Synthesis and characterization of LiFePO4/C composite obtained by cellulose template
2012
Аутори
Jugović, DraganaMitrić, Miodrag
Milović, Miloš
Jokić, Bojan M.
Uskoković, Dragan
Остала ауторства
Uskoković, DraganКонференцијски прилог
Метаподаци
Приказ свих података о документуАпстракт
In the on-going search for alternative cathode materials for Li-ion batteries olivine-type lithium iron phosphate (LiFePO4) is one of the most promising candidates due to its high energy density (with theoretical capacity of 170 mAh/g and plateau voltage of 3.5 V vs. Li+/Li), high safety, both electrochemical and thermal stability, environmental friendliness and low raw materials cost. Here is presented the synthesis of nanocrystalline LiFePO4/C composite powder through templating method. A quantitative filter paper serves as both template and carbon source that on rapid heating degrades pyrolytically through fragmentation reactions and formation of volatiles that further impact powder morphology. By taking extreme measures of rapid heating, short high-temperature delay, and subsequent quenching well-ordered 40 nm crystallites are obtained within 5 minutes. Preliminary electrochemical measurements in terms of galvanostatic cycling convince that adopted approach of rapid crystallization... is suitable for achieving almost theoretical capacity. The results of Rietveld crystal structure refinement, scanning electron microscopy, and galvanostatic charge/discharge tests are presented in detail.
Кључне речи:
lithium iron phosphate / filter paper / cellulose templateИзвор:
The Fourteenth Annual Conference YUCOMAT 2012: Programme and the Book of Abstracts, 2012, 76-76Издавач:
- Belgrade : Materials Research Society of Serbia
Финансирање / пројекти:
- Молекуларно дизајнирање наночестица контролисаних морфолошких и физичко-хемијских карактеристика и функционалних материјала на њиховој основи (RS-MESTD-Integrated and Interdisciplinary Research (IIR or III)-45004)
Колекције
Институција/група
VinčaTY - CONF AU - Jugović, Dragana AU - Mitrić, Miodrag AU - Milović, Miloš AU - Jokić, Bojan M. AU - Uskoković, Dragan PY - 2012 UR - http://dais.sanu.ac.rs/123456789/439 UR - https://vinar.vin.bg.ac.rs/handle/123456789/7438 AB - In the on-going search for alternative cathode materials for Li-ion batteries olivine-type lithium iron phosphate (LiFePO4) is one of the most promising candidates due to its high energy density (with theoretical capacity of 170 mAh/g and plateau voltage of 3.5 V vs. Li+/Li), high safety, both electrochemical and thermal stability, environmental friendliness and low raw materials cost. Here is presented the synthesis of nanocrystalline LiFePO4/C composite powder through templating method. A quantitative filter paper serves as both template and carbon source that on rapid heating degrades pyrolytically through fragmentation reactions and formation of volatiles that further impact powder morphology. By taking extreme measures of rapid heating, short high-temperature delay, and subsequent quenching well-ordered 40 nm crystallites are obtained within 5 minutes. Preliminary electrochemical measurements in terms of galvanostatic cycling convince that adopted approach of rapid crystallization is suitable for achieving almost theoretical capacity. The results of Rietveld crystal structure refinement, scanning electron microscopy, and galvanostatic charge/discharge tests are presented in detail. PB - Belgrade : Materials Research Society of Serbia C3 - The Fourteenth Annual Conference YUCOMAT 2012: Programme and the Book of Abstracts T1 - Synthesis and characterization of LiFePO4/C composite obtained by cellulose template SP - 76 EP - 76 UR - https://hdl.handle.net/21.15107/rcub_vinar_7438 ER -
@conference{ author = "Jugović, Dragana and Mitrić, Miodrag and Milović, Miloš and Jokić, Bojan M. and Uskoković, Dragan", year = "2012", abstract = "In the on-going search for alternative cathode materials for Li-ion batteries olivine-type lithium iron phosphate (LiFePO4) is one of the most promising candidates due to its high energy density (with theoretical capacity of 170 mAh/g and plateau voltage of 3.5 V vs. Li+/Li), high safety, both electrochemical and thermal stability, environmental friendliness and low raw materials cost. Here is presented the synthesis of nanocrystalline LiFePO4/C composite powder through templating method. A quantitative filter paper serves as both template and carbon source that on rapid heating degrades pyrolytically through fragmentation reactions and formation of volatiles that further impact powder morphology. By taking extreme measures of rapid heating, short high-temperature delay, and subsequent quenching well-ordered 40 nm crystallites are obtained within 5 minutes. Preliminary electrochemical measurements in terms of galvanostatic cycling convince that adopted approach of rapid crystallization is suitable for achieving almost theoretical capacity. The results of Rietveld crystal structure refinement, scanning electron microscopy, and galvanostatic charge/discharge tests are presented in detail.", publisher = "Belgrade : Materials Research Society of Serbia", journal = "The Fourteenth Annual Conference YUCOMAT 2012: Programme and the Book of Abstracts", title = "Synthesis and characterization of LiFePO4/C composite obtained by cellulose template", pages = "76-76", url = "https://hdl.handle.net/21.15107/rcub_vinar_7438" }
Jugović, D., Mitrić, M., Milović, M., Jokić, B. M.,& Uskoković, D.. (2012). Synthesis and characterization of LiFePO4/C composite obtained by cellulose template. in The Fourteenth Annual Conference YUCOMAT 2012: Programme and the Book of Abstracts Belgrade : Materials Research Society of Serbia., 76-76. https://hdl.handle.net/21.15107/rcub_vinar_7438
Jugović D, Mitrić M, Milović M, Jokić BM, Uskoković D. Synthesis and characterization of LiFePO4/C composite obtained by cellulose template. in The Fourteenth Annual Conference YUCOMAT 2012: Programme and the Book of Abstracts. 2012;:76-76. https://hdl.handle.net/21.15107/rcub_vinar_7438 .
Jugović, Dragana, Mitrić, Miodrag, Milović, Miloš, Jokić, Bojan M., Uskoković, Dragan, "Synthesis and characterization of LiFePO4/C composite obtained by cellulose template" in The Fourteenth Annual Conference YUCOMAT 2012: Programme and the Book of Abstracts (2012):76-76, https://hdl.handle.net/21.15107/rcub_vinar_7438 .