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Apricot kernel shells pyrolysis controlled by non-isothermal simultaneous thermal analysis (STA)

Authorized Users Only
2020
Authors
Manić, Nebojša G.
Janković, Bojan Ž.
Pijović, Milena
Waisi, Hadi
Dodevski, Vladimir
Stojiljković, Dragoslava
Jovanović, Vladimir V.
Article (Published version)
,
© 2020, Akadémiai Kiadó, Budapest, Hungary
Metadata
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Abstract
In order to clarify relationship between apricot kernel shell biomass slow pyrolysis mechanism and its main constituents (viz. hemicelluloses, cellulose and lignin), the reactivity effects of main constituents on pyrolysis characteristics were determined by the non-isothermal simultaneous thermal analysis. It was found that four-step (parallel) reaction model is suitable for studying the slow pyrolysis process, within the semi-global model which excludes the strong interaction between biomass constituents (pseudo-components). The application of the proposed model was allowed by the results obtained from KAS iterative isoconversional (model-free) approach. The valorization of the model was confirmed by the process optimization. The complex (cumulative) apricot kernel shell pyrolysis rate curves at different heating rates are successfully resolved into the individual decomposition rate curves (arising from thermal conversion of hemicelluloses, cellulose, and primary/secondary lignin frag...ments) by four-parameter Fraser–Suzuki function. Besides hemicelluloses and cellulose pyrolyses, the proposed model distinguishes primary and secondary lignin reactions, which enhance the gaseous products releasing (primarily CO and CO2 gases) and charification of the solid residue (increased the bio-char yield). © 2020, Akadémiai Kiadó, Budapest, Hungary.

Keywords:
Slow pyrolysis / Modeling / Apricot wastes / Fraser-Suzuki deconvolution / Iterative isoconversional method
Source:
Journal of Thermal Analysis and Calorimetry, 2020, 142, 2, 565-579
Funding / projects:
  • Photonics of micro and nano structured materials (RS-45010)
  • Dynamics of nonlinear physicochemical and biochemical systems with modeling and predicting of their behavior under nonequilibrium conditions (RS-172015)
  • Hydrogen Energy - Research and Development of New Materials: Electrolytic Hydrogen Production, Hydrogen Fuel Cells, Isotope Effects (RS-172045)
  • Functional, Functionalized and Advanced Nanomaterials (RS-45005)
  • Research and verification of the multidisciplinary forensic methods in (RS-37021)

DOI: 10.1007/s10973-020-09307-5

ISSN: 1388-6150

WoS: 000581102300003

Scopus: 2-s2.0-85078348824
[ Google Scholar ]
11
7
URI
https://vinar.vin.bg.ac.rs/handle/123456789/8904
Collections
  • Radovi istraživača
Institution/Community
Vinča
TY  - JOUR
AU  - Manić, Nebojša G.
AU  - Janković, Bojan Ž.
AU  - Pijović, Milena
AU  - Waisi, Hadi
AU  - Dodevski, Vladimir
AU  - Stojiljković, Dragoslava
AU  - Jovanović, Vladimir V.
PY  - 2020
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/8904
AB  - In order to clarify relationship between apricot kernel shell biomass slow pyrolysis mechanism and its main constituents (viz. hemicelluloses, cellulose and lignin), the reactivity effects of main constituents on pyrolysis characteristics were determined by the non-isothermal simultaneous thermal analysis. It was found that four-step (parallel) reaction model is suitable for studying the slow pyrolysis process, within the semi-global model which excludes the strong interaction between biomass constituents (pseudo-components). The application of the proposed model was allowed by the results obtained from KAS iterative isoconversional (model-free) approach. The valorization of the model was confirmed by the process optimization. The complex (cumulative) apricot kernel shell pyrolysis rate curves at different heating rates are successfully resolved into the individual decomposition rate curves (arising from thermal conversion of hemicelluloses, cellulose, and primary/secondary lignin fragments) by four-parameter Fraser–Suzuki function. Besides hemicelluloses and cellulose pyrolyses, the proposed model distinguishes primary and secondary lignin reactions, which enhance the gaseous products releasing (primarily CO and CO2 gases) and charification of the solid residue (increased the bio-char yield). © 2020, Akadémiai Kiadó, Budapest, Hungary.
T2  - Journal of Thermal Analysis and Calorimetry
T1  - Apricot kernel shells pyrolysis controlled by non-isothermal simultaneous thermal analysis (STA)
VL  - 142
IS  - 2
SP  - 565
EP  - 579
DO  - 10.1007/s10973-020-09307-5
ER  - 
@article{
author = "Manić, Nebojša G. and Janković, Bojan Ž. and Pijović, Milena and Waisi, Hadi and Dodevski, Vladimir and Stojiljković, Dragoslava and Jovanović, Vladimir V.",
year = "2020",
abstract = "In order to clarify relationship between apricot kernel shell biomass slow pyrolysis mechanism and its main constituents (viz. hemicelluloses, cellulose and lignin), the reactivity effects of main constituents on pyrolysis characteristics were determined by the non-isothermal simultaneous thermal analysis. It was found that four-step (parallel) reaction model is suitable for studying the slow pyrolysis process, within the semi-global model which excludes the strong interaction between biomass constituents (pseudo-components). The application of the proposed model was allowed by the results obtained from KAS iterative isoconversional (model-free) approach. The valorization of the model was confirmed by the process optimization. The complex (cumulative) apricot kernel shell pyrolysis rate curves at different heating rates are successfully resolved into the individual decomposition rate curves (arising from thermal conversion of hemicelluloses, cellulose, and primary/secondary lignin fragments) by four-parameter Fraser–Suzuki function. Besides hemicelluloses and cellulose pyrolyses, the proposed model distinguishes primary and secondary lignin reactions, which enhance the gaseous products releasing (primarily CO and CO2 gases) and charification of the solid residue (increased the bio-char yield). © 2020, Akadémiai Kiadó, Budapest, Hungary.",
journal = "Journal of Thermal Analysis and Calorimetry",
title = "Apricot kernel shells pyrolysis controlled by non-isothermal simultaneous thermal analysis (STA)",
volume = "142",
number = "2",
pages = "565-579",
doi = "10.1007/s10973-020-09307-5"
}
Manić, N. G., Janković, B. Ž., Pijović, M., Waisi, H., Dodevski, V., Stojiljković, D.,& Jovanović, V. V.. (2020). Apricot kernel shells pyrolysis controlled by non-isothermal simultaneous thermal analysis (STA). in Journal of Thermal Analysis and Calorimetry, 142(2), 565-579.
https://doi.org/10.1007/s10973-020-09307-5
Manić NG, Janković BŽ, Pijović M, Waisi H, Dodevski V, Stojiljković D, Jovanović VV. Apricot kernel shells pyrolysis controlled by non-isothermal simultaneous thermal analysis (STA). in Journal of Thermal Analysis and Calorimetry. 2020;142(2):565-579.
doi:10.1007/s10973-020-09307-5 .
Manić, Nebojša G., Janković, Bojan Ž., Pijović, Milena, Waisi, Hadi, Dodevski, Vladimir, Stojiljković, Dragoslava, Jovanović, Vladimir V., "Apricot kernel shells pyrolysis controlled by non-isothermal simultaneous thermal analysis (STA)" in Journal of Thermal Analysis and Calorimetry, 142, no. 2 (2020):565-579,
https://doi.org/10.1007/s10973-020-09307-5 . .

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