Synthesis and crystal structure of trans-dichloro(1,3-propylenediamine-N,N -diacetato)platinum(IV) monohydrate
Abstract
The trans-geometrical isomer of the first Pt(IV) complex with the tetradentate ligand 1,3-propylenediamine-N,N-diacetate ion (pdda) was prepared by a direct synthesis from potassium hexachloroplatinate(IV) and pdda in the presence of lithium hydroxide. The crystal structure of trans-[Pt(pdda)Cl-2] (.) H2O complex has been determined. The Pt(IV) ion has a distorted octahedral coordination due to intramolecular N-(HCl)-Cl-... interactions.
Keywords:
platinum(W) complex / crystal structure / Edda ligandsSource:
Journal of Coordination Chemistry, 2004, 57, 7, 535-541
DOI: 10.1080/00958970410001671110
ISSN: 0095-8972
WoS: 000222783800001
Scopus: 2-s2.0-3142750510
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VinčaTY - JOUR AU - Dinovic, VM AU - Bogdanović, Goran A. AU - Novaković, Slađana B. AU - Sabo, Tibor J. PY - 2004 UR - https://vinar.vin.bg.ac.rs/handle/123456789/2787 AB - The trans-geometrical isomer of the first Pt(IV) complex with the tetradentate ligand 1,3-propylenediamine-N,N-diacetate ion (pdda) was prepared by a direct synthesis from potassium hexachloroplatinate(IV) and pdda in the presence of lithium hydroxide. The crystal structure of trans-[Pt(pdda)Cl-2] (.) H2O complex has been determined. The Pt(IV) ion has a distorted octahedral coordination due to intramolecular N-(HCl)-Cl-... interactions. T2 - Journal of Coordination Chemistry T1 - Synthesis and crystal structure of trans-dichloro(1,3-propylenediamine-N,N -diacetato)platinum(IV) monohydrate VL - 57 IS - 7 SP - 535 EP - 541 DO - 10.1080/00958970410001671110 ER -
@article{ author = "Dinovic, VM and Bogdanović, Goran A. and Novaković, Slađana B. and Sabo, Tibor J.", year = "2004", abstract = "The trans-geometrical isomer of the first Pt(IV) complex with the tetradentate ligand 1,3-propylenediamine-N,N-diacetate ion (pdda) was prepared by a direct synthesis from potassium hexachloroplatinate(IV) and pdda in the presence of lithium hydroxide. The crystal structure of trans-[Pt(pdda)Cl-2] (.) H2O complex has been determined. The Pt(IV) ion has a distorted octahedral coordination due to intramolecular N-(HCl)-Cl-... interactions.", journal = "Journal of Coordination Chemistry", title = "Synthesis and crystal structure of trans-dichloro(1,3-propylenediamine-N,N -diacetato)platinum(IV) monohydrate", volume = "57", number = "7", pages = "535-541", doi = "10.1080/00958970410001671110" }
Dinovic, V., Bogdanović, G. A., Novaković, S. B.,& Sabo, T. J.. (2004). Synthesis and crystal structure of trans-dichloro(1,3-propylenediamine-N,N -diacetato)platinum(IV) monohydrate. in Journal of Coordination Chemistry, 57(7), 535-541. https://doi.org/10.1080/00958970410001671110
Dinovic V, Bogdanović GA, Novaković SB, Sabo TJ. Synthesis and crystal structure of trans-dichloro(1,3-propylenediamine-N,N -diacetato)platinum(IV) monohydrate. in Journal of Coordination Chemistry. 2004;57(7):535-541. doi:10.1080/00958970410001671110 .
Dinovic, VM, Bogdanović, Goran A., Novaković, Slađana B., Sabo, Tibor J., "Synthesis and crystal structure of trans-dichloro(1,3-propylenediamine-N,N -diacetato)platinum(IV) monohydrate" in Journal of Coordination Chemistry, 57, no. 7 (2004):535-541, https://doi.org/10.1080/00958970410001671110 . .