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Synthesis of new seven membered heterocyclic rings: An easy access to indeno-benzo[1,4]diazepines

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2020
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Authors
Alam, Mohd Gulfam
Trifunović, Srećko R.
Bogdanović, Goran A.
Malla, Ali Mohammed
Mehdi, Sayed Hasan
Ghalib, Raza Murad
Article (Published version)
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Abstract
An easy access has been demonstrated for seven membered diazepines and a six membered quinoxaline. The reaction proceeds rapidly with low-cost and readily available chemicals at mild temperature and provides straight forward access to diazepines and quinoxaline. All final products are new and confirmed by spectral analysis and by single crystal X-ray analysis. Two crystal structures of the diazepines have very similar compositions, exhibit similar conformations where four condensed and coplanar rings are placed in the same orientation to the rest of molecule.
Keywords:
Synthesis / Crystal structures / Ninhydrin / Diazepine / Benzoimidazole
Source:
Arabian Journal of Chemistry, 2020, 13, 10, 7338-7345
Funding / projects:
  • Ministry of Education, Science and Technological Development of the Republic of Serbia
  • DSR [UJ-02-050-DR]

DOI: 10.1016/j.arabjc.2020.08.011

ISSN: 1878-5352

WoS: 000576707900008

Scopus: 2-s2.0-85090133016
[ Google Scholar ]
4
1
URI
https://vinar.vin.bg.ac.rs/handle/123456789/9635
Collections
  • Radovi istraživača
Institution/Community
Vinča
TY  - JOUR
AU  - Alam, Mohd Gulfam
AU  - Trifunović, Srećko R.
AU  - Bogdanović, Goran A.
AU  - Malla, Ali Mohammed
AU  - Mehdi, Sayed Hasan
AU  - Ghalib, Raza Murad
PY  - 2020
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/9635
AB  - An easy access has been demonstrated for seven membered diazepines and a six membered quinoxaline. The reaction proceeds rapidly with low-cost and readily available chemicals at mild temperature and provides straight forward access to diazepines and quinoxaline. All final products are new and confirmed by spectral analysis and by single crystal X-ray analysis. Two crystal structures of the diazepines have very similar compositions, exhibit similar conformations where four condensed and coplanar rings are placed in the same orientation to the rest of molecule.
T2  - Arabian Journal of Chemistry
T1  - Synthesis of new seven membered heterocyclic rings: An easy access to indeno-benzo[1,4]diazepines
VL  - 13
IS  - 10
SP  - 7338
EP  - 7345
DO  - 10.1016/j.arabjc.2020.08.011
ER  - 
@article{
author = "Alam, Mohd Gulfam and Trifunović, Srećko R. and Bogdanović, Goran A. and Malla, Ali Mohammed and Mehdi, Sayed Hasan and Ghalib, Raza Murad",
year = "2020",
abstract = "An easy access has been demonstrated for seven membered diazepines and a six membered quinoxaline. The reaction proceeds rapidly with low-cost and readily available chemicals at mild temperature and provides straight forward access to diazepines and quinoxaline. All final products are new and confirmed by spectral analysis and by single crystal X-ray analysis. Two crystal structures of the diazepines have very similar compositions, exhibit similar conformations where four condensed and coplanar rings are placed in the same orientation to the rest of molecule.",
journal = "Arabian Journal of Chemistry",
title = "Synthesis of new seven membered heterocyclic rings: An easy access to indeno-benzo[1,4]diazepines",
volume = "13",
number = "10",
pages = "7338-7345",
doi = "10.1016/j.arabjc.2020.08.011"
}
Alam, M. G., Trifunović, S. R., Bogdanović, G. A., Malla, A. M., Mehdi, S. H.,& Ghalib, R. M.. (2020). Synthesis of new seven membered heterocyclic rings: An easy access to indeno-benzo[1,4]diazepines. in Arabian Journal of Chemistry, 13(10), 7338-7345.
https://doi.org/10.1016/j.arabjc.2020.08.011
Alam MG, Trifunović SR, Bogdanović GA, Malla AM, Mehdi SH, Ghalib RM. Synthesis of new seven membered heterocyclic rings: An easy access to indeno-benzo[1,4]diazepines. in Arabian Journal of Chemistry. 2020;13(10):7338-7345.
doi:10.1016/j.arabjc.2020.08.011 .
Alam, Mohd Gulfam, Trifunović, Srećko R., Bogdanović, Goran A., Malla, Ali Mohammed, Mehdi, Sayed Hasan, Ghalib, Raza Murad, "Synthesis of new seven membered heterocyclic rings: An easy access to indeno-benzo[1,4]diazepines" in Arabian Journal of Chemistry, 13, no. 10 (2020):7338-7345,
https://doi.org/10.1016/j.arabjc.2020.08.011 . .

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