The influence of monomer/solvent feed ratio on POEGDMA thermoresponsive hydrogels: Radiation-induced synthesis, swelling properties and VPTT

Suljovrujić, Edin H.; Rogić Miladinović, Zorana; Mićić, Maja M.; Suljovrujić, Denis; Miličević, Dejan S.

doi:10.1016/j.radphyschem.2018.12.034

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2019

Authors

Suljovrujić, Edin H.

Rogić Miladinović, Zorana

Mićić, Maja M.
Suljovrujić, Denis
Miličević, Dejan S.

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Abstract

The oligo(ethylene glycol) dimethacrylate (OEGDMA), one of the most commonly utilized crosslinking monomers, was used to tailor thermoresponsive POEGDMA hydrogels by varying the monomer/solvent feed ratio (from 10 to 100 wt% of monomer). For the first time, synthesis of different POEGDMA homopolymeric networks was performed by gamma radiation, and due to the expected thermoresponsiveness their temperature-dependent properties were extensively analysed. The sol-gel study was performed as the first step after radiation-induced synthesis. The swelling properties were investigated over the wide pH (2.2–9.0) and temperature (5–80 °C) range. Characterization of structure and properties was additionally conducted by SEM, DSC, FTIR, and UV–Vis spectroscopy. The results indicated that all POEGDMA hydrogels showed a high gel content, inverse thermoresponse and volume phase transition temperature (VPTT) with no respect to initial preparation. On the other hand, by altering the monomer/solvent rat...

Keywords:

Hydrogel / Temperature responsive / Oligo(ethylene glycol) dimethacrylate / VPTT

Source:
Radiation Physics and Chemistry, 2019, 158, 37-45

Funding / projects:

Note:

This is the peer-reviewed version of the following article: Suljovrujic, Edin, Zorana Rogic Miladinovic, Maja Micic, Denis Suljovrujic, and Dejan Milicevic. "The influence of monomer/solvent feed ratio on POEGDMA thermoresponsive hydrogels: Radiation-induced synthesis, swelling properties and VPTT." Radiation Physics and Chemistry 158 (2019): 37-45. http://dx.doi.org/10.1016/j.radphyschem.2018.12.034
Published version available at: http://vinar.vin.bg.ac.rs/handle/123456789/8048

DOI: 10.1016/j.radphyschem.2018.12.034

ISSN: 0969-806X

WoS: 000465509100006

Scopus: 2-s2.0-85060920683

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TY - JOUR
AU - Suljovrujić, Edin H.
AU - Rogić Miladinović, Zorana
AU - Mićić, Maja M.
AU - Suljovrujić, Denis
AU - Miličević, Dejan S.
PY - 2019
UR - https://vinar.vin.bg.ac.rs/handle/123456789/8051
AB - The oligo(ethylene glycol) dimethacrylate (OEGDMA), one of the most commonly utilized crosslinking monomers, was used to tailor thermoresponsive POEGDMA hydrogels by varying the monomer/solvent feed ratio (from 10 to 100 wt% of monomer). For the first time, synthesis of different POEGDMA homopolymeric networks was performed by gamma radiation, and due to the expected thermoresponsiveness their temperature-dependent properties were extensively analysed. The sol-gel study was performed as the first step after radiation-induced synthesis. The swelling properties were investigated over the wide pH (2.2–9.0) and temperature (5–80 °C) range. Characterization of structure and properties was additionally conducted by SEM, DSC, FTIR, and UV–Vis spectroscopy. The results indicated that all POEGDMA hydrogels showed a high gel content, inverse thermoresponse and volume phase transition temperature (VPTT) with no respect to initial preparation. On the other hand, by altering the monomer/solvent ratio in the prepolymerisation mixture a large diversity in the microstructure, swelling capacity and VPTT was obtained. © 2019 Elsevier Ltd
T2 - Radiation Physics and Chemistry
T1 - The influence of monomer/solvent feed ratio on POEGDMA thermoresponsive hydrogels: Radiation-induced synthesis, swelling properties and VPTT
VL - 158
SP - 37
EP - 45
DO - 10.1016/j.radphyschem.2018.12.034
ER -

@article{
author = "Suljovrujić, Edin H. and Rogić Miladinović, Zorana and Mićić, Maja M. and Suljovrujić, Denis and Miličević, Dejan S.",
year = "2019",
abstract = "The oligo(ethylene glycol) dimethacrylate (OEGDMA), one of the most commonly utilized crosslinking monomers, was used to tailor thermoresponsive POEGDMA hydrogels by varying the monomer/solvent feed ratio (from 10 to 100 wt% of monomer). For the first time, synthesis of different POEGDMA homopolymeric networks was performed by gamma radiation, and due to the expected thermoresponsiveness their temperature-dependent properties were extensively analysed. The sol-gel study was performed as the first step after radiation-induced synthesis. The swelling properties were investigated over the wide pH (2.2–9.0) and temperature (5–80 °C) range. Characterization of structure and properties was additionally conducted by SEM, DSC, FTIR, and UV–Vis spectroscopy. The results indicated that all POEGDMA hydrogels showed a high gel content, inverse thermoresponse and volume phase transition temperature (VPTT) with no respect to initial preparation. On the other hand, by altering the monomer/solvent ratio in the prepolymerisation mixture a large diversity in the microstructure, swelling capacity and VPTT was obtained. © 2019 Elsevier Ltd",
journal = "Radiation Physics and Chemistry",
title = "The influence of monomer/solvent feed ratio on POEGDMA thermoresponsive hydrogels: Radiation-induced synthesis, swelling properties and VPTT",
volume = "158",
pages = "37-45",
doi = "10.1016/j.radphyschem.2018.12.034"
}

Suljovrujić, E. H., Rogić Miladinović, Z., Mićić, M. M., Suljovrujić, D.,& Miličević, D. S.. (2019). The influence of monomer/solvent feed ratio on POEGDMA thermoresponsive hydrogels: Radiation-induced synthesis, swelling properties and VPTT. in Radiation Physics and Chemistry, 158, 37-45.
https://doi.org/10.1016/j.radphyschem.2018.12.034

Suljovrujić EH, Rogić Miladinović Z, Mićić MM, Suljovrujić D, Miličević DS. The influence of monomer/solvent feed ratio on POEGDMA thermoresponsive hydrogels: Radiation-induced synthesis, swelling properties and VPTT. in Radiation Physics and Chemistry. 2019;158:37-45.
doi:10.1016/j.radphyschem.2018.12.034 .

Suljovrujić, Edin H., Rogić Miladinović, Zorana, Mićić, Maja M., Suljovrujić, Denis, Miličević, Dejan S., "The influence of monomer/solvent feed ratio on POEGDMA thermoresponsive hydrogels: Radiation-induced synthesis, swelling properties and VPTT" in Radiation Physics and Chemistry, 158 (2019):37-45,
https://doi.org/10.1016/j.radphyschem.2018.12.034 . .