Приказ основних података о документу
Synthesis, structural and electrochemical characterization of novel ferrocene-containing tetrahydropyrimidin-2(1H)-ones
dc.creator | Minić, Aleksandra | |
dc.creator | Pešić, Marko S | |
dc.creator | Novaković, Slađana B. | |
dc.creator | Bogdanović, Goran A. | |
dc.creator | Todosijević, Anka | |
dc.creator | Ilić-Komatina, Danijela | |
dc.creator | Stevanović, Dragana D. | |
dc.date.accessioned | 2021-04-29T12:04:22Z | |
dc.date.available | 2021-04-29T12:04:22Z | |
dc.date.issued | 2020 | |
dc.identifier.issn | 0022-328X | |
dc.identifier.uri | https://vinar.vin.bg.ac.rs/handle/123456789/9119 | |
dc.description.abstract | Herein, we report an easy performable method for the synthesis of ferrocene-containing tetrahydropyrimidin-2(1H)-ones starting from the corresponding 3-arylamino-1-ferrocenylpropan-1-ols and sodium cyanate (NaOCN) in the presence of glacial acetic acid. The protocol is included an intramolecular cyclization of an in situ generated 1,3-hydroxyurea. The scope of the reaction towards eleven ferrocene-containing 1,3-amino alcohols has been explored and the targeted 1-aryl-4-ferrocenyltetrahidropyrimidin-2(1H)-ones were obtained in good to high yields (up to 93%). All products have been isolated in high purity >95%. In addition, we have provided a detailed structural characterization of the new compounds, which has been performed by IR and NMR spectroscopy. The single-crystal X-ray diffraction analysis was successfully performed on three representative examples, as well as elemental analysis. Moreover, molecular structure properties and intermolecular interactions of these three structures have been compared and analyzed in detail. Electrochemical properties of products were investigated by cyclic voltammetry. This investigation revealed the quasi-reversible one-electron redox process. | en |
dc.language.iso | en | |
dc.relation | info:eu-repo/grantAgreement/MESTD/inst-2020/200122/RS// | |
dc.rights | restrictedAccess | |
dc.source | Journal of Organometallic Chemistry | |
dc.subject | Ferrocene | en |
dc.subject | Tetrahydropyrimidin-2(1H)-ones | en |
dc.subject | One-pot reaction | en |
dc.subject | Crystal structure | en |
dc.subject | Electrochemistry | en |
dc.title | Synthesis, structural and electrochemical characterization of novel ferrocene-containing tetrahydropyrimidin-2(1H)-ones | en |
dc.type | article | en |
dc.rights.license | ARR | |
dcterms.abstract | Стевановић, Драгана; Минић, Aлександра; Новаковић, Слађана Б.; Тодосијевић, Aнка; Илић-Коматина, Данијела; Пешић, Марко С; Богдановић, Горан A.; | |
dc.rights.holder | © 2020 Elsevier B.V. | |
dc.citation.volume | 923 | |
dc.citation.spage | 121422 | |
dc.identifier.wos | 000575167700008 | |
dc.identifier.doi | 10.1016/j.jorganchem.2020.121422 | |
dc.citation.rank | M22 | |
dc.type.version | publishedVersion | |
dc.identifier.scopus | 2-s2.0-85089028968 |
Документи
Овај документ се појављује у следећим колекцијама
-
020 - Laboratorija za teorijsku fiziku i fiziku kondenzovane materije
Department of Theoretical Physics and Condensed Matter Physics -
Radovi istraživača
Researchers' publications