Synthesis, structural and DFT analysis of a binuclear nickel(II) complex with the 1,4-bis[2-[2-(diphenylphosphino)benzylidene]]phthalazinylhydrazone ligand
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2019
Authors
Perić, Marko R.
Kyne, Sara H.
Gruden, Maja

Rodić, Marko V.

Jeremić, Dejan

Stanković, Dalibor M.

Brčeski, Ilija

Article (Published version)

© 2019, Springer-Verlag GmbH Austria, part of Springer Nature
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In this work we present the synthesis, and experimental and theoretical analysis of a binuclear nickel(II) complex coordinated to a new phthalazine dihydrazone-based ligand. Single-crystal X-ray diffraction analysis of the metal complex shows that the coordination geometry around each nickel(II) atom is distorted octahedral. DFT calculations predict that the magnetic exchange coupling constant of the binuclear nickel(II) complex is predominantly anti-ferromagnetic.
Keywords:
Binuclear complex / Density functional theory / Magnetic properties / X-ray structure determinationSource:
Monatshefte fur Chemie, 2019, 150, 7, 1241-1248Funding / projects:
- Rational design and synthesis of biologically active and coordination compounds and functional materials, relevant for (bio)nanotechnology (RS-172035)
- Structure-properties relationships of natural and synthetic molecules and their metal complexes (RS-172017)
- Strengthening of the MagBioVin Research and Innovation Team for Development of Novel Approaches for Tumour Therapy based on Nanostructured Materials (EU-621375)
Note:
- Supplementary material: http://cherry.chem.bg.ac.rs/handle/123456789/3317
DOI: 10.1007/s00706-019-02405-7
ISSN: 0026-9247
WoS: 000475674200009
Scopus: 2-s2.0-85068563687
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VinčaTY - JOUR AU - Perić, Marko R. AU - Kyne, Sara H. AU - Gruden, Maja AU - Rodić, Marko V. AU - Jeremić, Dejan AU - Stanković, Dalibor M. AU - Brčeski, Ilija PY - 2019 UR - https://vinar.vin.bg.ac.rs/handle/123456789/8381 AB - In this work we present the synthesis, and experimental and theoretical analysis of a binuclear nickel(II) complex coordinated to a new phthalazine dihydrazone-based ligand. Single-crystal X-ray diffraction analysis of the metal complex shows that the coordination geometry around each nickel(II) atom is distorted octahedral. DFT calculations predict that the magnetic exchange coupling constant of the binuclear nickel(II) complex is predominantly anti-ferromagnetic. T2 - Monatshefte fur Chemie T1 - Synthesis, structural and DFT analysis of a binuclear nickel(II) complex with the 1,4-bis[2-[2-(diphenylphosphino)benzylidene]]phthalazinylhydrazone ligand VL - 150 IS - 7 SP - 1241 EP - 1248 DO - 10.1007/s00706-019-02405-7 ER -
@article{ author = "Perić, Marko R. and Kyne, Sara H. and Gruden, Maja and Rodić, Marko V. and Jeremić, Dejan and Stanković, Dalibor M. and Brčeski, Ilija", year = "2019", abstract = "In this work we present the synthesis, and experimental and theoretical analysis of a binuclear nickel(II) complex coordinated to a new phthalazine dihydrazone-based ligand. Single-crystal X-ray diffraction analysis of the metal complex shows that the coordination geometry around each nickel(II) atom is distorted octahedral. DFT calculations predict that the magnetic exchange coupling constant of the binuclear nickel(II) complex is predominantly anti-ferromagnetic.", journal = "Monatshefte fur Chemie", title = "Synthesis, structural and DFT analysis of a binuclear nickel(II) complex with the 1,4-bis[2-[2-(diphenylphosphino)benzylidene]]phthalazinylhydrazone ligand", volume = "150", number = "7", pages = "1241-1248", doi = "10.1007/s00706-019-02405-7" }
Perić, M. R., Kyne, S. H., Gruden, M., Rodić, M. V., Jeremić, D., Stanković, D. M.,& Brčeski, I.. (2019). Synthesis, structural and DFT analysis of a binuclear nickel(II) complex with the 1,4-bis[2-[2-(diphenylphosphino)benzylidene]]phthalazinylhydrazone ligand. in Monatshefte fur Chemie, 150(7), 1241-1248. https://doi.org/10.1007/s00706-019-02405-7
Perić MR, Kyne SH, Gruden M, Rodić MV, Jeremić D, Stanković DM, Brčeski I. Synthesis, structural and DFT analysis of a binuclear nickel(II) complex with the 1,4-bis[2-[2-(diphenylphosphino)benzylidene]]phthalazinylhydrazone ligand. in Monatshefte fur Chemie. 2019;150(7):1241-1248. doi:10.1007/s00706-019-02405-7 .
Perić, Marko R., Kyne, Sara H., Gruden, Maja, Rodić, Marko V., Jeremić, Dejan, Stanković, Dalibor M., Brčeski, Ilija, "Synthesis, structural and DFT analysis of a binuclear nickel(II) complex with the 1,4-bis[2-[2-(diphenylphosphino)benzylidene]]phthalazinylhydrazone ligand" in Monatshefte fur Chemie, 150, no. 7 (2019):1241-1248, https://doi.org/10.1007/s00706-019-02405-7 . .