Detection of Dimethoate Pesticide using Layer by Layer Deposition of PDAC/GO on Ag electrode

Ega, Tharun K; Al-Hamry, Ammar; Kanoun, Olfa; Lazarević-Pašti, Tamara; Bogdanović, Danica B.; Pašti, Igor A.; Rodriguez, Raul D.; Sheremet, Evgeniya; Paterno, Leonardo G.

doi:10.1109/SSD.2019.8893253

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Authors

Ega, Tharun K
Al-Hamry, Ammar
Kanoun, Olfa
Lazarević-Pašti, Tamara

Bogdanović, Danica B.
Pašti, Igor A.

Rodriguez, Raul D.

Sheremet, Evgeniya
Paterno, Leonardo G.

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Abstract

Dimethoate (DMT) is an organophosphate pesticide (OP), which is widely used against insects and mites and their control in agriculture. As other OPs, DMT is also an inhibitor of acetylcholinesterase, which is responsible for the disabling of cholinesterase required for the functioning of the central nervous system. This pesticide can invade living cells of the human body through contact or ingestion. We report an electrochemical sensor based on a layer by layer deposition of PDAC/GO on silver electrodes. The sensor fabrication, physical characterization i.e. Raman spectroscopy and scanning electron microscopy of PDAC/GO based films, and its electrochemical characterization are discussed. The detection of DMT by analyzing electrochemical measurements including cyclic voltammetry and impedance spectroscopy shows that functionalization using layer by layer deposition improves electrochemical response and presents a basis for detection of DMT. The highest response is observed in the case o...

Keywords:

cyclic voltammetry / electrochemical sensor / graphene oxide / impedance spectroscopy / Pesticide detection

Source:
2019 16th International Multi-Conference on Systems, Signals & Devices (SSD), 2019, 621-625

Publisher:

IEEE

Funding / projects:

Bilateral project Germany-Serbia, funded by DAAD [Theoretical and experimental development of novel sensor based on graphene composites for the detection of organophosphate pesticides (SeGraPhos)]
Sächsische Aufbaubank (SAB) and the European Social Fund (ESF) - InnoTeam-SimplySafe [100331073]
Studies of enzyme interactions with toxic and pharmacologically active molecules (RS-172023)
Lithium-ion batteries and fuel cells - research and development (RS-45014)
Tomsk Polytechnic University Competitiveness Enhancement Program

Note:

Conference of 16th International Multi-Conference on Systems, Signals and Devices, SSD 2019 ; Conference Date: 21 March 2019 Through 24 March 2019; Conference Code:154292

DOI: 10.1109/SSD.2019.8893253

ISBN: 978-1-7281-1820-8

Scopus: 2-s2.0-85075630055

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	2

TY - CONF
AU - Ega, Tharun K
AU - Al-Hamry, Ammar
AU - Kanoun, Olfa
AU - Lazarević-Pašti, Tamara
AU - Bogdanović, Danica B.
AU - Pašti, Igor A.
AU - Rodriguez, Raul D.
AU - Sheremet, Evgeniya
AU - Paterno, Leonardo G.
PY - 2019
UR - https://vinar.vin.bg.ac.rs/handle/123456789/8665
AB - Dimethoate (DMT) is an organophosphate pesticide (OP), which is widely used against insects and mites and their control in agriculture. As other OPs, DMT is also an inhibitor of acetylcholinesterase, which is responsible for the disabling of cholinesterase required for the functioning of the central nervous system. This pesticide can invade living cells of the human body through contact or ingestion. We report an electrochemical sensor based on a layer by layer deposition of PDAC/GO on silver electrodes. The sensor fabrication, physical characterization i.e. Raman spectroscopy and scanning electron microscopy of PDAC/GO based films, and its electrochemical characterization are discussed. The detection of DMT by analyzing electrochemical measurements including cyclic voltammetry and impedance spectroscopy shows that functionalization using layer by layer deposition improves electrochemical response and presents a basis for detection of DMT. The highest response is observed in the case of only one PDAC/GO layer which is attributed to the properly balanced interaction between DMT and PDAC/GO layer, and the increase of electrical resistivity of the PDAC/GO layer with its thickness. © 2019 IEEE.
PB - IEEE
C3 - 2019 16th International Multi-Conference on Systems, Signals & Devices (SSD)
C3 - 2019 16th International Multi-Conference on Systems, Signals & Devices (SSD)
T1 - Detection of Dimethoate Pesticide using Layer by Layer Deposition of PDAC/GO on Ag electrode
SP - 621
EP - 625
DO - 10.1109/SSD.2019.8893253
ER -

@conference{
author = "Ega, Tharun K and Al-Hamry, Ammar and Kanoun, Olfa and Lazarević-Pašti, Tamara and Bogdanović, Danica B. and Pašti, Igor A. and Rodriguez, Raul D. and Sheremet, Evgeniya and Paterno, Leonardo G.",
year = "2019",
abstract = "Dimethoate (DMT) is an organophosphate pesticide (OP), which is widely used against insects and mites and their control in agriculture. As other OPs, DMT is also an inhibitor of acetylcholinesterase, which is responsible for the disabling of cholinesterase required for the functioning of the central nervous system. This pesticide can invade living cells of the human body through contact or ingestion. We report an electrochemical sensor based on a layer by layer deposition of PDAC/GO on silver electrodes. The sensor fabrication, physical characterization i.e. Raman spectroscopy and scanning electron microscopy of PDAC/GO based films, and its electrochemical characterization are discussed. The detection of DMT by analyzing electrochemical measurements including cyclic voltammetry and impedance spectroscopy shows that functionalization using layer by layer deposition improves electrochemical response and presents a basis for detection of DMT. The highest response is observed in the case of only one PDAC/GO layer which is attributed to the properly balanced interaction between DMT and PDAC/GO layer, and the increase of electrical resistivity of the PDAC/GO layer with its thickness. © 2019 IEEE.",
publisher = "IEEE",
journal = "2019 16th International Multi-Conference on Systems, Signals & Devices (SSD), 2019 16th International Multi-Conference on Systems, Signals & Devices (SSD)",
title = "Detection of Dimethoate Pesticide using Layer by Layer Deposition of PDAC/GO on Ag electrode",
pages = "621-625",
doi = "10.1109/SSD.2019.8893253"
}

Ega, T. K., Al-Hamry, A., Kanoun, O., Lazarević-Pašti, T., Bogdanović, D. B., Pašti, I. A., Rodriguez, R. D., Sheremet, E.,& Paterno, L. G.. (2019). Detection of Dimethoate Pesticide using Layer by Layer Deposition of PDAC/GO on Ag electrode. in 2019 16th International Multi-Conference on Systems, Signals & Devices (SSD)
IEEE., 621-625.
https://doi.org/10.1109/SSD.2019.8893253

Ega TK, Al-Hamry A, Kanoun O, Lazarević-Pašti T, Bogdanović DB, Pašti IA, Rodriguez RD, Sheremet E, Paterno LG. Detection of Dimethoate Pesticide using Layer by Layer Deposition of PDAC/GO on Ag electrode. in 2019 16th International Multi-Conference on Systems, Signals & Devices (SSD). 2019;:621-625.
doi:10.1109/SSD.2019.8893253 .

Ega, Tharun K, Al-Hamry, Ammar, Kanoun, Olfa, Lazarević-Pašti, Tamara, Bogdanović, Danica B., Pašti, Igor A., Rodriguez, Raul D., Sheremet, Evgeniya, Paterno, Leonardo G., "Detection of Dimethoate Pesticide using Layer by Layer Deposition of PDAC/GO on Ag electrode" in 2019 16th International Multi-Conference on Systems, Signals & Devices (SSD) (2019):621-625,
https://doi.org/10.1109/SSD.2019.8893253 . .