Thermal behaviour of Co(II), Ni(II), Cu(II), Zn(II), Hg(II) and Pd(II) complexes with isatin-beta-thiosemicarbazone
Abstract
The isatin-beta-thiosemicarbazone (ITC) complexes of Co(II), Ni(II), Cu(II), Zn(II), Hg(II) and Pd(II) were prepared and characterized by elemental analysis, as well as molar conductivity, magnetic susceptibility, FTIR, UV-Vis and H-1 NMR spectroscopic methods. The complexes were also studied for its thermal stability. They all behaviour as anhydrous complexes and its thermolysis passes through the stages of deamination (517-547 K) and complete thermal decomposition (619-735 K).
Keywords:
Co(II) / Ni(II) / Cu(II) / Zn(H) / Hg(H) / Pd(II) complexes / isatin-beta-thiosemicarbazone / thermal stabilitySource:
Journal of Thermal Analysis and Calorimetry, 2007, 90, 2, 525-531Note:
- 32nd Workshop on Heterogeneous Equilibria between Phases (JEEP 2006), Mar 30-31, 2006, Univ Rouen, Rouen, France
DOI: 10.1007/s10973-006-7794-9
ISSN: 1388-6150
WoS: 000251088600034
Scopus: 2-s2.0-36949040361
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Institution/Community
VinčaTY - JOUR AU - Konstantinovic, Sandra S. AU - Radovanović, Blaga AU - Krklješ, Aleksandra N. PY - 2007 UR - https://vinar.vin.bg.ac.rs/handle/123456789/6704 AB - The isatin-beta-thiosemicarbazone (ITC) complexes of Co(II), Ni(II), Cu(II), Zn(II), Hg(II) and Pd(II) were prepared and characterized by elemental analysis, as well as molar conductivity, magnetic susceptibility, FTIR, UV-Vis and H-1 NMR spectroscopic methods. The complexes were also studied for its thermal stability. They all behaviour as anhydrous complexes and its thermolysis passes through the stages of deamination (517-547 K) and complete thermal decomposition (619-735 K). T2 - Journal of Thermal Analysis and Calorimetry T1 - Thermal behaviour of Co(II), Ni(II), Cu(II), Zn(II), Hg(II) and Pd(II) complexes with isatin-beta-thiosemicarbazone VL - 90 IS - 2 SP - 525 EP - 531 DO - 10.1007/s10973-006-7794-9 ER -
@article{ author = "Konstantinovic, Sandra S. and Radovanović, Blaga and Krklješ, Aleksandra N.", year = "2007", abstract = "The isatin-beta-thiosemicarbazone (ITC) complexes of Co(II), Ni(II), Cu(II), Zn(II), Hg(II) and Pd(II) were prepared and characterized by elemental analysis, as well as molar conductivity, magnetic susceptibility, FTIR, UV-Vis and H-1 NMR spectroscopic methods. The complexes were also studied for its thermal stability. They all behaviour as anhydrous complexes and its thermolysis passes through the stages of deamination (517-547 K) and complete thermal decomposition (619-735 K).", journal = "Journal of Thermal Analysis and Calorimetry", title = "Thermal behaviour of Co(II), Ni(II), Cu(II), Zn(II), Hg(II) and Pd(II) complexes with isatin-beta-thiosemicarbazone", volume = "90", number = "2", pages = "525-531", doi = "10.1007/s10973-006-7794-9" }
Konstantinovic, S. S., Radovanović, B.,& Krklješ, A. N.. (2007). Thermal behaviour of Co(II), Ni(II), Cu(II), Zn(II), Hg(II) and Pd(II) complexes with isatin-beta-thiosemicarbazone. in Journal of Thermal Analysis and Calorimetry, 90(2), 525-531. https://doi.org/10.1007/s10973-006-7794-9
Konstantinovic SS, Radovanović B, Krklješ AN. Thermal behaviour of Co(II), Ni(II), Cu(II), Zn(II), Hg(II) and Pd(II) complexes with isatin-beta-thiosemicarbazone. in Journal of Thermal Analysis and Calorimetry. 2007;90(2):525-531. doi:10.1007/s10973-006-7794-9 .
Konstantinovic, Sandra S., Radovanović, Blaga, Krklješ, Aleksandra N., "Thermal behaviour of Co(II), Ni(II), Cu(II), Zn(II), Hg(II) and Pd(II) complexes with isatin-beta-thiosemicarbazone" in Journal of Thermal Analysis and Calorimetry, 90, no. 2 (2007):525-531, https://doi.org/10.1007/s10973-006-7794-9 . .