A Voltammetric Sensor Based on MgFe2O4 Decorated on Reduced Graphene Oxide-modified Electrode for Sensitive and Simultaneous Determination of Catechol and Hydroquinone

Ognjanović, Miloš; Stanković, Dalibor M.; Fabian, Martin; Vukadinović, Aleksandar; Prijović, Željko; Dojčinović, Biljana P.; Antić, Bratislav

doi:10.1002/elan.201800357

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2018

Authors

Ognjanović, Miloš

Stanković, Dalibor M.

Fabian, Martin

Vukadinović, Aleksandar

Prijović, Željko
Dojčinović, Biljana P.

Antić, Bratislav

Article (Published version)

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Abstract

In this work facile one step synthesis of magnesium ferrite (MgFe2O4) nanoparticles decorated on reduced graphene oxide (MgFe@RGO) using a microwave assisted hydrothermal procedure is reported. The synthesized material was characterized with help of several techniques and applied for the modification of glassy carbon electrode. Such prepared electrode was utilized for successive simultaneous detection of structurally similar compounds, 1,2- and 1,4-dihydroxibenzenes (catechol (CC) and hydroquinone (HQ)), using differential pulse voltammetry technique. It was found that oxidation current increases linearly with the concentrations of both investigated compounds. Detection limits for both species are ≤0.31 μM. The best analytical response in the presence of both CC and HQ, taking into account peak shape and peak current, was obtained at pH 5.6 utilizing acetate buffer solution. The often-presented species in the surface waters as well as gallic acid and caffeine do not interfere with dete...

Keywords:

MgFe@RGO nanocomposite / Magnesium ferrite / Dihydroxibenzenes / Differential pulse voltammetry

Source:
Electroanalysis, 2018, 30, 11, 2620-2627

Funding / projects:

Ministry of Education, Science and Technological Development of the Republic of Serbia [E!9982]
Strengthening of the MagBioVin Research and Innovation Team for Development of Novel Approaches for Tumour Therapy based on Nanostructured Materials (EU-621375)

DOI: 10.1002/elan.201800357

ISSN: 1040-0397; 1521-4109

WoS: 000450148200013

Scopus: 2-s2.0-85052920134

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TY - JOUR
AU - Ognjanović, Miloš
AU - Stanković, Dalibor M.
AU - Fabian, Martin
AU - Vukadinović, Aleksandar
AU - Prijović, Željko
AU - Dojčinović, Biljana P.
AU - Antić, Bratislav
PY - 2018
UR - http://doi.wiley.com/10.1002/elan.201800357
UR - https://vinar.vin.bg.ac.rs/handle/123456789/7961
AB - In this work facile one step synthesis of magnesium ferrite (MgFe2O4) nanoparticles decorated on reduced graphene oxide (MgFe@RGO) using a microwave assisted hydrothermal procedure is reported. The synthesized material was characterized with help of several techniques and applied for the modification of glassy carbon electrode. Such prepared electrode was utilized for successive simultaneous detection of structurally similar compounds, 1,2- and 1,4-dihydroxibenzenes (catechol (CC) and hydroquinone (HQ)), using differential pulse voltammetry technique. It was found that oxidation current increases linearly with the concentrations of both investigated compounds. Detection limits for both species are ≤0.31 μM. The best analytical response in the presence of both CC and HQ, taking into account peak shape and peak current, was obtained at pH 5.6 utilizing acetate buffer solution. The often-presented species in the surface waters as well as gallic acid and caffeine do not interfere with determination of CC and HQ, while ascorbic acid shows high interference. The method is successfully applied for detection of catechol and hydroquinone in real samples analyses. © 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim
T2 - Electroanalysis
T1 - A Voltammetric Sensor Based on MgFe2O4 Decorated on Reduced Graphene Oxide-modified Electrode for Sensitive and Simultaneous Determination of Catechol and Hydroquinone
VL - 30
IS - 11
SP - 2620
EP - 2627
DO - 10.1002/elan.201800357
ER -

@article{
author = "Ognjanović, Miloš and Stanković, Dalibor M. and Fabian, Martin and Vukadinović, Aleksandar and Prijović, Željko and Dojčinović, Biljana P. and Antić, Bratislav",
year = "2018",
abstract = "In this work facile one step synthesis of magnesium ferrite (MgFe2O4) nanoparticles decorated on reduced graphene oxide (MgFe@RGO) using a microwave assisted hydrothermal procedure is reported. The synthesized material was characterized with help of several techniques and applied for the modification of glassy carbon electrode. Such prepared electrode was utilized for successive simultaneous detection of structurally similar compounds, 1,2- and 1,4-dihydroxibenzenes (catechol (CC) and hydroquinone (HQ)), using differential pulse voltammetry technique. It was found that oxidation current increases linearly with the concentrations of both investigated compounds. Detection limits for both species are ≤0.31 μM. The best analytical response in the presence of both CC and HQ, taking into account peak shape and peak current, was obtained at pH 5.6 utilizing acetate buffer solution. The often-presented species in the surface waters as well as gallic acid and caffeine do not interfere with determination of CC and HQ, while ascorbic acid shows high interference. The method is successfully applied for detection of catechol and hydroquinone in real samples analyses. © 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim",
journal = "Electroanalysis",
title = "A Voltammetric Sensor Based on MgFe2O4 Decorated on Reduced Graphene Oxide-modified Electrode for Sensitive and Simultaneous Determination of Catechol and Hydroquinone",
volume = "30",
number = "11",
pages = "2620-2627",
doi = "10.1002/elan.201800357"
}

Ognjanović, M., Stanković, D. M., Fabian, M., Vukadinović, A., Prijović, Ž., Dojčinović, B. P.,& Antić, B.. (2018). A Voltammetric Sensor Based on MgFe2O4 Decorated on Reduced Graphene Oxide-modified Electrode for Sensitive and Simultaneous Determination of Catechol and Hydroquinone. in Electroanalysis, 30(11), 2620-2627.
https://doi.org/10.1002/elan.201800357

Ognjanović M, Stanković DM, Fabian M, Vukadinović A, Prijović Ž, Dojčinović BP, Antić B. A Voltammetric Sensor Based on MgFe2O4 Decorated on Reduced Graphene Oxide-modified Electrode for Sensitive and Simultaneous Determination of Catechol and Hydroquinone. in Electroanalysis. 2018;30(11):2620-2627.
doi:10.1002/elan.201800357 .

Ognjanović, Miloš, Stanković, Dalibor M., Fabian, Martin, Vukadinović, Aleksandar, Prijović, Željko, Dojčinović, Biljana P., Antić, Bratislav, "A Voltammetric Sensor Based on MgFe2O4 Decorated on Reduced Graphene Oxide-modified Electrode for Sensitive and Simultaneous Determination of Catechol and Hydroquinone" in Electroanalysis, 30, no. 11 (2018):2620-2627,
https://doi.org/10.1002/elan.201800357 . .