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Properties of humic acids from copper tailings 20 years after reclamation

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2020
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Authors
Radmanović, Svjetlana B.
Marković, Mirjana
Jovanović, Uroš D.
Gajić-Kvaščev, Maja
Čokeša, Đuro
Lilić, Jasmina
Article (Published version)
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© 2020 Serbian Chemical Society
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Abstract
Part of Cu post flotation tailings of Serbia ZiJin Bor Copper, Serbia, was reclaimed by restoration of top soil with arable soils, and revegetation in 1991. Humic acids isolated from these Technosols were investigated to find out if their properties underwent any changes since reclamation. Two groups of control samples were used. Elemental composition (CHNS analysis) falls within the range of average soil humic acids. Humic acids belong to the type B pointing out to its lower humification degree (UV?Vis). Relative abundances of functional groups are ranged as follows: polysaccharide C ??aromatic C > carboxyl C > OH group > aliphatic C. Aromaticity indexes are low, 1.88? 3.25 (ATR-FTIR). Basic units at pH 10 are in the 11.7?26.8 nm range. Pronounced reaggregation (1462-?5218 nm) at pH 3 points out to less expressed humic acid sol stability, as well as to increase in aromatic condensation degree (dynamic light scattering). No significant changes have occurred in technosol humic acids sin...ce the recultivation, confirming stability of their properties over time (PCA). Nevertheless, humic acids from very strongly acidic Technosols show higher humifycation degree possibly originating from arable soils used in reclamation, but more likely from low soil pH and low litter input, results of unsuccessful reclamation.

Keywords:
Technosols / top soil restoration / revegetation / humification degree
Source:
Journal of the Serbian Chemical Society, 2020, 85, 3, 407-419
Funding / projects:
  • Study of the effects of soil and irrigation water quality on more efficient agricultural crop production and environment protection (RS-37006)
  • Synthesis, processing and characterization of nanostructured materials for application in the field of energy, mechanical engineering, environmental protection and biomedicine (RS-45012)

DOI: 10.2298/JSC190717112R

ISSN: 0352-5139

WoS: 000522797400011

Scopus: 2-s2.0-85085365742
[ Google Scholar ]
URI
https://vinar.vin.bg.ac.rs/handle/123456789/9020
Collections
  • Radovi istraživača
  • 060 - Laboratorija za hemijsku dinamiku i permanentno obrazovanje
Institution/Community
Vinča
TY  - JOUR
AU  - Radmanović, Svjetlana B.
AU  - Marković, Mirjana
AU  - Jovanović, Uroš D.
AU  - Gajić-Kvaščev, Maja
AU  - Čokeša, Đuro
AU  - Lilić, Jasmina
PY  - 2020
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/9020
AB  - Part of Cu post flotation tailings of Serbia ZiJin Bor Copper, Serbia, was reclaimed by restoration of top soil with arable soils, and revegetation in 1991. Humic acids isolated from these Technosols were investigated to find out if their properties underwent any changes since reclamation. Two groups of control samples were used. Elemental composition (CHNS analysis) falls within the range of average soil humic acids. Humic acids belong to the type B pointing out to its lower humification degree (UV?Vis). Relative abundances of functional groups are ranged as follows: polysaccharide C ??aromatic C > carboxyl C > OH group > aliphatic C. Aromaticity indexes are low, 1.88? 3.25 (ATR-FTIR). Basic units at pH 10 are in the 11.7?26.8 nm range. Pronounced reaggregation (1462-?5218 nm) at pH 3 points out to less expressed humic acid sol stability, as well as to increase in aromatic condensation degree (dynamic light scattering). No significant changes have occurred in technosol humic acids since the recultivation, confirming stability of their properties over time (PCA). Nevertheless, humic acids from very strongly acidic Technosols show higher humifycation degree possibly originating from arable soils used in reclamation, but more likely from low soil pH and low litter input, results of unsuccessful reclamation.
T2  - Journal of the Serbian Chemical Society
T1  - Properties of humic acids from copper tailings 20 years after reclamation
VL  - 85
IS  - 3
SP  - 407
EP  - 419
DO  - 10.2298/JSC190717112R
ER  - 
@article{
author = "Radmanović, Svjetlana B. and Marković, Mirjana and Jovanović, Uroš D. and Gajić-Kvaščev, Maja and Čokeša, Đuro and Lilić, Jasmina",
year = "2020",
abstract = "Part of Cu post flotation tailings of Serbia ZiJin Bor Copper, Serbia, was reclaimed by restoration of top soil with arable soils, and revegetation in 1991. Humic acids isolated from these Technosols were investigated to find out if their properties underwent any changes since reclamation. Two groups of control samples were used. Elemental composition (CHNS analysis) falls within the range of average soil humic acids. Humic acids belong to the type B pointing out to its lower humification degree (UV?Vis). Relative abundances of functional groups are ranged as follows: polysaccharide C ??aromatic C > carboxyl C > OH group > aliphatic C. Aromaticity indexes are low, 1.88? 3.25 (ATR-FTIR). Basic units at pH 10 are in the 11.7?26.8 nm range. Pronounced reaggregation (1462-?5218 nm) at pH 3 points out to less expressed humic acid sol stability, as well as to increase in aromatic condensation degree (dynamic light scattering). No significant changes have occurred in technosol humic acids since the recultivation, confirming stability of their properties over time (PCA). Nevertheless, humic acids from very strongly acidic Technosols show higher humifycation degree possibly originating from arable soils used in reclamation, but more likely from low soil pH and low litter input, results of unsuccessful reclamation.",
journal = "Journal of the Serbian Chemical Society",
title = "Properties of humic acids from copper tailings 20 years after reclamation",
volume = "85",
number = "3",
pages = "407-419",
doi = "10.2298/JSC190717112R"
}
Radmanović, S. B., Marković, M., Jovanović, U. D., Gajić-Kvaščev, M., Čokeša, Đ.,& Lilić, J.. (2020). Properties of humic acids from copper tailings 20 years after reclamation. in Journal of the Serbian Chemical Society, 85(3), 407-419.
https://doi.org/10.2298/JSC190717112R
Radmanović SB, Marković M, Jovanović UD, Gajić-Kvaščev M, Čokeša Đ, Lilić J. Properties of humic acids from copper tailings 20 years after reclamation. in Journal of the Serbian Chemical Society. 2020;85(3):407-419.
doi:10.2298/JSC190717112R .
Radmanović, Svjetlana B., Marković, Mirjana, Jovanović, Uroš D., Gajić-Kvaščev, Maja, Čokeša, Đuro, Lilić, Jasmina, "Properties of humic acids from copper tailings 20 years after reclamation" in Journal of the Serbian Chemical Society, 85, no. 3 (2020):407-419,
https://doi.org/10.2298/JSC190717112R . .

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