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Synthesis and crystal structure of Cu(II) and Co(II) complexes with the 1,3-dimethylpyrazole-5-carboxylic acid ligand
dc.creator | Jaćimović, Željko K. | |
dc.creator | Kosović, Milica | |
dc.creator | Novaković, Slađana B. | |
dc.creator | Giester, Gerald | |
dc.creator | Radović, Ana | |
dc.date.accessioned | 2018-03-01T16:20:59Z | |
dc.date.available | 2018-03-01T16:20:59Z | |
dc.date.issued | 2015 | |
dc.identifier.issn | 0352-5139 | |
dc.identifier.uri | https://vinar.vin.bg.ac.rs/handle/123456789/695 | |
dc.description.abstract | In the reaction of 1,3-dimethylpyrazole-5-carboxylic acid (HL) with M(OAc)(2)center dot 4H(2)O, (M = Cu or Co), two novel complexes were prepared, the square-planar [CuL2(H2O)(2)] and the octahedral [CoL2(MeOH)(4)]. The crystal structures were determined by single-crystal X-ray diffraction. In both complexes, the deprotonated acid displays monodentate coordination to the metal ions. According to the results of a CSD survey, this is the first structural report on the metal complexes with an N-1-substituted pyrazole-5-carboxylic ligand. | en |
dc.relation | info:eu-repo/grantAgreement/MESTD/Basic Research (BR or ON)/172014/RS// | |
dc.relation | info:eu-repo/grantAgreement/MESTD/Basic Research (BR or ON)/172035/RS// | |
dc.relation | Ministry of Science of the Republic of Montenegro/Natonal project | |
dc.rights | openAccess | en |
dc.source | Journal of the Serbian Chemical Society | en |
dc.subject | pyrazole-based ligand | en |
dc.subject | transition metal complex | en |
dc.subject | crystal structure | en |
dc.title | Synthesis and crystal structure of Cu(II) and Co(II) complexes with the 1,3-dimethylpyrazole-5-carboxylic acid ligand | en |
dc.type | article | en |
dc.rights.license | ARR | |
dcterms.abstract | Јацимовиц, Зељко К.; Гиестер, Гералд; Косовиц, Милица; Радовиц, Aна; Новаковић Слађана; | |
dc.citation.volume | 80 | |
dc.citation.issue | 7 | |
dc.citation.spage | 867 | |
dc.citation.epage | 875 | |
dc.identifier.wos | 000359326100003 | |
dc.identifier.doi | 10.2298/JSC140722009J | |
dc.citation.rank | M23 | |
dc.type.version | publishedVersion | |
dc.identifier.scopus | 2-s2.0-84938928831 | |
dc.identifier.fulltext | https://vinar.vin.bg.ac.rs//bitstream/id/13825/691.pdf |