Influence of the type of electrolyte on the morphological and crystallographic characteristics of lead powder particles
Аутори
Nikolić, Nebojša D.Maksimović, Vesna
Branković, Goran O.
Živković, Predrag M.
Pavlović, Miomir G.
Чланак у часопису (Објављена верзија)
Метаподаци
Приказ свих података о документуАпстракт
Lead electrodeposition processes from basic (nitrate) and complex (acetate) electrolytes were mutually compared by scanning electron microscopy and X-ray diffraction investigation of the produced powder particles. The shape of dendritic particles strongly depended on the type of electrolyte. Dendrites composed of a stalk and weakly developed primary branches (the primary type) were predominantly formed from the basic electrolyte. Ramified dendrites composed of a stalk and of both primary and secondary branches (the secondary type) were mainly formed from the complex electrolyte. In both types of powder particles, Pb crystallites were predominantly oriented in the (111) plane. The formation of powder particles of different shapes with strong (111) preferred orientation is discussed and explained by consideration of the general characteristics of the growth of crystals in electrocrystallization processes.
Кључне речи:
electrodeposition / lead / powder / dendrite / scanning electron microscopy (SEM) / X-ray diffraction (XRD) analysisИзвор:
Journal of the Serbian Chemical Society, 2013, 78, 9, 1387-1395Финансирање / пројекти:
- Електрохемијска синтеза и карактеризација наноструктурираних функционалних материјала за примену у новим технологијама (RS-MESTD-Basic Research (BR or ON)-172046)
DOI: 10.2298/JSC130211034N
ISSN: 0352-5139
WoS: 000326199200010
Scopus: 2-s2.0-84885139059
Колекције
Институција/група
VinčaTY - JOUR AU - Nikolić, Nebojša D. AU - Maksimović, Vesna AU - Branković, Goran O. AU - Živković, Predrag M. AU - Pavlović, Miomir G. PY - 2013 UR - https://vinar.vin.bg.ac.rs/handle/123456789/5732 AB - Lead electrodeposition processes from basic (nitrate) and complex (acetate) electrolytes were mutually compared by scanning electron microscopy and X-ray diffraction investigation of the produced powder particles. The shape of dendritic particles strongly depended on the type of electrolyte. Dendrites composed of a stalk and weakly developed primary branches (the primary type) were predominantly formed from the basic electrolyte. Ramified dendrites composed of a stalk and of both primary and secondary branches (the secondary type) were mainly formed from the complex electrolyte. In both types of powder particles, Pb crystallites were predominantly oriented in the (111) plane. The formation of powder particles of different shapes with strong (111) preferred orientation is discussed and explained by consideration of the general characteristics of the growth of crystals in electrocrystallization processes. T2 - Journal of the Serbian Chemical Society T1 - Influence of the type of electrolyte on the morphological and crystallographic characteristics of lead powder particles VL - 78 IS - 9 SP - 1387 EP - 1395 DO - 10.2298/JSC130211034N ER -
@article{ author = "Nikolić, Nebojša D. and Maksimović, Vesna and Branković, Goran O. and Živković, Predrag M. and Pavlović, Miomir G.", year = "2013", abstract = "Lead electrodeposition processes from basic (nitrate) and complex (acetate) electrolytes were mutually compared by scanning electron microscopy and X-ray diffraction investigation of the produced powder particles. The shape of dendritic particles strongly depended on the type of electrolyte. Dendrites composed of a stalk and weakly developed primary branches (the primary type) were predominantly formed from the basic electrolyte. Ramified dendrites composed of a stalk and of both primary and secondary branches (the secondary type) were mainly formed from the complex electrolyte. In both types of powder particles, Pb crystallites were predominantly oriented in the (111) plane. The formation of powder particles of different shapes with strong (111) preferred orientation is discussed and explained by consideration of the general characteristics of the growth of crystals in electrocrystallization processes.", journal = "Journal of the Serbian Chemical Society", title = "Influence of the type of electrolyte on the morphological and crystallographic characteristics of lead powder particles", volume = "78", number = "9", pages = "1387-1395", doi = "10.2298/JSC130211034N" }
Nikolić, N. D., Maksimović, V., Branković, G. O., Živković, P. M.,& Pavlović, M. G.. (2013). Influence of the type of electrolyte on the morphological and crystallographic characteristics of lead powder particles. in Journal of the Serbian Chemical Society, 78(9), 1387-1395. https://doi.org/10.2298/JSC130211034N
Nikolić ND, Maksimović V, Branković GO, Živković PM, Pavlović MG. Influence of the type of electrolyte on the morphological and crystallographic characteristics of lead powder particles. in Journal of the Serbian Chemical Society. 2013;78(9):1387-1395. doi:10.2298/JSC130211034N .
Nikolić, Nebojša D., Maksimović, Vesna, Branković, Goran O., Živković, Predrag M., Pavlović, Miomir G., "Influence of the type of electrolyte on the morphological and crystallographic characteristics of lead powder particles" in Journal of the Serbian Chemical Society, 78, no. 9 (2013):1387-1395, https://doi.org/10.2298/JSC130211034N . .