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Investigation of structural, microstructural and magnetic properties of YbxY1-xF3 solid solutions
dc.creator | Aleksić, Jelena | |
dc.creator | Barudžija, Tanja | |
dc.creator | Jugović, Dragana | |
dc.creator | Mitrić, Miodrag | |
dc.creator | Bošković, Marko | |
dc.creator | Jagličić, Zvonko | |
dc.creator | Lisjak, Darja | |
dc.creator | Kostić, Ljiljana | |
dc.date.accessioned | 2020-12-01T11:45:37Z | |
dc.date.available | 2020-12-01T11:45:37Z | |
dc.date.issued | 2020 | |
dc.identifier.issn | 0022-3697 | |
dc.identifier.uri | https://vinar.vin.bg.ac.rs/handle/123456789/8858 | |
dc.description.abstract | In this investigation, we have synthesized YbxY1-xF3 solid solutions by fluorination of yttrium and ytterbium sesquioxides with ammonium hydrogen difluoride. According to the XRD analysis, all synthesized YbxY1-xF3 samples have an orthorhombic crystal structure belonging to the β-YF3 structural type. The refinement of crystal structure was done by the Rietveld method within the Pnma space group using the TCH pseudo-Voigt function. The anisotropic peak broadening was analyzed, and the average apparent crystallite size is about 50 nm with a small anisotropy of shape, while the significant microstrain that is highly anisotropic is present in all samples. The temperature-dependent magnetic susceptibility was analyzed by applying the model of a free ion perturbed by the crystal field. We have obtained the effective magnetic quantum numbers Mieff of four Kramer's doublets of Yb3+ ion along with the entire crystal field splitting of the 2F7/2 manifold of Yb3+ in YF3. The acquired maximum energy splitting of the ground level is about 150 K in our most diluted samples. The field-dependent isothermal magnetization measurements were carried out at various temperatures and analyzed by classical Langevin function. Results obtained from magnetic measurements show that all YbxY1-xF3 (x ≠ 0) solid solutions exhibit pure paramagnetic behavior in the whole temperature range from 2 to 300 K, with a predominant antiferromagnetic exchange interactions. © 2020 Elsevier Ltd | en |
dc.language.iso | en | |
dc.relation | info:eu-repo/grantAgreement/MESTD/Integrated and Interdisciplinary Research (IIR or III)/45015/RS// | |
dc.relation | info:eu-repo/grantAgreement/MESTD/Integrated and Interdisciplinary Research (IIR or III)/45004/RS// | |
dc.relation | info:eu-repo/grantAgreement/MESTD/Basic Research (BR or ON)/171025/RS// | |
dc.relation | info:eu-repo/grantAgreement/MESTD/Technological Development (TD or TR)/32026/RS// | |
dc.relation | Bilateral Serbia-Slovenia [06-00-118/2018-09/32/02] | |
dc.relation | Bilateral Serbia-Slovenia [BI-RS/18-19-031] | |
dc.relation | Slovenian Research Agency [P2-0089] | |
dc.rights | restrictedAccess | |
dc.source | Journal of Physics and Chemistry of Solids | |
dc.subject | Rare-earth fluorides | en |
dc.subject | Crystal and ligand fields | en |
dc.subject | X-ray diffraction | en |
dc.subject | Magnetic measurements | en |
dc.title | Investigation of structural, microstructural and magnetic properties of YbxY1-xF3 solid solutions | en |
dc.type | article | en |
dc.rights.license | ARR | |
dcterms.abstract | Митрић, Миодраг; Бошковић, Марко; Јагличић, Звонко; Баруджија, Тања; Лисјак, Дарја; Костић, Љиљана; Aлексић, Јелена; Југовић, Драгана; | |
dc.rights.holder | © 2020 Elsevier Ltd. | |
dc.citation.volume | 142 | |
dc.citation.spage | 109449 | |
dc.identifier.wos | 000528271700008 | |
dc.identifier.doi | 10.1016/j.jpcs.2020.109449 | |
dc.citation.rank | M22 | |
dc.type.version | publishedVersion | |
dc.identifier.scopus | 2-s2.0-85081116825 |
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