Hydrothermal carbonization of spent mushroom substrate: Physicochemical characterization, combustion behavior, kinetic and thermodynamic study
Само за регистроване кориснике
2021
Аутори
Kojić, MarijaPetrović, Jelena T.
Petrović, Marija S.
Stanković, Slavka M.
Porobić, Slavica
Marinović-Cincović, Milena
Mihajlović, Marija
Чланак у часопису (Објављена верзија)
,
© 2021 Elsevier B.V.
Метаподаци
Приказ свих података о документуАпстракт
Hydrothermal carbonization (HTC) was employed for the conversion of the spent mushroom substrate (SMS) into a carbonaceous hydrochar. The effect of operating temperature (180, 200, 220, 240, and 260 °C) on the physicochemical, structural, and combustion properties of the obtained hydrochars was analyzed. The HTC treatment caused the increase of the higher heating value (HHV) and the lower heating value (LHV) of hydrochars for 58 % and 65 % in comparison with SMS, respectively. Analysis of morphology and functional groups showed the formation of microspheres and cracks on the hydrochar surface, which are predominantly dominated by aromatic and oxygen-rich functional groups. Thermal and kinetics analysis showed that HTC treatment improves the combustion behavior of the obtained solids. Combustion kinetic parameters of SMS and hydrochars were determined by the methods of Kissenger-Akahira-Sunose (KAS) and Flynn-Wall-Ozawa (FWO). The thermodynamic parameters and pre-exponential factors rev...eal a complex mechanism of SMS and hydrochars decomposition process. © 2021 Elsevier B.V.
Кључне речи:
Combustion kinetic / Hydrochar / Hydrothermal carbonization / Isoconversional / Spent mushroom substrate / Thermodynamic analysisИзвор:
Journal of Analytical and Applied Pyrolysis, 2021, 155, 105028-Финансирање / пројекти:
- Развој технологија и производа на бази минералних сировина и отпадне биомасе у циљу заштите ресурса за производњу безбедне хране (RS-MESTD-Technological Development (TD or TR)-31003)
DOI: 10.1016/j.jaap.2021.105028
ISSN: 0165-2370
WoS: 000640938600001
Scopus: 2-s2.0-85103726273
Институција/група
VinčaTY - JOUR AU - Kojić, Marija AU - Petrović, Jelena T. AU - Petrović, Marija S. AU - Stanković, Slavka M. AU - Porobić, Slavica AU - Marinović-Cincović, Milena AU - Mihajlović, Marija PY - 2021 UR - https://vinar.vin.bg.ac.rs/handle/123456789/9625 AB - Hydrothermal carbonization (HTC) was employed for the conversion of the spent mushroom substrate (SMS) into a carbonaceous hydrochar. The effect of operating temperature (180, 200, 220, 240, and 260 °C) on the physicochemical, structural, and combustion properties of the obtained hydrochars was analyzed. The HTC treatment caused the increase of the higher heating value (HHV) and the lower heating value (LHV) of hydrochars for 58 % and 65 % in comparison with SMS, respectively. Analysis of morphology and functional groups showed the formation of microspheres and cracks on the hydrochar surface, which are predominantly dominated by aromatic and oxygen-rich functional groups. Thermal and kinetics analysis showed that HTC treatment improves the combustion behavior of the obtained solids. Combustion kinetic parameters of SMS and hydrochars were determined by the methods of Kissenger-Akahira-Sunose (KAS) and Flynn-Wall-Ozawa (FWO). The thermodynamic parameters and pre-exponential factors reveal a complex mechanism of SMS and hydrochars decomposition process. © 2021 Elsevier B.V. T2 - Journal of Analytical and Applied Pyrolysis T1 - Hydrothermal carbonization of spent mushroom substrate: Physicochemical characterization, combustion behavior, kinetic and thermodynamic study VL - 155 SP - 105028 DO - 10.1016/j.jaap.2021.105028 ER -
@article{ author = "Kojić, Marija and Petrović, Jelena T. and Petrović, Marija S. and Stanković, Slavka M. and Porobić, Slavica and Marinović-Cincović, Milena and Mihajlović, Marija", year = "2021", abstract = "Hydrothermal carbonization (HTC) was employed for the conversion of the spent mushroom substrate (SMS) into a carbonaceous hydrochar. The effect of operating temperature (180, 200, 220, 240, and 260 °C) on the physicochemical, structural, and combustion properties of the obtained hydrochars was analyzed. The HTC treatment caused the increase of the higher heating value (HHV) and the lower heating value (LHV) of hydrochars for 58 % and 65 % in comparison with SMS, respectively. Analysis of morphology and functional groups showed the formation of microspheres and cracks on the hydrochar surface, which are predominantly dominated by aromatic and oxygen-rich functional groups. Thermal and kinetics analysis showed that HTC treatment improves the combustion behavior of the obtained solids. Combustion kinetic parameters of SMS and hydrochars were determined by the methods of Kissenger-Akahira-Sunose (KAS) and Flynn-Wall-Ozawa (FWO). The thermodynamic parameters and pre-exponential factors reveal a complex mechanism of SMS and hydrochars decomposition process. © 2021 Elsevier B.V.", journal = "Journal of Analytical and Applied Pyrolysis", title = "Hydrothermal carbonization of spent mushroom substrate: Physicochemical characterization, combustion behavior, kinetic and thermodynamic study", volume = "155", pages = "105028", doi = "10.1016/j.jaap.2021.105028" }
Kojić, M., Petrović, J. T., Petrović, M. S., Stanković, S. M., Porobić, S., Marinović-Cincović, M.,& Mihajlović, M.. (2021). Hydrothermal carbonization of spent mushroom substrate: Physicochemical characterization, combustion behavior, kinetic and thermodynamic study. in Journal of Analytical and Applied Pyrolysis, 155, 105028. https://doi.org/10.1016/j.jaap.2021.105028
Kojić M, Petrović JT, Petrović MS, Stanković SM, Porobić S, Marinović-Cincović M, Mihajlović M. Hydrothermal carbonization of spent mushroom substrate: Physicochemical characterization, combustion behavior, kinetic and thermodynamic study. in Journal of Analytical and Applied Pyrolysis. 2021;155:105028. doi:10.1016/j.jaap.2021.105028 .
Kojić, Marija, Petrović, Jelena T., Petrović, Marija S., Stanković, Slavka M., Porobić, Slavica, Marinović-Cincović, Milena, Mihajlović, Marija, "Hydrothermal carbonization of spent mushroom substrate: Physicochemical characterization, combustion behavior, kinetic and thermodynamic study" in Journal of Analytical and Applied Pyrolysis, 155 (2021):105028, https://doi.org/10.1016/j.jaap.2021.105028 . .