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Influence of Alginate Encapsulation on Point of Zero Charge (pHpzc) and Thermodynamic Properties of the Natural and Fe(III) - Modified Zeolite

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2019
1-s2.0-S2351978919302513-main.pdf (1.029Mb)
Authors
Kragović, Milan M.
Stojmenović, Marija
Petrović, Jelena T.
Loredo, Jorge
Pašalić, Snežana
Nedeljković, Andrijana
Ristović, Ivica
Conference object (Published version)
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(C) 2019 The Authors. Published by Elsevier Ltd
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Abstract
In this paper influence of alginate encapsulation on point of zero charge (pH pzc ) and thermodynamic properties of the natural and Fe(III)- modified zeolite were investigated. The pH pzc was determined by using 0.1000 g of the samples and 50 cm 3 of the solution containing KNO 3 in concentrations of 0.0001-0.01 mol/dm 3 for initial pH (pH i ) in range between 2 and 12. The obtained pH pzc were 6.2 for natural (NZA) and 6.5 for modified zeolite encapsulated with alginate (FeA). Influence of the temperature on the adsorption of lead was investigated for different initial lead ions concentrations (180-3200 mgPb 2+ /dm 3 ) and temperatures of 30, 40 and 60 o C. For both adsorbents, adsorption of lead ions increased with increasing its initial concentration as well as with increasing of the temperature. Also, the best fits of the experimental data were obtained by Freundlich isotherm. The temperature had positive influence adsorption and removal of lead ions increased with increasing its i...nitial concentration as well as with increasing of the temperature. The thermodynamic parameters (the standard free energy of adsorption, standard enthalpy and standard entropy) were also determined. The results showed that lead ions removal from aqueous solutions is much favourable for FeA then NZA. © 2019 The Authors.

Keywords:
natural zeolite / Fe(III)-modified zeolite / encapsulation by alginate / point of zero charge / lead removal / thermodynamic
Source:
Procedia Manufacturing, 2019, 32, 286-293
Funding / projects:
  • Development of technological processes for obtaining of ecological materials based on nonmetallic minerals (RS-34013)
  • Oxide-based environmentally-friendly porous materials for genotoxic substances removal (RS-172018)
  • Improvement Of Lignite Opencast Mining Technology In Order To Increase Energy Efficiency And Occupational Safety (RS-33039)

DOI: 10.1016/j.promfg.2019.02.216

ISSN: 2351-9789

WoS: 000471295800041

Scopus: 2-s2.0-85065656635
[ Google Scholar ]
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URI
https://linkinghub.elsevier.com/retrieve/pii/S2351978919302513
https://vinar.vin.bg.ac.rs/handle/123456789/8198
Collections
  • Radovi istraživača
Institution/Community
Vinča
TY  - CONF
AU  - Kragović, Milan M.
AU  - Stojmenović, Marija
AU  - Petrović, Jelena T.
AU  - Loredo, Jorge
AU  - Pašalić, Snežana
AU  - Nedeljković, Andrijana
AU  - Ristović, Ivica
PY  - 2019
UR  - https://linkinghub.elsevier.com/retrieve/pii/S2351978919302513
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/8198
AB  - In this paper influence of alginate encapsulation on point of zero charge (pH pzc ) and thermodynamic properties of the natural and Fe(III)- modified zeolite were investigated. The pH pzc was determined by using 0.1000 g of the samples and 50 cm 3 of the solution containing KNO 3 in concentrations of 0.0001-0.01 mol/dm 3 for initial pH (pH i ) in range between 2 and 12. The obtained pH pzc were 6.2 for natural (NZA) and 6.5 for modified zeolite encapsulated with alginate (FeA). Influence of the temperature on the adsorption of lead was investigated for different initial lead ions concentrations (180-3200 mgPb 2+ /dm 3 ) and temperatures of 30, 40 and 60 o C. For both adsorbents, adsorption of lead ions increased with increasing its initial concentration as well as with increasing of the temperature. Also, the best fits of the experimental data were obtained by Freundlich isotherm. The temperature had positive influence adsorption and removal of lead ions increased with increasing its initial concentration as well as with increasing of the temperature. The thermodynamic parameters (the standard free energy of adsorption, standard enthalpy and standard entropy) were also determined. The results showed that lead ions removal from aqueous solutions is much favourable for FeA then NZA. © 2019 The Authors.
C3  - Procedia Manufacturing
T1  - Influence of Alginate Encapsulation on Point of Zero Charge (pHpzc) and Thermodynamic Properties of the Natural and Fe(III) - Modified Zeolite
VL  - 32
SP  - 286
EP  - 293
DO  - 10.1016/j.promfg.2019.02.216
ER  - 
@conference{
author = "Kragović, Milan M. and Stojmenović, Marija and Petrović, Jelena T. and Loredo, Jorge and Pašalić, Snežana and Nedeljković, Andrijana and Ristović, Ivica",
year = "2019",
abstract = "In this paper influence of alginate encapsulation on point of zero charge (pH pzc ) and thermodynamic properties of the natural and Fe(III)- modified zeolite were investigated. The pH pzc was determined by using 0.1000 g of the samples and 50 cm 3 of the solution containing KNO 3 in concentrations of 0.0001-0.01 mol/dm 3 for initial pH (pH i ) in range between 2 and 12. The obtained pH pzc were 6.2 for natural (NZA) and 6.5 for modified zeolite encapsulated with alginate (FeA). Influence of the temperature on the adsorption of lead was investigated for different initial lead ions concentrations (180-3200 mgPb 2+ /dm 3 ) and temperatures of 30, 40 and 60 o C. For both adsorbents, adsorption of lead ions increased with increasing its initial concentration as well as with increasing of the temperature. Also, the best fits of the experimental data were obtained by Freundlich isotherm. The temperature had positive influence adsorption and removal of lead ions increased with increasing its initial concentration as well as with increasing of the temperature. The thermodynamic parameters (the standard free energy of adsorption, standard enthalpy and standard entropy) were also determined. The results showed that lead ions removal from aqueous solutions is much favourable for FeA then NZA. © 2019 The Authors.",
journal = "Procedia Manufacturing",
title = "Influence of Alginate Encapsulation on Point of Zero Charge (pHpzc) and Thermodynamic Properties of the Natural and Fe(III) - Modified Zeolite",
volume = "32",
pages = "286-293",
doi = "10.1016/j.promfg.2019.02.216"
}
Kragović, M. M., Stojmenović, M., Petrović, J. T., Loredo, J., Pašalić, S., Nedeljković, A.,& Ristović, I.. (2019). Influence of Alginate Encapsulation on Point of Zero Charge (pHpzc) and Thermodynamic Properties of the Natural and Fe(III) - Modified Zeolite. in Procedia Manufacturing, 32, 286-293.
https://doi.org/10.1016/j.promfg.2019.02.216
Kragović MM, Stojmenović M, Petrović JT, Loredo J, Pašalić S, Nedeljković A, Ristović I. Influence of Alginate Encapsulation on Point of Zero Charge (pHpzc) and Thermodynamic Properties of the Natural and Fe(III) - Modified Zeolite. in Procedia Manufacturing. 2019;32:286-293.
doi:10.1016/j.promfg.2019.02.216 .
Kragović, Milan M., Stojmenović, Marija, Petrović, Jelena T., Loredo, Jorge, Pašalić, Snežana, Nedeljković, Andrijana, Ristović, Ivica, "Influence of Alginate Encapsulation on Point of Zero Charge (pHpzc) and Thermodynamic Properties of the Natural and Fe(III) - Modified Zeolite" in Procedia Manufacturing, 32 (2019):286-293,
https://doi.org/10.1016/j.promfg.2019.02.216 . .

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