VinaR - Repository of the Vinča Nuclear Institute
    • English
    • Српски
    • Српски (Serbia)
  • English 
    • English
    • Serbian (Cyrillic)
    • Serbian (Latin)
  • Login
View Item 
  •   Vinar
  • Vinča
  • Radovi istraživača
  • View Item
  •   Vinar
  • Vinča
  • Radovi istraživača
  • View Item
JavaScript is disabled for your browser. Some features of this site may not work without it.

Facile Upcycling of Hazardous Cr-Containing Electroplating Sludge into Value-Added Metal–Organic Frameworks for Efficient Adsorptive Desulfurization

Authorized Users Only
2020
Authors
Kabtamu, Daniel Manaye
Wu, Yi-nan
Chen, Qian
Zheng, Lu
Otake, Ken-ichi
Matović, Ljiljana
Li, Fengting
Article (Published version)
Metadata
Show full item record
Abstract
The recycling of heavy metals from solid wastes and transforming these metals into useful materials, such as metal oxides, nanocomposites, and metal–organic frameworks (MOFs), are beneficial for both sustainable development and environmental protection. MOFs are promising for adsorptive desulfurization, owing to their extremely high surface areas and tunable structures. In this paper, for the first time, MIL-53(Cr) was successfully fabricated from electroplating sludge (EPS) as a metal source through a facile hydrothermal method with and without HF. Our synthetic method is novel, green, scalable, and time-efficient. The obtained MIL-53(Cr) was employed as an adsorbent for adsorptive dibenzothiophene removal from liquid fuel. MIL-53(Cr) with HF exhibits a higher desulfurization capacity (40.11 mg g–1) than that of MIL-53(Cr) without HF (32.80 mg g–1). The improved adsorption performance of MIL-53(Cr) with HF is attributed to adding a small amount of HF, which produces highly crystalline... and relativity pure MIL-53(Cr) microrods with a high surface area and porosity, and is due to a robust metal–sulfur interaction. Furthermore, the regenerated adsorbent can retain 94% of its initial sulfur adsorption capability even after 5 cycles, implying that MIL-53(Cr) prepared from Cr-EPS is an efficient adsorbent for fuel desulfurization. This study provides new insight for the production of high-value-added MOF materials from solid wastes following the principle of “resource reuse”.

Keywords:
Thiophenes / Sulfur / Adsorption / Metal organic frameworks / Desulfurization
Source:
ACS Sustainable Chemistry & Engineering, 2020, 8, 33, 12443-12452
Funding / projects:
  • National Natural Science Foundation of China [21777119]
  • Science & Technology Commission of Shanghai Municipality [18230742300, 17230711600]
  • Talented Young Scientist Program of the Ministry of Science and Technology of China

DOI: 10.1021/acssuschemeng.0c03110

ISSN: 2168-0485

WoS: 000563783100012

Scopus: 2-s2.0-85094202866
[ Google Scholar ]
12
6
URI
https://vinar.vin.bg.ac.rs/handle/123456789/9716
Collections
  • Radovi istraživača
Institution/Community
Vinča
TY  - JOUR
AU  - Kabtamu, Daniel Manaye
AU  - Wu, Yi-nan
AU  - Chen, Qian
AU  - Zheng, Lu
AU  - Otake, Ken-ichi
AU  - Matović, Ljiljana
AU  - Li, Fengting
PY  - 2020
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/9716
AB  - The recycling of heavy metals from solid wastes and transforming these metals into useful materials, such as metal oxides, nanocomposites, and metal–organic frameworks (MOFs), are beneficial for both sustainable development and environmental protection. MOFs are promising for adsorptive desulfurization, owing to their extremely high surface areas and tunable structures. In this paper, for the first time, MIL-53(Cr) was successfully fabricated from electroplating sludge (EPS) as a metal source through a facile hydrothermal method with and without HF. Our synthetic method is novel, green, scalable, and time-efficient. The obtained MIL-53(Cr) was employed as an adsorbent for adsorptive dibenzothiophene removal from liquid fuel. MIL-53(Cr) with HF exhibits a higher desulfurization capacity (40.11 mg g–1) than that of MIL-53(Cr) without HF (32.80 mg g–1). The improved adsorption performance of MIL-53(Cr) with HF is attributed to adding a small amount of HF, which produces highly crystalline and relativity pure MIL-53(Cr) microrods with a high surface area and porosity, and is due to a robust metal–sulfur interaction. Furthermore, the regenerated adsorbent can retain 94% of its initial sulfur adsorption capability even after 5 cycles, implying that MIL-53(Cr) prepared from Cr-EPS is an efficient adsorbent for fuel desulfurization. This study provides new insight for the production of high-value-added MOF materials from solid wastes following the principle of “resource reuse”.
T2  - ACS Sustainable Chemistry & Engineering
T1  - Facile Upcycling of Hazardous Cr-Containing Electroplating Sludge into Value-Added Metal–Organic Frameworks for Efficient Adsorptive Desulfurization
VL  - 8
IS  - 33
SP  - 12443
EP  - 12452
DO  - 10.1021/acssuschemeng.0c03110
ER  - 
@article{
author = "Kabtamu, Daniel Manaye and Wu, Yi-nan and Chen, Qian and Zheng, Lu and Otake, Ken-ichi and Matović, Ljiljana and Li, Fengting",
year = "2020",
abstract = "The recycling of heavy metals from solid wastes and transforming these metals into useful materials, such as metal oxides, nanocomposites, and metal–organic frameworks (MOFs), are beneficial for both sustainable development and environmental protection. MOFs are promising for adsorptive desulfurization, owing to their extremely high surface areas and tunable structures. In this paper, for the first time, MIL-53(Cr) was successfully fabricated from electroplating sludge (EPS) as a metal source through a facile hydrothermal method with and without HF. Our synthetic method is novel, green, scalable, and time-efficient. The obtained MIL-53(Cr) was employed as an adsorbent for adsorptive dibenzothiophene removal from liquid fuel. MIL-53(Cr) with HF exhibits a higher desulfurization capacity (40.11 mg g–1) than that of MIL-53(Cr) without HF (32.80 mg g–1). The improved adsorption performance of MIL-53(Cr) with HF is attributed to adding a small amount of HF, which produces highly crystalline and relativity pure MIL-53(Cr) microrods with a high surface area and porosity, and is due to a robust metal–sulfur interaction. Furthermore, the regenerated adsorbent can retain 94% of its initial sulfur adsorption capability even after 5 cycles, implying that MIL-53(Cr) prepared from Cr-EPS is an efficient adsorbent for fuel desulfurization. This study provides new insight for the production of high-value-added MOF materials from solid wastes following the principle of “resource reuse”.",
journal = "ACS Sustainable Chemistry & Engineering",
title = "Facile Upcycling of Hazardous Cr-Containing Electroplating Sludge into Value-Added Metal–Organic Frameworks for Efficient Adsorptive Desulfurization",
volume = "8",
number = "33",
pages = "12443-12452",
doi = "10.1021/acssuschemeng.0c03110"
}
Kabtamu, D. M., Wu, Y., Chen, Q., Zheng, L., Otake, K., Matović, L.,& Li, F.. (2020). Facile Upcycling of Hazardous Cr-Containing Electroplating Sludge into Value-Added Metal–Organic Frameworks for Efficient Adsorptive Desulfurization. in ACS Sustainable Chemistry & Engineering, 8(33), 12443-12452.
https://doi.org/10.1021/acssuschemeng.0c03110
Kabtamu DM, Wu Y, Chen Q, Zheng L, Otake K, Matović L, Li F. Facile Upcycling of Hazardous Cr-Containing Electroplating Sludge into Value-Added Metal–Organic Frameworks for Efficient Adsorptive Desulfurization. in ACS Sustainable Chemistry & Engineering. 2020;8(33):12443-12452.
doi:10.1021/acssuschemeng.0c03110 .
Kabtamu, Daniel Manaye, Wu, Yi-nan, Chen, Qian, Zheng, Lu, Otake, Ken-ichi, Matović, Ljiljana, Li, Fengting, "Facile Upcycling of Hazardous Cr-Containing Electroplating Sludge into Value-Added Metal–Organic Frameworks for Efficient Adsorptive Desulfurization" in ACS Sustainable Chemistry & Engineering, 8, no. 33 (2020):12443-12452,
https://doi.org/10.1021/acssuschemeng.0c03110 . .

DSpace software copyright © 2002-2015  DuraSpace
About the VinaR Repository | Send Feedback

OpenAIRERCUB
 

 

All of DSpaceCommunitiesAuthorsTitlesSubjectsThis institutionAuthorsTitlesSubjects

Statistics

View Usage Statistics

DSpace software copyright © 2002-2015  DuraSpace
About the VinaR Repository | Send Feedback

OpenAIRERCUB