Photocatalytic degradation of metoprolol in water suspension of TiO2 nanopowders prepared using sol-gel route
Нема приказа
Аутори
Šćepanović, MajaAbramović, Biljana F.
Golubović, Aleksandar V.
Kler, Sanja
Grujić-Brojčin, Mirjana
Dohčević-Mitrović, Zorana
Babić, Biljana M.
Matović, Branko
Popović, Zoran V.
Чланак у часопису
Метаподаци
Приказ свих података о документуАпстракт
Nanocrystalline titanium dioxide (TiO2) powders have been synthesized by sol-gel method using titanium tetrachloride (TiCl4) or tetrabutyl titanate (Ti(OC4H9)(4) as precursors, different alcohols and calcination temperatures in the range from 400 to 650 A degrees C. The photocatalytic activity of as-prepared powders has been tested for the degradation of metoprolol tartrate salt, a selective beta-blocker used to treat a variety of cardiovascular diseases, and compared to photocatalytic activity obtained from Degussa P25. Nanosized TiO2 powders prepared from TiCl4 and amyl-alcohol, calcined at 550 A degrees C, displayed an activity comparable to Degussa P25, whereas the sample from the same series, calcined at 650 A degrees C, showed higher photocatalytic activity in the whole range of the catalyst loading. Structural, morphological and surface properties of synthesized TiO2 nanopowders have been investigated by XRD, SEM, EDS and BET measurements, as well as FTIR and Raman spectroscopy,... in order to find out the material properties which enable rapid an efficient decomposition of metoprolol under UV radiation.
Кључне речи:
Nanopowder / TiO2 / Sol-gel synthesis / Raman spectroscopy / PhotocatalysisИзвор:
Journal of Sol-gel Science and Technology, 2012, 61, 2, 390-402Финансирање / пројекти:
- Наноструктурни мултифункционални материјали и нанокомпозити (RS-MESTD-Integrated and Interdisciplinary Research (IIR or III)-45018)
- Физика наноструктурних оксидних материјала и јако корелисаних система (RS-MESTD-Basic Research (BR or ON)-171032)
- Развој метода праћења и уклањања биолошки активних супстанци у циљу унапређења квалитета животне средине (RS-MESTD-Basic Research (BR or ON)-172042)
- SASA [F-134], Swiss National Science Foundation [IZ73Z0-128169]
DOI: 10.1007/s10971-011-2639-9
ISSN: 0928-0707
WoS: 000299332500014
Scopus: 2-s2.0-84856254215
Колекције
Институција/група
VinčaTY - JOUR AU - Šćepanović, Maja AU - Abramović, Biljana F. AU - Golubović, Aleksandar V. AU - Kler, Sanja AU - Grujić-Brojčin, Mirjana AU - Dohčević-Mitrović, Zorana AU - Babić, Biljana M. AU - Matović, Branko AU - Popović, Zoran V. PY - 2012 UR - https://vinar.vin.bg.ac.rs/handle/123456789/4656 AB - Nanocrystalline titanium dioxide (TiO2) powders have been synthesized by sol-gel method using titanium tetrachloride (TiCl4) or tetrabutyl titanate (Ti(OC4H9)(4) as precursors, different alcohols and calcination temperatures in the range from 400 to 650 A degrees C. The photocatalytic activity of as-prepared powders has been tested for the degradation of metoprolol tartrate salt, a selective beta-blocker used to treat a variety of cardiovascular diseases, and compared to photocatalytic activity obtained from Degussa P25. Nanosized TiO2 powders prepared from TiCl4 and amyl-alcohol, calcined at 550 A degrees C, displayed an activity comparable to Degussa P25, whereas the sample from the same series, calcined at 650 A degrees C, showed higher photocatalytic activity in the whole range of the catalyst loading. Structural, morphological and surface properties of synthesized TiO2 nanopowders have been investigated by XRD, SEM, EDS and BET measurements, as well as FTIR and Raman spectroscopy, in order to find out the material properties which enable rapid an efficient decomposition of metoprolol under UV radiation. T2 - Journal of Sol-gel Science and Technology T1 - Photocatalytic degradation of metoprolol in water suspension of TiO2 nanopowders prepared using sol-gel route VL - 61 IS - 2 SP - 390 EP - 402 DO - 10.1007/s10971-011-2639-9 ER -
@article{ author = "Šćepanović, Maja and Abramović, Biljana F. and Golubović, Aleksandar V. and Kler, Sanja and Grujić-Brojčin, Mirjana and Dohčević-Mitrović, Zorana and Babić, Biljana M. and Matović, Branko and Popović, Zoran V.", year = "2012", abstract = "Nanocrystalline titanium dioxide (TiO2) powders have been synthesized by sol-gel method using titanium tetrachloride (TiCl4) or tetrabutyl titanate (Ti(OC4H9)(4) as precursors, different alcohols and calcination temperatures in the range from 400 to 650 A degrees C. The photocatalytic activity of as-prepared powders has been tested for the degradation of metoprolol tartrate salt, a selective beta-blocker used to treat a variety of cardiovascular diseases, and compared to photocatalytic activity obtained from Degussa P25. Nanosized TiO2 powders prepared from TiCl4 and amyl-alcohol, calcined at 550 A degrees C, displayed an activity comparable to Degussa P25, whereas the sample from the same series, calcined at 650 A degrees C, showed higher photocatalytic activity in the whole range of the catalyst loading. Structural, morphological and surface properties of synthesized TiO2 nanopowders have been investigated by XRD, SEM, EDS and BET measurements, as well as FTIR and Raman spectroscopy, in order to find out the material properties which enable rapid an efficient decomposition of metoprolol under UV radiation.", journal = "Journal of Sol-gel Science and Technology", title = "Photocatalytic degradation of metoprolol in water suspension of TiO2 nanopowders prepared using sol-gel route", volume = "61", number = "2", pages = "390-402", doi = "10.1007/s10971-011-2639-9" }
Šćepanović, M., Abramović, B. F., Golubović, A. V., Kler, S., Grujić-Brojčin, M., Dohčević-Mitrović, Z., Babić, B. M., Matović, B.,& Popović, Z. V.. (2012). Photocatalytic degradation of metoprolol in water suspension of TiO2 nanopowders prepared using sol-gel route. in Journal of Sol-gel Science and Technology, 61(2), 390-402. https://doi.org/10.1007/s10971-011-2639-9
Šćepanović M, Abramović BF, Golubović AV, Kler S, Grujić-Brojčin M, Dohčević-Mitrović Z, Babić BM, Matović B, Popović ZV. Photocatalytic degradation of metoprolol in water suspension of TiO2 nanopowders prepared using sol-gel route. in Journal of Sol-gel Science and Technology. 2012;61(2):390-402. doi:10.1007/s10971-011-2639-9 .
Šćepanović, Maja, Abramović, Biljana F., Golubović, Aleksandar V., Kler, Sanja, Grujić-Brojčin, Mirjana, Dohčević-Mitrović, Zorana , Babić, Biljana M., Matović, Branko, Popović, Zoran V., "Photocatalytic degradation of metoprolol in water suspension of TiO2 nanopowders prepared using sol-gel route" in Journal of Sol-gel Science and Technology, 61, no. 2 (2012):390-402, https://doi.org/10.1007/s10971-011-2639-9 . .