Приказ основних података о документу
Structural and electrical properties of the 2Bi(2)O(3) center dot 3ZrO(2) system
dc.creator | Jovalekić, Čedomir | |
dc.creator | Zdujić, Miodrag | |
dc.creator | Poleti, Dejan | |
dc.creator | Karanović, Ljiljana | |
dc.creator | Mitrić, Miodrag | |
dc.date.accessioned | 2018-03-01T20:27:10Z | |
dc.date.available | 2018-03-01T20:27:10Z | |
dc.date.issued | 2008 | |
dc.identifier.issn | 0022-4596 | |
dc.identifier.uri | https://vinar.vin.bg.ac.rs/handle/123456789/3465 | |
dc.description.abstract | Powder mixtures of alpha-Bi2O3 (bismite) and monoclinic m-ZrO2 (baddeleyite) in the molar ratio 2:3 were mechanochemically and thermally treated with the goal to examine the phases, which may appear during such procedures. The prepared samples were characterized by X-ray powder diffraction, differential scanning calorimetry (DSC), electrical measurements, as well as scanning electron microscopy (SEM) and transmission election microscopy (TEM). The mechanochemical reaction leads to the gradual formation of a nanocrystalline phase, which resembles delta-Bi2O3, a high-temperature Bi2O3 polymorph. Isothermal sintering in air at a temperature of 820 degrees C for 24 h followed by quenching to room temperature yielded a mixture of ZrO2-stabilized beta-Bi2O3 and m-ZrO2 phases, whereas in slowly cooled products, the complete separation of the initial alpha-Bi2O3 and m-ZrO2 constituents was observed. The dielectric permittivity of the sintered samples significantly depended on the temperature. The sintered and quenched samples exhibited a hysteresis dependence of the dielectric shift, showing that the ZrO2-doped beta-Bi2O3 phase possess ferroelectric properties, which were detected for the first time. This fact, together with Rietveld refinement of the beta-Bi2O3/m-ZrO2 mixture based on neutron powder diffraction data showed that ZrO2-doped beta-Bi2O3 has a non-centrosymmetric structure with P $(4) over bar $2(1)c as the true space group. The ZrO2 content in the doped beta-Bi2O3 and the crystal chemical reasons for the stabilization of the beta-Bi2O3 phase by the addition Of m-ZrO2 are discussed. (c) 2008 Elsevier Inc. All rights reserved. | en |
dc.rights | restrictedAccess | en |
dc.source | Journal of Solid State Chemistry | en |
dc.subject | ferroelectricity | en |
dc.subject | mechanochemical treatment | en |
dc.subject | Bi2O3 | en |
dc.subject | ZrO2 | en |
dc.title | Structural and electrical properties of the 2Bi(2)O(3) center dot 3ZrO(2) system | en |
dc.type | article | en |
dcterms.abstract | Здујиц, Миодраг; Карановиц, Љиљана; Митрић Миодраг; Јовалекиц, Цедомир; Полети, Дејан; | |
dc.citation.volume | 181 | |
dc.citation.issue | 6 | |
dc.citation.spage | 1321 | |
dc.citation.epage | 1329 | |
dc.identifier.wos | 000256857600007 | |
dc.identifier.doi | 10.1016/j.jssc.2008.02.038 | |
dc.citation.rank | M22 | |
dc.identifier.scopus | 2-s2.0-44649097464 |
Документи
Датотеке | Величина | Формат | Преглед |
---|---|---|---|
Уз овај запис нема датотека. |