Near-Infrared Luminescent Lifetime-Based Thermometry with Mn5+-Activated Sr3(PO4)2and Ba3(PO4)2Phosphors
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2022
Authors
Ristić, ZoranPiotrowski, Wojciech
Medić, Mina M.
Periša, Jovana
Antić, Željka
Marciniak, Lukasz
Dramićanin, Miroslav
Article (Published version)
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This paper describes Mn5+-activated Sr3(PO4)2and Ba3(PO4)2phosphors as near-infrared lifetime-based luminescence thermometry probes. Materials were prepared by a solid-state method, and their rhombohedral structures were confirmed by X-ray diffraction analysis. Diffuse reflectance measurements showed broad and strong absorption between 650 and 950 nm covering the first biological transparency window and having an absorption maximum at ∼660 nm. By switching Sr with Ba, the following changes in the photoluminescent properties were observed: (i) a red shift of the emission maximum (1173 nm → 1191 nm) and (ii) a decrease in the excited-state lifetime. Thermometric properties of the phosphors were assessed by measuring and analyzing the temperature dependence of the Mn5+excited-state lifetime. Lifetime-based luminescence thermometry revealed a relative sensitivity of 0.5% K-1at 310 K (physiologically relevant range) and a maximal value of ∼1% K-1at temperatures between 400 and 500 K. © 2022... American Chemical Society.
Keywords:
Ba3(PO4)2 / lifetime-based thermometry / luminescence thermometry / Mn5+ / NIR phosphor / Sr3(PO4)2Source:
ACS Applied Electronic Materials, 2022, 4, 3, 1057-1062Funding / projects:
- NATO [Grant No. G5751]
- Ministry of Education, Science and Technological Development of the Republic of Serbia
DOI: 10.1021/acsaelm.1c01207
ISSN: 2637-6113
WoS: 00079589650001
Scopus: 2-s2.0-85126817280
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VinčaTY - JOUR AU - Ristić, Zoran AU - Piotrowski, Wojciech AU - Medić, Mina M. AU - Periša, Jovana AU - Antić, Željka AU - Marciniak, Lukasz AU - Dramićanin, Miroslav PY - 2022 UR - https://vinar.vin.bg.ac.rs/handle/123456789/10225 AB - This paper describes Mn5+-activated Sr3(PO4)2and Ba3(PO4)2phosphors as near-infrared lifetime-based luminescence thermometry probes. Materials were prepared by a solid-state method, and their rhombohedral structures were confirmed by X-ray diffraction analysis. Diffuse reflectance measurements showed broad and strong absorption between 650 and 950 nm covering the first biological transparency window and having an absorption maximum at ∼660 nm. By switching Sr with Ba, the following changes in the photoluminescent properties were observed: (i) a red shift of the emission maximum (1173 nm → 1191 nm) and (ii) a decrease in the excited-state lifetime. Thermometric properties of the phosphors were assessed by measuring and analyzing the temperature dependence of the Mn5+excited-state lifetime. Lifetime-based luminescence thermometry revealed a relative sensitivity of 0.5% K-1at 310 K (physiologically relevant range) and a maximal value of ∼1% K-1at temperatures between 400 and 500 K. © 2022 American Chemical Society. T2 - ACS Applied Electronic Materials T1 - Near-Infrared Luminescent Lifetime-Based Thermometry with Mn5+-Activated Sr3(PO4)2and Ba3(PO4)2Phosphors VL - 4 IS - 3 SP - 1057 EP - 1062 DO - 10.1021/acsaelm.1c01207 ER -
@article{ author = "Ristić, Zoran and Piotrowski, Wojciech and Medić, Mina M. and Periša, Jovana and Antić, Željka and Marciniak, Lukasz and Dramićanin, Miroslav", year = "2022", abstract = "This paper describes Mn5+-activated Sr3(PO4)2and Ba3(PO4)2phosphors as near-infrared lifetime-based luminescence thermometry probes. Materials were prepared by a solid-state method, and their rhombohedral structures were confirmed by X-ray diffraction analysis. Diffuse reflectance measurements showed broad and strong absorption between 650 and 950 nm covering the first biological transparency window and having an absorption maximum at ∼660 nm. By switching Sr with Ba, the following changes in the photoluminescent properties were observed: (i) a red shift of the emission maximum (1173 nm → 1191 nm) and (ii) a decrease in the excited-state lifetime. Thermometric properties of the phosphors were assessed by measuring and analyzing the temperature dependence of the Mn5+excited-state lifetime. Lifetime-based luminescence thermometry revealed a relative sensitivity of 0.5% K-1at 310 K (physiologically relevant range) and a maximal value of ∼1% K-1at temperatures between 400 and 500 K. © 2022 American Chemical Society.", journal = "ACS Applied Electronic Materials", title = "Near-Infrared Luminescent Lifetime-Based Thermometry with Mn5+-Activated Sr3(PO4)2and Ba3(PO4)2Phosphors", volume = "4", number = "3", pages = "1057-1062", doi = "10.1021/acsaelm.1c01207" }
Ristić, Z., Piotrowski, W., Medić, M. M., Periša, J., Antić, Ž., Marciniak, L.,& Dramićanin, M.. (2022). Near-Infrared Luminescent Lifetime-Based Thermometry with Mn5+-Activated Sr3(PO4)2and Ba3(PO4)2Phosphors. in ACS Applied Electronic Materials, 4(3), 1057-1062. https://doi.org/10.1021/acsaelm.1c01207
Ristić Z, Piotrowski W, Medić MM, Periša J, Antić Ž, Marciniak L, Dramićanin M. Near-Infrared Luminescent Lifetime-Based Thermometry with Mn5+-Activated Sr3(PO4)2and Ba3(PO4)2Phosphors. in ACS Applied Electronic Materials. 2022;4(3):1057-1062. doi:10.1021/acsaelm.1c01207 .
Ristić, Zoran, Piotrowski, Wojciech, Medić, Mina M., Periša, Jovana, Antić, Željka, Marciniak, Lukasz, Dramićanin, Miroslav, "Near-Infrared Luminescent Lifetime-Based Thermometry with Mn5+-Activated Sr3(PO4)2and Ba3(PO4)2Phosphors" in ACS Applied Electronic Materials, 4, no. 3 (2022):1057-1062, https://doi.org/10.1021/acsaelm.1c01207 . .