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Physico-chemical characterization of carbonized apricot kernel shell as precursor for activated carbon preparation in clean technology utilization

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Authors
Janković, Bojan Ž.
Manić, Nebojša G.
Dodevski, Vladimir
Radović, Ivana M.
Pijović, Milena
Katnić, Đurica B.
Tasić, Gvozden S.
Article (Published version)
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© 2019 Elsevier Ltd
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Abstract
This paper investigates the ability of waste apricot (Prunus armeniaca) kernel shells (AKS) bio-char prepared by single-step carbonization process at 850 °C (residence time of 1 h) for possible removal of toxic elements and organic micro-pollutants. The experiment that was performed as well as parameters used proved to be optimal for bio-char production as adsorbing medium, where last issue is validated by multiform material characterization techniques. It has been shown that the produced bio-char possess highly-porous morphology features, with large specific surface area (328.570 m2 g−1). The obtained product was characterized by various pore sizes (including super-micropores and mesopores with maximum pore size of 2.24 nm) structures. Preliminary results are indicated that obtained bio-char can shows increased affinity to possible adsorption of the small organic molecule contaminants upgraded by its physico-chemical properties. Cost estimation of AKS bio-char production substantiated... its cost effectiveness and its good physical and chemical properties for future design in batch adsorption and regeneration tests. It was established that AKS produced bio-char was 2.5 times cheaper than the commercially available activated carbon. Bio-char exhibits promising removal performances for potential adsorption of heavy metal and organic micro-pollutants from wastewaters systems, as indicated by material textures and spectroscopy measurements. © 2019 Elsevier Ltd

Keywords:
Bio-char / Carbonization / Hydrophobic surface / Adsorbing medium / Wastewater systems
Source:
Journal of Cleaner Production, 2019, 236, 117614-
Funding / projects:
  • Dynamics of nonlinear physicochemical and biochemical systems with modeling and predicting of their behavior under nonequilibrium conditions (RS-172015)
  • Hydrogen Energy - Research and Development of New Materials: Electrolytic Hydrogen Production, Hydrogen Fuel Cells, Isotope Effects (RS-172045)
  • Pollution Reduction from Thermal Power Plants of the Public Enterprise “Electric Power Industry of Serbia” (RS-42010)
  • Functional, Functionalized and Advanced Nanomaterials (RS-45005)
  • Predefined functional properties polymer composite materials processes and equipment development (RS-34011)

DOI: 10.1016/j.jclepro.2019.117614

ISSN: 0959-6526; 1879-1786

WoS: 000483414000072

Scopus: 2-s2.0-85068844807
[ Google Scholar ]
40
12
URI
https://vinar.vin.bg.ac.rs/handle/123456789/8393
Collections
  • Radovi istraživača
Institution/Community
Vinča
TY  - JOUR
AU  - Janković, Bojan Ž.
AU  - Manić, Nebojša G.
AU  - Dodevski, Vladimir
AU  - Radović, Ivana M.
AU  - Pijović, Milena
AU  - Katnić, Đurica B.
AU  - Tasić, Gvozden S.
PY  - 2019
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/8393
AB  - This paper investigates the ability of waste apricot (Prunus armeniaca) kernel shells (AKS) bio-char prepared by single-step carbonization process at 850 °C (residence time of 1 h) for possible removal of toxic elements and organic micro-pollutants. The experiment that was performed as well as parameters used proved to be optimal for bio-char production as adsorbing medium, where last issue is validated by multiform material characterization techniques. It has been shown that the produced bio-char possess highly-porous morphology features, with large specific surface area (328.570 m2 g−1). The obtained product was characterized by various pore sizes (including super-micropores and mesopores with maximum pore size of 2.24 nm) structures. Preliminary results are indicated that obtained bio-char can shows increased affinity to possible adsorption of the small organic molecule contaminants upgraded by its physico-chemical properties. Cost estimation of AKS bio-char production substantiated its cost effectiveness and its good physical and chemical properties for future design in batch adsorption and regeneration tests. It was established that AKS produced bio-char was 2.5 times cheaper than the commercially available activated carbon. Bio-char exhibits promising removal performances for potential adsorption of heavy metal and organic micro-pollutants from wastewaters systems, as indicated by material textures and spectroscopy measurements. © 2019 Elsevier Ltd
T2  - Journal of Cleaner Production
T1  - Physico-chemical characterization of carbonized apricot kernel shell as precursor for activated carbon preparation in clean technology utilization
VL  - 236
SP  - 117614
DO  - 10.1016/j.jclepro.2019.117614
ER  - 
@article{
author = "Janković, Bojan Ž. and Manić, Nebojša G. and Dodevski, Vladimir and Radović, Ivana M. and Pijović, Milena and Katnić, Đurica B. and Tasić, Gvozden S.",
year = "2019",
abstract = "This paper investigates the ability of waste apricot (Prunus armeniaca) kernel shells (AKS) bio-char prepared by single-step carbonization process at 850 °C (residence time of 1 h) for possible removal of toxic elements and organic micro-pollutants. The experiment that was performed as well as parameters used proved to be optimal for bio-char production as adsorbing medium, where last issue is validated by multiform material characterization techniques. It has been shown that the produced bio-char possess highly-porous morphology features, with large specific surface area (328.570 m2 g−1). The obtained product was characterized by various pore sizes (including super-micropores and mesopores with maximum pore size of 2.24 nm) structures. Preliminary results are indicated that obtained bio-char can shows increased affinity to possible adsorption of the small organic molecule contaminants upgraded by its physico-chemical properties. Cost estimation of AKS bio-char production substantiated its cost effectiveness and its good physical and chemical properties for future design in batch adsorption and regeneration tests. It was established that AKS produced bio-char was 2.5 times cheaper than the commercially available activated carbon. Bio-char exhibits promising removal performances for potential adsorption of heavy metal and organic micro-pollutants from wastewaters systems, as indicated by material textures and spectroscopy measurements. © 2019 Elsevier Ltd",
journal = "Journal of Cleaner Production",
title = "Physico-chemical characterization of carbonized apricot kernel shell as precursor for activated carbon preparation in clean technology utilization",
volume = "236",
pages = "117614",
doi = "10.1016/j.jclepro.2019.117614"
}
Janković, B. Ž., Manić, N. G., Dodevski, V., Radović, I. M., Pijović, M., Katnić, Đ. B.,& Tasić, G. S.. (2019). Physico-chemical characterization of carbonized apricot kernel shell as precursor for activated carbon preparation in clean technology utilization. in Journal of Cleaner Production, 236, 117614.
https://doi.org/10.1016/j.jclepro.2019.117614
Janković BŽ, Manić NG, Dodevski V, Radović IM, Pijović M, Katnić ĐB, Tasić GS. Physico-chemical characterization of carbonized apricot kernel shell as precursor for activated carbon preparation in clean technology utilization. in Journal of Cleaner Production. 2019;236:117614.
doi:10.1016/j.jclepro.2019.117614 .
Janković, Bojan Ž., Manić, Nebojša G., Dodevski, Vladimir, Radović, Ivana M., Pijović, Milena, Katnić, Đurica B., Tasić, Gvozden S., "Physico-chemical characterization of carbonized apricot kernel shell as precursor for activated carbon preparation in clean technology utilization" in Journal of Cleaner Production, 236 (2019):117614,
https://doi.org/10.1016/j.jclepro.2019.117614 . .

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