Show simple item record

dc.creatorKabtamu, Daniel Manaye
dc.creatorWu, Yi-nan
dc.creatorChen, Qian
dc.creatorZheng, Lu
dc.creatorOtake, Ken-ichi
dc.creatorMatović, Ljiljana
dc.creatorLi, Fengting
dc.date.accessioned2021-10-26T07:00:25Z
dc.date.available2021-10-26T07:00:25Z
dc.date.issued2020
dc.identifier.issn2168-0485
dc.identifier.urihttps://vinar.vin.bg.ac.rs/handle/123456789/9716
dc.description.abstractThe recycling of heavy metals from solid wastes and transforming these metals into useful materials, such as metal oxides, nanocomposites, and metal–organic frameworks (MOFs), are beneficial for both sustainable development and environmental protection. MOFs are promising for adsorptive desulfurization, owing to their extremely high surface areas and tunable structures. In this paper, for the first time, MIL-53(Cr) was successfully fabricated from electroplating sludge (EPS) as a metal source through a facile hydrothermal method with and without HF. Our synthetic method is novel, green, scalable, and time-efficient. The obtained MIL-53(Cr) was employed as an adsorbent for adsorptive dibenzothiophene removal from liquid fuel. MIL-53(Cr) with HF exhibits a higher desulfurization capacity (40.11 mg g–1) than that of MIL-53(Cr) without HF (32.80 mg g–1). The improved adsorption performance of MIL-53(Cr) with HF is attributed to adding a small amount of HF, which produces highly crystalline and relativity pure MIL-53(Cr) microrods with a high surface area and porosity, and is due to a robust metal–sulfur interaction. Furthermore, the regenerated adsorbent can retain 94% of its initial sulfur adsorption capability even after 5 cycles, implying that MIL-53(Cr) prepared from Cr-EPS is an efficient adsorbent for fuel desulfurization. This study provides new insight for the production of high-value-added MOF materials from solid wastes following the principle of “resource reuse”.en
dc.relationNational Natural Science Foundation of China [21777119]
dc.relationScience & Technology Commission of Shanghai Municipality [18230742300, 17230711600]
dc.relationTalented Young Scientist Program of the Ministry of Science and Technology of China
dc.rightsrestrictedAccess
dc.sourceACS Sustainable Chemistry & Engineering
dc.subjectThiophenesen
dc.subjectSulfuren
dc.subjectAdsorptionen
dc.subjectMetal organic frameworksen
dc.subjectDesulfurizationen
dc.titleFacile Upcycling of Hazardous Cr-Containing Electroplating Sludge into Value-Added Metal–Organic Frameworks for Efficient Adsorptive Desulfurizationen
dc.typearticleen
dc.rights.licenseARR
dcterms.abstractМатовић, Љиљана; Цхен, Qиан; Ли, Фенгтинг; Кабтаму, Даниел Манаyе; Wу, Yи-нан; Зхенг, Лу; Отаке, Кен-ицхи;
dc.citation.volume8
dc.citation.issue33
dc.citation.spage12443
dc.citation.epage12452
dc.identifier.wos000563783100012
dc.identifier.doi10.1021/acssuschemeng.0c03110
dc.citation.rankaM21
dc.type.versionpublishedVersion
dc.identifier.scopus2-s2.0-85094202866


Files in this item

Thumbnail

This item appears in the following Collection(s)

Show simple item record