Optical emission of graphite plasma generated in ambient air using low-irradiance carbon dioxide laser pulses
Samo za registrovane korisnike
2019
Autori
Kuzmanović, Miroslav M.Ranković, Dragan
Trtica, Milan
Ciganović, Jovan
Petrović, Jelena
Savović, Jelena
Članak u časopisu (Objavljena verzija)
,
© 2019 Elsevier B.V.
Metapodaci
Prikaz svih podataka o dokumentuApstrakt
Optical emission studies of graphite plasma induced by infrared (IR) Transversely Excited Atmospheric carbon dioxide (TEA CO2) laser pulses in ambient air at atmospheric pressure are reported. The plasma was induced at relatively low-irradiance, up to 40 MW cm−2, and the plasma emission was recorded using time-integrated LIBS measurements. The time profile of the 160 mJ laser pulse is composed of a short, 100 ns long initial spike, and a long 2 μs tail. About 60 mJ is contained in the initial pulse, and the 100-mJ tail contribution is favorable for extended plasma absorption that promotes creation of long-lasting highly-excited plasma. With laser pulse focused behind the target surface, recorded spectra consisted of intensive, sharp atomic and single charged ionic spectral lines of carbon, and trace elements, e.g. Ca, Cu, V, Si, and Ti. Good signal to background ratios obtained indicate potential application in the analysis of impurities in graphite, and also elemental analysis of othe...r materials with high carbon content. The average electron number density was determined from Stark-broadened emission profile of C I 247.9 nm line, and the line intensity ratio of CII 250.9 nm/C I 247.9 nm line pair was used for estimation of ionization temperature. Depending on the applied fluence, electron density was in the range 2.6–4.8 × 1017 cm−3, and ionization temperature between 19,000 and 22,000 K. Beside line spectra, intensive and well-developed band spectra of diatomic molecules C2 (Swan system), and CN (violet system) were obtained. Pulse energy threshold for observation of molecular emission was 50 mJ. From the spectroscopic studies of the emission bands, the rotational and vibrational temperatures were estimated by comparing the experimental and simulated emission spectra. Vibrational and rotational temperatures deduced from Δν = 0 sequences of the Swan system of C2 were 3100 K and 3850 K, respectively. The most intense band of the CN violet system showed strong self-absorption and led to overestimated temperature values, Tvib = Trot = 4900 K. © 2019 Elsevier B.V.
Ključne reči:
LIBS / TEA CO2 laser / Graphite / Atomic and molecular spectra / Trace analysis / Plasma diagnosticsIzvor:
Spectrochimica Acta. Part B: Atomic Spectroscopy, 2019, 157, 37-46Finansiranje / projekti:
- Efekti dejstva laserskog zračenja i plazme na savremene materijale pri njihovoj sintezi, modifikaciji i analizi (RS-MESTD-Basic Research (BR or ON)-172019)
- COST action (Developing the Physics and the Scientific Community for Inertial Confinement Fusion at the Time of NIF Ignition) [MP1208]
DOI: 10.1016/j.sab.2019.05.006
ISSN: 0584-8547
WoS: 000472222500007
Scopus: 2-s2.0-85066035407
URI
https://linkinghub.elsevier.com/retrieve/pii/S0584854719300849https://vinar.vin.bg.ac.rs/handle/123456789/8204
Kolekcije
Institucija/grupa
VinčaTY - JOUR AU - Kuzmanović, Miroslav M. AU - Ranković, Dragan AU - Trtica, Milan AU - Ciganović, Jovan AU - Petrović, Jelena AU - Savović, Jelena PY - 2019 UR - https://linkinghub.elsevier.com/retrieve/pii/S0584854719300849 UR - https://vinar.vin.bg.ac.rs/handle/123456789/8204 AB - Optical emission studies of graphite plasma induced by infrared (IR) Transversely Excited Atmospheric carbon dioxide (TEA CO2) laser pulses in ambient air at atmospheric pressure are reported. The plasma was induced at relatively low-irradiance, up to 40 MW cm−2, and the plasma emission was recorded using time-integrated LIBS measurements. The time profile of the 160 mJ laser pulse is composed of a short, 100 ns long initial spike, and a long 2 μs tail. About 60 mJ is contained in the initial pulse, and the 100-mJ tail contribution is favorable for extended plasma absorption that promotes creation of long-lasting highly-excited plasma. With laser pulse focused behind the target surface, recorded spectra consisted of intensive, sharp atomic and single charged ionic spectral lines of carbon, and trace elements, e.g. Ca, Cu, V, Si, and Ti. Good signal to background ratios obtained indicate potential application in the analysis of impurities in graphite, and also elemental analysis of other materials with high carbon content. The average electron number density was determined from Stark-broadened emission profile of C I 247.9 nm line, and the line intensity ratio of CII 250.9 nm/C I 247.9 nm line pair was used for estimation of ionization temperature. Depending on the applied fluence, electron density was in the range 2.6–4.8 × 1017 cm−3, and ionization temperature between 19,000 and 22,000 K. Beside line spectra, intensive and well-developed band spectra of diatomic molecules C2 (Swan system), and CN (violet system) were obtained. Pulse energy threshold for observation of molecular emission was 50 mJ. From the spectroscopic studies of the emission bands, the rotational and vibrational temperatures were estimated by comparing the experimental and simulated emission spectra. Vibrational and rotational temperatures deduced from Δν = 0 sequences of the Swan system of C2 were 3100 K and 3850 K, respectively. The most intense band of the CN violet system showed strong self-absorption and led to overestimated temperature values, Tvib = Trot = 4900 K. © 2019 Elsevier B.V. T2 - Spectrochimica Acta. Part B: Atomic Spectroscopy T1 - Optical emission of graphite plasma generated in ambient air using low-irradiance carbon dioxide laser pulses VL - 157 SP - 37 EP - 46 DO - 10.1016/j.sab.2019.05.006 ER -
@article{ author = "Kuzmanović, Miroslav M. and Ranković, Dragan and Trtica, Milan and Ciganović, Jovan and Petrović, Jelena and Savović, Jelena", year = "2019", abstract = "Optical emission studies of graphite plasma induced by infrared (IR) Transversely Excited Atmospheric carbon dioxide (TEA CO2) laser pulses in ambient air at atmospheric pressure are reported. The plasma was induced at relatively low-irradiance, up to 40 MW cm−2, and the plasma emission was recorded using time-integrated LIBS measurements. The time profile of the 160 mJ laser pulse is composed of a short, 100 ns long initial spike, and a long 2 μs tail. About 60 mJ is contained in the initial pulse, and the 100-mJ tail contribution is favorable for extended plasma absorption that promotes creation of long-lasting highly-excited plasma. With laser pulse focused behind the target surface, recorded spectra consisted of intensive, sharp atomic and single charged ionic spectral lines of carbon, and trace elements, e.g. Ca, Cu, V, Si, and Ti. Good signal to background ratios obtained indicate potential application in the analysis of impurities in graphite, and also elemental analysis of other materials with high carbon content. The average electron number density was determined from Stark-broadened emission profile of C I 247.9 nm line, and the line intensity ratio of CII 250.9 nm/C I 247.9 nm line pair was used for estimation of ionization temperature. Depending on the applied fluence, electron density was in the range 2.6–4.8 × 1017 cm−3, and ionization temperature between 19,000 and 22,000 K. Beside line spectra, intensive and well-developed band spectra of diatomic molecules C2 (Swan system), and CN (violet system) were obtained. Pulse energy threshold for observation of molecular emission was 50 mJ. From the spectroscopic studies of the emission bands, the rotational and vibrational temperatures were estimated by comparing the experimental and simulated emission spectra. Vibrational and rotational temperatures deduced from Δν = 0 sequences of the Swan system of C2 were 3100 K and 3850 K, respectively. The most intense band of the CN violet system showed strong self-absorption and led to overestimated temperature values, Tvib = Trot = 4900 K. © 2019 Elsevier B.V.", journal = "Spectrochimica Acta. Part B: Atomic Spectroscopy", title = "Optical emission of graphite plasma generated in ambient air using low-irradiance carbon dioxide laser pulses", volume = "157", pages = "37-46", doi = "10.1016/j.sab.2019.05.006" }
Kuzmanović, M. M., Ranković, D., Trtica, M., Ciganović, J., Petrović, J.,& Savović, J.. (2019). Optical emission of graphite plasma generated in ambient air using low-irradiance carbon dioxide laser pulses. in Spectrochimica Acta. Part B: Atomic Spectroscopy, 157, 37-46. https://doi.org/10.1016/j.sab.2019.05.006
Kuzmanović MM, Ranković D, Trtica M, Ciganović J, Petrović J, Savović J. Optical emission of graphite plasma generated in ambient air using low-irradiance carbon dioxide laser pulses. in Spectrochimica Acta. Part B: Atomic Spectroscopy. 2019;157:37-46. doi:10.1016/j.sab.2019.05.006 .
Kuzmanović, Miroslav M., Ranković, Dragan, Trtica, Milan, Ciganović, Jovan, Petrović, Jelena, Savović, Jelena, "Optical emission of graphite plasma generated in ambient air using low-irradiance carbon dioxide laser pulses" in Spectrochimica Acta. Part B: Atomic Spectroscopy, 157 (2019):37-46, https://doi.org/10.1016/j.sab.2019.05.006 . .