Interactions of acidic soil near copper mining and smelting complex and waste-derived alkaline additives
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2019
Authors
Egerić, MarijaSmičiklas, Ivana D.
Dojčinović, Biljana P.
Sikirić, Biljana
Jović, Mihajlo D.
Šljivić-Ivanović, Marija Z.
Čakmak, Dragan
Article (Published version)
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© 2019 Elsevier B.V.
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Liming is a common practice in the treatment of acidic and metal contaminated soils, aiming at pH regulation, enhancing of the nutrient availability and attenuation of trace metals mobility. Replacement of natural limestone with alternative soil alkalizers found among waste materials represents a step towards sustainable resource management and reduced waste storage. In this study, waste seashells (SW) and red mud (RM) were applied in different doses to the soil sampled in the vicinity of mining and smelting complex. The soil was characterized by acidic reaction (pH 4.93), increased Cu concentration (219.2 mg/kg) and a very low level of P-supply (3.61 mg P2O5/100 g). The study aimed to quantify and compare additive-induced effects onto soil physicochemical properties, the status of macronutrients and distribution of trace metals. Targeted effect on soil pH was achieved with SW dose of 0.3% and RM dose of 2%. RM was found to be a source of available P and gave rise to the available P co...ncentrations in the soil. Medium level of P-supply (15.60 mg P2O5/100 g) was achieved with RM dose of 5%, however, the increase in soil salinity and total trace elements concentrations have become significant adverse effects at such dose. The decrease in the ion-exchangeable content of Cu and other trace metals was in correlation with the increase in soil pH after the treatments. Redistribution of metal cations was mainly directed to carbonate/acid soluble and Fe, Mn-oxide bonded fraction after SW addition. Even though trace metals concentration has increased in the soil after application of the RM, they were principally found in the residual fraction. The results emphasize low amounts of contained trace elements and lower doses for achieving targeted effects on pH and metal mobility as the main benefits of SW treatments. On the other hand, moderate and controlled use of RM may represent multiple benefits in terms of simultaneous pH regulation, P-supply, and reduced trace metals mobility. © 2019 Elsevier B.V.
Keywords:
Acidic soil / Remediation / Waste recycling / Red mud / Seashell wasteSource:
Geoderma, 2019, 352, 241-250Funding / projects:
- Advanced technologies for monitoring and environmental protection from chemical pollutants and radiation burden (RS-MESTD-Integrated and Interdisciplinary Research (IIR or III)-43009)
- Study of the effects of soil and irrigation water quality on more efficient agricultural crop production and environment protection (RS-MESTD-Technological Development (TD or TR)-37006)
- Ecophysiological adaptive strategies of plants in conditions of multiple stress (RS-MESTD-Basic Research (BR or ON)-173018)
Note:
- Peer-reviewed version of the article (Accepted Manuscript or postprint) available at: https://vinar.vin.bg.ac.rs/handle/123456789/8368
DOI: 10.1016/j.geoderma.2019.06.015
ISSN: 0016-7061
WoS: 000485207300024
Scopus: 2-s2.0-85067396931
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VinčaTY - JOUR AU - Egerić, Marija AU - Smičiklas, Ivana D. AU - Dojčinović, Biljana P. AU - Sikirić, Biljana AU - Jović, Mihajlo D. AU - Šljivić-Ivanović, Marija Z. AU - Čakmak, Dragan PY - 2019 UR - https://vinar.vin.bg.ac.rs/handle/123456789/8345 AB - Liming is a common practice in the treatment of acidic and metal contaminated soils, aiming at pH regulation, enhancing of the nutrient availability and attenuation of trace metals mobility. Replacement of natural limestone with alternative soil alkalizers found among waste materials represents a step towards sustainable resource management and reduced waste storage. In this study, waste seashells (SW) and red mud (RM) were applied in different doses to the soil sampled in the vicinity of mining and smelting complex. The soil was characterized by acidic reaction (pH 4.93), increased Cu concentration (219.2 mg/kg) and a very low level of P-supply (3.61 mg P2O5/100 g). The study aimed to quantify and compare additive-induced effects onto soil physicochemical properties, the status of macronutrients and distribution of trace metals. Targeted effect on soil pH was achieved with SW dose of 0.3% and RM dose of 2%. RM was found to be a source of available P and gave rise to the available P concentrations in the soil. Medium level of P-supply (15.60 mg P2O5/100 g) was achieved with RM dose of 5%, however, the increase in soil salinity and total trace elements concentrations have become significant adverse effects at such dose. The decrease in the ion-exchangeable content of Cu and other trace metals was in correlation with the increase in soil pH after the treatments. Redistribution of metal cations was mainly directed to carbonate/acid soluble and Fe, Mn-oxide bonded fraction after SW addition. Even though trace metals concentration has increased in the soil after application of the RM, they were principally found in the residual fraction. The results emphasize low amounts of contained trace elements and lower doses for achieving targeted effects on pH and metal mobility as the main benefits of SW treatments. On the other hand, moderate and controlled use of RM may represent multiple benefits in terms of simultaneous pH regulation, P-supply, and reduced trace metals mobility. © 2019 Elsevier B.V. T2 - Geoderma T1 - Interactions of acidic soil near copper mining and smelting complex and waste-derived alkaline additives VL - 352 SP - 241 EP - 250 DO - 10.1016/j.geoderma.2019.06.015 ER -
@article{ author = "Egerić, Marija and Smičiklas, Ivana D. and Dojčinović, Biljana P. and Sikirić, Biljana and Jović, Mihajlo D. and Šljivić-Ivanović, Marija Z. and Čakmak, Dragan", year = "2019", abstract = "Liming is a common practice in the treatment of acidic and metal contaminated soils, aiming at pH regulation, enhancing of the nutrient availability and attenuation of trace metals mobility. Replacement of natural limestone with alternative soil alkalizers found among waste materials represents a step towards sustainable resource management and reduced waste storage. In this study, waste seashells (SW) and red mud (RM) were applied in different doses to the soil sampled in the vicinity of mining and smelting complex. The soil was characterized by acidic reaction (pH 4.93), increased Cu concentration (219.2 mg/kg) and a very low level of P-supply (3.61 mg P2O5/100 g). The study aimed to quantify and compare additive-induced effects onto soil physicochemical properties, the status of macronutrients and distribution of trace metals. Targeted effect on soil pH was achieved with SW dose of 0.3% and RM dose of 2%. RM was found to be a source of available P and gave rise to the available P concentrations in the soil. Medium level of P-supply (15.60 mg P2O5/100 g) was achieved with RM dose of 5%, however, the increase in soil salinity and total trace elements concentrations have become significant adverse effects at such dose. The decrease in the ion-exchangeable content of Cu and other trace metals was in correlation with the increase in soil pH after the treatments. Redistribution of metal cations was mainly directed to carbonate/acid soluble and Fe, Mn-oxide bonded fraction after SW addition. Even though trace metals concentration has increased in the soil after application of the RM, they were principally found in the residual fraction. The results emphasize low amounts of contained trace elements and lower doses for achieving targeted effects on pH and metal mobility as the main benefits of SW treatments. On the other hand, moderate and controlled use of RM may represent multiple benefits in terms of simultaneous pH regulation, P-supply, and reduced trace metals mobility. © 2019 Elsevier B.V.", journal = "Geoderma", title = "Interactions of acidic soil near copper mining and smelting complex and waste-derived alkaline additives", volume = "352", pages = "241-250", doi = "10.1016/j.geoderma.2019.06.015" }
Egerić, M., Smičiklas, I. D., Dojčinović, B. P., Sikirić, B., Jović, M. D., Šljivić-Ivanović, M. Z.,& Čakmak, D.. (2019). Interactions of acidic soil near copper mining and smelting complex and waste-derived alkaline additives. in Geoderma, 352, 241-250. https://doi.org/10.1016/j.geoderma.2019.06.015
Egerić M, Smičiklas ID, Dojčinović BP, Sikirić B, Jović MD, Šljivić-Ivanović MZ, Čakmak D. Interactions of acidic soil near copper mining and smelting complex and waste-derived alkaline additives. in Geoderma. 2019;352:241-250. doi:10.1016/j.geoderma.2019.06.015 .
Egerić, Marija, Smičiklas, Ivana D., Dojčinović, Biljana P., Sikirić, Biljana, Jović, Mihajlo D., Šljivić-Ivanović, Marija Z., Čakmak, Dragan, "Interactions of acidic soil near copper mining and smelting complex and waste-derived alkaline additives" in Geoderma, 352 (2019):241-250, https://doi.org/10.1016/j.geoderma.2019.06.015 . .