Influence of the alkyl chain length on densities and volumetric properties of 1,3-dialkylimidazolium bromide ionic liquids and their aqueous solutions
Samo za registrovane korisnike
2018
Autori
Zec, NebojšaVraneš, Milan
Bešter-Rogač, Marija
Trtić-Petrović, Tatjana M.
Dimitrijević, Aleksandra
Čobanov, Isidora
Gadžurić, Slobodan
Članak u časopisu (Objavljena verzija)
,
© Copyright 2018 Elsevier B.V.
Metapodaci
Prikaz svih podataka o dokumentuApstrakt
In this manuscript eight new 1,3-dialkylimidazolium bromide ionic liquids, {[}CnCmim]{[}Br], were synthesized and characterized. Densities of ionic liquids and their diluted aqueous solutions have been measured over the whole composition range at selected temperatures from (293.15 to 323.15) K and at atmospheric pressure (p = 0.1 MPa). Influence of alkyl chain length and cation symmetry on densities and volumetric properties as well as nature of the interactions in aqueous {[}CnCmim]{[}Br] solutions have been discussed and compared with previously published aqueous {[}C(2)C(4)im]{[}Br] system. Densities of pure bromide based ionic liquids decrease with increasing alkyl chain length on imidazolium cation and depend on total number of methyl group in both side alkyl chains. Apparent molar volumes at infinite dilution of investigated ionic liquids in water increase linearly with increase of the total number of the C atoms in the side alkyl chain. (C) 2018 Elsevier Ltd.
Ključne reči:
density / imidazolium / ionic liquids / volumetric properties / alkyl chain lengthIzvor:
The Journal of Chemical Thermodynamics, 2018, 121, 72-78Finansiranje / projekti:
- Pristupi održivosti i zelene hemije u razvoju ekološki pogodnih analitičkih metoda i skladištenju energije (RS-MESTD-Basic Research (BR or ON)-172012)
DOI: 10.1016/j.jct.2018.02.001
ISSN: 0021-9614
WoS: 000428715000009
Scopus: 2-s2.0-85042010326
Kolekcije
Institucija/grupa
VinčaTY - JOUR AU - Zec, Nebojša AU - Vraneš, Milan AU - Bešter-Rogač, Marija AU - Trtić-Petrović, Tatjana M. AU - Dimitrijević, Aleksandra AU - Čobanov, Isidora AU - Gadžurić, Slobodan PY - 2018 UR - https://vinar.vin.bg.ac.rs/handle/123456789/7660 AB - In this manuscript eight new 1,3-dialkylimidazolium bromide ionic liquids, {[}CnCmim]{[}Br], were synthesized and characterized. Densities of ionic liquids and their diluted aqueous solutions have been measured over the whole composition range at selected temperatures from (293.15 to 323.15) K and at atmospheric pressure (p = 0.1 MPa). Influence of alkyl chain length and cation symmetry on densities and volumetric properties as well as nature of the interactions in aqueous {[}CnCmim]{[}Br] solutions have been discussed and compared with previously published aqueous {[}C(2)C(4)im]{[}Br] system. Densities of pure bromide based ionic liquids decrease with increasing alkyl chain length on imidazolium cation and depend on total number of methyl group in both side alkyl chains. Apparent molar volumes at infinite dilution of investigated ionic liquids in water increase linearly with increase of the total number of the C atoms in the side alkyl chain. (C) 2018 Elsevier Ltd. T2 - The Journal of Chemical Thermodynamics T1 - Influence of the alkyl chain length on densities and volumetric properties of 1,3-dialkylimidazolium bromide ionic liquids and their aqueous solutions VL - 121 SP - 72 EP - 78 DO - 10.1016/j.jct.2018.02.001 ER -
@article{ author = "Zec, Nebojša and Vraneš, Milan and Bešter-Rogač, Marija and Trtić-Petrović, Tatjana M. and Dimitrijević, Aleksandra and Čobanov, Isidora and Gadžurić, Slobodan", year = "2018", abstract = "In this manuscript eight new 1,3-dialkylimidazolium bromide ionic liquids, {[}CnCmim]{[}Br], were synthesized and characterized. Densities of ionic liquids and their diluted aqueous solutions have been measured over the whole composition range at selected temperatures from (293.15 to 323.15) K and at atmospheric pressure (p = 0.1 MPa). Influence of alkyl chain length and cation symmetry on densities and volumetric properties as well as nature of the interactions in aqueous {[}CnCmim]{[}Br] solutions have been discussed and compared with previously published aqueous {[}C(2)C(4)im]{[}Br] system. Densities of pure bromide based ionic liquids decrease with increasing alkyl chain length on imidazolium cation and depend on total number of methyl group in both side alkyl chains. Apparent molar volumes at infinite dilution of investigated ionic liquids in water increase linearly with increase of the total number of the C atoms in the side alkyl chain. (C) 2018 Elsevier Ltd.", journal = "The Journal of Chemical Thermodynamics", title = "Influence of the alkyl chain length on densities and volumetric properties of 1,3-dialkylimidazolium bromide ionic liquids and their aqueous solutions", volume = "121", pages = "72-78", doi = "10.1016/j.jct.2018.02.001" }
Zec, N., Vraneš, M., Bešter-Rogač, M., Trtić-Petrović, T. M., Dimitrijević, A., Čobanov, I.,& Gadžurić, S.. (2018). Influence of the alkyl chain length on densities and volumetric properties of 1,3-dialkylimidazolium bromide ionic liquids and their aqueous solutions. in The Journal of Chemical Thermodynamics, 121, 72-78. https://doi.org/10.1016/j.jct.2018.02.001
Zec N, Vraneš M, Bešter-Rogač M, Trtić-Petrović TM, Dimitrijević A, Čobanov I, Gadžurić S. Influence of the alkyl chain length on densities and volumetric properties of 1,3-dialkylimidazolium bromide ionic liquids and their aqueous solutions. in The Journal of Chemical Thermodynamics. 2018;121:72-78. doi:10.1016/j.jct.2018.02.001 .
Zec, Nebojša, Vraneš, Milan, Bešter-Rogač, Marija, Trtić-Petrović, Tatjana M., Dimitrijević, Aleksandra, Čobanov, Isidora, Gadžurić, Slobodan, "Influence of the alkyl chain length on densities and volumetric properties of 1,3-dialkylimidazolium bromide ionic liquids and their aqueous solutions" in The Journal of Chemical Thermodynamics, 121 (2018):72-78, https://doi.org/10.1016/j.jct.2018.02.001 . .