Tuning the thermoresponsive properties of poly(oligo(propylene glycol) methacrylate) hydrogels via gradient copolymerization with 2-hydroxyethyl methacrylate
Апстракт
Gamma radiation was used to prepare copolymer hydrogel libraries based on oligo(propylene glycol) methacrylate (OPGMA) and 2-hydroxyethyl methacrylate (HEMA); a complete screening in composition of P(OPGMA/HEMA) copolymers was elaborated from 0% to 100% of OPGMA. Determination of gel fraction was performed as the first step after radiation induced synthesis. Tuning of the volume phase transition temperature (VPTT) of P(OPGMA/HEMA) copolymeric hydrogels was investigated by swelling study. Additional characterization of structure and properties was conducted by FTIR, DSC, and UV-Vis spectroscopy. All results indicate that new P(OPGMA/HEMA) copolymeric hydrogels have wide diversity in thermoresponsive properties which strongly depend on their composition. [GRAPHICS] .
Кључне речи:
Radiation synthesis / P(OPGMA/HEMA) / LCST / VPTT / thermoresponsive hydrogelИзвор:
International Journal of Polymeric Materials and Polymeric Biomaterials, 2016, 65, 1, 18-27Финансирање / пројекти:
- Хемијско и структурно дизајнирање наноматеријала за примену у медицини и инжењерству ткива (RS-MESTD-Basic Research (BR or ON)-172026)
- Функционални, функционализовани и усавршени нано материјали (RS-MESTD-Integrated and Interdisciplinary Research (IIR or III)-45005)
DOI: 10.1080/00914037.2015.1055627
ISSN: 0091-4037; 1563-535X
WoS: 000362723600003
Scopus: 2-s2.0-84944145330
Колекције
Институција/група
VinčaTY - JOUR AU - Mićić, Maja M. AU - Rogić Miladinović, Zorana AU - Suljovrujić, Edin H. PY - 2016 UR - https://vinar.vin.bg.ac.rs/handle/123456789/765 AB - Gamma radiation was used to prepare copolymer hydrogel libraries based on oligo(propylene glycol) methacrylate (OPGMA) and 2-hydroxyethyl methacrylate (HEMA); a complete screening in composition of P(OPGMA/HEMA) copolymers was elaborated from 0% to 100% of OPGMA. Determination of gel fraction was performed as the first step after radiation induced synthesis. Tuning of the volume phase transition temperature (VPTT) of P(OPGMA/HEMA) copolymeric hydrogels was investigated by swelling study. Additional characterization of structure and properties was conducted by FTIR, DSC, and UV-Vis spectroscopy. All results indicate that new P(OPGMA/HEMA) copolymeric hydrogels have wide diversity in thermoresponsive properties which strongly depend on their composition. [GRAPHICS] . T2 - International Journal of Polymeric Materials and Polymeric Biomaterials T1 - Tuning the thermoresponsive properties of poly(oligo(propylene glycol) methacrylate) hydrogels via gradient copolymerization with 2-hydroxyethyl methacrylate VL - 65 IS - 1 SP - 18 EP - 27 DO - 10.1080/00914037.2015.1055627 ER -
@article{ author = "Mićić, Maja M. and Rogić Miladinović, Zorana and Suljovrujić, Edin H.", year = "2016", abstract = "Gamma radiation was used to prepare copolymer hydrogel libraries based on oligo(propylene glycol) methacrylate (OPGMA) and 2-hydroxyethyl methacrylate (HEMA); a complete screening in composition of P(OPGMA/HEMA) copolymers was elaborated from 0% to 100% of OPGMA. Determination of gel fraction was performed as the first step after radiation induced synthesis. Tuning of the volume phase transition temperature (VPTT) of P(OPGMA/HEMA) copolymeric hydrogels was investigated by swelling study. Additional characterization of structure and properties was conducted by FTIR, DSC, and UV-Vis spectroscopy. All results indicate that new P(OPGMA/HEMA) copolymeric hydrogels have wide diversity in thermoresponsive properties which strongly depend on their composition. [GRAPHICS] .", journal = "International Journal of Polymeric Materials and Polymeric Biomaterials", title = "Tuning the thermoresponsive properties of poly(oligo(propylene glycol) methacrylate) hydrogels via gradient copolymerization with 2-hydroxyethyl methacrylate", volume = "65", number = "1", pages = "18-27", doi = "10.1080/00914037.2015.1055627" }
Mićić, M. M., Rogić Miladinović, Z.,& Suljovrujić, E. H.. (2016). Tuning the thermoresponsive properties of poly(oligo(propylene glycol) methacrylate) hydrogels via gradient copolymerization with 2-hydroxyethyl methacrylate. in International Journal of Polymeric Materials and Polymeric Biomaterials, 65(1), 18-27. https://doi.org/10.1080/00914037.2015.1055627
Mićić MM, Rogić Miladinović Z, Suljovrujić EH. Tuning the thermoresponsive properties of poly(oligo(propylene glycol) methacrylate) hydrogels via gradient copolymerization with 2-hydroxyethyl methacrylate. in International Journal of Polymeric Materials and Polymeric Biomaterials. 2016;65(1):18-27. doi:10.1080/00914037.2015.1055627 .
Mićić, Maja M., Rogić Miladinović, Zorana, Suljovrujić, Edin H., "Tuning the thermoresponsive properties of poly(oligo(propylene glycol) methacrylate) hydrogels via gradient copolymerization with 2-hydroxyethyl methacrylate" in International Journal of Polymeric Materials and Polymeric Biomaterials, 65, no. 1 (2016):18-27, https://doi.org/10.1080/00914037.2015.1055627 . .