Efficient arsenic removal by cross-linked macroporous polymer impregnated with hydrous iron oxide: Material performance
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Taleb, KhaledMarkovski, Jasmina S.
Milosavljevic, Milutin
Marinović-Cincović, Milena
Rusmirović, Jelena D.
Ristić, Mirjana
Marinković, Aleksandar D.
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Optimization of the synthesis of cross-linked macroporous polymer impregnated with hydrous iron oxide and post-process of obtained material by application of freeze/drying technique, produces high performance adsorbent applicable for efficient arsenic removal. Characterization and analysis of adsorbent performances encompass material characterization, equilibrium and kinetic study, influences of interfering ions and modeling of adsorption data in ion free and competitive conditions. Kinetic study, i.e. fitting by Weber-Morris model and single resistance mass transfer model predicts intra-particle diffusion as a rate-controlling step. Thermodynamic parameters indicate endothermic, feasible and spontaneous nature of adsorption process. Competitive kinetic study in the presence of interfering ions shows low detrimental effect on both capacity and kinetic of arsenic removal. Visual MINTEQ modeling software was used for the prediction of adsorbent performances and interfering ion influences.... Preliminary fixed-bed column study was accomplished by the use of Bohart-Adams, Yoon-Nelson, Thomas and Modified dose-response model. High arsenic removal capacity of 31.0 mg g(-1), at 25 degrees C, and multi-cycle reusability of ER/DETA/FO/FD, significantly affects the affordability of techno-economic indicators based on the operating costs of the process. (C) 2015 Elsevier B.V. All rights reserved.
Keywords:
Arsenic / Hydrous iron oxide / Ion-exchanger / Macroporous polymerSource:
Chemical Engineering Journal, 2015, 279, 66-78Funding / projects:
- Synthesis, processing and applications of nanostructured multifunctional materials with defined properties (RS-MESTD-Integrated and Interdisciplinary Research (IIR or III)-45019)
- Development and Application of Methods and Materials for Monitoring New Organic Contaminants, Toxic Compounds and Heavy Metals (RS-MESTD-Basic Research (BR or ON)-172007)
DOI: 10.1016/j.cej.2015.04.147
ISSN: 1385-8947; 1873-3212
WoS: 000359873500008
Scopus: 2-s2.0-84929353194
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VinčaTY - JOUR AU - Taleb, Khaled AU - Markovski, Jasmina S. AU - Milosavljevic, Milutin AU - Marinović-Cincović, Milena AU - Rusmirović, Jelena D. AU - Ristić, Mirjana AU - Marinković, Aleksandar D. PY - 2015 UR - https://vinar.vin.bg.ac.rs/handle/123456789/704 AB - Optimization of the synthesis of cross-linked macroporous polymer impregnated with hydrous iron oxide and post-process of obtained material by application of freeze/drying technique, produces high performance adsorbent applicable for efficient arsenic removal. Characterization and analysis of adsorbent performances encompass material characterization, equilibrium and kinetic study, influences of interfering ions and modeling of adsorption data in ion free and competitive conditions. Kinetic study, i.e. fitting by Weber-Morris model and single resistance mass transfer model predicts intra-particle diffusion as a rate-controlling step. Thermodynamic parameters indicate endothermic, feasible and spontaneous nature of adsorption process. Competitive kinetic study in the presence of interfering ions shows low detrimental effect on both capacity and kinetic of arsenic removal. Visual MINTEQ modeling software was used for the prediction of adsorbent performances and interfering ion influences. Preliminary fixed-bed column study was accomplished by the use of Bohart-Adams, Yoon-Nelson, Thomas and Modified dose-response model. High arsenic removal capacity of 31.0 mg g(-1), at 25 degrees C, and multi-cycle reusability of ER/DETA/FO/FD, significantly affects the affordability of techno-economic indicators based on the operating costs of the process. (C) 2015 Elsevier B.V. All rights reserved. T2 - Chemical Engineering Journal T1 - Efficient arsenic removal by cross-linked macroporous polymer impregnated with hydrous iron oxide: Material performance VL - 279 SP - 66 EP - 78 DO - 10.1016/j.cej.2015.04.147 ER -
@article{ author = "Taleb, Khaled and Markovski, Jasmina S. and Milosavljevic, Milutin and Marinović-Cincović, Milena and Rusmirović, Jelena D. and Ristić, Mirjana and Marinković, Aleksandar D.", year = "2015", abstract = "Optimization of the synthesis of cross-linked macroporous polymer impregnated with hydrous iron oxide and post-process of obtained material by application of freeze/drying technique, produces high performance adsorbent applicable for efficient arsenic removal. Characterization and analysis of adsorbent performances encompass material characterization, equilibrium and kinetic study, influences of interfering ions and modeling of adsorption data in ion free and competitive conditions. Kinetic study, i.e. fitting by Weber-Morris model and single resistance mass transfer model predicts intra-particle diffusion as a rate-controlling step. Thermodynamic parameters indicate endothermic, feasible and spontaneous nature of adsorption process. Competitive kinetic study in the presence of interfering ions shows low detrimental effect on both capacity and kinetic of arsenic removal. Visual MINTEQ modeling software was used for the prediction of adsorbent performances and interfering ion influences. Preliminary fixed-bed column study was accomplished by the use of Bohart-Adams, Yoon-Nelson, Thomas and Modified dose-response model. High arsenic removal capacity of 31.0 mg g(-1), at 25 degrees C, and multi-cycle reusability of ER/DETA/FO/FD, significantly affects the affordability of techno-economic indicators based on the operating costs of the process. (C) 2015 Elsevier B.V. All rights reserved.", journal = "Chemical Engineering Journal", title = "Efficient arsenic removal by cross-linked macroporous polymer impregnated with hydrous iron oxide: Material performance", volume = "279", pages = "66-78", doi = "10.1016/j.cej.2015.04.147" }
Taleb, K., Markovski, J. S., Milosavljevic, M., Marinović-Cincović, M., Rusmirović, J. D., Ristić, M.,& Marinković, A. D.. (2015). Efficient arsenic removal by cross-linked macroporous polymer impregnated with hydrous iron oxide: Material performance. in Chemical Engineering Journal, 279, 66-78. https://doi.org/10.1016/j.cej.2015.04.147
Taleb K, Markovski JS, Milosavljevic M, Marinović-Cincović M, Rusmirović JD, Ristić M, Marinković AD. Efficient arsenic removal by cross-linked macroporous polymer impregnated with hydrous iron oxide: Material performance. in Chemical Engineering Journal. 2015;279:66-78. doi:10.1016/j.cej.2015.04.147 .
Taleb, Khaled, Markovski, Jasmina S., Milosavljevic, Milutin, Marinović-Cincović, Milena, Rusmirović, Jelena D., Ristić, Mirjana, Marinković, Aleksandar D., "Efficient arsenic removal by cross-linked macroporous polymer impregnated with hydrous iron oxide: Material performance" in Chemical Engineering Journal, 279 (2015):66-78, https://doi.org/10.1016/j.cej.2015.04.147 . .