

(Odesa: Політехперіодика, 2024)

TY  - CONF
AU  - Stolić, P.
AU  - Petrović, S.
AU  - Mravik, Ž.
AU  - Radovanović, I.
AU  - Petronić, S.
AU  - Dimitrijević, S.
AU  - Stević, Z.
PY  - 2024
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/13357
AB  - In the implementation of different types of instrumentation, one of the measurement and control components is often represented by a computer with a significant role in the system. The paper will show that instrumentation goals can often be achieved with computers of older generations without loss of reliability and performance, while additional benefits are realized in the form of reduction of electronic waste and reduction of the price of implementation of the given instrumentation.
AB  - ри реалізації різних типів контрольно-вимірювальних приладів одним із компонентів вимірювання та керування частотою є комп'ютер, який відіграє значну роль в системі. У роботі показано, що цілі вимірювання часто можуть бути досягнуті за допомогою комп'ютерів старих поколінь без втрати надійності та продуктивності, при цьому додаткові переваги реалізуються у формі зменшення відходів електронної промисловості та зниження ціни впровадження цих контрольно-вимірювальних приладів.
PB  - Odesa: Політехперіодика
C3  - MІЕТ-2024 : XXV International Scientific-Practical Conference Modern Information and Electronic Technologies : Proceedings
T1  - Instrumentation Development Based on Reduce and Reuse Principles
T1  - Розробка контрольно-вимірювальних приладів на основі принципів економії та повторного використання
SP  - 78
EP  - 81
ER  - 
@conference{
author = "Stolić, P. and Petrović, S. and Mravik, Ž. and Radovanović, I. and Petronić, S. and Dimitrijević, S. and Stević, Z.",
year = "2024",
abstract = "In the implementation of different types of instrumentation, one of the measurement and control components is often represented by a computer with a significant role in the system. The paper will show that instrumentation goals can often be achieved with computers of older generations without loss of reliability and performance, while additional benefits are realized in the form of reduction of electronic waste and reduction of the price of implementation of the given instrumentation., ри реалізації різних типів контрольно-вимірювальних приладів одним із компонентів вимірювання та керування частотою є комп'ютер, який відіграє значну роль в системі. У роботі показано, що цілі вимірювання часто можуть бути досягнуті за допомогою комп'ютерів старих поколінь без втрати надійності та продуктивності, при цьому додаткові переваги реалізуються у формі зменшення відходів електронної промисловості та зниження ціни впровадження цих контрольно-вимірювальних приладів.",
publisher = "Odesa: Політехперіодика",
journal = "MІЕТ-2024 : XXV International Scientific-Practical Conference Modern Information and Electronic Technologies : Proceedings",
title = "Instrumentation Development Based on Reduce and Reuse Principles, Розробка контрольно-вимірювальних приладів на основі принципів економії та повторного використання",
pages = "78-81"
}
Stolić, P., Petrović, S., Mravik, Ž., Radovanović, I., Petronić, S., Dimitrijević, S.,& Stević, Z.. (2024). Instrumentation Development Based on Reduce and Reuse Principles. in MІЕТ-2024 : XXV International Scientific-Practical Conference Modern Information and Electronic Technologies : Proceedings
Odesa: Політехперіодика., 78-81.
Stolić P, Petrović S, Mravik Ž, Radovanović I, Petronić S, Dimitrijević S, Stević Z. Instrumentation Development Based on Reduce and Reuse Principles. in MІЕТ-2024 : XXV International Scientific-Practical Conference Modern Information and Electronic Technologies : Proceedings. 2024;:78-81..
Stolić, P., Petrović, S., Mravik, Ž., Radovanović, I., Petronić, S., Dimitrijević, S., Stević, Z., "Instrumentation Development Based on Reduce and Reuse Principles" in MІЕТ-2024 : XXV International Scientific-Practical Conference Modern Information and Electronic Technologies : Proceedings (2024):78-81.

Application of LoRa Network in Permanent Thermal Imaging Monitoring Process

Stolić, P.; Petrović, S.; Dimitrijević, S.; Jovanović, Z.; Radovanović, I.; Petronić, S.; Stević, Z.

(Odesa: Політехперіодика, 2024)

TY  - CONF
AU  - Stolić, P.
AU  - Petrović, S.
AU  - Dimitrijević, S.
AU  - Jovanović, Z.
AU  - Radovanović, I.
AU  - Petronić, S.
AU  - Stević, Z.
PY  - 2024
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/13358
AB  - Today, monitoring systems, which include the monitoring of a temperature process, are often based, partially or entirely, on the application of thermal imaging procedures. In such systems, thermogram transmission techniques are generally represented via classic LAN or WLAN networks. In this work, instead of applying the usual techniques, the thermogram is transformed into a corresponding set of temperature data that is distributed using the LoRa network.
AB  - Сьогодні системи моніторингу, які включають спостереження за температурним процесом, часто частково або повністю базуються на застосуванні тепловізійних процедур. У таких системах технології передачі термограм зазвичай представлені за допомогою класичних мереж LAN або WLAN. У цій роботі замість застосування звичайних технологій термограма перетворюється на відповідний набір даних про температуру, який поширюється за допомогою мережі LoRa.
PB  - Odesa: Політехперіодика
C3  - MІЕТ-2024 : XXV International Scientific-Practical Conference Modern Information and Electronic Technologies : Proceedings
T1  - Application of LoRa Network in Permanent Thermal Imaging Monitoring Process
T1  - Застосування мережі LoRa в процесі постійного тепловізійного моніторингу
SP  - 21
EP  - 24
ER  - 
@conference{
author = "Stolić, P. and Petrović, S. and Dimitrijević, S. and Jovanović, Z. and Radovanović, I. and Petronić, S. and Stević, Z.",
year = "2024",
abstract = "Today, monitoring systems, which include the monitoring of a temperature process, are often based, partially or entirely, on the application of thermal imaging procedures. In such systems, thermogram transmission techniques are generally represented via classic LAN or WLAN networks. In this work, instead of applying the usual techniques, the thermogram is transformed into a corresponding set of temperature data that is distributed using the LoRa network., Сьогодні системи моніторингу, які включають спостереження за температурним процесом, часто частково або повністю базуються на застосуванні тепловізійних процедур. У таких системах технології передачі термограм зазвичай представлені за допомогою класичних мереж LAN або WLAN. У цій роботі замість застосування звичайних технологій термограма перетворюється на відповідний набір даних про температуру, який поширюється за допомогою мережі LoRa.",
publisher = "Odesa: Політехперіодика",
journal = "MІЕТ-2024 : XXV International Scientific-Practical Conference Modern Information and Electronic Technologies : Proceedings",
title = "Application of LoRa Network in Permanent Thermal Imaging Monitoring Process, Застосування мережі LoRa в процесі постійного тепловізійного моніторингу",
pages = "21-24"
}
Stolić, P., Petrović, S., Dimitrijević, S., Jovanović, Z., Radovanović, I., Petronić, S.,& Stević, Z.. (2024). Application of LoRa Network in Permanent Thermal Imaging Monitoring Process. in MІЕТ-2024 : XXV International Scientific-Practical Conference Modern Information and Electronic Technologies : Proceedings
Odesa: Політехперіодика., 21-24.
Stolić P, Petrović S, Dimitrijević S, Jovanović Z, Radovanović I, Petronić S, Stević Z. Application of LoRa Network in Permanent Thermal Imaging Monitoring Process. in MІЕТ-2024 : XXV International Scientific-Practical Conference Modern Information and Electronic Technologies : Proceedings. 2024;:21-24..
Stolić, P., Petrović, S., Dimitrijević, S., Jovanović, Z., Radovanović, I., Petronić, S., Stević, Z., "Application of LoRa Network in Permanent Thermal Imaging Monitoring Process" in MІЕТ-2024 : XXV International Scientific-Practical Conference Modern Information and Electronic Technologies : Proceedings (2024):21-24.

Temperature Sensors Based on Graphene Oxide and Graphene Oxide / 12 Tungstophosphoric Acid Thin Films on Interdigital Electrodes

Mravik, Ž.; Pejčić, M.; Petković, D.; Stolić, P.; Stević, M.; Stević, Z.; Jovanović, Z.

(Odesa: Політехперіодика, 2024)

TY  - CONF
AU  - Mravik, Ž.
AU  - Pejčić, M.
AU  - Petković, D.
AU  - Stolić, P.
AU  - Stević, M.
AU  - Stević, Z.
AU  - Jovanović, Z.
PY  - 2024
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/13359
AB  - Easy-to-develop sensing devices are important for modern technology where materials with modifiable properties that are dependent on the environmental conditions play key role. Graphene oxide nanocomposites possess interesting surface chemistry that is closely correlated to their electric properties. In this work, composite of graphene oxide and 12-tungstophosphoric acid was dip coated on interdigital electrode and thermally treated while dependence of its electric properties on environment temperature was examined with impedance spectroscopy. Results outline potential applicability of these materials for temperature sensors.
AB  - Сенсорні пристрої, які легко розробляти, є важливими для сучасних технологій, де ключову роль відіграють матеріали зі змінними властивостями, що залежать від умов навколишнього середовища. Нанокомпозити на основі оксиду графену мають цікаву хімію поверхні, яка тісно корелює з їхніми електричними властивостями. У цій роботі композит з оксиду графену та 12-вольфрамової кислоти наносили на зустрічно-штирьовий електрод і термічно обробляли. Залежність його електричних властивостей від температури середовища досліджували за допомогою імпедансної спектроскопії. Отримані результати вказують на потенційну можливість застосування цих матеріалів для датчиків температури.
PB  - Odesa: Політехперіодика
C3  - MІЕТ-2024 : XXV International Scientific-Practical Conference Modern Information and Electronic Technologies : Proceedings
T1  - Temperature Sensors Based on Graphene Oxide and Graphene Oxide / 12 Tungstophosphoric Acid Thin Films on Interdigital Electrodes
T1  - Датчики температури на основі тонких плівок оксиду графену та композиту оксиду графену та 12-воль-фрамофосфорної кислоти на зустрічно-штирьових електродах
SP  - 61
EP  - 64
ER  - 
@conference{
author = "Mravik, Ž. and Pejčić, M. and Petković, D. and Stolić, P. and Stević, M. and Stević, Z. and Jovanović, Z.",
year = "2024",
abstract = "Easy-to-develop sensing devices are important for modern technology where materials with modifiable properties that are dependent on the environmental conditions play key role. Graphene oxide nanocomposites possess interesting surface chemistry that is closely correlated to their electric properties. In this work, composite of graphene oxide and 12-tungstophosphoric acid was dip coated on interdigital electrode and thermally treated while dependence of its electric properties on environment temperature was examined with impedance spectroscopy. Results outline potential applicability of these materials for temperature sensors., Сенсорні пристрої, які легко розробляти, є важливими для сучасних технологій, де ключову роль відіграють матеріали зі змінними властивостями, що залежать від умов навколишнього середовища. Нанокомпозити на основі оксиду графену мають цікаву хімію поверхні, яка тісно корелює з їхніми електричними властивостями. У цій роботі композит з оксиду графену та 12-вольфрамової кислоти наносили на зустрічно-штирьовий електрод і термічно обробляли. Залежність його електричних властивостей від температури середовища досліджували за допомогою імпедансної спектроскопії. Отримані результати вказують на потенційну можливість застосування цих матеріалів для датчиків температури.",
publisher = "Odesa: Політехперіодика",
journal = "MІЕТ-2024 : XXV International Scientific-Practical Conference Modern Information and Electronic Technologies : Proceedings",
title = "Temperature Sensors Based on Graphene Oxide and Graphene Oxide / 12 Tungstophosphoric Acid Thin Films on Interdigital Electrodes, Датчики температури на основі тонких плівок оксиду графену та композиту оксиду графену та 12-воль-фрамофосфорної кислоти на зустрічно-штирьових електродах",
pages = "61-64"
}
Mravik, Ž., Pejčić, M., Petković, D., Stolić, P., Stević, M., Stević, Z.,& Jovanović, Z.. (2024). Temperature Sensors Based on Graphene Oxide and Graphene Oxide / 12 Tungstophosphoric Acid Thin Films on Interdigital Electrodes. in MІЕТ-2024 : XXV International Scientific-Practical Conference Modern Information and Electronic Technologies : Proceedings
Odesa: Політехперіодика., 61-64.
Mravik Ž, Pejčić M, Petković D, Stolić P, Stević M, Stević Z, Jovanović Z. Temperature Sensors Based on Graphene Oxide and Graphene Oxide / 12 Tungstophosphoric Acid Thin Films on Interdigital Electrodes. in MІЕТ-2024 : XXV International Scientific-Practical Conference Modern Information and Electronic Technologies : Proceedings. 2024;:61-64..
Mravik, Ž., Pejčić, M., Petković, D., Stolić, P., Stević, M., Stević, Z., Jovanović, Z., "Temperature Sensors Based on Graphene Oxide and Graphene Oxide / 12 Tungstophosphoric Acid Thin Films on Interdigital Electrodes" in MІЕТ-2024 : XXV International Scientific-Practical Conference Modern Information and Electronic Technologies : Proceedings (2024):61-64.

Resonant Tunnelling and Intersubband Optical Properties of ZnO/ZnMgO Semiconductor Heterostructures: Impact of Doping and Layer Structure Variation

Atić, Aleksandar; Wang, Xizhe; Vuković, Nikola; Stanojević, Novak; Demić, Aleksandar; Indjin, Dragan; Radovanović, Jelena

(2024)

TY  - JOUR
AU  - Atić, Aleksandar
AU  - Wang, Xizhe
AU  - Vuković, Nikola
AU  - Stanojević, Novak
AU  - Demić, Aleksandar
AU  - Indjin, Dragan
AU  - Radovanović, Jelena
PY  - 2024
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/12868
AB  - ZnO-based heterostructures are up-and-coming candidates for terahertz (THz) optoelectronic devices, largely owing to their innate material attributes. The significant ZnO LO-phonon energy plays a pivotal role in mitigating thermally induced LO-phonon scattering, potentially significantly elevating the temperature performance of quantum cascade lasers (QCLs). In this work, we calculate the electronic structure and absorption of ZnO/ZnMgO multiple semiconductor quantum wells (MQWs) and the current density–voltage characteristics of nonpolar m-plane ZnO/ZnMgO double-barrier resonant tunnelling diodes (RTDs). Both MQWs and RTDs are considered here as two building blocks of a QCL. We show how the doping, Mg percentage and layer thickness affect the absorption of MQWs at room temperature. We confirm that in the high doping concentrations regime, a full quantum treatment that includes the depolarisation shift effect must be considered, as it shifts mid-infrared absorption peak energy for several tens of meV. Furthermore, we also focus on the performance of RTDs for various parameter changes and conclude that, to maximise the peak-to-valley ratio (PVR), the optimal doping density of the analysed ZnO/Zn88Mg12O double-barrier RTD should be approximately 1018 cm−3, whilst the optimal barrier thickness should be 1.3 nm, with a Mg mole fraction of ~9%.
T2  - Materials
T1  - Resonant Tunnelling and Intersubband Optical Properties of ZnO/ZnMgO Semiconductor Heterostructures: Impact of Doping and Layer Structure Variation
VL  - 17
IS  - 4
SP  - 927
DO  - 10.3390/ma17040927
ER  - 
@article{
author = "Atić, Aleksandar and Wang, Xizhe and Vuković, Nikola and Stanojević, Novak and Demić, Aleksandar and Indjin, Dragan and Radovanović, Jelena",
year = "2024",
abstract = "ZnO-based heterostructures are up-and-coming candidates for terahertz (THz) optoelectronic devices, largely owing to their innate material attributes. The significant ZnO LO-phonon energy plays a pivotal role in mitigating thermally induced LO-phonon scattering, potentially significantly elevating the temperature performance of quantum cascade lasers (QCLs). In this work, we calculate the electronic structure and absorption of ZnO/ZnMgO multiple semiconductor quantum wells (MQWs) and the current density–voltage characteristics of nonpolar m-plane ZnO/ZnMgO double-barrier resonant tunnelling diodes (RTDs). Both MQWs and RTDs are considered here as two building blocks of a QCL. We show how the doping, Mg percentage and layer thickness affect the absorption of MQWs at room temperature. We confirm that in the high doping concentrations regime, a full quantum treatment that includes the depolarisation shift effect must be considered, as it shifts mid-infrared absorption peak energy for several tens of meV. Furthermore, we also focus on the performance of RTDs for various parameter changes and conclude that, to maximise the peak-to-valley ratio (PVR), the optimal doping density of the analysed ZnO/Zn88Mg12O double-barrier RTD should be approximately 1018 cm−3, whilst the optimal barrier thickness should be 1.3 nm, with a Mg mole fraction of ~9%.",
journal = "Materials",
title = "Resonant Tunnelling and Intersubband Optical Properties of ZnO/ZnMgO Semiconductor Heterostructures: Impact of Doping and Layer Structure Variation",
volume = "17",
number = "4",
pages = "927",
doi = "10.3390/ma17040927"
}
Atić, A., Wang, X., Vuković, N., Stanojević, N., Demić, A., Indjin, D.,& Radovanović, J.. (2024). Resonant Tunnelling and Intersubband Optical Properties of ZnO/ZnMgO Semiconductor Heterostructures: Impact of Doping and Layer Structure Variation. in Materials, 17(4), 927.
https://doi.org/10.3390/ma17040927
Atić A, Wang X, Vuković N, Stanojević N, Demić A, Indjin D, Radovanović J. Resonant Tunnelling and Intersubband Optical Properties of ZnO/ZnMgO Semiconductor Heterostructures: Impact of Doping and Layer Structure Variation. in Materials. 2024;17(4):927.
doi:10.3390/ma17040927 .
Atić, Aleksandar, Wang, Xizhe, Vuković, Nikola, Stanojević, Novak, Demić, Aleksandar, Indjin, Dragan, Radovanović, Jelena, "Resonant Tunnelling and Intersubband Optical Properties of ZnO/ZnMgO Semiconductor Heterostructures: Impact of Doping and Layer Structure Variation" in Materials, 17, no. 4 (2024):927,
https://doi.org/10.3390/ma17040927 . .

LIBS Hydrogen Isotopes Detection: Significance in Nuclear/Fusion Technology

Trtica, Milan; Savović, Jelena; Kuzmanović, M.; Ranković, D.; Stašić, Jelena

(2024)

TY  - JOUR
AU  - Trtica, Milan
AU  - Savović, Jelena
AU  - Kuzmanović, M.
AU  - Ranković, D.
AU  - Stašić, Jelena
PY  - 2024
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/12052
AB  - The aspect of the detection of hydrogen isotopes in nuclear materials was analyzed in this review. Particular attention was paid to the spectroscopic methods for the detection of hydrogen isotopes in fusion reactor materials since their presence can induce severe problems in terms of material degradation and shortening of its lifetime. The main focus is on laser-induced breakdown spectroscopy, an optical emission method that is efficient, reliable, and fast. Recent results obtained at the VINCA Institute will also be presented.
T2  - Journal of Applied Spectroscopy
T1  - LIBS Hydrogen Isotopes Detection: Significance in Nuclear/Fusion Technology
VL  - 90
VL  - 90
IS  - 6
SP  - 1318
EP  - 1324
DO  - 10.1007/s10812-024-01669-0
UR  - https://hdl.handle.net/21.15107/rcub_vinar_12052
ER  - 
@article{
author = "Trtica, Milan and Savović, Jelena and Kuzmanović, M. and Ranković, D. and Stašić, Jelena",
year = "2024",
abstract = "The aspect of the detection of hydrogen isotopes in nuclear materials was analyzed in this review. Particular attention was paid to the spectroscopic methods for the detection of hydrogen isotopes in fusion reactor materials since their presence can induce severe problems in terms of material degradation and shortening of its lifetime. The main focus is on laser-induced breakdown spectroscopy, an optical emission method that is efficient, reliable, and fast. Recent results obtained at the VINCA Institute will also be presented.",
journal = "Journal of Applied Spectroscopy",
title = "LIBS Hydrogen Isotopes Detection: Significance in Nuclear/Fusion Technology",
volume = "90, 90",
number = "6",
pages = "1318-1324",
doi = "10.1007/s10812-024-01669-0",
url = "https://hdl.handle.net/21.15107/rcub_vinar_12052"
}
Trtica, M., Savović, J., Kuzmanović, M., Ranković, D.,& Stašić, J.. (2024). LIBS Hydrogen Isotopes Detection: Significance in Nuclear/Fusion Technology. in Journal of Applied Spectroscopy, 90(6), 1318-1324.
https://doi.org/10.1007/s10812-024-01669-0
https://hdl.handle.net/21.15107/rcub_vinar_12052
Trtica M, Savović J, Kuzmanović M, Ranković D, Stašić J. LIBS Hydrogen Isotopes Detection: Significance in Nuclear/Fusion Technology. in Journal of Applied Spectroscopy. 2024;90(6):1318-1324.
doi:10.1007/s10812-024-01669-0
https://hdl.handle.net/21.15107/rcub_vinar_12052 .
Trtica, Milan, Savović, Jelena, Kuzmanović, M., Ranković, D., Stašić, Jelena, "LIBS Hydrogen Isotopes Detection: Significance in Nuclear/Fusion Technology" in Journal of Applied Spectroscopy, 90, no. 6 (2024):1318-1324,
https://doi.org/10.1007/s10812-024-01669-0 .,
https://hdl.handle.net/21.15107/rcub_vinar_12052 .
2
2

Microstructure Formations Resulting from Nanosecond and Picosecond Laser Irradiation of a Ti-Based Alloy under Controlled Atmospheric Conditions and Optimization of the Irradiation Process

Milovanović, Dubravka; Rajčić, Boris; Ranković, Dragan; Stankov, Biljana; Čekada, Miha; Ciganović, Jovan; Đurđević-Milošević, Dragica; Stević, Zoran; Kuzmanović, Miroslav; Šibalija, Tatjana; Petronić, Sanja

(2024)

TY  - JOUR
AU  - Milovanović, Dubravka
AU  - Rajčić, Boris
AU  - Ranković, Dragan
AU  - Stankov, Biljana
AU  - Čekada, Miha
AU  - Ciganović, Jovan
AU  - Đurđević-Milošević, Dragica
AU  - Stević, Zoran
AU  - Kuzmanović, Miroslav
AU  - Šibalija, Tatjana
AU  - Petronić, Sanja
PY  - 2024
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/12723
AB  - This paper presents a study and comparison of surface effects induced by picosecond and nanosecond laser modification of a Ti6Al4V alloy surface under different ambient conditions: air and argon- and nitrogen-rich atmospheres. Detailed surface characterization was performed for all experimental conditions. Damage threshold fluences for picosecond and nanosecond laser irradiation in all three ambient conditions were determined. The observed surface features were a resolidified pool of molten material, craters, hydrodynamic effects and parallel periodic surface structures. Laser-induced periodic surface structures are formed by multi-mode-beam nanosecond laser action and picosecond laser action. Crown-like structures at crater rims are specific features for picosecond Nd:YAG laser action in argon-rich ambient conditions. Elemental analysis of the surfaces indicated nitride compound formation only in the nitrogen-rich ambient conditions. The constituents of the formed plasma were also investigated. Exploring the impact of process control parameters on output responses has been undertaken within the context of laser modification under different environmental conditions. Parametric optimization of the nanosecond laser modification was carried out by implementing an advanced method based on Taguchi’s parametric design and multivariate statistical techniques, and optimal settings are proposed for each atmosphere.
T2  - Micromachines
T1  - Microstructure Formations Resulting from Nanosecond and Picosecond Laser Irradiation of a Ti-Based Alloy under Controlled Atmospheric Conditions and Optimization of the Irradiation Process
VL  - 15
IS  - 1
SP  - 5
DO  - 10.3390/mi15010005
ER  - 
@article{
author = "Milovanović, Dubravka and Rajčić, Boris and Ranković, Dragan and Stankov, Biljana and Čekada, Miha and Ciganović, Jovan and Đurđević-Milošević, Dragica and Stević, Zoran and Kuzmanović, Miroslav and Šibalija, Tatjana and Petronić, Sanja",
year = "2024",
abstract = "This paper presents a study and comparison of surface effects induced by picosecond and nanosecond laser modification of a Ti6Al4V alloy surface under different ambient conditions: air and argon- and nitrogen-rich atmospheres. Detailed surface characterization was performed for all experimental conditions. Damage threshold fluences for picosecond and nanosecond laser irradiation in all three ambient conditions were determined. The observed surface features were a resolidified pool of molten material, craters, hydrodynamic effects and parallel periodic surface structures. Laser-induced periodic surface structures are formed by multi-mode-beam nanosecond laser action and picosecond laser action. Crown-like structures at crater rims are specific features for picosecond Nd:YAG laser action in argon-rich ambient conditions. Elemental analysis of the surfaces indicated nitride compound formation only in the nitrogen-rich ambient conditions. The constituents of the formed plasma were also investigated. Exploring the impact of process control parameters on output responses has been undertaken within the context of laser modification under different environmental conditions. Parametric optimization of the nanosecond laser modification was carried out by implementing an advanced method based on Taguchi’s parametric design and multivariate statistical techniques, and optimal settings are proposed for each atmosphere.",
journal = "Micromachines",
title = "Microstructure Formations Resulting from Nanosecond and Picosecond Laser Irradiation of a Ti-Based Alloy under Controlled Atmospheric Conditions and Optimization of the Irradiation Process",
volume = "15",
number = "1",
pages = "5",
doi = "10.3390/mi15010005"
}
Milovanović, D., Rajčić, B., Ranković, D., Stankov, B., Čekada, M., Ciganović, J., Đurđević-Milošević, D., Stević, Z., Kuzmanović, M., Šibalija, T.,& Petronić, S.. (2024). Microstructure Formations Resulting from Nanosecond and Picosecond Laser Irradiation of a Ti-Based Alloy under Controlled Atmospheric Conditions and Optimization of the Irradiation Process. in Micromachines, 15(1), 5.
https://doi.org/10.3390/mi15010005
Milovanović D, Rajčić B, Ranković D, Stankov B, Čekada M, Ciganović J, Đurđević-Milošević D, Stević Z, Kuzmanović M, Šibalija T, Petronić S. Microstructure Formations Resulting from Nanosecond and Picosecond Laser Irradiation of a Ti-Based Alloy under Controlled Atmospheric Conditions and Optimization of the Irradiation Process. in Micromachines. 2024;15(1):5.
doi:10.3390/mi15010005 .
Milovanović, Dubravka, Rajčić, Boris, Ranković, Dragan, Stankov, Biljana, Čekada, Miha, Ciganović, Jovan, Đurđević-Milošević, Dragica, Stević, Zoran, Kuzmanović, Miroslav, Šibalija, Tatjana, Petronić, Sanja, "Microstructure Formations Resulting from Nanosecond and Picosecond Laser Irradiation of a Ti-Based Alloy under Controlled Atmospheric Conditions and Optimization of the Irradiation Process" in Micromachines, 15, no. 1 (2024):5,
https://doi.org/10.3390/mi15010005 . .

Impact of Microstructural and Surface Modifications on the Ti-45Nb Alloy’s Response to Bio-Environment

Cvijović-Alagić, Ivana; Laketić, Slađana; Momčilović, Miloš; Ciganović, Jovan; Bajat, Jelena; Kojić, Vesna

(2024)

TY  - JOUR
AU  - Cvijović-Alagić, Ivana
AU  - Laketić, Slađana
AU  - Momčilović, Miloš
AU  - Ciganović, Jovan
AU  - Bajat, Jelena
AU  - Kojić, Vesna
PY  - 2024
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/13227
AB  - The Ti-45Nb (mass%) alloy’s corrosive and biocompatible response in simulated physiological conditions was investigated before and after its additional high-pressure torsion (HPT) and laser irradiation processing. The grain size reduction from 2.76 μm to ~ 200 nm and the appearance of laser-induced morphologically altered and highly oxidized surface led to the significant improvement of alloy corrosion resistance and cell–implant interaction. Moreover, an additional increase of the laser pulse energy from 5 to 15 mJ during the alloy irradiation in the air led to an increase in the surface oxygen content from 13.64 to 23.89% accompanied by an increase of excellent cell viability from 127.18 to 134.42%. As a result of the controlled alloy microstructural and surface modifications, the formation of protective bi-modal mixed Ti- and Nb-oxide external scale was enabled. The presence of this surface oxide scale enhanced the alloy’s resistance to corrosion deterioration and simultaneously boosted cell viability and proliferation.
T2  - Acta Metallurgica Sinica (English Letters)
T1  - Impact of Microstructural and Surface Modifications on the Ti-45Nb Alloy’s Response to Bio-Environment
DO  - 10.1007/s40195-024-01705-0
ER  - 
@article{
author = "Cvijović-Alagić, Ivana and Laketić, Slađana and Momčilović, Miloš and Ciganović, Jovan and Bajat, Jelena and Kojić, Vesna",
year = "2024",
abstract = "The Ti-45Nb (mass%) alloy’s corrosive and biocompatible response in simulated physiological conditions was investigated before and after its additional high-pressure torsion (HPT) and laser irradiation processing. The grain size reduction from 2.76 μm to ~ 200 nm and the appearance of laser-induced morphologically altered and highly oxidized surface led to the significant improvement of alloy corrosion resistance and cell–implant interaction. Moreover, an additional increase of the laser pulse energy from 5 to 15 mJ during the alloy irradiation in the air led to an increase in the surface oxygen content from 13.64 to 23.89% accompanied by an increase of excellent cell viability from 127.18 to 134.42%. As a result of the controlled alloy microstructural and surface modifications, the formation of protective bi-modal mixed Ti- and Nb-oxide external scale was enabled. The presence of this surface oxide scale enhanced the alloy’s resistance to corrosion deterioration and simultaneously boosted cell viability and proliferation.",
journal = "Acta Metallurgica Sinica (English Letters)",
title = "Impact of Microstructural and Surface Modifications on the Ti-45Nb Alloy’s Response to Bio-Environment",
doi = "10.1007/s40195-024-01705-0"
}
Cvijović-Alagić, I., Laketić, S., Momčilović, M., Ciganović, J., Bajat, J.,& Kojić, V.. (2024). Impact of Microstructural and Surface Modifications on the Ti-45Nb Alloy’s Response to Bio-Environment. in Acta Metallurgica Sinica (English Letters).
https://doi.org/10.1007/s40195-024-01705-0
Cvijović-Alagić I, Laketić S, Momčilović M, Ciganović J, Bajat J, Kojić V. Impact of Microstructural and Surface Modifications on the Ti-45Nb Alloy’s Response to Bio-Environment. in Acta Metallurgica Sinica (English Letters). 2024;.
doi:10.1007/s40195-024-01705-0 .
Cvijović-Alagić, Ivana, Laketić, Slađana, Momčilović, Miloš, Ciganović, Jovan, Bajat, Jelena, Kojić, Vesna, "Impact of Microstructural and Surface Modifications on the Ti-45Nb Alloy’s Response to Bio-Environment" in Acta Metallurgica Sinica (English Letters) (2024),
https://doi.org/10.1007/s40195-024-01705-0 . .

Waste biomass derived highly-porous carbon material for toxic metal removal: Optimisation, mechanisms and environmental implications

Radenković, Marina; Petrović, Jelena; Pap, Sabolc; Kalijadis, Ana; Momčilović, Miloš; Krstulović, Nikša; Živković, Sanja

(2024)

TY  - JOUR
AU  - Radenković, Marina
AU  - Petrović, Jelena
AU  - Pap, Sabolc
AU  - Kalijadis, Ana
AU  - Momčilović, Miloš
AU  - Krstulović, Nikša
AU  - Živković, Sanja
PY  - 2024
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/12206
AB  - Toxic elements, lead, and copper are often found in wastewater discharged from industries such as mining. The discharge of untreated effluent poses severe environmental challenges and sorption methods using agricultural waste materials are proposed as an efficient and cost-effective solution. For this research, activated sunflower material (ASM) was prepared from abundantly available agricultural sunflower waste residues and utilised to remove Pb2+ and Cu2+ ions from an aqueous medium. To begin, we examine variables that may have an impact on the adsorption process, such as pH, contact time, adsorbent dose, and initial concentration using Box-Behnken Design (BBD) to find optimal conditions. Maximum removal efficiency was found at a pH of 5, contact time of 180 min, and initial concentration of 50 mg/L for Pb2+ and 150 mg/L for Cu2+. Additionally, adsorbent dose differed by element, for Cu2+ it was 200 mg, whilst for Pb2+ it was 124 mg. Features of activated carbon such as morphology, elemental composition, textural properties, and surface functionalities were characterised using SEM-EDS, BET, FTIR, and XPS. The adsorption equilibrium data were analysed by Langmuir, Freundlich, and Dubinin-Radushkevich isotherm models. It was found that the obtained results for Pb2+ adsorption were better described with the Freundlich isotherm model. Maximum adsorption capacities for Pb2+ and Cu2+ were 91.8 mg/g and 20.5 mg/g, respectively. Furthermore, kinetic studies confirmed that the adsorption process followed a pseudo-first-order kinetic model for Pb2+, but for Cu2+ all applied kinetic models fitted experimental data with the same values of the correlation coefficient (R2 = 0.99). After comprehensive analysis using the methods mentioned above, ASM was tested for the removal of Cu2+ from mining wastewater sample, and the obtained removal efficiency was 98.6% ± 2.0%. The results of desorption experiments conducted, confirm that ASM has good potential to be reused for the purpose of removing Cu2+ from wastewater.
T2  - Chemosphere
T1  - Waste biomass derived highly-porous carbon material for toxic metal removal: Optimisation, mechanisms and environmental implications
VL  - 347
SP  - 140684
DO  - 10.1016/j.chemosphere.2023.140684
ER  - 
@article{
author = "Radenković, Marina and Petrović, Jelena and Pap, Sabolc and Kalijadis, Ana and Momčilović, Miloš and Krstulović, Nikša and Živković, Sanja",
year = "2024",
abstract = "Toxic elements, lead, and copper are often found in wastewater discharged from industries such as mining. The discharge of untreated effluent poses severe environmental challenges and sorption methods using agricultural waste materials are proposed as an efficient and cost-effective solution. For this research, activated sunflower material (ASM) was prepared from abundantly available agricultural sunflower waste residues and utilised to remove Pb2+ and Cu2+ ions from an aqueous medium. To begin, we examine variables that may have an impact on the adsorption process, such as pH, contact time, adsorbent dose, and initial concentration using Box-Behnken Design (BBD) to find optimal conditions. Maximum removal efficiency was found at a pH of 5, contact time of 180 min, and initial concentration of 50 mg/L for Pb2+ and 150 mg/L for Cu2+. Additionally, adsorbent dose differed by element, for Cu2+ it was 200 mg, whilst for Pb2+ it was 124 mg. Features of activated carbon such as morphology, elemental composition, textural properties, and surface functionalities were characterised using SEM-EDS, BET, FTIR, and XPS. The adsorption equilibrium data were analysed by Langmuir, Freundlich, and Dubinin-Radushkevich isotherm models. It was found that the obtained results for Pb2+ adsorption were better described with the Freundlich isotherm model. Maximum adsorption capacities for Pb2+ and Cu2+ were 91.8 mg/g and 20.5 mg/g, respectively. Furthermore, kinetic studies confirmed that the adsorption process followed a pseudo-first-order kinetic model for Pb2+, but for Cu2+ all applied kinetic models fitted experimental data with the same values of the correlation coefficient (R2 = 0.99). After comprehensive analysis using the methods mentioned above, ASM was tested for the removal of Cu2+ from mining wastewater sample, and the obtained removal efficiency was 98.6% ± 2.0%. The results of desorption experiments conducted, confirm that ASM has good potential to be reused for the purpose of removing Cu2+ from wastewater.",
journal = "Chemosphere",
title = "Waste biomass derived highly-porous carbon material for toxic metal removal: Optimisation, mechanisms and environmental implications",
volume = "347",
pages = "140684",
doi = "10.1016/j.chemosphere.2023.140684"
}
Radenković, M., Petrović, J., Pap, S., Kalijadis, A., Momčilović, M., Krstulović, N.,& Živković, S.. (2024). Waste biomass derived highly-porous carbon material for toxic metal removal: Optimisation, mechanisms and environmental implications. in Chemosphere, 347, 140684.
https://doi.org/10.1016/j.chemosphere.2023.140684
Radenković M, Petrović J, Pap S, Kalijadis A, Momčilović M, Krstulović N, Živković S. Waste biomass derived highly-porous carbon material for toxic metal removal: Optimisation, mechanisms and environmental implications. in Chemosphere. 2024;347:140684.
doi:10.1016/j.chemosphere.2023.140684 .
Radenković, Marina, Petrović, Jelena, Pap, Sabolc, Kalijadis, Ana, Momčilović, Miloš, Krstulović, Nikša, Živković, Sanja, "Waste biomass derived highly-porous carbon material for toxic metal removal: Optimisation, mechanisms and environmental implications" in Chemosphere, 347 (2024):140684,
https://doi.org/10.1016/j.chemosphere.2023.140684 . .
3
2
2

Synergy of Nd:YAG Picosecond Pulsed Laser Irradiation and Electrochemical Anodization in the Formation of TiO2 Nanostructures for the Photocatalytic Degradation of Pesticide Carbofuran

Tošić, Miloš; Rajić, Vladimir; Pjević, Dejan; Stojadinović, Stevan; Krstulović, Nikša; Dimitrijević-Branković, Suzana; Momčilović, Miloš

(2024)

TY  - JOUR
AU  - Tošić, Miloš
AU  - Rajić, Vladimir
AU  - Pjević, Dejan
AU  - Stojadinović, Stevan
AU  - Krstulović, Nikša
AU  - Dimitrijević-Branković, Suzana
AU  - Momčilović, Miloš
PY  - 2024
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/13091
AB  - This study proposes a simple and controlled method for producing TiO2 with phase junction, oxygen vacancies, and Ti3+ by combining picosecond pulsed laser irradiation and electrochemical anodization. Ti mesh was pretreated by irradiating with a picosecond pulsed laser technique using an Nd:YAG laser (1064 nm) at two fluencies, 15 J/cm2 and 30 J/cm2 . The samples were then subjected to electrochemical anodization to form TiO2 nanotube arrays on the previously laser-treated surface. This study will investigate the possibility of forming TiO2 nanotube arrays on a pre-laser-treated Ti substrate and determine their physicochemical and photocatalytic properties. The samples were characterized by FESEM, XRD, Raman, XPS, and UV-Vis DRS. UV-Vis spectroscopy was used to observe the progress of photocatalytic degradation for all samples, and degradation products were determined using GC-MS. With the synergistic effects of phase junction, oxygen vacancies, and Ti3+, the laser-treated TiO2 with 30 J/cm2 showed a higher photocatalytic degradation rate (85.1%) of the pesticide carbofuran compared to non-laser-treated TiO2 (54.8%), remaining stable during successive degradation cycles, which has promising practical applications.
T2  - Photonics
T1  - Synergy of Nd:YAG Picosecond Pulsed Laser Irradiation and Electrochemical Anodization in the Formation of TiO2 Nanostructures for the Photocatalytic Degradation of Pesticide Carbofuran
VL  - 11
IS  - 3
SP  - 284
DO  - 10.3390/photonics11030284
ER  - 
@article{
author = "Tošić, Miloš and Rajić, Vladimir and Pjević, Dejan and Stojadinović, Stevan and Krstulović, Nikša and Dimitrijević-Branković, Suzana and Momčilović, Miloš",
year = "2024",
abstract = "This study proposes a simple and controlled method for producing TiO2 with phase junction, oxygen vacancies, and Ti3+ by combining picosecond pulsed laser irradiation and electrochemical anodization. Ti mesh was pretreated by irradiating with a picosecond pulsed laser technique using an Nd:YAG laser (1064 nm) at two fluencies, 15 J/cm2 and 30 J/cm2 . The samples were then subjected to electrochemical anodization to form TiO2 nanotube arrays on the previously laser-treated surface. This study will investigate the possibility of forming TiO2 nanotube arrays on a pre-laser-treated Ti substrate and determine their physicochemical and photocatalytic properties. The samples were characterized by FESEM, XRD, Raman, XPS, and UV-Vis DRS. UV-Vis spectroscopy was used to observe the progress of photocatalytic degradation for all samples, and degradation products were determined using GC-MS. With the synergistic effects of phase junction, oxygen vacancies, and Ti3+, the laser-treated TiO2 with 30 J/cm2 showed a higher photocatalytic degradation rate (85.1%) of the pesticide carbofuran compared to non-laser-treated TiO2 (54.8%), remaining stable during successive degradation cycles, which has promising practical applications.",
journal = "Photonics",
title = "Synergy of Nd:YAG Picosecond Pulsed Laser Irradiation and Electrochemical Anodization in the Formation of TiO2 Nanostructures for the Photocatalytic Degradation of Pesticide Carbofuran",
volume = "11",
number = "3",
pages = "284",
doi = "10.3390/photonics11030284"
}
Tošić, M., Rajić, V., Pjević, D., Stojadinović, S., Krstulović, N., Dimitrijević-Branković, S.,& Momčilović, M.. (2024). Synergy of Nd:YAG Picosecond Pulsed Laser Irradiation and Electrochemical Anodization in the Formation of TiO2 Nanostructures for the Photocatalytic Degradation of Pesticide Carbofuran. in Photonics, 11(3), 284.
https://doi.org/10.3390/photonics11030284
Tošić M, Rajić V, Pjević D, Stojadinović S, Krstulović N, Dimitrijević-Branković S, Momčilović M. Synergy of Nd:YAG Picosecond Pulsed Laser Irradiation and Electrochemical Anodization in the Formation of TiO2 Nanostructures for the Photocatalytic Degradation of Pesticide Carbofuran. in Photonics. 2024;11(3):284.
doi:10.3390/photonics11030284 .
Tošić, Miloš, Rajić, Vladimir, Pjević, Dejan, Stojadinović, Stevan, Krstulović, Nikša, Dimitrijević-Branković, Suzana, Momčilović, Miloš, "Synergy of Nd:YAG Picosecond Pulsed Laser Irradiation and Electrochemical Anodization in the Formation of TiO2 Nanostructures for the Photocatalytic Degradation of Pesticide Carbofuran" in Photonics, 11, no. 3 (2024):284,
https://doi.org/10.3390/photonics11030284 . .

Mechanical properties and behavior of the Ti–45Nb alloy subjected to extreme conditions

Zagorac, Dejan; Prasad, Dasari; Škundrić, Tamara; Yadav, Kedar; Singh, Surender; Laketić, Slađana; Zagorac, Jelena; Momčilović, Miloš; Cvijović-Alagić, Ivana

(2024)

TY  - JOUR
AU  - Zagorac, Dejan
AU  - Prasad, Dasari
AU  - Škundrić, Tamara
AU  - Yadav, Kedar
AU  - Singh, Surender
AU  - Laketić, Slađana
AU  - Zagorac, Jelena
AU  - Momčilović, Miloš
AU  - Cvijović-Alagić, Ivana
PY  - 2024
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/13300
AB  - Mechanical properties and structure-property relationship of the Ti-45Nb (mass%) alloy with potential applications in biomedicine were investigated using a multidisciplinary approach. Because the biomechanical compatibility of metallic implant materials can be significantly improved by microstructural refinement and laser surface modification (LSM), the present study concentrates on the investigation of the mechanical properties of the Ti-45Nb alloy subjected to extreme processing conditions to evaluate their impact on the alloy improved applicability in the bio-environment. The alloy was therefore subjected to high-pressure torsion (HPT) and LSM processing to obtain favorable alloy characteristics. Crystal structure prediction was conducted using data mining (DM) and evolutionary algorithms (EA). All the obtained potential structure candidates were submitted to the local optimizations at the level of density functional theory (DFT); subsequently, the phonon lattice dynamics and mechanical properties were systematically investigated. The alloy structure progression and mechanical characteristics were examined under the influence of extremely high temperatures induced during the LSM processing and the extreme pressure achieved during the HPT treatment. XRD characterization was performed using experimental and theoretical methods showing the presence of bcc β-Ti and orthorhombic Cmcm Ti4Nb phase. Mechanical properties such as Young's modulus, Vicker's hardness, and plasticity of the most relevant Ti4Nb modifications predicted after DM-EA-DFT were found to corroborate well with the experimental results of nanoindentation measurements. The present study reveals that the additional processing of the Ti-45Nb alloy under extreme conditions leads to significant improvement in the alloy's bio-mechanical compatibility.
T2  - CrystEngComm
T1  - Mechanical properties and behavior of the Ti–45Nb alloy subjected to extreme conditions
VL  - 26
IS  - 22
SP  - 2989
EP  - 3004
DO  - 10.1039/D4CE00076E
ER  - 
@article{
author = "Zagorac, Dejan and Prasad, Dasari and Škundrić, Tamara and Yadav, Kedar and Singh, Surender and Laketić, Slađana and Zagorac, Jelena and Momčilović, Miloš and Cvijović-Alagić, Ivana",
year = "2024",
abstract = "Mechanical properties and structure-property relationship of the Ti-45Nb (mass%) alloy with potential applications in biomedicine were investigated using a multidisciplinary approach. Because the biomechanical compatibility of metallic implant materials can be significantly improved by microstructural refinement and laser surface modification (LSM), the present study concentrates on the investigation of the mechanical properties of the Ti-45Nb alloy subjected to extreme processing conditions to evaluate their impact on the alloy improved applicability in the bio-environment. The alloy was therefore subjected to high-pressure torsion (HPT) and LSM processing to obtain favorable alloy characteristics. Crystal structure prediction was conducted using data mining (DM) and evolutionary algorithms (EA). All the obtained potential structure candidates were submitted to the local optimizations at the level of density functional theory (DFT); subsequently, the phonon lattice dynamics and mechanical properties were systematically investigated. The alloy structure progression and mechanical characteristics were examined under the influence of extremely high temperatures induced during the LSM processing and the extreme pressure achieved during the HPT treatment. XRD characterization was performed using experimental and theoretical methods showing the presence of bcc β-Ti and orthorhombic Cmcm Ti4Nb phase. Mechanical properties such as Young's modulus, Vicker's hardness, and plasticity of the most relevant Ti4Nb modifications predicted after DM-EA-DFT were found to corroborate well with the experimental results of nanoindentation measurements. The present study reveals that the additional processing of the Ti-45Nb alloy under extreme conditions leads to significant improvement in the alloy's bio-mechanical compatibility.",
journal = "CrystEngComm",
title = "Mechanical properties and behavior of the Ti–45Nb alloy subjected to extreme conditions",
volume = "26",
number = "22",
pages = "2989-3004",
doi = "10.1039/D4CE00076E"
}
Zagorac, D., Prasad, D., Škundrić, T., Yadav, K., Singh, S., Laketić, S., Zagorac, J., Momčilović, M.,& Cvijović-Alagić, I.. (2024). Mechanical properties and behavior of the Ti–45Nb alloy subjected to extreme conditions. in CrystEngComm, 26(22), 2989-3004.
https://doi.org/10.1039/D4CE00076E
Zagorac D, Prasad D, Škundrić T, Yadav K, Singh S, Laketić S, Zagorac J, Momčilović M, Cvijović-Alagić I. Mechanical properties and behavior of the Ti–45Nb alloy subjected to extreme conditions. in CrystEngComm. 2024;26(22):2989-3004.
doi:10.1039/D4CE00076E .
Zagorac, Dejan, Prasad, Dasari, Škundrić, Tamara, Yadav, Kedar, Singh, Surender, Laketić, Slađana, Zagorac, Jelena, Momčilović, Miloš, Cvijović-Alagić, Ivana, "Mechanical properties and behavior of the Ti–45Nb alloy subjected to extreme conditions" in CrystEngComm, 26, no. 22 (2024):2989-3004,
https://doi.org/10.1039/D4CE00076E . .
1

A morphology-preserving algorithm for denoising of EMG-contaminated ECG signals

Atanasoski, Vladimir; Petrović, Jovana S.; Popović Maneski, Lana; Miletić, Marjan; Babić, Miloš; Nikolić, Aleksandra; Panescu, Dorin; Ivanović, Marija D.

(2024)

TY  - JOUR
AU  - Atanasoski, Vladimir
AU  - Petrović, Jovana S.
AU  - Popović Maneski, Lana
AU  - Miletić, Marjan
AU  - Babić, Miloš
AU  - Nikolić, Aleksandra
AU  - Panescu, Dorin
AU  - Ivanović, Marija D.
PY  - 2024
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/13128
AB  - Clinical interpretation of an electrocardiogram (ECG) can be detrimentally affected by noise. Removal of the electromyographic (EMG) noise is particularly challenging due to its spectral overlap with the QRS complex. The existing EMG-denoising algorithms often distort signal morphology, thus obscuring diagnostically relevant information. Here, a new iterative regeneration method (IRM) for efficient EMG-noise suppression is proposed. The main hypothesis is that the temporary removal of the dominant ECG components enables extraction of the noise with the minimum alteration to the signal. The method is validated on SimEMG database of simultaneously recorded reference and noisy signals, MIT-BIH arrhythmia database and synthesized ECG signals, both with the noise from MIT Noise Stress Test Database. IRM denoising and morphology-preserving performance is superior to the wavelet- and FIR-based benchmark methods. : IRM is reliable, computationally non-intensive, fast and applicable to any number of ECG channels recorded by mobile or standard ECG devices.
T2  - IEEE Open Journal of Engineering in Medicine and Biology
T1  - A morphology-preserving algorithm for denoising of EMG-contaminated ECG signals
SP  - 1
EP  - 10
DO  - 10.1109/OJEMB.2024.3380352
ER  - 
@article{
author = "Atanasoski, Vladimir and Petrović, Jovana S. and Popović Maneski, Lana and Miletić, Marjan and Babić, Miloš and Nikolić, Aleksandra and Panescu, Dorin and Ivanović, Marija D.",
year = "2024",
abstract = "Clinical interpretation of an electrocardiogram (ECG) can be detrimentally affected by noise. Removal of the electromyographic (EMG) noise is particularly challenging due to its spectral overlap with the QRS complex. The existing EMG-denoising algorithms often distort signal morphology, thus obscuring diagnostically relevant information. Here, a new iterative regeneration method (IRM) for efficient EMG-noise suppression is proposed. The main hypothesis is that the temporary removal of the dominant ECG components enables extraction of the noise with the minimum alteration to the signal. The method is validated on SimEMG database of simultaneously recorded reference and noisy signals, MIT-BIH arrhythmia database and synthesized ECG signals, both with the noise from MIT Noise Stress Test Database. IRM denoising and morphology-preserving performance is superior to the wavelet- and FIR-based benchmark methods. : IRM is reliable, computationally non-intensive, fast and applicable to any number of ECG channels recorded by mobile or standard ECG devices.",
journal = "IEEE Open Journal of Engineering in Medicine and Biology",
title = "A morphology-preserving algorithm for denoising of EMG-contaminated ECG signals",
pages = "1-10",
doi = "10.1109/OJEMB.2024.3380352"
}
Atanasoski, V., Petrović, J. S., Popović Maneski, L., Miletić, M., Babić, M., Nikolić, A., Panescu, D.,& Ivanović, M. D.. (2024). A morphology-preserving algorithm for denoising of EMG-contaminated ECG signals. in IEEE Open Journal of Engineering in Medicine and Biology, 1-10.
https://doi.org/10.1109/OJEMB.2024.3380352
Atanasoski V, Petrović JS, Popović Maneski L, Miletić M, Babić M, Nikolić A, Panescu D, Ivanović MD. A morphology-preserving algorithm for denoising of EMG-contaminated ECG signals. in IEEE Open Journal of Engineering in Medicine and Biology. 2024;:1-10.
doi:10.1109/OJEMB.2024.3380352 .
Atanasoski, Vladimir, Petrović, Jovana S., Popović Maneski, Lana, Miletić, Marjan, Babić, Miloš, Nikolić, Aleksandra, Panescu, Dorin, Ivanović, Marija D., "A morphology-preserving algorithm for denoising of EMG-contaminated ECG signals" in IEEE Open Journal of Engineering in Medicine and Biology (2024):1-10,
https://doi.org/10.1109/OJEMB.2024.3380352 . .

Structures and growth pathways of AunCln+3-(n≤7) cluster anions

Xu, Shiyin; Liu, Xinhe; Hou, Yameng; Kou, Min; Xu, Xinshi; Veljković, Filip; Veličković, Suzana; Kong, Xianglei

(2024)

TY  - JOUR
AU  - Xu, Shiyin
AU  - Liu, Xinhe
AU  - Hou, Yameng
AU  - Kou, Min
AU  - Xu, Xinshi
AU  - Veljković, Filip
AU  - Veličković, Suzana
AU  - Kong, Xianglei
PY  - 2024
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/12955
AB  - Gold chloride clusters play an important role in catalysis and materials chemistry. Due to the diversity of their species and isomers, there is still a dearth of structural studies at the molecular level. In this work, anions of AunCln+3- and AunCln+5- (n = 2–4) clusters were obtained by laser desorption/ionization mass spectrometry (LDI MS), and the most stable isomers of AunCln+3- were determined after a thorough search and optimization at the TPSSh/aug-cc-pVTZ/ECP60MDF level. The results indicate that all isomers with the lowest energy have a planar zigzag skeleton. In each species, there is one Au(III) atom at the edge connected with four Cl atoms, which sets it from the other Au(I) atoms. Four growth pathways for AunCln+3- (n = 2–7) clusters are proposed (labelled R1, R2, R3 and R4). They are all associated with an aurophilic contact and are exothermic. The binding energies tend to stabilize at ~ −41 kcal/mol when the size of the cluster increases in all pathways. The pathway R1, which connects all the most stable isomers of the respective clusters, is characterized by cluster growth due to aurophilic interactions at the terminal atom of Au(I) in the zigzag chains. In the pathway of R4 involving Au-Au bonding in its initial structures (n ≤ 3), the distance between intermediate gold atoms grows with cluster size, ultimately resulting in the transfer of the intermediate Au-Au bonding into aurophilic interaction. The size effect on the structure and aurophilic interactions of these clusters will be better understood based on these discoveries, potentially providing new insights into the active but elusive chemical species involved in the corresponding catalytic reactions or nanoparticle synthesis processes.
T2  - Frontiers in Chemistry
T1  - Structures and growth pathways of AunCln+3-(n≤7) cluster anions
VL  - 12
SP  - 1382443
DO  - 10.3389/fchem.2024.1382443
ER  - 
@article{
author = "Xu, Shiyin and Liu, Xinhe and Hou, Yameng and Kou, Min and Xu, Xinshi and Veljković, Filip and Veličković, Suzana and Kong, Xianglei",
year = "2024",
abstract = "Gold chloride clusters play an important role in catalysis and materials chemistry. Due to the diversity of their species and isomers, there is still a dearth of structural studies at the molecular level. In this work, anions of AunCln+3- and AunCln+5- (n = 2–4) clusters were obtained by laser desorption/ionization mass spectrometry (LDI MS), and the most stable isomers of AunCln+3- were determined after a thorough search and optimization at the TPSSh/aug-cc-pVTZ/ECP60MDF level. The results indicate that all isomers with the lowest energy have a planar zigzag skeleton. In each species, there is one Au(III) atom at the edge connected with four Cl atoms, which sets it from the other Au(I) atoms. Four growth pathways for AunCln+3- (n = 2–7) clusters are proposed (labelled R1, R2, R3 and R4). They are all associated with an aurophilic contact and are exothermic. The binding energies tend to stabilize at ~ −41 kcal/mol when the size of the cluster increases in all pathways. The pathway R1, which connects all the most stable isomers of the respective clusters, is characterized by cluster growth due to aurophilic interactions at the terminal atom of Au(I) in the zigzag chains. In the pathway of R4 involving Au-Au bonding in its initial structures (n ≤ 3), the distance between intermediate gold atoms grows with cluster size, ultimately resulting in the transfer of the intermediate Au-Au bonding into aurophilic interaction. The size effect on the structure and aurophilic interactions of these clusters will be better understood based on these discoveries, potentially providing new insights into the active but elusive chemical species involved in the corresponding catalytic reactions or nanoparticle synthesis processes.",
journal = "Frontiers in Chemistry",
title = "Structures and growth pathways of AunCln+3-(n≤7) cluster anions",
volume = "12",
pages = "1382443",
doi = "10.3389/fchem.2024.1382443"
}
Xu, S., Liu, X., Hou, Y., Kou, M., Xu, X., Veljković, F., Veličković, S.,& Kong, X.. (2024). Structures and growth pathways of AunCln+3-(n≤7) cluster anions. in Frontiers in Chemistry, 12, 1382443.
https://doi.org/10.3389/fchem.2024.1382443
Xu S, Liu X, Hou Y, Kou M, Xu X, Veljković F, Veličković S, Kong X. Structures and growth pathways of AunCln+3-(n≤7) cluster anions. in Frontiers in Chemistry. 2024;12:1382443.
doi:10.3389/fchem.2024.1382443 .
Xu, Shiyin, Liu, Xinhe, Hou, Yameng, Kou, Min, Xu, Xinshi, Veljković, Filip, Veličković, Suzana, Kong, Xianglei, "Structures and growth pathways of AunCln+3-(n≤7) cluster anions" in Frontiers in Chemistry, 12 (2024):1382443,
https://doi.org/10.3389/fchem.2024.1382443 . .
1

Combustion Behavior of Cellulose Ester Fibrous Bundles from Used Cigarette Filters: Kinetic Analysis Study

Veljković, Filip; Dodevski, Vladimir; Marinović-Cincović, Milena; Veličković, Suzana; Janković, Bojan Ž.

(2024)

TY  - JOUR
AU  - Veljković, Filip
AU  - Dodevski, Vladimir
AU  - Marinović-Cincović, Milena
AU  - Veličković, Suzana
AU  - Janković, Bojan Ž.
PY  - 2024
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/13292
AB  - This study is focused on the detailed examination of the combustion properties and kinetic analysis of a cellulose acetate fibrous bundle (CAFB), separated from used cigarette filters. It was shown that the faster rate of CAFB heating allows a large amount of heat to be supplied to a combustion system in the initial stages, where the increase in heating rate has a positive response to ignition behavior. The best combustion stability of CAFB is achieved at the lowest heating rate. Through the use of different kinetic methods, it was shown that combustion takes place through two series of consecutive reaction steps and one independent single-step reaction. By optimizing the kinetic parameters within the proposed reaction models, it was found that the steps related to the generation of levoglucosenone (LGO) (by catalytic dehydration of levoglucosan (LG)) and acrolein (by breakdown of glycerol during CAFB burning—which was carried out through glycerol adsorption on a TiO2 surface in a the developed dehydration mechanism) represent rate-controlling steps, which are strongly controlled by applied heating rate. Isothermal predictions have shown that CAFB manifests very good long-term stability at 60 °C (which corresponds to storage in a sea shipping container), while at 200 °C, it shows a sudden loss in thermal stability, which is related to the physical properties of the sample.
T2  - Polymers
T1  - Combustion Behavior of Cellulose Ester Fibrous Bundles from Used Cigarette Filters: Kinetic Analysis Study
VL  - 16
IS  - 11
SP  - 1480
DO  - 10.3390/polym16111480
ER  - 
@article{
author = "Veljković, Filip and Dodevski, Vladimir and Marinović-Cincović, Milena and Veličković, Suzana and Janković, Bojan Ž.",
year = "2024",
abstract = "This study is focused on the detailed examination of the combustion properties and kinetic analysis of a cellulose acetate fibrous bundle (CAFB), separated from used cigarette filters. It was shown that the faster rate of CAFB heating allows a large amount of heat to be supplied to a combustion system in the initial stages, where the increase in heating rate has a positive response to ignition behavior. The best combustion stability of CAFB is achieved at the lowest heating rate. Through the use of different kinetic methods, it was shown that combustion takes place through two series of consecutive reaction steps and one independent single-step reaction. By optimizing the kinetic parameters within the proposed reaction models, it was found that the steps related to the generation of levoglucosenone (LGO) (by catalytic dehydration of levoglucosan (LG)) and acrolein (by breakdown of glycerol during CAFB burning—which was carried out through glycerol adsorption on a TiO2 surface in a the developed dehydration mechanism) represent rate-controlling steps, which are strongly controlled by applied heating rate. Isothermal predictions have shown that CAFB manifests very good long-term stability at 60 °C (which corresponds to storage in a sea shipping container), while at 200 °C, it shows a sudden loss in thermal stability, which is related to the physical properties of the sample.",
journal = "Polymers",
title = "Combustion Behavior of Cellulose Ester Fibrous Bundles from Used Cigarette Filters: Kinetic Analysis Study",
volume = "16",
number = "11",
pages = "1480",
doi = "10.3390/polym16111480"
}
Veljković, F., Dodevski, V., Marinović-Cincović, M., Veličković, S.,& Janković, B. Ž.. (2024). Combustion Behavior of Cellulose Ester Fibrous Bundles from Used Cigarette Filters: Kinetic Analysis Study. in Polymers, 16(11), 1480.
https://doi.org/10.3390/polym16111480
Veljković F, Dodevski V, Marinović-Cincović M, Veličković S, Janković BŽ. Combustion Behavior of Cellulose Ester Fibrous Bundles from Used Cigarette Filters: Kinetic Analysis Study. in Polymers. 2024;16(11):1480.
doi:10.3390/polym16111480 .
Veljković, Filip, Dodevski, Vladimir, Marinović-Cincović, Milena, Veličković, Suzana, Janković, Bojan Ž., "Combustion Behavior of Cellulose Ester Fibrous Bundles from Used Cigarette Filters: Kinetic Analysis Study" in Polymers, 16, no. 11 (2024):1480,
https://doi.org/10.3390/polym16111480 . .

Comparable Toxicity of Surface-Modified TiO2 Nanoparticles: An In Vivo Experimental Study on Reproductive Toxicity in Rats

Todorović, Ana; Bobić, Katarina; Veljković, Filip; Pejić, Snežana; Glumac, Sofija; Stanković, Sanja; Milovanović, Tijana; Vukoje, Ivana; Nedeljković, Jovan; Radojević Škodrić, Sanja; Pajović, Snežana B.; Drakulić, Dunja

(2024)

TY  - JOUR
AU  - Todorović, Ana
AU  - Bobić, Katarina
AU  - Veljković, Filip
AU  - Pejić, Snežana
AU  - Glumac, Sofija
AU  - Stanković, Sanja
AU  - Milovanović, Tijana
AU  - Vukoje, Ivana
AU  - Nedeljković, Jovan
AU  - Radojević Škodrić, Sanja
AU  - Pajović, Snežana B.
AU  - Drakulić, Dunja
PY  - 2024
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/13090
AB  - Nanoparticles (NPs), a distinct class of particles ranging in size from 1 to 100 nm, are one of the most promising technologies of the 21st century, and titanium dioxide NPs (TiO2 NPs) are among the most widely produced and used NPs globally. The increased application of TiO2 NPs raises concerns regarding their global safety and risks of exposure. Many animal studies have reported the accumulation of TiO2 NPs in female reproductive organs; however, evidence of the resultant toxicity remains ambiguous. Since the surface area and chemical modifications of NPs can significantly change their cytotoxicity, we aimed to compare the toxic effects of pristine TiO2 powder with surface-modified TiO2 powders with salicylic acid (TiO2/SA) and 5-aminosalicylic acid (TiO2/5-ASA) on the ovaries, oviducts, and uterus on the 14th day following acute oral treatment. The results, based on alterations in food and water intake, body mass, organ-to-body mass ratio, hormonal status, histological features of tissues of interest, and antioxidant parameters, suggest that the modification with 5-ASA can mitigate some of the observed toxic effects of TiO2 powder and encourage future investigations to create NPs that can potentially reduce the harmful effects of TiO2 NPs while preserving their positive impacts.
T2  - Antioxidants
T1  - Comparable Toxicity of Surface-Modified TiO2 Nanoparticles: An In Vivo Experimental Study on Reproductive Toxicity in Rats
VL  - 13
IS  - 2
SP  - 231
DO  - 10.3390/antiox13020231
ER  - 
@article{
author = "Todorović, Ana and Bobić, Katarina and Veljković, Filip and Pejić, Snežana and Glumac, Sofija and Stanković, Sanja and Milovanović, Tijana and Vukoje, Ivana and Nedeljković, Jovan and Radojević Škodrić, Sanja and Pajović, Snežana B. and Drakulić, Dunja",
year = "2024",
abstract = "Nanoparticles (NPs), a distinct class of particles ranging in size from 1 to 100 nm, are one of the most promising technologies of the 21st century, and titanium dioxide NPs (TiO2 NPs) are among the most widely produced and used NPs globally. The increased application of TiO2 NPs raises concerns regarding their global safety and risks of exposure. Many animal studies have reported the accumulation of TiO2 NPs in female reproductive organs; however, evidence of the resultant toxicity remains ambiguous. Since the surface area and chemical modifications of NPs can significantly change their cytotoxicity, we aimed to compare the toxic effects of pristine TiO2 powder with surface-modified TiO2 powders with salicylic acid (TiO2/SA) and 5-aminosalicylic acid (TiO2/5-ASA) on the ovaries, oviducts, and uterus on the 14th day following acute oral treatment. The results, based on alterations in food and water intake, body mass, organ-to-body mass ratio, hormonal status, histological features of tissues of interest, and antioxidant parameters, suggest that the modification with 5-ASA can mitigate some of the observed toxic effects of TiO2 powder and encourage future investigations to create NPs that can potentially reduce the harmful effects of TiO2 NPs while preserving their positive impacts.",
journal = "Antioxidants",
title = "Comparable Toxicity of Surface-Modified TiO2 Nanoparticles: An In Vivo Experimental Study on Reproductive Toxicity in Rats",
volume = "13",
number = "2",
pages = "231",
doi = "10.3390/antiox13020231"
}
Todorović, A., Bobić, K., Veljković, F., Pejić, S., Glumac, S., Stanković, S., Milovanović, T., Vukoje, I., Nedeljković, J., Radojević Škodrić, S., Pajović, S. B.,& Drakulić, D.. (2024). Comparable Toxicity of Surface-Modified TiO2 Nanoparticles: An In Vivo Experimental Study on Reproductive Toxicity in Rats. in Antioxidants, 13(2), 231.
https://doi.org/10.3390/antiox13020231
Todorović A, Bobić K, Veljković F, Pejić S, Glumac S, Stanković S, Milovanović T, Vukoje I, Nedeljković J, Radojević Škodrić S, Pajović SB, Drakulić D. Comparable Toxicity of Surface-Modified TiO2 Nanoparticles: An In Vivo Experimental Study on Reproductive Toxicity in Rats. in Antioxidants. 2024;13(2):231.
doi:10.3390/antiox13020231 .
Todorović, Ana, Bobić, Katarina, Veljković, Filip, Pejić, Snežana, Glumac, Sofija, Stanković, Sanja, Milovanović, Tijana, Vukoje, Ivana, Nedeljković, Jovan, Radojević Škodrić, Sanja, Pajović, Snežana B., Drakulić, Dunja, "Comparable Toxicity of Surface-Modified TiO2 Nanoparticles: An In Vivo Experimental Study on Reproductive Toxicity in Rats" in Antioxidants, 13, no. 2 (2024):231,
https://doi.org/10.3390/antiox13020231 . .
1