Apricot kernel shells pyrolysis controlled by non-isothermal simultaneous thermal analysis (STA)
Само за регистроване кориснике
2020
Аутори
Manić, Nebojša G.Janković, Bojan Ž.
Pijović, Milena
Waisi, Hadi
Dodevski, Vladimir
Stojiljković, Dragoslava
Jovanović, Vladimir V.
Чланак у часопису (Објављена верзија)
,
© 2020, Akadémiai Kiadó, Budapest, Hungary
Метаподаци
Приказ свих података о документуАпстракт
In order to clarify relationship between apricot kernel shell biomass slow pyrolysis mechanism and its main constituents (viz. hemicelluloses, cellulose and lignin), the reactivity effects of main constituents on pyrolysis characteristics were determined by the non-isothermal simultaneous thermal analysis. It was found that four-step (parallel) reaction model is suitable for studying the slow pyrolysis process, within the semi-global model which excludes the strong interaction between biomass constituents (pseudo-components). The application of the proposed model was allowed by the results obtained from KAS iterative isoconversional (model-free) approach. The valorization of the model was confirmed by the process optimization. The complex (cumulative) apricot kernel shell pyrolysis rate curves at different heating rates are successfully resolved into the individual decomposition rate curves (arising from thermal conversion of hemicelluloses, cellulose, and primary/secondary lignin frag...ments) by four-parameter Fraser–Suzuki function. Besides hemicelluloses and cellulose pyrolyses, the proposed model distinguishes primary and secondary lignin reactions, which enhance the gaseous products releasing (primarily CO and CO2 gases) and charification of the solid residue (increased the bio-char yield). © 2020, Akadémiai Kiadó, Budapest, Hungary.
Кључне речи:
Slow pyrolysis / Modeling / Apricot wastes / Fraser-Suzuki deconvolution / Iterative isoconversional methodИзвор:
Journal of Thermal Analysis and Calorimetry, 2020, 142, 2, 565-579Финансирање / пројекти:
- Фотоника микро и нано структурних материјала (RS-MESTD-Integrated and Interdisciplinary Research (IIR or III)-45010)
- Динамика нелинеарних физичкохемијских и биохемијских система са моделирањем и предвиђањем њихових понашања под неравнотежним условима (RS-MESTD-Basic Research (BR or ON)-172015)
- Водонична енергија - развој нових материјала: електролитичко добијање водоника, водоничне горивне ћелије, изотопски ефекти (RS-MESTD-Basic Research (BR or ON)-172045)
- Функционални, функционализовани и усавршени нано материјали (RS-MESTD-Integrated and Interdisciplinary Research (IIR or III)-45005)
- Испитивање и верификација метода за мултидисциплинарне форензичке анализе у функцији непролиферације оружја за масовно уништење (RS-MESTD-Technological Development (TD or TR)-37021)
DOI: 10.1007/s10973-020-09307-5
ISSN: 1388-6150
WoS: 000581102300003
Scopus: 2-s2.0-85078348824
Колекције
Институција/група
VinčaTY - JOUR AU - Manić, Nebojša G. AU - Janković, Bojan Ž. AU - Pijović, Milena AU - Waisi, Hadi AU - Dodevski, Vladimir AU - Stojiljković, Dragoslava AU - Jovanović, Vladimir V. PY - 2020 UR - https://vinar.vin.bg.ac.rs/handle/123456789/8904 AB - In order to clarify relationship between apricot kernel shell biomass slow pyrolysis mechanism and its main constituents (viz. hemicelluloses, cellulose and lignin), the reactivity effects of main constituents on pyrolysis characteristics were determined by the non-isothermal simultaneous thermal analysis. It was found that four-step (parallel) reaction model is suitable for studying the slow pyrolysis process, within the semi-global model which excludes the strong interaction between biomass constituents (pseudo-components). The application of the proposed model was allowed by the results obtained from KAS iterative isoconversional (model-free) approach. The valorization of the model was confirmed by the process optimization. The complex (cumulative) apricot kernel shell pyrolysis rate curves at different heating rates are successfully resolved into the individual decomposition rate curves (arising from thermal conversion of hemicelluloses, cellulose, and primary/secondary lignin fragments) by four-parameter Fraser–Suzuki function. Besides hemicelluloses and cellulose pyrolyses, the proposed model distinguishes primary and secondary lignin reactions, which enhance the gaseous products releasing (primarily CO and CO2 gases) and charification of the solid residue (increased the bio-char yield). © 2020, Akadémiai Kiadó, Budapest, Hungary. T2 - Journal of Thermal Analysis and Calorimetry T1 - Apricot kernel shells pyrolysis controlled by non-isothermal simultaneous thermal analysis (STA) VL - 142 IS - 2 SP - 565 EP - 579 DO - 10.1007/s10973-020-09307-5 ER -
@article{ author = "Manić, Nebojša G. and Janković, Bojan Ž. and Pijović, Milena and Waisi, Hadi and Dodevski, Vladimir and Stojiljković, Dragoslava and Jovanović, Vladimir V.", year = "2020", abstract = "In order to clarify relationship between apricot kernel shell biomass slow pyrolysis mechanism and its main constituents (viz. hemicelluloses, cellulose and lignin), the reactivity effects of main constituents on pyrolysis characteristics were determined by the non-isothermal simultaneous thermal analysis. It was found that four-step (parallel) reaction model is suitable for studying the slow pyrolysis process, within the semi-global model which excludes the strong interaction between biomass constituents (pseudo-components). The application of the proposed model was allowed by the results obtained from KAS iterative isoconversional (model-free) approach. The valorization of the model was confirmed by the process optimization. The complex (cumulative) apricot kernel shell pyrolysis rate curves at different heating rates are successfully resolved into the individual decomposition rate curves (arising from thermal conversion of hemicelluloses, cellulose, and primary/secondary lignin fragments) by four-parameter Fraser–Suzuki function. Besides hemicelluloses and cellulose pyrolyses, the proposed model distinguishes primary and secondary lignin reactions, which enhance the gaseous products releasing (primarily CO and CO2 gases) and charification of the solid residue (increased the bio-char yield). © 2020, Akadémiai Kiadó, Budapest, Hungary.", journal = "Journal of Thermal Analysis and Calorimetry", title = "Apricot kernel shells pyrolysis controlled by non-isothermal simultaneous thermal analysis (STA)", volume = "142", number = "2", pages = "565-579", doi = "10.1007/s10973-020-09307-5" }
Manić, N. G., Janković, B. Ž., Pijović, M., Waisi, H., Dodevski, V., Stojiljković, D.,& Jovanović, V. V.. (2020). Apricot kernel shells pyrolysis controlled by non-isothermal simultaneous thermal analysis (STA). in Journal of Thermal Analysis and Calorimetry, 142(2), 565-579. https://doi.org/10.1007/s10973-020-09307-5
Manić NG, Janković BŽ, Pijović M, Waisi H, Dodevski V, Stojiljković D, Jovanović VV. Apricot kernel shells pyrolysis controlled by non-isothermal simultaneous thermal analysis (STA). in Journal of Thermal Analysis and Calorimetry. 2020;142(2):565-579. doi:10.1007/s10973-020-09307-5 .
Manić, Nebojša G., Janković, Bojan Ž., Pijović, Milena, Waisi, Hadi, Dodevski, Vladimir, Stojiljković, Dragoslava, Jovanović, Vladimir V., "Apricot kernel shells pyrolysis controlled by non-isothermal simultaneous thermal analysis (STA)" in Journal of Thermal Analysis and Calorimetry, 142, no. 2 (2020):565-579, https://doi.org/10.1007/s10973-020-09307-5 . .