Synthesis and structural properties of sodium cobalt oxide
Authors
Aleksić, JelenaJugović, Dragana

Milović, Miloš

Mitrić, Miodrag

Uskoković, Dragan

Contributors
Marković, Smilja
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Sodium transition-metal oxides with general formula NaxTMO2 (TM = Co, Mn, Ni, etc.) have attracted a lot of interest in the battery community due to low cost of sodium in contrast to lithium. Sodium cobalt oxide is the most attractive of them for cathode application because of its conductive, thermic and magnetic characteristics. In this study, sodium cobalt oxide, NaxCoO2 , was synthesized by simple method which involves solid state reaction in air, at temperature of 900 ºC; starting materials were Na2CO3 and Co3O4 in stoichiometric amounts. Additionally, fluorination of the synthesized sodium cobalt oxide was carried out in vacuum at 200ºC; NH4HF2 was used as a fluorine source. Then, structural and microstructural properties of the obtained powders were examined.
Keywords:
sodium cobalt oxide / transition-metal oxidesSource:
Program and the Book of Abstracts / Sixteenth Young Researchers' Conference Materials Sciences and Engineering, December 6-8, 2017, Belgrade, Serbia, 2017, 37-37Publisher:
- Belgrade : Institute of Technical Sciences of SASA
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VinčaTY - CONF AU - Aleksić, Jelena AU - Jugović, Dragana AU - Milović, Miloš AU - Mitrić, Miodrag AU - Uskoković, Dragan PY - 2017 UR - https://vinar.vin.bg.ac.rs/handle/123456789/7564 AB - Sodium transition-metal oxides with general formula NaxTMO2 (TM = Co, Mn, Ni, etc.) have attracted a lot of interest in the battery community due to low cost of sodium in contrast to lithium. Sodium cobalt oxide is the most attractive of them for cathode application because of its conductive, thermic and magnetic characteristics. In this study, sodium cobalt oxide, NaxCoO2 , was synthesized by simple method which involves solid state reaction in air, at temperature of 900 ºC; starting materials were Na2CO3 and Co3O4 in stoichiometric amounts. Additionally, fluorination of the synthesized sodium cobalt oxide was carried out in vacuum at 200ºC; NH4HF2 was used as a fluorine source. Then, structural and microstructural properties of the obtained powders were examined. PB - Belgrade : Institute of Technical Sciences of SASA C3 - Program and the Book of Abstracts / Sixteenth Young Researchers' Conference Materials Sciences and Engineering, December 6-8, 2017, Belgrade, Serbia T1 - Synthesis and structural properties of sodium cobalt oxide SP - 37 EP - 37 UR - https://hdl.handle.net/21.15107/rcub_vinar_7564 ER -
@conference{ editor = "Marković, Smilja", author = "Aleksić, Jelena and Jugović, Dragana and Milović, Miloš and Mitrić, Miodrag and Uskoković, Dragan", year = "2017", abstract = "Sodium transition-metal oxides with general formula NaxTMO2 (TM = Co, Mn, Ni, etc.) have attracted a lot of interest in the battery community due to low cost of sodium in contrast to lithium. Sodium cobalt oxide is the most attractive of them for cathode application because of its conductive, thermic and magnetic characteristics. In this study, sodium cobalt oxide, NaxCoO2 , was synthesized by simple method which involves solid state reaction in air, at temperature of 900 ºC; starting materials were Na2CO3 and Co3O4 in stoichiometric amounts. Additionally, fluorination of the synthesized sodium cobalt oxide was carried out in vacuum at 200ºC; NH4HF2 was used as a fluorine source. Then, structural and microstructural properties of the obtained powders were examined.", publisher = "Belgrade : Institute of Technical Sciences of SASA", journal = "Program and the Book of Abstracts / Sixteenth Young Researchers' Conference Materials Sciences and Engineering, December 6-8, 2017, Belgrade, Serbia", title = "Synthesis and structural properties of sodium cobalt oxide", pages = "37-37", url = "https://hdl.handle.net/21.15107/rcub_vinar_7564" }
Marković, S., Aleksić, J., Jugović, D., Milović, M., Mitrić, M.,& Uskoković, D.. (2017). Synthesis and structural properties of sodium cobalt oxide. in Program and the Book of Abstracts / Sixteenth Young Researchers' Conference Materials Sciences and Engineering, December 6-8, 2017, Belgrade, Serbia Belgrade : Institute of Technical Sciences of SASA., 37-37. https://hdl.handle.net/21.15107/rcub_vinar_7564
Marković S, Aleksić J, Jugović D, Milović M, Mitrić M, Uskoković D. Synthesis and structural properties of sodium cobalt oxide. in Program and the Book of Abstracts / Sixteenth Young Researchers' Conference Materials Sciences and Engineering, December 6-8, 2017, Belgrade, Serbia. 2017;:37-37. https://hdl.handle.net/21.15107/rcub_vinar_7564 .
Marković, Smilja, Aleksić, Jelena, Jugović, Dragana, Milović, Miloš, Mitrić, Miodrag, Uskoković, Dragan, "Synthesis and structural properties of sodium cobalt oxide" in Program and the Book of Abstracts / Sixteenth Young Researchers' Conference Materials Sciences and Engineering, December 6-8, 2017, Belgrade, Serbia (2017):37-37, https://hdl.handle.net/21.15107/rcub_vinar_7564 .