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Analysis of the structures of the Cu(I) and Cu(II) complexes with 3-acetylpyridine and thiocyanate
dc.creator | Čobeljić, Božidar | |
dc.creator | Pevec, Andrej | |
dc.creator | Turel, Iztok | |
dc.creator | Spasojević, Vojislav | |
dc.creator | Milčić, Miloš K. | |
dc.creator | Mitić, Dragana | |
dc.creator | Sladić, Dušan M. | |
dc.creator | Anđelković, Katarina | |
dc.date.accessioned | 2018-03-01T23:59:23Z | |
dc.date.available | 2018-03-01T23:59:23Z | |
dc.date.issued | 2014 | |
dc.identifier.issn | 0277-5387 | |
dc.identifier.uri | https://vinar.vin.bg.ac.rs/handle/123456789/5887 | |
dc.description.abstract | 3-Acetylpyridine thiosemicarbazone hydrochloride was synthesized and structurally characterized. Complexes of Cu(II) with this ligand could not be obtained by direct synthesis. By synthesis in situ mixing Cu(BF4)(2)center dot 6H(2)O, 3-acetylpyridine (3-Acpy) and semicarbazide, a Cu(I) polymer, {[Cu(SCN)(3-Acpy)(2)]}(n) was obtained and structurally characterized. Reaction of Cu(BF4)(2)center dot 6H(2)O, 3-acetylpyridine and ammonium thiocyanate afforded a dinuclear Cu(II) complex with two thiocyanate ions in bridges, which was structurally characterized. Magnetic measurements were performed for the dinuclear complex. OFT calculations provided explanation for inability to obtain a mononuclear complex. (C) 2013 Elsevier Ltd. All rights reserved. | en |
dc.relation | info:eu-repo/grantAgreement/MESTD/Basic Research (BR or ON)/172055/RS// | |
dc.relation | Slovenian Research Agency (ARRS) [P-0175] | |
dc.rights | restrictedAccess | en |
dc.source | Polyhedron | en |
dc.subject | Cu(I) and Cu(II) complexes | en |
dc.subject | 3-Acetylpyridine | en |
dc.subject | Thiocyanate | en |
dc.subject | DFT calculations | en |
dc.subject | Magnetic properties | en |
dc.title | Analysis of the structures of the Cu(I) and Cu(II) complexes with 3-acetylpyridine and thiocyanate | en |
dc.type | article | en |
dcterms.abstract | Митиц, Драгана; Цобељиц, Бозидар; Милциц, Милос; Сладиц, Дусан; Aнделковиц, Катарина; Спасојевић Војислав; Певец, Aндреј; Турел, Изток; | |
dc.citation.volume | 69 | |
dc.citation.spage | 77 | |
dc.citation.epage | 83 | |
dc.identifier.wos | 000331502500011 | |
dc.identifier.doi | 10.1016/j.poly.2013.11.027 | |
dc.citation.rank | M22 | |
dc.identifier.scopus | 2-s2.0-84890443353 |
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