Hydrogen evolution reaction on bimetallic Ir/Pt(poly) electrodes in alkaline solution

Štrbac, Svetlana; Smiljanić, Milutin Lj.; Wakelin, Thomas; Potočnik, Jelena; Rakočević, Zlatko Lj.

doi:10.1016/j.electacta.2019.03.100

Само за регистроване кориснике

2019

Аутори

Štrbac, Svetlana

Smiljanić, Milutin Lj.

Wakelin, Thomas
Potočnik, Jelena

Rakočević, Zlatko Lj.

Чланак у часопису (Објављена верзија)

Метаподаци

Приказ свих података о документу

Апстракт

Hydrogen evolution reaction (HER) was studied in alkaline solution on Pt(poly) electrode modified by spontaneously deposited Ir nanoislands. Comprehensive insight into the characteristics of the bimetallic Ir/Pt(poly) catalysts was obtained by a combination of Atomic Force Microscopy (AFM), Field Emission Scanning Electron Microscopy (FESEM), X-ray Photoelectron Spectroscopy (XPS) and classical electrochemical techniques. HER investigations have shown that the presence of spontaneously deposited Ir enhances the activity of bare Pt(poly) in alkaline solution. This was attributed to the heterogeneity of the active surface sites and to the electronic interaction between two metals in close contact which together facilitated the adsorption of the H intermediate species. © 2019 Elsevier Ltd

Кључне речи:

Platinum / Iridium / Hydrogen evolution / AFM / FESEM / XPS

Извор:
Electrochimica Acta, 2019, 306, 18-27

Финансирање / пројекти:

Функционални, функционализовани и усавршени нано материјали (RS-MESTD-Integrated and Interdisciplinary Research (IIR or III)-45005)

DOI: 10.1016/j.electacta.2019.03.100

ISSN: 0013-4686; 1873-3859

WoS: 000464148700003

Scopus: 2-s2.0-85063634442

[ Google Scholar ]


	24
	24

TY  - JOUR
AU  - Štrbac, Svetlana
AU  - Smiljanić, Milutin Lj.
AU  - Wakelin, Thomas
AU  - Potočnik, Jelena
AU  - Rakočević, Zlatko Lj.
PY  - 2019
UR  - https://linkinghub.elsevier.com/retrieve/pii/S001346861930516X
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/8126
AB  - Hydrogen evolution reaction (HER) was studied in alkaline solution on Pt(poly) electrode modified by spontaneously deposited Ir nanoislands. Comprehensive insight into the characteristics of the bimetallic Ir/Pt(poly) catalysts was obtained by a combination of Atomic Force Microscopy (AFM), Field Emission Scanning Electron Microscopy (FESEM), X-ray Photoelectron Spectroscopy (XPS) and classical electrochemical techniques. HER investigations have shown that the presence of spontaneously deposited Ir enhances the activity of bare Pt(poly) in alkaline solution. This was attributed to the heterogeneity of the active surface sites and to the electronic interaction between two metals in close contact which together facilitated the adsorption of the H intermediate species. © 2019 Elsevier Ltd
T2  - Electrochimica Acta
T1  - Hydrogen evolution reaction on bimetallic Ir/Pt(poly) electrodes in alkaline solution
VL  - 306
SP  - 18
EP  - 27
DO  - 10.1016/j.electacta.2019.03.100
ER  -

@article{
author = "Štrbac, Svetlana and Smiljanić, Milutin Lj. and Wakelin, Thomas and Potočnik, Jelena and Rakočević, Zlatko Lj.",
year = "2019",
abstract = "Hydrogen evolution reaction (HER) was studied in alkaline solution on Pt(poly) electrode modified by spontaneously deposited Ir nanoislands. Comprehensive insight into the characteristics of the bimetallic Ir/Pt(poly) catalysts was obtained by a combination of Atomic Force Microscopy (AFM), Field Emission Scanning Electron Microscopy (FESEM), X-ray Photoelectron Spectroscopy (XPS) and classical electrochemical techniques. HER investigations have shown that the presence of spontaneously deposited Ir enhances the activity of bare Pt(poly) in alkaline solution. This was attributed to the heterogeneity of the active surface sites and to the electronic interaction between two metals in close contact which together facilitated the adsorption of the H intermediate species. © 2019 Elsevier Ltd",
journal = "Electrochimica Acta",
title = "Hydrogen evolution reaction on bimetallic Ir/Pt(poly) electrodes in alkaline solution",
volume = "306",
pages = "18-27",
doi = "10.1016/j.electacta.2019.03.100"
}

Štrbac, S., Smiljanić, M. Lj., Wakelin, T., Potočnik, J.,& Rakočević, Z. Lj.. (2019). Hydrogen evolution reaction on bimetallic Ir/Pt(poly) electrodes in alkaline solution. in Electrochimica Acta, 306, 18-27.
https://doi.org/10.1016/j.electacta.2019.03.100

Štrbac S, Smiljanić ML, Wakelin T, Potočnik J, Rakočević ZL. Hydrogen evolution reaction on bimetallic Ir/Pt(poly) electrodes in alkaline solution. in Electrochimica Acta. 2019;306:18-27.
doi:10.1016/j.electacta.2019.03.100 .

Štrbac, Svetlana, Smiljanić, Milutin Lj., Wakelin, Thomas, Potočnik, Jelena, Rakočević, Zlatko Lj., "Hydrogen evolution reaction on bimetallic Ir/Pt(poly) electrodes in alkaline solution" in Electrochimica Acta, 306 (2019):18-27,
https://doi.org/10.1016/j.electacta.2019.03.100 . .