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Synthesis, characterization and antimicrobial activity of Pd(II) and Fe(III) complexes with ethyl (2E)-2-[2-(diphenylphosphino)benzylidene]hydrazinecarboxylate
Complexes of Pd(II) and Fe(III) with the condensation derivative of 2-(diphenylphosphino)benzaldehyde and ethyl carbazate were synthesized, characterized, and their antimicrobial activity was evaluated. The structures of the Pd(II) and Fe(III) complexes in solid state were determined by IR, elemental analysis and X-ray analysis. The structure of Pd(II) complex in solution was determined by NMR spectroscopy. Results of magnetic measurements for Fe(III) complex were reported. In both complexes the ligand is coordinated as tridentate via the phosphorus, the imine nitrogen and the carbonyl oxygen atoms. Results of antimicrobial activity investigation indicate that the activity of the ligand is enhanced upon complexation, and that the MIC values of the iron complex to some bacterial strains are not much higher than those of cefotaxime. (C) 2014 Elsevier Ltd. All rights reserved.
TY - JOUR
AU - Milenkovic, Milica
AU - Cantoni, Giulia
AU - Bacchi, Alessia
AU - Spasojević, Vojislav
AU - Milenkovic, Marina
AU - Sladić, Dušan M.
AU - Krstic, Natalija
AU - Anđelković, Katarina
PY - 2014
UR - http://vinar.vin.bg.ac.rs/handle/123456789/99
AB - Complexes of Pd(II) and Fe(III) with the condensation derivative of 2-(diphenylphosphino)benzaldehyde and ethyl carbazate were synthesized, characterized, and their antimicrobial activity was evaluated. The structures of the Pd(II) and Fe(III) complexes in solid state were determined by IR, elemental analysis and X-ray analysis. The structure of Pd(II) complex in solution was determined by NMR spectroscopy. Results of magnetic measurements for Fe(III) complex were reported. In both complexes the ligand is coordinated as tridentate via the phosphorus, the imine nitrogen and the carbonyl oxygen atoms. Results of antimicrobial activity investigation indicate that the activity of the ligand is enhanced upon complexation, and that the MIC values of the iron complex to some bacterial strains are not much higher than those of cefotaxime. (C) 2014 Elsevier Ltd. All rights reserved.
T2 - Polyhedron
T1 - Synthesis, characterization and antimicrobial activity of Pd(II) and Fe(III) complexes with ethyl (2E)-2-[2-(diphenylphosphino)benzylidene]hydrazinecarboxylate
VL - 80
IS - SI
SP - 47
EP - 52
DO - 10.1016/j.poly.2014.01.022
ER -
@article{
author = "Milenkovic, Milica and Cantoni, Giulia and Bacchi, Alessia and Spasojević, Vojislav and Milenkovic, Marina and Sladić, Dušan M. and Krstic, Natalija and Anđelković, Katarina",
year = "2014",
url = "http://vinar.vin.bg.ac.rs/handle/123456789/99",
abstract = "Complexes of Pd(II) and Fe(III) with the condensation derivative of 2-(diphenylphosphino)benzaldehyde and ethyl carbazate were synthesized, characterized, and their antimicrobial activity was evaluated. The structures of the Pd(II) and Fe(III) complexes in solid state were determined by IR, elemental analysis and X-ray analysis. The structure of Pd(II) complex in solution was determined by NMR spectroscopy. Results of magnetic measurements for Fe(III) complex were reported. In both complexes the ligand is coordinated as tridentate via the phosphorus, the imine nitrogen and the carbonyl oxygen atoms. Results of antimicrobial activity investigation indicate that the activity of the ligand is enhanced upon complexation, and that the MIC values of the iron complex to some bacterial strains are not much higher than those of cefotaxime. (C) 2014 Elsevier Ltd. All rights reserved.",
journal = "Polyhedron",
title = "Synthesis, characterization and antimicrobial activity of Pd(II) and Fe(III) complexes with ethyl (2E)-2-[2-(diphenylphosphino)benzylidene]hydrazinecarboxylate",
volume = "80",
number = "SI",
pages = "47-52",
doi = "10.1016/j.poly.2014.01.022"
}
Milenkovic M, Cantoni G, Bacchi A, Spasojević V, Milenkovic M, Sladić DM, Krstic N, Anđelković K. Synthesis, characterization and antimicrobial activity of Pd(II) and Fe(III) complexes with ethyl (2E)-2-[2-(diphenylphosphino)benzylidene]hydrazinecarboxylate. Polyhedron. 2014;80(SI):47-52
Milenkovic, M., Cantoni, G., Bacchi, A., Spasojević, V., Milenkovic, M., Sladić, D. M., Krstic, N.,& Anđelković, K. (2014). Synthesis, characterization and antimicrobial activity of Pd(II) and Fe(III) complexes with ethyl (2E)-2-[2-(diphenylphosphino)benzylidene]hydrazinecarboxylate.
Polyhedron, 80(SI), 47-52.
https://doi.org/10.1016/j.poly.2014.01.022
Milenkovic Milica, Cantoni Giulia, Bacchi Alessia, Spasojević Vojislav, Milenkovic Marina, Sladić Dušan M., Krstic Natalija, Anđelković Katarina, "Synthesis, characterization and antimicrobial activity of Pd(II) and Fe(III) complexes with ethyl (2E)-2-[2-(diphenylphosphino)benzylidene]hydrazinecarboxylate" 80, no. SI (2014):47-52,
https://doi.org/10.1016/j.poly.2014.01.022 .
