Synthesis of new seven membered heterocyclic rings: An easy access to indeno-benzo[1,4]diazepines
Authors
Alam, Mohd Gulfam
Trifunović, Srećko R.

Bogdanović, Goran A.

Malla, Ali Mohammed
Mehdi, Sayed Hasan
Ghalib, Raza Murad
Article (Published version)
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An easy access has been demonstrated for seven membered diazepines and a six membered quinoxaline. The reaction proceeds rapidly with low-cost and readily available chemicals at mild temperature and provides straight forward access to diazepines and quinoxaline. All final products are new and confirmed by spectral analysis and by single crystal X-ray analysis. Two crystal structures of the diazepines have very similar compositions, exhibit similar conformations where four condensed and coplanar rings are placed in the same orientation to the rest of molecule.
Keywords:
Synthesis / Crystal structures / Ninhydrin / Diazepine / BenzoimidazoleSource:
Arabian Journal of Chemistry, 2020, 13, 10, 7338-7345Funding / projects:
- Ministry of Education, Science and Technological Development of the Republic of Serbia
- DSR [UJ-02-050-DR]
DOI: 10.1016/j.arabjc.2020.08.011
ISSN: 1878-5352
WoS: 000576707900008
Scopus: 2-s2.0-85090133016
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VinčaTY - JOUR AU - Alam, Mohd Gulfam AU - Trifunović, Srećko R. AU - Bogdanović, Goran A. AU - Malla, Ali Mohammed AU - Mehdi, Sayed Hasan AU - Ghalib, Raza Murad PY - 2020 UR - https://vinar.vin.bg.ac.rs/handle/123456789/9635 AB - An easy access has been demonstrated for seven membered diazepines and a six membered quinoxaline. The reaction proceeds rapidly with low-cost and readily available chemicals at mild temperature and provides straight forward access to diazepines and quinoxaline. All final products are new and confirmed by spectral analysis and by single crystal X-ray analysis. Two crystal structures of the diazepines have very similar compositions, exhibit similar conformations where four condensed and coplanar rings are placed in the same orientation to the rest of molecule. T2 - Arabian Journal of Chemistry T1 - Synthesis of new seven membered heterocyclic rings: An easy access to indeno-benzo[1,4]diazepines VL - 13 IS - 10 SP - 7338 EP - 7345 DO - 10.1016/j.arabjc.2020.08.011 ER -
@article{ author = "Alam, Mohd Gulfam and Trifunović, Srećko R. and Bogdanović, Goran A. and Malla, Ali Mohammed and Mehdi, Sayed Hasan and Ghalib, Raza Murad", year = "2020", abstract = "An easy access has been demonstrated for seven membered diazepines and a six membered quinoxaline. The reaction proceeds rapidly with low-cost and readily available chemicals at mild temperature and provides straight forward access to diazepines and quinoxaline. All final products are new and confirmed by spectral analysis and by single crystal X-ray analysis. Two crystal structures of the diazepines have very similar compositions, exhibit similar conformations where four condensed and coplanar rings are placed in the same orientation to the rest of molecule.", journal = "Arabian Journal of Chemistry", title = "Synthesis of new seven membered heterocyclic rings: An easy access to indeno-benzo[1,4]diazepines", volume = "13", number = "10", pages = "7338-7345", doi = "10.1016/j.arabjc.2020.08.011" }
Alam, M. G., Trifunović, S. R., Bogdanović, G. A., Malla, A. M., Mehdi, S. H.,& Ghalib, R. M.. (2020). Synthesis of new seven membered heterocyclic rings: An easy access to indeno-benzo[1,4]diazepines. in Arabian Journal of Chemistry, 13(10), 7338-7345. https://doi.org/10.1016/j.arabjc.2020.08.011
Alam MG, Trifunović SR, Bogdanović GA, Malla AM, Mehdi SH, Ghalib RM. Synthesis of new seven membered heterocyclic rings: An easy access to indeno-benzo[1,4]diazepines. in Arabian Journal of Chemistry. 2020;13(10):7338-7345. doi:10.1016/j.arabjc.2020.08.011 .
Alam, Mohd Gulfam, Trifunović, Srećko R., Bogdanović, Goran A., Malla, Ali Mohammed, Mehdi, Sayed Hasan, Ghalib, Raza Murad, "Synthesis of new seven membered heterocyclic rings: An easy access to indeno-benzo[1,4]diazepines" in Arabian Journal of Chemistry, 13, no. 10 (2020):7338-7345, https://doi.org/10.1016/j.arabjc.2020.08.011 . .