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The Applications of New Inorganic Polymer for Adsorption Cadmium from Waste Water

Authorized Users Only
2020
Authors
Mladenović, Nataša
Kljajević, Ljiljana M.
Nenadović, Snežana S.
Ivanović, Marija M.
Čalija, Bojan
Gulicovski, Jelena J.
Trivunac, Katarina V.
Article (Published version)
,
© 2019, Springer Science+Business Media, LLC, part of Springer Nature
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Abstract
Fundamental research of inorganic polymers prepared from available aluminosilicate precursors represent an innovative class of materials characterized by low energy consumption for production. This is just one of the reasons why their use is focused in protecting the environment for removing of heavy metals from aqueous solutions. The concentration of hydroxide as activator solution plays an important role in the geopolymerization process. The present study examined the use of geopolymer materials, obtained in reaction of geopolymerizations of metakaolin as precursor activated with NaOH concentration 2.0, 4.0, 6.0 and 8.0 mol/dm3 for removal of cadmium ions from aqueous solutions. The structure and properties of the obtained geopolymer samples were studied by X-ray diffraction (XRD), scanning electron microscopy (SEM) and diffuse reflection infrared spectroscopy (DRIFTS). To investigate the surface charge of geopolymers the zeta potential measurements were performed. Batch adsorption e...xperiments conducted at room temperature (23 ± 1 °C) showed that the adsorption pattern followed the Freundlich isotherm model. The maximum removal of cadmium obtained from batch studies was 84.1% for GP6M at pH ≈ 6.7. The results generally showed that geopolymer samples could be considered as a potential adsorbent for cadmium removal from aqueous solutions. © 2019, Springer Science+Business Media, LLC, part of Springer Nature.

Keywords:
Geopolymer / DRIFT / Chemical properties / Functional applications / Freundlich isotherm model
Source:
Journal of Inorganic and Organometallic Polymers and Materials, 2020, 30, 2, 554-563
Funding / projects:
  • Synthesis, processing and characterization of nanostructured materials for application in the field of energy, mechanical engineering, environmental protection and biomedicine (RS-45012)
  • Development and Application of Methods and Materials for Monitoring New Organic Contaminants, Toxic Compounds and Heavy Metals (RS-172007)

DOI: 10.1007/s10904-019-01215-y

ISSN: 1574-1443

WoS: 000519151600029

Scopus: 2-s2.0-85067236118
[ Google Scholar ]
16
7
URI
https://vinar.vin.bg.ac.rs/handle/123456789/8561
Collections
  • Radovi istraživača
Institution/Community
Vinča
TY  - JOUR
AU  - Mladenović, Nataša
AU  - Kljajević, Ljiljana M.
AU  - Nenadović, Snežana S.
AU  - Ivanović, Marija M.
AU  - Čalija, Bojan
AU  - Gulicovski, Jelena J.
AU  - Trivunac, Katarina V.
PY  - 2020
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/8561
AB  - Fundamental research of inorganic polymers prepared from available aluminosilicate precursors represent an innovative class of materials characterized by low energy consumption for production. This is just one of the reasons why their use is focused in protecting the environment for removing of heavy metals from aqueous solutions. The concentration of hydroxide as activator solution plays an important role in the geopolymerization process. The present study examined the use of geopolymer materials, obtained in reaction of geopolymerizations of metakaolin as precursor activated with NaOH concentration 2.0, 4.0, 6.0 and 8.0 mol/dm3 for removal of cadmium ions from aqueous solutions. The structure and properties of the obtained geopolymer samples were studied by X-ray diffraction (XRD), scanning electron microscopy (SEM) and diffuse reflection infrared spectroscopy (DRIFTS). To investigate the surface charge of geopolymers the zeta potential measurements were performed. Batch adsorption experiments conducted at room temperature (23 ± 1 °C) showed that the adsorption pattern followed the Freundlich isotherm model. The maximum removal of cadmium obtained from batch studies was 84.1% for GP6M at pH ≈ 6.7. The results generally showed that geopolymer samples could be considered as a potential adsorbent for cadmium removal from aqueous solutions. © 2019, Springer Science+Business Media, LLC, part of Springer Nature.
T2  - Journal of Inorganic and Organometallic Polymers and Materials
T1  - The Applications of New Inorganic Polymer for Adsorption Cadmium from Waste Water
VL  - 30
IS  - 2
SP  - 554
EP  - 563
DO  - 10.1007/s10904-019-01215-y
ER  - 
@article{
author = "Mladenović, Nataša and Kljajević, Ljiljana M. and Nenadović, Snežana S. and Ivanović, Marija M. and Čalija, Bojan and Gulicovski, Jelena J. and Trivunac, Katarina V.",
year = "2020",
abstract = "Fundamental research of inorganic polymers prepared from available aluminosilicate precursors represent an innovative class of materials characterized by low energy consumption for production. This is just one of the reasons why their use is focused in protecting the environment for removing of heavy metals from aqueous solutions. The concentration of hydroxide as activator solution plays an important role in the geopolymerization process. The present study examined the use of geopolymer materials, obtained in reaction of geopolymerizations of metakaolin as precursor activated with NaOH concentration 2.0, 4.0, 6.0 and 8.0 mol/dm3 for removal of cadmium ions from aqueous solutions. The structure and properties of the obtained geopolymer samples were studied by X-ray diffraction (XRD), scanning electron microscopy (SEM) and diffuse reflection infrared spectroscopy (DRIFTS). To investigate the surface charge of geopolymers the zeta potential measurements were performed. Batch adsorption experiments conducted at room temperature (23 ± 1 °C) showed that the adsorption pattern followed the Freundlich isotherm model. The maximum removal of cadmium obtained from batch studies was 84.1% for GP6M at pH ≈ 6.7. The results generally showed that geopolymer samples could be considered as a potential adsorbent for cadmium removal from aqueous solutions. © 2019, Springer Science+Business Media, LLC, part of Springer Nature.",
journal = "Journal of Inorganic and Organometallic Polymers and Materials",
title = "The Applications of New Inorganic Polymer for Adsorption Cadmium from Waste Water",
volume = "30",
number = "2",
pages = "554-563",
doi = "10.1007/s10904-019-01215-y"
}
Mladenović, N., Kljajević, L. M., Nenadović, S. S., Ivanović, M. M., Čalija, B., Gulicovski, J. J.,& Trivunac, K. V.. (2020). The Applications of New Inorganic Polymer for Adsorption Cadmium from Waste Water. in Journal of Inorganic and Organometallic Polymers and Materials, 30(2), 554-563.
https://doi.org/10.1007/s10904-019-01215-y
Mladenović N, Kljajević LM, Nenadović SS, Ivanović MM, Čalija B, Gulicovski JJ, Trivunac KV. The Applications of New Inorganic Polymer for Adsorption Cadmium from Waste Water. in Journal of Inorganic and Organometallic Polymers and Materials. 2020;30(2):554-563.
doi:10.1007/s10904-019-01215-y .
Mladenović, Nataša, Kljajević, Ljiljana M., Nenadović, Snežana S., Ivanović, Marija M., Čalija, Bojan, Gulicovski, Jelena J., Trivunac, Katarina V., "The Applications of New Inorganic Polymer for Adsorption Cadmium from Waste Water" in Journal of Inorganic and Organometallic Polymers and Materials, 30, no. 2 (2020):554-563,
https://doi.org/10.1007/s10904-019-01215-y . .

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